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缺陷对单层硅烯纳米梁振动频率的影响

原子与分子物理学报 2025年第6期42卷 76-82页

作者：张文博王静新疆大学物理科学与技术学院乌鲁木齐830017

由于硅纳米谐振器在量子计算、传感器、医学等方面存在广泛的应用,使其物理性质的研究具有重要意义.本文通过分子动力学模拟方法研究了掺杂元素、空位缺陷、掺杂浓度对单层硅烯纳米梁振动特性的影响.研究结果表明,单层硅烯纳米梁的振动... 详细信息

由于硅纳米谐振器在量子计算、传感器、医学等方面存在广泛的应用,使其物理性质的研究具有重要意义.本文通过分子动力学模拟方法研究了掺杂元素、空位缺陷、掺杂浓度对单层硅烯纳米梁振动特性的影响.研究结果表明,单层硅烯纳米梁的振动频率随着纳米梁长度的增加而减小.单元素、双元素掺杂均会导致单层硅烯纳米梁的振动频率的增加,且随着掺杂浓度的增加纳米梁的振动频率整体呈现增大的趋势.此外,单空位缺陷会导致单层硅烯纳米梁的振动频率随着缺陷浓度的增加而减小.掺杂-单空位缺陷的单层硅烯纳米梁的振动频率则呈现了随着掺杂浓度的增加先减小后增加的变化趋势.这些变化规律均是由掺杂元素、空位缺陷以及它们共同作用的结果.此研究结果对硅烯纳米谐振器,振荡器等纳米器件的设计具有一定的理论指导意义.

关键词：硅烯掺杂振动频率分子动力学

An ionic liquid-assisted strategy for enhanced anticorrosion of low-energy PEO coatings on magnesium–lithium alloy

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Journal of Magnesium and Alloys 2024年第6期12卷 2380-2396页

作者： you zhang Chuping Chen Haoyue Tian Shuqi Wang Chen wen Fei Chen College of New Materials and Chemical Engineering Hydrogen Energy Research CentreBeijing Institute of Petrochemical TechnologyBeijing 102617China Key Laboratory of Advanced Structure-Function Integrated Materials and Green Manufacturing Technology Harbin Institute of TechnologyHarbin 150001China Beijing Spacecrafts China Academy of Space TechnologyBeijing 100190China

A low-energy plasma electrolytic oxidation(LePEO)technique is developed to simultaneously improve energy efficiency and *** liquids(1-butyl-3-methylimidazole tetrafluoroborate(BmimBF_(4)))as sustainable corrosion inhibitors are chosen to investigate the corrosion inhibition behavior of ionic liquid(ILs)during the LePEO process for LA91 magnesium-lithium(Mg-Li)*** show that the ionic liquid BmimBF_(4)participates in the LePEO coating formation process,causing an increment in coating thickness and surface *** low conductivity of the ionic liquid is responsible for the voltage and breakdown voltage increases during the LePEO with IL process(LePEO-IL).After adding BmimBF_(4),corrosion current density decreases from 1.159×10^(−4)A·cm^(−2)to 8.143×10^(−6)A·cm^(−2).The impedance modulus increases to 1.048×10^(4)Ω·cm^(−2)and neutral salt spray remains intact for 24 *** superior corrosion resistance of the LePEO coating assisted by ionic liquid could be mainly attributed to its compact and thick barrier layer and physical absorption of ionic *** ionic liquid-assisted LePEO technique provides a promising approach to reducing energy consumption and improving film performance.

关键词： Magnesium-lithium alloy Plasma electrolytic oxidation Low energy Ionic liquid Corrosion resistance

Uninvolved liver dose prediction in stereotactic body radiation therapy for liver cancer based on the neural network method

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World Journal of Gastrointestinal Oncology 2024年第10期16卷 4146-4156页

作者： Huai-wen zhang you-Hua Wang Bo Hu Hao-wen Pang Department of Radiotherapy Jiangxi Cancer HospitalNanchang 330029Jiangxi ProvinceChina Department of Oncology Gulin People’s HospitalLuzhou 646500Sichuan ProvinceChina Key Laboratory of Nondestructive Testing(Ministry of Education) Nanchang Hang Kong UniversityNanchang 330063Jiangxi ProvinceChina Department of Oncology The Affiliated Hospital of Southwest Medical UniversityLuzhou 646000Sichuan ProvinceChina

BACKGROUND The quality of a radiotherapy plan often depends on the knowledge and expertise of the plan *** To predict the uninvolved liver dose in stereotactic body radiotherapy(SBRT)for liver cancer using a neural network-based *** A total of 114 SBRT plans for liver cancer were used to test the neural network ***-organs of the uninvolved liver were automatically *** between the volume of each sub-organ,uninvolved liver dose,and neural network prediction model were established using *** the cases,70%were selected as the training set,15%as the validation set,and 15%as the test *** regression R-value and mean square error(MSE)were used to evaluate the *** The volume of the uninvolved liver was related to the volume of the corresponding *** all sets of Rvalues of the prediction model,except for D_(n0)which was 0.7513,all R-values of D_(n10)-D_(n100)and D_(nmean)were>*** MSE of the prediction model was also *** We developed a neural network-based method to predict the uninvolved liver dose in SBRT for liver *** is simple and easy to use and warrants further promotion and application.

关键词： Dose prediction Sub-organ Machine learning Stereotactic body radiotherapy Liver cancer

Rh(III)-Catalyzed Enantioselective Intermolecular Aryl C—H Bond Addition to Aldehydes

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Chinese Journal of Chemistry 2022年第23期40卷 2780-2784页

作者： Zhi-Jie Wu Zhuo Wu wen-wen zhang Qing Gu Shu-Li you State Key Laboratory of Organometalic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of Sciences345 Lingling LuShanghai 200032China School of Physical Science and Technology Shanghai Tech University100 Haike RoadShanghai 201210China

The direct addition of aryl C—H bond to carbon-heteroatom double bond by transition-metal-catalyzed C—H activation has been extensively investigated in the past decade. However, the enantioselective intermolecular C—H addition to aldehyde has not yet been reported and is of significant challenge. Rh(III)-catalyzed highly enantioselective intermolecular C—H addition of aryl oxime ethers to glyoxylates is reported. Chiral mandelic acid esters were obtained in excellent yields (up to 98%) and enantioselectivity (up to 99% ee) in the presence of a chiral CpRh(III) catalyst under mild conditions. The substituents on the Cp ring and BINOL skeleton were responsible for the high enantioselectivity observed. The method displays a broad substrate scope and good functionality tolerance. These results provide not only a promising C—H addition approach but also a proof of concept for developing broader asymmetric C—H addition reactions.

关键词： Asymmetric catalysis C-H addition Chiral cyclopentadiene Mandelate Rh catalysis

Analysis of the anti-T2DM components in dichloromethane fraction of Schisandra sphenanthera and its mechanism

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Traditional Medicine Research 2025年第1期10卷 27-43页

作者： Shi-Bo Feng Hai-Hui Jiang Hui-Li Kang Yi Jiang Hua-Wei zhang Xiao-Mei Song Yu-Ze Li wen-Li Huang Dong-Dong zhang Chong Deng School of Pharmacy Shaanxi University of Chinese MedicineXianyang 712046China School of Pharmacy and Shaanxi Qinling Application Development and Engineering Center of Chinese Herbal Medicine Shaanxi University of Chinese MedicineXianyang 712046China Key Laboratory for Research and Development of“Qin Medicine”of Shaanxi Administration of Traditional Chinese Medicine Xianyang 712046China Shaanxi Key Laboratory of Research and Application of“Taibai Qi Yao” Xianyang 712046China

Background:The type 2 diabetes mellitus(T2DM)pharmacodynamic study of various parts of Schisandra sphenanthera was conducted in the previous stage,and it was found that dichloromethane extracted part(SDP)had a significant hypoglycemic ***,the components of SDP were analyzed,and the specific mechanism of its anti-T2DM was ***:We used a high-fat,high-sugar diet in combination with streptozotocin to induce a T2DM rat model,and the model rats were divided into two groups according to body weight and blood ***,oral glucose tolerance test,fasting blood glucose,low density lipoprotein cholesterol,superoxide dismutase,insulin,glycated hemoglobin,total cholesterol,nonesterified free fatty acids,alanine aminotransferase,high-density lipoprotein cholesterol,aspartate aminotransferase,malondialdehyde,and glutathione peroxidase were measured,organ indices were calculated,and pathological sections of pancreas and liver were *** 16S rRNA V3–V4 region of intestinal flora was sequenced to explore the effect of SDP on biochemical indicators and intestinal *** on the above indicators,the anti-T2DM mechanism of SDP in Schisandra sphenanthera was ***:After six weeks of administration,the biochemical indices of diabetic rats were diminished compared to the control *** SDP could significantly increase the gut microbialα-diversity index,resulting in significant changes in the flora of T2DM rats,with increased richness and diversity,reduced harmful flora,and significantly back-regulated the levels of acetic acid,propionic acid,and butyric ***:SDP can improve the symptoms associated with elevated blood glucose,dyslipidemia,elevated fasting insulin levels,and damaged glucose tolerance in *** against T2DM may be through the control of intestinal flora to normalize and exert anti-diabetic effect;its main active components may be lignans and terpenoids.

关键词： Schisandra sphenanthera T2DM intestinal flora HPLC

Hemocholecyst caused by accidental injury associated with radiofrequency ablation for hepatocellular carcinoma:A case report

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World Journal of Clinical Cases 2023年第23期11卷 5610-5614页

作者： you-wen Tan Xin-Yue zhang Department of Hepatology The Third Hospital of Zhenjiang Affiliated Jiangsu UniversityZhenjiang 212003Jiangsu ProvinceChina

BACKGROUND Radiofrequency ablation(RFA)is an effective and safe treatment for hepatocellular carcinoma that features a lower incidence of serious complications than surgical *** caused by RFA is a rare complication of secondary damage to the intrahepatic bile duct that results in *** SUMMARY Here we report on a case of a hemocholecyst caused by accidental injury during RFA that induced hematemesis and *** subtraction angiography revealed no gallbladder arterial *** conservative treatment and transcatheter arterial chemoembolization,the patient’s condition stabilized,and she was discharged 1 wk *** Therefore,when performing interventional procedures such as RFA,clinicians must be vigilant because even minor injuries can lead to serious complications such as hemocholecyst.

关键词： Radiofrequency ablation Hepatocellular carcinoma Complication Case report Hepatitis B

Ωω States in a Chiral Quark Model

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Communications in Theoretical Physics 2007年第4X期48卷 695-698页

作者： WANG wen-Ling HUANG Fei zhang Zong-Ye YU you-wen LIU Feng Institute of Particle Physics Huazhong Normal University Wuhan 430079 China CCAST (World Laboratory) P.O. Box 8730 Beijing 100080 China Institute of High Energy Physics P.O. Box 918-4 Beijing 100049 China

The structures of Ωω states with spin-parity JP= 5/2^-, 3/2^-, and 1/2^- are dynamically studied in both the chlral SU（3） quark model and the extended chiral SU（3） quark model by solving a resonating group method （RGM） equation. The model parameters are taken from our previous work, which gave a satisfactory description of the energies of the baryon ground states, the binding energy of the deuteron, the nucleon-nucleon （NN） scattering phase shifts, and the hyperon-nucleon （YN） cross sections. The calculated results show that the Ωω state has an attractive interaction, and in the extended chiral SU（3） quark model such attraction can make for a Ωω quasi-bound state with spin-parity JP = 3/2^- or 5/2^- and the binding energy of about several MeV.

关键词： Ωω quasi-bound states quark model chiral symmetry

Reciprocal Regulation between Fur and Two RyhB Homologs in Yersinia pestis,and Roles of RyhBs in Biofilm Formation

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Biomedical and Environmental Sciences 2021年第4期34卷 299-308页

作者： NI Bin WU Hai Sheng XIN you Quan zhang Qing wen zhang Yi Quan School of Medicine Jiangsu UniversityZhenjiang 212013JiangsuChina Qinghai Institute for Endemic Disease Prevention and Control Xining 811602QinghaiChina Wuxi School of Medicine Jiangnan UniversityWuxi 214122JiangsuChina

Objective To investigate reciprocal regulation between Fur and two RyhB homologs in Yersinia pestis(***),as well as the roles of RyhBs in biofilm *** Regulatory relationships were assessed by a combination of colony morphology assay,primer extension,electrophoretic mobility shift assay and DNase I *** Fur bound to the promoter-proximal DNA regions of ryhB1 and ryhB2 to repress their transcription,while both RyhB1 and RyhB2 repressed the expression of Fur at the post-transcriptional *** addition,both RyhB1 and RyhB2 positively regulated *** biofilm exopolysaccharide(EPS)production and the expression of hmsHFRS and *** Fur and the two RyhB homologs exert negative reciprocal regulation,and RyhB homologs have a positive regulatory effect on biofilm formation in ***.

关键词： Yersinia pestis RyhB Fur Biofilm

Therapeutic plasma exchange and a double plasma molecular absorption system in the treatment of thyroid storm with severe liver injury: A case report

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World Journal of Clinical Cases 2019年第10期7卷 1184-1190页

作者： you-wen Tan Li Sun Kai zhang Li Zhu Department of Hepatology the Third Hospital of Zhenjiang Affiliated Jiangsu University

BACKGROUND Thyroid storm is resistant to conventional treatments including antithyroid drugs and 131I therapeutic *** exchange(PE)and double plasma molecular absorption system(DPMAS)can be used as an effective treatment for thyroid storm with severe liver *** SUMMARY A 52-year-old woman presented with a 10-day history of nausea and vomiting accompanied by yellowing of the skin and ***,her free T3(FT3)and FT4 levels were significantly elevated,whereas her thyrotropin level was *** admission,her condition continued to deteriorate,and she presented with continued high fever,vomiting,palpitation,and shortness of *** being diagnosed with thyroid storm,the patient was immediately treated with PE combined with *** symptoms improved *** three PE+DPMAS treatments,and she was discharged from the *** was treated with methylprednisolone and *** six months,the patient spontaneously discontinued methylthimidazole *** previous clinical manifestations and liver dysfunction *** patient was treated with PE+DPMAS two times,and her condition rapidly *** histopathology indicated immunological liver *** Our experience suggests that PE combined with DPMAS can effectively relieve the development of thyroid storm.

关键词： Plasma exchange Thyroid storm Immunological liver injury Case report