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Competition of Composition Fluctuation Modes in Weakly Segregated Salt-doped Symmetric Diblock Copolymers

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Chinese Journal of Polymer Science 2024年第9期42卷 1375-1385,I0008页

作者： yuan-Xin zhou Xian Kong South China Advanced Institute for Soft Matter Science and Technology School of Emergent Soft MatterSouth China University of TechnologyGuangzhou510640China Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices South China University of TechnologyGuangzhou510640China

Salt-doped block copolymers have widespread applications in batteries,fuel cells,semiconductors,and various industries,where their properties crucially depend on phase separation ***,investigations into salt-doped diblock copolymers have predominantly focused on microphase separation,overlooking the segregation between ionic and polymeric *** study employs weak segregation theory to explore the interplay between phase separation dominated by the polymer-modulated mode and the salt-out-modulated mode,corresponding to microscopic and macroscopic phase separations,*** comparing diblock copolymers doped with salts to those doped with neutral solvents,we elucidate the significant role of charged species in modulating phase *** phase separation mode exhibits a transition between the polymer-modulated and salt-out-modulated modes at different *** systems doped with neutral solvents,this transition is stepwise,while in salt-ion-doped systems,it is *** a sufficiently large Flory-Huggins parameter between ions and polymers,the salt-out-modulated mode becomes dominant,promoting macrophase *** to the solvation effect of salt ions,salt-doped systems are more inclined to undergo microphase ***,we explore factors influencing the critical wavenumber of phase separation,including doping level and the Flory-Huggins parameters between two blocks and between ions and polymeric *** findings reveal that in a neutral solvent environment,these factors alter only the boundary between micro-and macro-phase separations,leaving the critical wavenumber unchanged in microphase separation ***,in a salt-doped environment,the critical wavenumber of microphase separation varies with these *** provides valuable insights into the pivotal role of electrostatics in the phase separation of salt-doped block copolymers.

关键词： Block copolymer Phase separation Field theory Salt-doped

Comparative Analysis of Human Genes Frequently and Occasionally Regulated by m^6A Modification

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Genomics, Proteomics & Bioinformatics 2018年第2期16卷 127-135页

作者： yuan zhou Qinghua Cui Department of Biomedical Informatics School of Basic Medical Sciences Peking University

The m^6A modification has been implicated as an important epitranscriptomic marker, which plays extensive roles in the regulation of transcript stability, splicing, translation, and localization. Nevertheless, only some genes are repeatedly modified across various conditions and the principle of m^6A regulation remains elusive. In this study, we performed a systems-level analysis of human genes frequently regulated by m^6A modification （m^6Afreq genes） and those occasionally regulated by m^6A modification （m^6Aocca genes）. Compared to the m^6Aocca genes, the m^6Afreq genes exhibit gene importance-related features, such as lower dN/dS ratio, higher protein-protein interaction network degree, and reduced tissue expression specificity. Signaling network analysis indicates that the m^6Afreq genes are associated with downstream components of signaling cascades, high-linked signaling adaptors, and specific network motifs like incoherent feed forward loops. Moreover, functional enrichment analysis indicates significant overlaps between the m^6Afreq genes and genes involved in various layers of gene expression, such as being the microRNA targets and the regulators of RNA processing. Therefore, our findings suggest the potential interplay between m^6A epitranscriptomic regulation and other gene expression regulatory machineries.

关键词： m^6A Epitranscriptome Signaling network Gene expression regulation Gene importance

Boundedness of Marcinkiewicz integrals and their commutators in H^1(R^n×R^m)

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Science China Mathematics 2006年第6期49卷 770-790页

作者： YANG Dachun zhou yuan School of Mathematical Sciences Beijing Normal University Beijing 100875 China School of Mathematical Sciences Beijing Normal University Beijing 100875 China

The authors establish the boundedness of Marcinkiewicz integrals from the Hardy space H1(Rn × Rm) to the Lebesgue space L1(Rn × Rm) and their commutators with Lipschitz functions from the Hardy space H1(Rn × Rm) to... 详细信息

关键词： Marcinkiewicz integral, commutator, Lipschitz function, atom, Hardy space,Lebesgue space, boundedness.

A New Hybrid Model Rotor Flux Observer and Its Application

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Journal of China University of Mining and Technology 2006年第1期16卷 71-76页

作者： zhou yuan-shen Department of Electronic Engineering Huaihai Institute of Technology Lianyungang Jiangsu 222005 China

A new hybrid model rotor flux observer, based on a new voltage model, is presented. In the first place, the voltage model of an induction machine was constructed by using the modeling method discussed in this paper and then the current model using a flux feedback was adopted in this flux observer. Secondly, the two models were com- bined via a filter and then the rotor flux observer was established. In the M-T synchronous coordinate, the observer was analyzed theoretically and several important functions were derived. A comparison between the observer and the traditional models was made using Matlab software. The simulation results show that the observer model had a better performance than the traditional model.

关键词： new hybrid model rotor flux observer induction machine: cycloconverter

Hydrolysis Process of the Anticancer Agents Novel Non-classical trans-Platinum(Ⅱ) with Aliphatic Amines

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Chinese Journal of Structural Chemistry 2007年第8期26卷 962-972页

作者： yuan Qing-Hui zhou Li-Xin Department of Chemistry Jinan University Guangzhou Guangdong 510632 China

The hydrolysis process of the anticancer agents novel non-classical transplatinum（ Ⅱ ） with aliphatic amines and the influence of solvent models therein have been studied by using hybrid density functional theory （B3LYP）. In this study, the stepwise hydrolysis, trans[PtCl2（Am）（isopropylamine）] ＋ 2H2O → trans-[Pt（Am）（isopropylamine）（OH2）2]^2＋＋ 2Cl^-, was explored. Implicit solvent effects were incorporated through polarized continuum models. The stationary points on the potential energy surfaces for the first and second hydrolysis steps,proceeding via a general SN2 pathway, were fully optimized and characterized. It was found that the first hydrolysis reaction is easier than the second one and the hydrolysis of trans- [PtCl2-（isopropylamine）2] is the easiest in our studying systems. The result can assist in under- tanding the hydrolysis mechanism of trans-[PtCl2（Am）（isopropylamine）] and designing novel Pt-based anticancer drugs.

关键词： hydrolysis DFT non-classical trans-platinum aliphatic amines transition state

Shear strength degradation of gas hydrate-bearing sediment due to partial hydrate dissociation

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第7期16卷 2749-2763页

作者： yuan zhou Jiazuo zhou Pan Chen Changfu Wei State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China University of Chinese Academy of Sciences Beijing100049China China University of Geosciences Wuhan430074China

Extraction of methane hydrate from subseafloor reservoir may potentially trigger seabed slides and induce *** address the problems,it is crucial to properly characterize the phase equilibrium condition of pore hydrate and the shear strength of the *** one of the key constitutive components,the phase equilibrium condition enforces a constraint over pore gas pressure,temperature and unhydrated water *** a constraint,however,has been traditionally ignored in analyzing the mechanical behavior of hydrate-bearing *** this paper,a series of stepwise hydrate dissociation tests was performed,and the phase equilibrium condition of pore hydrate was determined,providing an effective way to evaluate the unhydrated water content during hydrate ***,a series of direct shear tests was also conducted to explore the shear strength characteristics of the *** is shown that the shear strength of the hydrate-bearing soil can be significantly influenced by pore gas pressure,unhydrated water content,hydrate saturation and several other *** particular,the measured shear strength depends upon the initial water content of the sample,pointing to a potential problem that the shear strength could be wrongly determined if not properly interpreted.A shear strength criterion,which enforces the equilibrium condition of pore hydrate,is developed for hydrate-bearing soil,establishing a link between the equilibrium condition and the shear *** proposed equation describes well the shear strength characteristics of hydrate-bearing soils,remarkably unifying the effects of pore pressure,temperature,water content and hydrate saturation.

关键词： Hydrate-bearing soil Phase equilibrium condition Shear strength Unhydrated water content Mechanical behavior

A Note on Economic Equilibrium and Financial Networks

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Acta Mathematicae Applicatae Sinica 2014年第1期30卷 89-98页

作者： Li-ping ZHANG yuan zhou Department of Mathematical Sciences Tsinghua University

Nagurney （1999） used variational inequalities to study economic equilibrium and financial networks and applied the modified projection method to solve the problem. In this paper, we formulate the problem as a nonlinear complementarity problem. The complementarity model is just the KKT condition for the model of Nagurney （1999）. It is a simpler model than that of Nagurney （1999）. We also establish sufficient conditions for existence and uniqueness of the equilibrium pattern, which are weaker than those in Nagurney （]999）. Finally, we apply a smoothing Newton-type algorithm to solve the problem and report some numerical results.

关键词： economic equilibrium financial networks nonlinear complementarity problem smoothing Newton method

Performance Assessment and Improvement of Photovoltaic-Thermal System based on Energy, Exergy, Economic and Environment Analysis

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Journal of Thermal Science 2024年第6期33卷 2166-2178页

作者： zhou yuan WANG Jiangjiang QIN Yanbo LIU Boxiang Hebei Key Laboratory of Low Carbon and High Efficiency Power Generation Technology North China Electric Power UniversityBaoding 071003Chin

A photovoltaic thermal(PV/T)system with parallel cooling channels was designed in this work to decrease the PV panel temperature and improve its photoelectric conversion efficiency.A 4E analysis method(includes energy,exergy,economic,and environmental aspects)was formulated to comprehensively evaluate the performances of the PV/T system,combining experimental and simulation ***,the experiment was performed using water as the cooling *** show that the PV/T system can reduce daily CO_(2) emissions by 1682.47-1705.98 g,and compared to the PV system,the added cooling module can increase electrical efficiency and environmental performance by 12.19%and 6.2%,*** the mass flow of water rose from 0.017 kg/s to 0.023 kg/s,the electrical,thermal,and overall efficiencies were improved by 3.82%,11.36%,and 8.27%,***,a numerical simulation model was constructed based on the experimental results to predict operations of the presented PV/T system using nanofluids as the cooling medium,including Ag,Al_(2)O_(3),and SiO_(2).Simulation results show that the Al_(2)O_(3)-nanofluid-based PV/T system has a higher application value,enabling an electrical efficiency of up to 15.13%.Its thermal efficiency can be enhanced by 5.43%when the volume fraction of Al_(2)O_(3);increases from 1%to 5%.

关键词： photovoltaic/thermal system parallel cooling channels 4E analysis method nanofluid numer analysis

The third type DC flow in pulse tube cryocooler

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Science China(Technological Sciences) 2009年第12期52卷 3491-3496页

作者： zhou yuan GU Chao CAI HuiKun Key Laboratory of Cryogenics Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China Graduate University of Chinese Academy of Sciences Beijing 100049China

New phenomena discovered in the experimental research of the ultra-high frequency pulse tube cryocooler were *** cause of the new phenomena was analyzed and the third type DC flow was discovered in the pulse tube *** third type DC flow not only deteriorated cooling capacity but also led to temperature instability of the pulse tube *** the fluid network theory and the simple regenerator model,the root of the third type DC flow was concisely investigated in theory. The asymmetric resistance of oscillating flow in pulse tube cryocooler was the key mechanism of the third type DC *** suppression methods were briefly discussed.

关键词： pulse tube cryocooler DC flow fluid network theory flow resistance