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Adsorption,selectivity,and phase behavior in organic nanopores for shale gas and oil development

Petroleum Research 2021年第3期6卷 187-203页

作者： Jinrong Cao Yunfeng Liang Yoshihiro Masuda Kohei Tamura Hiroyuki Tanaka Tomoaki Ishiwata yoshiharu ito Toshifumi Matsuoka Department ofSystemsInnovation TheUniversityofTokyoTokyo113-8656Japan Japan Oil GasandMetalsNationalCorporation(JOGMEC)Chiba261-0025Japan Fukada GeologicalInstitute Tokyo113-0021Japan

In a shale gas and oil reservoir,hydrocarbon fluids are stored in organic nanopores with sizes on the order of~1-100 *** adsorption,selectivity,and phase behavior of hydrocarbons in the nanopores are crucial for estimating the gas-in-place and predicting the *** this study,to understand the characteristics of the phase behavior of multicomponent hydrocarbon systems in shale reservoirs,the phase behavior of a CH_(4)/n-C_(4)H_(10)binary mixture in graphite nanopores was investigated by Grand Ca-nonical Monte Carlo(GCMC)molecular *** method for determining the dew-point pressure and bubble-point pressure in the nanopores was *** condensation phenomenon was observed owing to the difference in the adsorption selectivities of the hydrocarbon molecules on the nanopore surfaces,and hence the dew-point pressure(and bubble-point pressure)of hydrocarbon mixtures in the nanopores significantly *** GCMC simulations reproduced both the higher and lower bubble-point pressures in nanopores in previous *** work highlights the crucial role of the selec-tivity in the phase behavior of hydrocarbons in nanopores.

关键词： Shale gas and oil Nanopores Adsorption Selectivity Phase behavior Bubble point pressure Dew point pressure Molecular simulation

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Efficacy of a newly developed dilator for endoscopic ultrasound-guided biliary drainage

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World Journal of Gastrointestinal Endoscopy 2017年第7期9卷 304-309页

作者： Yoshihide Kanno Kei ito Shinsuke Koshita Takahisa Ogawa Kaori Masu yoshiharu Masaki Yutaka Noda Department of Gastroenterology Sendai City Medical CenterSendaiMiyagi 983-0824Japan

To evaluate the efficacy of a newly developed dilator for endoscopic ultrasound (EUS)-guided drainage (ES Dilator). METHODSFourteen consecutive patients who had undergone EUS-guided choledochoduodenostomy (EUS-CDS) with the ES Dilator were identified from a prospectively maintained database and enrolled in the study group. Fourteen other patients who had undergone EUS-CDS without the dilator just prior to its introduction were analyzed as the control group. A historical cohort study was carried out comparing the two groups. The main outcome measurement was the procedure time. The technical success rate and early AE rate were also compared between the two groups. RESULTSThere were no significant differences in age, sex and etiology of biliary obstruction. The utilization rate of a plastic stent was higher in the control group (36% vs 0%). The technical success rate was 100% in both groups. The mean procedure time was significantly shorter in the study group than in the control group (27 ± 7 min vs 44 ± 26 min, P = 0.026). Additionally, there were no patients who required more than 40 min for the procedure in the study group. Early adverse events occurred in 29% (4/14) of the control group whereas none in the study group. The adverse events in all 4 patients was bile peritonitis, including pan-peritonitis in one patient. All patients recovered with conservative treatment by medication. CONCLUSIONThe newly developed dilator was found to be useful for shortening procedure time and would prevent adverse events related to bile leakage in EUS-CDS.

关键词： Endoscopic ultrasound Dilation Adverse event ES Dilator Cautery

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