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A novel and promising engineering application of carbon dots:Enhancing the chloride binding performance of cement

Chinese Chemical Letters 2024年第6期35卷 409-416页

作者： wu-jian Long Yang yu Chuang He Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering Key Lab of Coastal Urban Resilient InfrastructureMOECollege of Civil and Transportation EngineeringShenzhen UniversityShenzhen 518060China

Corrosion of reinforcement induced by chloride invasion is extensively considered as the dominating deterioration mechanism of reinforced concrete(RC)structures,leading to serious safety hazards and tremendous economic ***,it still lacks well dispersive and cost-efficient nanomaterials to improve the anti-chloride-corrosion ability of RC ***,specific carbon dots(CDs)with high dispersity and low cost are deliberately designed,successfully prepared by hydrothermal processing,and then firstly applied to immensely enhance chloride binding performance of cement,thereby contributing to suppressing the corrosion of ***,the tailored CDs are composed of the carbon core with highly crystalline sp^(2)C structures and oxygen-containing groups connecting on the carbon core;The typical equilibrium test confirms that with respect to that of the blank cement paste,the chloride binding capacity of cement paste involving 0.2 wt%(by weight of cement)CDs is increased by 109% after 14-day exposure to 3 mol/L Na Cl solution;according to comprehensive analyses of phase compositions,the chloride binding mechanism of CDs-modified cement is rationally attributed to the fact that the incorporation of CDs advances the formation of calcium silicate hydrate(C-S-H)gels and Friedel's salt(Fs),thus enormously enhancing the physically adsorbed and chemically bound chloride ions of cement *** work not only firstly provides a novel high-dispersity and low-cost nanomaterial toward the durability enhancement of RC structures,but also broadens the application of CDs in the field of engineering,conducing to stimulating their industrialization development.

关键词： Carbon dots Chloride binding Cement Chloride binding mechanism Friedel’s salt

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Current improvement in substrate structured Sb2S3 solar cells with MoSe2 interlayer

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Chinese Physics B 2020年第5期29卷 579-585页

作者： Lu Liu Sheng-Li Zhang jian-yu wu Wei-Huang Wang Wei Liu Li wu Yi Zhang Institute of Photoelectronic Thin Film Devices and Technology and Tianjin Key Laboratory of Thin Film Devices and Technology Nankai UniversityTianjin 300350China School of Physical Science Nankai UniversityTianjin 300071China

Sb2S3 solar cells with substrate structure usually suffer from pretty low short circuit current(JSC)due to the defects and poor carrier *** Sb2S3,as a one-dimensional material,exhibits orientation-dependent carrier transport *** this work,a thin MoSe2 layer is directly synthesized on the Mo substrate followed by depositing the Sb2S3 thin *** x-ray diffraction(XRD)patterns confirm that a thin MoSe2 layer can improve the crystallization of the Sb2S3 film and induce(hk1)orientations,which can provide more carrier transport *** probe force microscopy(KPFM)results suggest that this modified Sb2S3 film has a benign surface with less defects and dangling *** variation of the surface potential of Sb2S3 indicates a much more efficient carrier ***,the power conversion efficiency(PCE)of the substrate structured Sb2S3 thin film solar cell is improved from 1.36%to 1.86%,which is the best efficiency of the substrate structured Sb2S3 thin film solar cell,and JSC significantly increases to 13.6 mA/cm^*** to the external quantum efficiency(EQE)and C-V measurements,the modified crystallization and elevated built-in electric field are the main causes.

关键词： Sb2S3 thin film super thin MoSe2 built-in electric filed Kelvin probe force microscopy

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Prolonged overall survival in gastric cancer patients after adoptive immunotherapy

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World Journal of Gastroenterology 2015年第9期21卷 2777-2785页

作者： Guo-Qing Zhang Hong Zhao jian-yu wu Jin-yu Li Xiang Yan Gang Wang Liang-Liang wu Xiao-Gang Zhang Yi Shao yu Wang Shun-Chang Jiao Department of Clinical Oncology Chinese PLA General Hospital Laboratory of Tumor Research Center Chinese PLA General Hospital Beijing Immunotech Applied Science Limited

AIM:To assess the efficacy of immunotherapy with expanded activated autologous lymphocytes(EAALs) in gastric ***:An observational study was designed to retrospectively analyze the clinical data of 84 gastric cancer patients,of whom 42 were treated by EAAL immunotherapy plus conventional treatment and another 42 only received conventional treatment(control group).EAALs were obtained by proliferation of peripheral blood mononuclear cells from patients followed by phenotype *** data including age,gender,clinical stage,chemotherapeutic regimens,hospitalization,surgical,radiotherapy,and survival data were collected along with EAAL therapy details and side *** were followed and the relationship between treatment and overall survival(OS) data obtained for the immunotherapy and control groups were compared *** safety of EAAL immunotherapy was also ***:After in vitro culture and proliferation,the percentages of CD3+,CD3+CD8+,CD8+CD27+,CD8+CD28+,and CD3+CD16+/CD56+cells increased remarkably(P < 0.05),while the percentages of CD3+CD4+,CD4+CD25+,and CD3-CD16+/CD56+(natural killer cells) were overtly decreased(P < 0.05); no significant change was observed in CD4+CD25+CD127- cells(P =0.448).Interestingly,OS in the immunotherapy group was significantly higher than that in the control group,with 27.0 and 13.9 mo obtained for the two groups,respectively(P =0.028,HR =0.573,95%CI:0.347-0.945).These findings indicated a 42.7% decrease in the risk of *** addition,we found that clinical stage and application of EAAL immunotherapy wereindependent prognostic factors for gastric cancer ***,the OS in stage Ⅲc and Ⅳ patients that had received surgery was prolonged after EAAL immunotherapy(P < 0.05).Importantly,in vitro induction and proliferation of EAAL were easy and biologically ***:Overall,EAAL adoptive immunotherapy might prolong the OS in gastric cancer patients.

关键词： Adoptive immunotherapy Gastric cancer Expanded act

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Postoperative pneumocranium after endoscopic transnasal optic canal decompression

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International Journal of Ophthalmology(English edition) 2024年第5期17卷 973-975页

作者： Sheng-jian Lu Bo yu Wen-Can wu The Eye Hospital School of Ophthalmology&OptometryWenzhou Medical UniversityWenzhou 325027Zhejiang ProvinceChina

Dear Editor,We present the first time,a case of a patient developed cerebrospinal fluid(CSF)leak and pneumocranium following optic canal decompression(OCD).INTRODUCTION Indirect traumatic optic neuropathy(ITON)impairs visual functions and quality of *** transnasal optic canal decompression(ETOCD)is one of the standard treatment strategies for the *** the ETOCD,the optic nerve sheath are usually incised for sufficient decompression of optic nerve after removal of optic canal,which is associated with complications like CSF leakage,ophthalmic artery injury,and optic nerve injury[1].Generally,the mild CSF leak is common and can heal spontaneously using conventional treatment,the severe CSF leak requires surgical repair[2].

关键词： decompression nasal traumatic

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Efficient stochastic parallel gradient descent training for on-chip optical processor

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Opto-Electronic Advances 2024年第4期7卷 5-15页

作者： yuanjian Wan Xudong Liu Guangze wu Min Yang Guofeng Yan yu Zhang jian Wang wuhan National Laboratory for Optoelectronics and School of Optical and Electronic Information Huazhong University of Science and TechnologyWuhan 430074China Optics Valley Laboratory Wuhan 430074China

In recent years,space-division multiplexing(SDM)technology,which involves transmitting data information on multiple parallel channels for efficient capacity scaling,has been widely used in fiber and free-space optical communication *** enable flexible data management and cope with the mixing between different channels,the integrated reconfig-urable optical processor is used for optical switching and mitigating the channel ***,efficient online train-ing becomes intricate and challenging,particularly when dealing with a significant number of *** we use the stochastic parallel gradient descent(SPGD)algorithm to configure the integrated optical processor,which has less com-putation than the traditional gradient descent(GD)*** design and fabricate a 6×6 on-chip optical processor on silicon platform to implement optical switching and descrambling assisted by the online training with the SPDG ***,we apply the on-chip processor configured by the SPGD algorithm to optical communications for optical switching and efficiently mitigating the channel crosstalk in SDM *** comparison with the traditional GD al-gorithm,it is found that the SPGD algorithm features better performance especially when the scale of matrix is large,which means it has the potential to optimize large-scale optical matrix computation acceleration chips.

关键词： optical communications optical signal processing channel descrambling optical neural network chip silicon photonics

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Stress corrosion cracking behavior of buried oil and gas pipeline steel under the coexistence of magnetic field and sulfate-reducing bacteria

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Petroleum Science 2024年第2期21卷 1320-1332页

作者： jian-yu He Fei Xie Dan Wang Guang-Xin Liu Ming wu yue Qin College of Petroleum Engineering Liaoning Petrochemical UniversityFushun113001LiaoningChina Key Laboratory of Oil and Gas Storage and Transportation Technology in Liaoning Province Fushun113001LiaoningChina State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing100084China PipeChina West East Gas Pipeline Company Shanghai200120China

Magnetic field and microorganisms are important factors influencing the stress corrosion cracking(SCC)of buried oil and gas pipelines. Once SCC occurs in buried pipelines, it will cause serious hazards to the soil environment. The SCC behavior of X80 pipeline steel under the magnetic field and sulfate-reducing bacteria(SRB) environment was investigated by immersion tests, electrochemical tests, and slow strain rate tensile(SSRT) tests. The results showed that the corrosion and SCC sensitivity of X80 steel decreased with increasing the magnetic field strength in the sterile environment. The SCC sensitivity was higher in the biotic environment inoculated with SRB, but it also decreased with increasing magnetic field strength, which was due to the magnetic field reduces microbial activity and promotes the formation of dense film layer. This work provided theoretical guidance on the prevention of SCC in pipeline steel under magnetic field and SRB coexistence.

关键词： Magnetic field Sulfate-reducing bacteria Film layer Stress corrosion cracking Oil and gas pipelines

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Extraordinary effects of liquid capsule application after resection of a giant meningioma

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Chinese Medical Journal 2008年第12期121卷 1140-1142页

作者： HU yu-hua wu jian-liang SHAO En-de wu jian-ling JI jian-wen Department of Neurosurgery Second Hospital of Hebei Medical University Shijiazhuang Hebei 050000 China

Memnglomas are the second most common intracranial benign rumors and represent about15%-24% of primary brain tumors.1 Most meningiomas grow slowly at a rate of only 2.4 mm annually.2 Due to their slow growth, few clinical symptoms occur until the tumor reaches a large size. If the meningioma grows at the front or rear of the cranial cavity, it can grow to be very large before that area＇s vital functions are affected. Therefore, giant meningiomas are not infrequent, and actually account for 11.9% of meningiomas in our hospital. Because the volume of the giant meningioma is large,

关键词： giant meningioma resection liquid capsule complication

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Experimental Study on Engineering Behavior of Solidified Soil for Scour Repair and Protection

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China Ocean Engineering 2024年第4期38卷 625-635页

作者： wu Xiao-ni LI Ru-yu SHU jian TANG Chao CHEN Jin-jian WANG Hui-li jianG Hai-li WANG Xiao State Key Laboratory of Ocean Engineering Department of Civil EngineeringShanghai Jiao Tong UniversityShanghai 200240China Shanghai Road and Bridge Group Co. Ltd.Shanghai 200433China Shanghai Engineering Research Center of Urban Infrastructure Renewal Shanghai 200032China jiangsu Kunze Technology Co. Ltd.Nanjing 210000China

A new scour countermeasure using solidified slurry for offshore foundation has been proposed *** solidified slurry is pumped to seabed area around foundation for scour protection or pumped into the developed scour holes for scour repair as the fluidized material solidifies *** the pumping operation and solidification,the engineering behaviors of solidified slurry require to be considered synthetically for the reliable application in scour repair and protection of ocean engineering such as the pumpability related flow value,flow diffusion behavior related rheological property,anti-scour performance related retention rate in solidification and bearing capacity related strength property after *** this study,a series of laboratory tests are conducted to investigate the effects of mix proportion(initial water content and binder content)on the flow value,rheological properties,density,retention rate of solidified slurry and unconfined compressive strength(UCS).The results reveal that the flow value increases with the water content and decreases with the binder *** the solidified slurry exhibits Bingham plastic behavior when the shear rate is larger than 5 s^(-1).The Bingham model has been employed to fit the rheology test results,and empirical formulas for obtaining the density,yield stress and viscosity are established,providing scientific support for the numerical assessment of flow and diffusion of solidified *** rate of solidified slurry decreases with the water flow velocity and flow value,which means the pumpability of solidified slurry is contrary to anti-scour *** unconfined compressive strength after solidification reduces as the water content increases and binder content decreases.A design and application procedure of solidified soil for scour repair and protection is also proposed for engineering reference.

关键词： scour repair and protection solidified soil pumpability strength flow properties anti-scour performance

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Study of dynamic pressure roadway supporting scheme under condi- tion of thick composite roof

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Journal of Coal Science & Engineering(China) 2013年第2期19卷 119-125页

作者： Wei-Jun WANG Li-Qiang LUO Wei-jian yu Hai wu Yan-Si QU Hunan Provincial Key Laboratory of Safe Mining Techniques of Coal Mines Hunan University of Science and TechnologyXiangtan 411201 China

This paper analyzed the strata behaviors of solid-coal roadway, gob-side entry driving and deformation law of surrounding rock in depth under high stress and thick composite roof based on the dynamic pressure roadway as engineering background in Fengcheng mining area, jiangxi province. The results, both field measurement and numerical simulation show that gob-side entry driving results the deformation of coal roadway main wall, however, entity-coal roadway driving results deformation of main roof and floor. The maintenance state of gob-side entry driving is better than entity-coal roadway, this situation is relevant to thick composite roof layered and easy collapse characteristics. At the same time, this paper put fox＇ward and proved proper dynamic pressure roadway supporting scheme under the surrounding rock condition and stress environment.

关键词： thick composite roof dynamic pressurized roadway high stress surrounding rock control

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The MELD scoring system for predicting prognosis in patients with severe hepatitis after plasma exchange treatment

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Hepatobiliary & Pancreatic Diseases International 2007年第5期6卷 492-496页

作者： yu, jian-wu Wang, Gui-Qiang Zhao, Yong-Hua Sun, Li-Jie Wang, Shu-Qin Li, Shu-Chen Harbin Med Coll Dept Infect Dis Affiliated Hosp 2 Harbin 150086 Peoples R China Peking Univ First Hosp Dept Infect Dis Beijing 100034 Peoples R China

BACKGROUND: Hepatic failure caused by severe hepatitis is a clinical syndrome where the major liver functions, particularly detoxification, synthetic functions, and metabolic regulation are impaired to different degrees, and may result in major life-threatening complications such as hepatic encephalopathy, ascites, jaundice, cholestasis, bleeding and hepatorenal syndrome. Plasma exchange (PE) has been found useful in treating patients with fulminant hepatic failure by removing hepatic toxins and replacement of clotting factors, so PE treatment has temporary supportive effects on liver failure caused by severe viral hepatitis. in this study, our aim was to predict the prognosis of patients with severe hepatitis after PE treatment using the end-stage liver disease (MELD) scoring system. METHODS: Two hundred and twenty patients were randomly divided into PE and control groups, and the MELD score was calculated for each patient according to the original formula. The efficacy of PE was assessed by mortality or improvement in biochemical parameters and MELD score. RESULTS: The levels of total bilirubin and international normalised ratio (INR) in patients whose MELD scores were between 30 and 39 were lower than those before PE treatment, as those in patients whose MELD scores were 40 or higher. The mortality of patients in the PE group with MELD scores from 30 to 39 was 50.0%, while it was 83.3% in the control group (P0.05). CONCLUSIONS: PE treatment can decrease the serum total bilirubin level and INR and MELD score of patients with severe hepatitis and improve liver function. Compared with the control group, PE can significantly decrease the mortality of patients with MELD scores from 30 to 39, but has no effect in patients with MELD scores of 40 or higher.

关键词： severe hepatitis model for end-stage liver disease plasma exchange mortality

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