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Structural Design and Application of Azo-based Supramolecular Polymer Systems

Chinese Journal of Polymer Science 2019年第12期37卷 1183-1199,I0004页

作者： Hui-Tao yua Jun-Wen Tang Yi-Yu feng Wei feng School of Materials Science and Engineering Tianjin UniversityTianjin 300072China Key Laboratory of Advanced Ceramics and Machining Technology Ministry of EducationTianjin 300072China Tianjin Key Laboratory of Composite and Functional Materials Tianjin 300072China Collaborative Innovation Center of Chemical Science and Engineering Tianjin 300072China

This article presents a brief overview of recent advances in azo-containing supramolecular *** literature,it has been shown that azo supramolecular polymers and their composite materials exhibit fast and intelligent responses to various external stimuli,such as temperature,pH change,redox reagents,ligands,coupling reagents,*** applications,these systems are widely used for molecular motors,shape memory,liquid crystal,solar thermal energy storage,signal transmission,intelligent encryption,and other ***,these systems can function as key components for device upgrade ***,the design and rules of azo supramolecular polymers are still not supported by an exact *** about the relationship between the spatial structure and behavior is lacking,and new supramolecular materials cannot be designed by adding functional moieties to known azo *** on the current research status,this review mainly summarizes the structural design principles as well as structures and applications of known azo supramolecules;meanwhile,it highlights the emerging development fields,recent advances,and prospects in fabricating sei住assembling intelligent supramolecular systems with azo supramolecular polymers as responsive *** goal of this review is to bring new inspiration to researchers who want to optimize the chemical structure,steric conformation,electrostatic environment,and specific molecular functionalization.

关键词： Azo Supramolecular Structures Application Prospect

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驱控一体的旋拧式果实采摘执行器设计与试验

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农机化研究 2025年第3期47卷 48-55页

作者：严童杰冯青春郭鑫杨宁江苏大学电气信息工程学院江苏镇江212000 北京市农林科学院智能装备技术研究中心北京100097 国家农业智能装备工程技术研究中心北京100097 农业智能装备技术北京市重点实验室北京100097

针对果园智能化采收作业需要,设计了支持总线扩展的驱控一体旋拧采摘末端执行器,旨在为多臂并行采摘机器人研发提供支撑。在对标准苹果树果实物理形态统计分析基础上,结合人工采摘方法,提出了“吸附-夹持-旋拧”的采摘机械操作方法,并... 详细信息

针对果园智能化采收作业需要,设计了支持总线扩展的驱控一体旋拧采摘末端执行器,旨在为多臂并行采摘机器人研发提供支撑。在对标准苹果树果实物理形态统计分析基础上,结合人工采摘方法,提出了“吸附-夹持-旋拧”的采摘机械操作方法,并设计了基于双舵机驱动的紧凑型采摘执行机构,对其吸盘、夹持和旋拧电机的关键参数进行了优化设计。面向多执行并行采摘需要,设计了基于CANopen通讯的采摘操作驱动器,实现了多执行器的总线扩展。通过现场试验对执行器作业性能进行了测试,结果表明:果实大小在60~100 mm之间,采摘成功率可达到90%,吸盘最优停留时间为1.00 s,吸盘最优接近距离为1.0 mm,最优旋拧角度为360°。

关键词：采摘机器人驱控一体旋拧采摘 CANopen

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An Unprecedented Efficiency with Approaching 21%Enabled by Additive‑Assisted Layer‑by‑Layer Processing in Organic Solar Cells

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Nano-Micro Letters 2025年第2期17卷 372-375页

作者： Shuai Xu Youdi Zhang Yanna Sun Pei Cheng Zhaoyang Yao ning Li Long Ye Lijian Zuo Ke Gao Key Laboratory of Advanced Green Functional Materials College of ChemistryChangchun Normal UniversityChangchun 130032People’s Republic of China Shandong Provincial Key Laboratory for Science of Material Creation and Energy Conversion School of Chemistry and Chemical EngineeringShandong UniversityQingdao 266237People’s Republic of China College of Polymer Science and Engineering Sichuan UniversityChengdu 610065People’s Republic of China State Key Laboratory and Institute of Elemento‑Organic Chemistry Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer MaterialsRenewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin 300071People’s Republic of China Institute of Polymer Optoelectronic Materials and Devices State Key Laboratory of Luminescent Materials and Devices South China University of TechnologyGuangzhou 510640People’s Republic of China Tianjin Key Laboratory of Molecular Optoelectronic Sciences School of Materials Science and EngineeringTianjin UniversityTianjin 300350People’s Republic of China State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China

Recently published in Joule,feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network active layer morphology,featuring a bulk p-in structure and proper vertical segregation achieved through additive-assisted layer-by-layer *** optimized hierarchical gradient fibrillar morphology and optical management synergistically facilitates exciton diffusion,reduces recombination losses,and enhances light capture *** approach not only offers a solution to achieving high-efficiency devices but also demonstrates the potential for commercial applications of OSCs.

关键词： Organic solar cells Additive-assisted layer-by-layer processing Three-dimensional fibril morphology Bulk p-i-n structure Optical management

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Numerical investigation of the dynamics of flexible vegetations in turbulent open-channel flows

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Journal of Hydrodynamics 2022年第4期34卷 681-699页

作者： Dong Xu Jia-ning Liu Yun-feng Wu Chun-ning Ji State Key Laboratory of Hydraulic Engineering Simulation and Safety Tianjin UniversityTianjin 300072China

Aquatic vegetations widely exist in natural rivers and play an essential role in the evolution of the water environment and ecosystem by changing the river’s hydrodynamic characteristics and transporting sediments and *** reality,most aquatic vegetations are highly flexible,which invalidates the“rigid-cylinder”assumption widely adopted in many *** explore the dynamics of submerged flexible vegetation in open-channel flows and its feedback to turbulent flow structures,numerical simulations are carried out using an in-house fluid-structure interaction(FSI)*** the simulations,the geometry of vegetation plants is grid-resolved,the turbulent flow is simulated using the large eddy simulation(LES),the dynamics of the flexible plants are solved using the vector form intrinsic finite element(VFIFE)method,and the turbulent flow and the plants are two-way coupled using the immersed boundary(IB)*** dynamic responses of the flexible vegetation with different plant flexibility,spacing,and submergence are *** results show that flexible plants are subjected to complex flow-induced vibrations(FIVs)rather than static *** FIV involves both streamwise and cross-flow motions driven by the small-scale vortex shedding around the plants and the large-scale Kelvin-Helmholtz(K-H)vortices developed in the vegetation canopy *** vegetations exhibit pulsive wave motion of different patterns in relatively long and narrow open *** with the open-channel flows with static plants with equivalent bending deformation,the dynamic responses of flexible plants may increase the turbulent Reynolds stress of the open-channel flow by 70%–100%and increase the invasion depth of the K-H vortices by 30%–50%.

关键词： Flexible vegetation dynamic responses flow-induced vibration(FIV) fluid-structure interaction(FSI)

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Superparamagnetic iron oxide nanoparticles assembled magnetic nanobubbles and their application for neural stem cells labeling

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Journal of Materials Science & Technology 2021年第4期63卷 124-132页

作者： Jing Li Zhenqiang feng ning Gu Fang Yang State Key Laboratory of Bioelectronics Jiangsu Key Laboratory for Biomaterials and DevicesSchool of Biological Sciences and Medical EngineeringSoutheast UniversityNanjing 210096China

Micro/nanobubbles for use as ultrasound contrast agents have been fabricated with different shell *** various biomedical nanoparticles have been embedded in the shells of bubbles,the composite structures have shown promising applications in multi-modal imaging,drug/gene delivery,and biomedical *** this study,we developed a new gas-liquid interface self-assembly method to prepare magnetic nanobubbles embedded with superparamagnetic iron oxide nanoparticles(SPIONs).The diameter of the generated assembled nanobubbles was 227.40±87.21 nm with a good polydispersity index(PDI)of *** the condition of 150 compression cycles,the nanobubble concentration could reach about 6.12×10^(9)/*** electron microscopy(TEM)and scanning electronic microscopy(SEM)demonstrated that the assembled nanobubbles had a hollow gas core with SPIONs adsorbed on the ***(US)imaging and magnetic resonance imaging(MRI)experiments indicated that the assembled magnetic nanobubbles exhibited good US and MR contrast ***,the assembled magnetic nanobubbles were used to label neural stem cells under ultrasound *** 40 s US exposure,the magnetic nanobubbles could be delivered into cells with 2.80 pg Fe per cell,which could be observed in the intracellular endosome by *** with common incubation methods,the ultrasound exposure method did not introduce the potential cytotoxicity of transfection reagents and the efficiency was about twice as high as the efficiency of ***,the assembled magnetic nanobubbles prepared through the pressure-driven gas-liquid interface assembly approach could be a potential US/MRI dual model imaging nanocarrier for regenerative applications.

关键词： magnetic shells bubble

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An FTIR Study of Kyanite in the Maobei Kyanite-Bearing Eclogites from the Sulu Orogenic Belt, Eastern China

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Journal of Earth Science 2018年第1期29卷 21-29页

作者： Yi-ning Wu Yong-feng Wang School of Earth Sciences China University of Geosciences State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Global Tectonic Center School of Earth Sciences China University of Geosciences

As a minor phase, kyanite has been repeatedly shown to have experienced ultrahigh pressure （UHP） metamorphism together with its host eclogites. Thus, it could play some role in trans- porting water into the deep earth. Here we present a detailed investigation of water concentrations of kyanite, and for reference, of garnet and omphacite from four Maobei eclogites in the Sulu orogenic belt, eastern China. Fourier transform infrared （FTIR） measurements show that kyanites, garnets, and omphacites all have distinct hydroxyl absorption bands due to OH groups bound in their crystal struc- ture. The FTIR profile analyses on ten grains from different samples reveal a homogeneous distribution of water across kyanite, suggesting insignificant water loss during exhumation. The calculated water concentrations in kyanite （21 wt ppm-41 wt ppm） are comparable to those reported previously for kyanite from various geological occurrences when using the most recent calibration. They are however much lower compared with those in garnet （46 wt ppm-83 wt ppm） and omphacite （302 wt ppm-548 wt ppm） from the Maobei eclogites. This implies that kyanite is not a major water carrier in eclogites con- sidering its low volume fraction and contributes negligibly to transport water into the deep mantle ac- companying subducted oceanic crust until its possible transformation to AISiO3OH.

关键词： kyanite water contents eclogite Sulu orogenic belt.

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Effect of Zener-Hollomon Parameter on Microstructure and Mechanical Properties of Copper Subjected to Friction Stir Welding

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Acta Metallurgica Sinica(English Letters) 2020年第2期33卷 319-326页

作者： Nan Xu Ruo-Nan feng Wen-feng Guo Qi-ning Song Ye-feng Bao College of Mechanical and Electrical Engineering Hohai UniversityChangzhou 213022China

In this work,the influence of the Zener-Hollomon(Z)parameter on the microstructure and mechanical properties of copper subjected to friction stir welding(FSW)was *** N2 cooling was conducted to control the cooling rate after the *** obtained results demonstrate that the Z parameter was dependent on the tool rotation rate during the FSW,i.e.,a higher tool rotating rate resulted in a lower Z *** grain size in the stir zone decreased with the increase in the Z *** relationship between the yield strength and the Z parameter is established asσ0.2=σ0+*** relationship exhibited two different plots under the conditions of air cooling and liquid N2 *** at a similar Z parameter,a significant yield strength difference occurred because massive dislocations,which were caused by the prevention of the post-annealing effect,were maintained in the stir *** study suggests that the influence of the post-annealing effect should not be neglected when analyzing the relationship between the Z parameter,micro structure,and mechanical properties.

关键词： Copper Friction stir welding Microstructure Mechanical properties

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Social-Aware Cooperation Among Mobile Terminals for Wireless Downlink Transmission

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China Communications 2015年第9期12卷 1-10页

作者： Mao Hongliang feng Wei Ge ning Tsinghua National Lab for Information Science and Technology Tsinghua University

This paper investigates the social-aware cooperation(SAC) among mobile terminals(MTs), motivated by the fact that modern smart devices have much improved context awareness. Aware of the social ties, the cooperative network contains two layers of property: social and physical. In order to observe how the social awareness benefit the cooperation performance, we first formulate the social ties between MTs into parameters that can describe the cooperative behaviors by taking the mobility feature into account, defined as the conviction-approval-suspicion(CAS) model. Limited by the processing capability, partner selection is of great practical significance. To this end, the social-aware partner selection strategy is analyzed, and a significant superiority is observed compared to social-unaware selection. By analyzing the cooperative throughput, an explicit relationship between the degrees-of-freedom gain and the social-physical property is finally derived. Simulation results validate the theoretical analysis.

关键词： social-aware cooperation partner selection degrees-of-freedom

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Vanadium-Doped Semi-Insulating 6H-SiC for Microwave Power Device Applications

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Journal of Materials Science & Technology 2009年第1期25卷 102-104页

作者： Liana ning Zhihong feng Yingmin Wang Kai Zhang Zhen feng State Key Laboratory of Crystal Materials Shandong University Jinan 250100 Hebei Semiconductor Research Institute Shijiazhuang 050051 China

Two-inch semi-insulating SiC bulk crystals with resistivity higher than 1 × 10^6 Qcm were achieved by vanadium doping during sublimation. Secondary-ion-mass-spectrometry （SIMS） was employed to determine the concentration of impurities in the crystals, such as B, AI, V and N. These results indicated that the concentration of nitrogen and aluminum kept on decreasing and the concentration of B and V was almost constant during the whole growth. An inner crucible was used to control the exhausting of vanadium, which made the uniformity of the high resistivity （〉1×10^6 Ωcm） in the wafer up to 80%. High-performance AlGaN/GaN high-electronmobility-transistor （HEMT） materials and devices were grown and fabricated on semi-insulating 6H-SiC sub- strates. The two-dimensional electron gas （2DEG） mobility at room-temperature was 1795 cm^2/V-s. The charge carrier concentration of the substrate determined by capacitance-voltage （C-V） test was 7.3×10^15 cm^-3. The device with a gate width of I mm exhibits a maximum output power of 5.5 W at 8 GHz, which proves the semi-insulating property of the substrates indirectly.

关键词： Silicon Carbide Semi-insulating Vanadium-doped AlGaN/GaN HEMT

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Shock control bump optimization for a low sweep supercritical wing

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Science China(Technological Sciences) 2013年第10期56卷 2385-2390页

作者： DENG feng QIN ning LIU XueQiang YU XiongQing ZHAO ning Key Laboratory of Fundamental Science for National Defense-Advanced Design Technology of Flight Vehicle Nanjing University of Aeronautics and Astronautics Department of Mechanical Engineering University of SheffieldSheffield S1 3JD UK

Shock control bumps are a promising technique in reducing wave drag of civil transport aircraft flying at transonic *** paper investigates the optimization of 3D shock control bumps on a supercritical wing with a sweep angle of 16°at the1/4 chord.A similar supercritical wing with a higher sweep angle of 24.5°at the 1/4 chord has been adopted as a baseline for the *** results show that the drag coefficient of the low sweep wing with the optimized 3D shock control bumps is reduced below that for the high sweep wing,indicating shock control bumps can be used as an effective means to reduce the wave drag caused by reducing the wing sweep *** the point of view of the wing structure design,lower sweep angle will also bring the benefits of weight reduction,resulting in further fuel reduction.

关键词： supercritical wing low sweep angle shock control bump aerodynamic shape optimization computational fluiddynamics

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