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Pure phase MoN: preparation by chemical-diffused permeation and enhanced conductivity with rare earth Gd

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Rare Metals 2015年第2期34卷 137-142页

作者： Xin Li Chao Gao yu-zhi jiang Xi-Kun Li School of Materials Science and Engineering Shenyang Ligong University

MoN was prepared by rare earth Gd thermaldiffused permeation method via solid–gas interface reaction using（NH_4）_4[NiMo6O_24H_6]·7H_2O（abbreviated as NiMo6） as the precursor. Thermo-gravimetric differential thermal analysis（TG–DTA） was used to study the product＇s stability. The results of X-ray diffractometer（XRD）and X-ray photoelectron spectroscopy（XPS） indicate that a new hexagonal crystal MoN forms after the rare earth gas permeation and Gd3＋are diffused as substitution ions into the crystal lattice of MoN, and the surface valence of elemental content was measured by XPS. The conductivity results by direct current（DC） four-probe method show that MoN obtained from the Gd thermal permeation exhibits conductor character in the temperature range of 298–740 K and semiconductor behavior in 740–800 K.

关键词： Rare earth permeation MoN Conductivity Gd

Magnesium hydroxide whisker modified via in situ copolymerization of n-butyl acrylate and maleic anhydride

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Rare Metals 2017年第12期36卷 997-1002页

作者： yu-zhi jiang yu-Lian Wang Chun-Yan Wang Li-Mei Bai Xin Li Yan-Bo Li Collogy of Materials Science and Engineering Shenyang Ligong University Shenyang 110159 China Kailong Lanfeng New Material Technology Co. LtdZhenjiang 212132 China College of Mining Engineering Hebei United UniversityTangshan 063009 China School of Materials Science and Engineering Central South University Changsha 410083 China

Magnesium hydroxide(MH) whiskers were modified via in situ polymerization of n-butyl acrylate and maleic anhydride. Sodium dodecyl sulfonate was used as emulsifier. The modifying effect was evaluated by using contact angle and activation index. The thermal stability,functional groups, structure, morphology, phase composition and surface element valence of MH whiskers were characterized by thermogravimetry-differential scanning calorimetry(TG-DSC), Fourier transform infrared spectroscopy(FTIR), X-ray diffraction(XRD), scanning electron microscopy(SEM) and X-ray photoelectron spectroscopy(XPS). Results reveal that the contact angle and activation index of modified MH whiskers are 105°and 76.5%, the thermal stability shows little change, and the decomposition temperature ranges between 38 and419 ℃. The copolymer of n-butyl acrylate and maleic anhydride absorbed on the surface of MH whiskers leads to the increased diameter and makes the surface of whiskers be rougher. Furthermore, the absorption of element C on the surface of MH whiskers increases, and the diffraction intensity of C 1 s spectra increases; thus, the compatibility of whiskers in the organic phase can be improved significantly. Lastly, the surface molecular model of MH whiskers modified via in situ copolymerization of n-butyl acrylate and maleic anhydride is established.

关键词： Magnesium hydroxide whiskers n-Butyl acrylate Maleic anhydride In situ copolymerization Surface molecular model

Electrochemical property of LiFePO4/C composite cathode with different carbon sources

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Rare Metals 2018年第9期37卷 743-749页

作者： Xin Li yu zhi jiang Xi Kun Li Hai Xia jiang Jun Long Liu Jun Feng Shi Bin Lin Xin Guan Shenyang Ligong University Shenyang 110159 China

To improve the performance of battery cathode materials that consist of carbonaceous organic material, carbon coatings on lithium iron phosphate （LiFePO4/C） materials were synthesized by different carbon sources. LiFePO4/C was synthesized by a combination method of sol-gel and gas-phase diffused permeation. LiFeO4/C materials were prepared by coating different carbon con- tents. High-performance composite materials were pre- pared by combining carbon with element doped by two modified methods. The elements of Fe and C came from Fe3＋ and sucrose, glucose, citric acid. Thermogravimetry- differential thermal analysis （TG-DTA）, X-ray diffrac- tometer （XRD）, scanning electron microscope （SEM）, cycle voltammetry （CV）, and charge-discharge test were used to characterize and test the surface morphology, structure, and electrochemical performance. The results show that LiFePO4/C synthesized with sucrose has higher specific discharge capacity than the other materials. The specific discharge capacity of this material is 84.27 mAh.g-1. The capacity retention could attain 94 % of the initial discharge capacity after 30 cycles, showing good electrochemical performance.

关键词： Solgel Gas-phase diffused permeation LiFePO4/C Sucrose Citric acid

Promising key genes associated with tumor microenvironments and prognosis of hepatocellular carcinoma

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World Journal of Gastroenterology 2020年第8期26卷 789-803页

作者： Long Pan Jing Fang Ming-yu Chen Shu-Ting Zhai Bin Zhang zhi-yu jiang Sarun Juengpanich Yi-Fan Wang Xiu-Jun Cai Key Laboratory of Laparoscopic Technique Research of Zhejiang Province Department of General SurgerySir Run Run Shaw HospitalZhejiang University School of MedicineHangzhou 310016Zhejiang ProvinceChina Zhejiang Province Medical Research Center of Minimally Invasive Diagnosis and Treatment of Abdominal Diseases Hangzhou 310016Zhejiang ProvinceChina

BACKGROUND Despite significant advances in multimodality treatments,hepatocellular carcinoma(HCC)remains one of the most common malignant *** of novel prognostic biomarkers and molecular targets is urgently *** To identify potential key genes associated with tumor microenvironments and the prognosis of *** The infiltration levels of immune cells and stromal cells were calculated and quantified based on the ESTIMATE *** expressed genes(DEGs)between high and low groups according to immune or stromal scores were screened using the gene expression profile of HCC patients in The Cancer Genome Atlas and were further linked to the prognosis of *** genes were validated in four independent HCC ***-related key genes were identified by a LASSO Cox regression *** HCC patients with a high immune/stromal score had better survival benefits than patients with a low score.A total of 899 DEGs were identified and found to be involved in immune responses and extracellular matrices,147 of which were associated with overall ***,52 of 147 survival-related DEGs were validated in additional ***,ten key genes(STSL2,TMC5,DOK5,RASGRP2,NLRC3,KLRB1,CD5L,CFHR3,ADH1C,and UGT2B15)were selected and used to construct a prognostic gene signature,which presented a good performance in predicting overall *** This study extracted a list of genes associated with tumor microenvironments and the prognosis of HCC,thereby providing several valuable directions for the prognostic prediction and molecular targeted therapy of HCC in the future.

关键词： Hepatocellular carcinoma Tumor microenvironment Differentially expressed genes Overall survival

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苦瓜多糖对运动力竭小鼠疲劳的干预研究

食品研究与开发 2017年第17期38卷 186-188,224页

作者：于志江河南科技学院河南新乡453003

研究苦瓜多糖对一次性力竭运动后小鼠疲劳缓解及氧化损伤影响。以醇沉水提法制备的苦瓜多糖灌胃小鼠21 d后,采用力竭游泳试验,测定小鼠力竭游泳时间,血清乳酸,乳酸脱氢酶及尿素氮,肝肌糖原及组织(心肌、肝脏)中谷胱甘肽过氧化物酶(gluta... 详细信息

研究苦瓜多糖对一次性力竭运动后小鼠疲劳缓解及氧化损伤影响。以醇沉水提法制备的苦瓜多糖灌胃小鼠21 d后,采用力竭游泳试验,测定小鼠力竭游泳时间,血清乳酸,乳酸脱氢酶及尿素氮,肝肌糖原及组织(心肌、肝脏)中谷胱甘肽过氧化物酶(glutathione peroxidase,GPX)与超氧化物歧化酶(superoxide dismutase,SOD)活力、丙二醛(malondialdehyde,MDA)含量。同力竭对照小鼠比较,苦瓜多糖能延长小鼠负重游泳时间,提高肝脏及肌肉糖原水平,减少运动后血乳酸,尿素氮的堆积,提高乳酸脱氢酶活性。此外,还可提高心脏及肝脏中SOD及GPX活性,降低MDA水平。结果表明苦瓜多糖具有显著的抗疲劳功效,可减轻大强度运动后自由基造成的氧化损伤,促进机体功能恢复。

关键词：苦瓜粗多糖抗疲劳氧化应激力竭

Ideal Bi‑Based Hybrid Anode Material for Ultrafast Charging of Sodium‑Ion Batteries at Extremely Low Temperatures

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Nano-Micro Letters 2025年第3期17卷 152-167页

作者： Jie Bai Jian Hui Jia yu Wang Chun Cheng Yang Qing jiang Key Laboratory of Automobile Materials(Jilin University) Ministry of EducationSchool of Materials Science and EngineeringJilin UniversityChangchun 130022People’s Republic of China

Sodium-ion batteries have emerged as competitive substitutes for low-temperature applications due to severe capacity loss and safety concerns of lithium-ion batteries at−20°C or ***,the key capability of ultrafast charging at ultralow temperature for SIBs is rarely ***,a hybrid of Bi nanoparticles embedded in carbon nanorods is demonstrated as an ideal material to address this issue,which is synthesized via a high temperature shock *** a hybrid shows an unprecedented rate performance(237.9 mAh g^(−1)at 2 A g^(−1))at−60℃,outperforming all reported SIB anode *** with a Na_(3)V_(2)(PO_(4))_(3)cathode,the energy density of the full cell can reach to 181.9 Wh kg^(−1)at−40°*** on this work,a novel strategy of high-rate activation is proposed to enhance performances of Bi-based materials in cryogenic conditions by creating new active sites for interfacial reaction under large current.

关键词： Bi nanoparticles High temperature shock High-rate activation Ultrafast charging Low-temperature sodium-ion batteries

Constructing 2D bismuth-based heterostructure for highly efficient photocatalytic CO2 reduction

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Tungsten 2025年第1期7卷 71-79页

作者： Ruo-Hang Xu Hao-yu jiang Dan-Dan Cui Kun-Rong Du Hong-Run Zhang Sheng-Jie Xu Ya-Qi Li zhi-Zhen Ren Liang Wang Wei-Chang Hao Yi Du School of Physics and BUAA-UOW Joint Research Centre Beihang University Shenzhen Institute of Beihang University Centre for Catalysis and Clean Energy School of Environment and Science Griffith University

Reforming carbon dioxide（CO2） into fuels and valuable chemicals using solar energy holds significant potential for emission reduction and addressing energy supply *** recombination of photocarriers remains a major obstacle,however,to enhancing solar energy conversion efficiency in the photocatalytic reaction *** two-dimensional materials,constructing heterogeneous structures has emerged as an effective strategy to enhance the separation of photoexcited carriers by leveraging the internal electric field at the heterogeneous ***,we present a facile strategy for preparing Bi4NbO8Br/Bi2WO6plate-on-plate Z-scheme junctions with a strong internal electric field by in situ *** unique heterostructure facilitates efficient separation and transport of photoexcited charges by harnessing the internal electric field induced by chemical bonding at the lateral ***,the Bi4NbO8Br/Bi2WO6heterostructure exhibits enhanced CO2photoreduction properties,along with a CO yield rate of approximately 35 μmol·g-1·h-1under full light *** work offers novel insights into the synthesis of unique hetero structures intended to enhance the efficiency of photocatalytic CO2reduction.

关键词： Bi4NbO8Br/Bi2WO6 CO2 reduction Heterostructures Photocatalysts

Probing the Electronic Structure of the CoB16- Drum Complex: Unusual Oxidation State of Co-1

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Chinese Journal of Chemical Physics 2019年第2期32卷 241-247,I0003页

作者： Wan-Lu Li Wan-Lu Lia zhi-yu jiang Wei-Jia Chen Han-Shi Hu Lai-Sheng Wang Jun Li Probing the Electronic Structure of the CoB16- Drum Complex: Unusual Oxidation State of Co-1 Probing the Electronic Structure of the CoB16- Drum Complex: Unusual Oxidation State of Co-1

Since the discovery of the first drum-like CoB16- complex, metal-doped drum-like boron nanotubular structures have been investigated with various metal dopants and different tubular size, forming a new class of novel nanostructures. The CoB16- cluster was found to be composed of a central Co atom coordinated by two fused B8 rings in a tubular structure, representing the potential embryo of metal-filled boron nanotubes and providing opportunities to design one-dimensional metal-boron nanostructures. Here we report improved photoelectron spectroscopy and a more in-depth electronic structure analysis of CoB16-, providing further insight into the chemical bonding and stability of the drum-like doped boron tubular structures. Most interestingly, we find that the central Co atom has an unusually low oxidation state of ?1 and neutral CoB16 can be viewed as a charge transfer complex (Co-@BB16+), suggesting both covalent and electrostatic interactions between the dopant and the boron drum.

关键词： Photoelectron spectroscopy Metal-boron clusters Ab initio calculations Chemical bonding

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基于半定量法的地铁工程地面塌陷风险评估

铁道工程学报 2014年第12期31卷 93-95,105页

作者：张昌新余志江郑太航铁道第三勘察设计院集团有限公司天津300142

研究目的：针对地铁工程地面塌陷风险评估工作存在较大随意性和模糊性的特点,定性分析地铁施工诱发地面塌陷的本质和影响因素,从众多影响因素中提取出关键影响因子建立半定量评估模型,预测地铁施工诱发地面塌陷的风险。研究结论：（1）... 详细信息

研究目的：针对地铁工程地面塌陷风险评估工作存在较大随意性和模糊性的特点,定性分析地铁施工诱发地面塌陷的本质和影响因素,从众多影响因素中提取出关键影响因子建立半定量评估模型,预测地铁施工诱发地面塌陷的风险。研究结论：（1）评估线路地铁施工引发地面塌陷的风险等级主要在基本稳定~较不稳定之间;（2）局部地段砂层侵入洞身或距隧道顶板的距离较小,由于砂层厚度较大,地下水丰富、隧道上覆土层松散且厚度不大,地铁施工引发地面塌陷的风险等级为不稳定;（3）局部区段隧道在完整基岩内通过,且上覆基岩厚度较大,地铁施工引发地面塌陷的风险等级为稳定;（4）定性半定量评估法的评估结果与深圳地铁7号线工程实际吻合较好,对今后类似城市轨道交通工程地质灾害评估工作具有一定参考意义。

关键词：半定量法地面塌陷风险评估