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Fabrication of zinc-based coordination polymer nano-cubes and post-modification through copper decoration

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Nano Research 2018年第11期11卷 5890-5901页

作者： Ngoc Minh Tran Hien Duy Mai Hyojong yoo Department of Chemistry Hallym University Chuncheon Gangwon-do 24252 Republic of Korea

Coordination polymer particles (CPPs) with a high degree of porosity and multi-functional reaction sites are promising for diverse applications. The integration of open sites favorable for the post-modification of CPPs presents a unique opportunity for the rational design of inorganic materials with target-oriented functions. Herein, we report a shape-controllable synthetic protocol for zinc-based coordination polymer nanocubes (Zn-CPNs). In the synthesis, 2,6-bis[(4-carboxyanilino)carbonyl] pyridine ([N3]) ligand is employed as an efficient shape-directing modulator to control the size and shape of Zn-CPNs. More importantly, the [N3] ligand provides metal binding sites suitable for the decoration of other functional metals such as copper ions. The copper-modified Zn-CPNs (Cu_Zn-CPNs) show good activities in a heterogeneous catalytic reaction.

关键词： zinc-based coordination polymer nanocubes shape-directing modulator size and shape controls post-modification heterogeneous catalytic reaction

Metadynamics sampling in atomic environment space for collecting training data for machine learning potentials

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npj Computational Materials 2021年第1期7卷 1171-1179页

作者： Dongsun yoo Jisu Jung Wonseok Jeong Seungwu Han Department of Materials Science and Engineering and Research Institute of Advanced Materials Seoul National UniversitySeoulKorea Samsung Display Co. Ltd.1Samsung-roGiheung-guYongin-siGyeonggi-doKorea

The universal mathematical form of machine-learning potentials(MLPs)shifts the core of development of interatomic potentials to collecting proper training ***,the training set should encompass diverse local atomic environments but conventional approaches are prone to sampling similar configurations repeatedly,mainly due to the Boltzmann *** such,practitioners handpick a large pool of distinct configurations manually,stretching the development period *** overcome this hurdle,methods are being proposed that automatically generate training ***,we suggest a sampling method optimized for gathering diverse yet relevant configurations *** is achieved by applying the metadynamics with the descriptor for the local atomic environment as a collective *** a result,the simulation is automatically steered toward unvisited local environment space such that each atom experiences diverse chemical environments without *** apply the proposed metadynamics sampling to H:Pt(111),GeTe,and Si *** these examples,a small number of metadynamics trajectories can provide reference structures necessary for training high-fidelity *** proposing a semiautomatic sampling method tuned for MLPs,the present work paves the way to wider applications of MLPs to many challenging applications.

关键词： dynamics collective stretching

Stick-and-play system based on interfacial adhesion control enhanced by micro/nanostructures

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Nano Research 2021年第9期14卷 3143-3158页

作者： Jung II yoo Seung Hyun Kim Heung Cho Ko School of Materials Science and Engineering Gwangju Institute of Science and Technology(GIST)Gwangju 61005Republic of Korea

The evolution of membrane-type electronics has facilitated the development of stick-and-play systems,which confer diverse electrical functions to various planar or arbitrary curvilinear *** stick-and-play concept is based on the development of thin electronic devices in a printable format and their subsequent transfer to target *** development of this technology requires control of the interfacial adhesion of the electronic prints for retrieval from a carrier and transfer to the target ***,we discuss the transfer printing for membrane-type electronics,starting from an overview of materials available for flexible substrates,transfer printing of electronic prints for retrieval,and assembly for further ***,we explain the stick-and-play concept based on fabricated membrane-type electronics;"stick" and “play"refer to the transfer of electronic devices and the performance of their electronic functions,*** particular,we broadly survey various methods based on micro/nanostructures,including gecko-inspired,interlocking,cephalopod-sucker-inspired,and cilia structures,which can be employed to stick-and-play systems for enhancing interfacial adhesion with complex target surfaces under dynamic and wet ***,we highlight the stick-and-play system application of micro/nanostructures for skin-attachable biomedical electronics,e-textiles,and environmental monitoring electronics.

关键词： transfer printing interfacial adhesion flexible electronics stick-and-play system bioinspired adhesive

Intestinal enteroids/organoids: A novel platform for drug discovery in inflammatory bowel diseases

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World Journal of Gastroenterology 2019年第30期25卷 4125-4147页

作者： Jun-Hwan yoo Mark Donowitz Department of Medicine Division of Gastroenterology and HepatologyJohns Hopkins University School of MedicineBaltimoreMD 21205United States Digestive Disease Center CHA Bundang Medical CenterCHA UniversitySeongnam 13496South Korea

The introduction of biologics such as anti-tumor necrosis factor(TNF)monoclonal antibodies followed by anti-integrins has dramatically changed the therapeutic paradigm of inflammatory bowel diseases(IBD).Furthermore,a newly developed anti-p40 subunit of interleukin(IL)-12 and IL-23(ustekinumab)has been recently approved in the United States for patients with moderate to severe Crohn’s disease who have failed treatment with ***,these immunosuppressive therapeutics which focus on anti-inflammatory mechanisms or immune cells still fail to achieve long-term remission in a significant percentage of *** strongly underlines the need to identify novel treatment targets beyond immune suppression to treat *** studies have revealed the critical role of intestinal epithelial cells(IECs)in the pathogenesis of ***,biochemical and immunologic driven barrier dysfunctions of epithelial cells contribute to the development of *** addition,the recent establishment of adult stem cell-derived intestinal enteroid/organoid culture technology has allowed an exciting opportunity to study human IECs comprising all normal epithelial *** long-term epithelial culture model can be generated from endoscopic biopsies or surgical resections and recapitulates the tissue of origin,representing a promising platform for novel drug discovery in *** review describes the advantages of intestinal enteroids/organoids as a research tool for intestinal diseases,introduces studies with these models in IBD,and gives a description of the current status of therapeutic approaches in ***,we provide an overview of the current endeavors to identify a novel drug target for IBD therapy based on studies with human enteroids/organoids and describe the challenges in using enteroids/organoids as an IBD model.

关键词： Enteroids Organoids Inflammatory bowel diseases Crohn’s disease Ulcerative colitis

The effects of video based peer-evaluation on communication skills and learning motivation in nursing students

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The effects of video based peer-evaluation on communication ...

Diffusionless-Like Transformation Unlocks Pseudocapacitance with Bulk Utilization: Reinventing Fe_(2)O_(3) in Alkaline Electrolyte

第一届上海国际护理大会

作者： moon Sook yoo Sun-Mi Chae Ajou University College of Nursing

Background: Communication is an essential element in nursing practice. Patients expressed low satisfaction at communication with nurses. Nursing students feel pressured on communication with patients and are not properly prepared to effectively communicate with the patients. Even newly graduated nurses also present communication with patients as the most difficult job in nursing practice. Hence communication skills should be learned and well trained throughout the college education in order to utilize the skills properly in clinical practice. Peer-evaluation in learning has been identified as an effective method in diverse populations of students from elementary students to adults. In addition, it has been demonstrated that peer-evaluation was useful to understand communication problems with patients in a sample of medical doctors. Peer-evaluation can improve learning motivation as well as communication skills of students. Among the visual audio devices, a video is the fastest method to facilitate comprehensive memory that leads to transmit learning. It has also been known as an effective method to develop a rapport with a patient and improve communication skills of health care practitioners. Objectives: This study aimed to investigate the effects of video based peer-evaluation on communication skills and learning motivation in nursing students. Methods: A non-equivalent control with pre-posttest design was used. The participants were 47 sophomore nursing students who enrolled in a course of fundamental nursing at a nursing college in South Korea in the Fall semester of 2008. Their grade point averages（GPA） were used to assign them to one of the groups;those with even numbers of GPA ranks were assigned to the intervention group and odd numbers to the control group. The intervention group had 24 students and the control group with 23 students. The nursing students in both groups performed history taking skills to a standardized patient, and the performance was videot

关键词： Peer-evaluation Communication skills Learning motivation Nursing students

来源： cnki会议评论

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Energy & Environmental Materials 2023年第1期6卷 145-154页

作者： Taowen Dong Wencai Yi Ting Deng Tingting Qin Xianyu Chu He Yang Lirong Zheng Seung Jo yoo Jin-Gyu Kim Zizhun Wang Yan Wang Wei Zhang Weitao Zheng State Key Laboratory of Automotive Simulation and Control and School of Materials Science&EngineeringKey Laboratory of Automobile Materials MOEand Electron Microscopy Centerand International Center of Future ScienceJilin UniversityChangchun 130012China Laboratory of High Pressure Physics and Material Science(HPPMS) School of Physics and Physical EngineeringQufu Normal UniversityQufu 273165China Beijing Synchrotron Radiation Facility Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China Electron Microscopy Research Center Korea Basic Science InstituteDaejeon 34133South Korea Wuhan National Laboratory for Optoelectronics Huazhong University of Science and TechnologyWuhan 430074China IKERBASQUE Basque Foundation for ScienceBilbao 48013Spain

Energy density can be substantially raised and even maximized if the bulk of an electrode material is fully *** metal oxides based on conversion reaction mechanism are the imperative choice due to either constructing nanostructure or intercalation pseudocapacitance with their intrinsic ***,the fully bulk utilization of transition metal oxides is hindered by the poor understanding of atomic-level conversion reaction mechanism,particularly it is largely missing at clarifying how the phase transformation(conversion reaction)determines the electrochemical performance such as power density and cyclic ***,α-Fe_(2)O_(3) is a case provided to claim how the diffusional and diffusionless transformation determine the electrochemical behaviors,as of its conversion reaction mechanism with fully bulk utilization in alkaline ***,the discharge productα-FeOOH diffusional from Fe(OH)2 is structurally identified as the atomic-level arch criminal for its cyclic stability deterioration,whereas the counterpartδ-FeOOH is theoretically diffusionless-like,unlocking the full potential of the pseudocapacitance with fully bulk ***,such pseudocapacitance,in proof-of-concept and termed as conversion pseudocapacitance,is achieved via diffusionless-like *** work not only provides an atomic-level perspective to reassess the potential electrochemical performance of the transition metal oxides electrode materials based on conversion reaction mechanism but also debuts a new paradigm for pseudocapacitance.

关键词： bulk utilization,conversion pseudocapacitance diffusionless transformation Fe_(2)O_(3) phase transformation

Earth rotation deceleration/acceleration due to semidiurnal oceanic/atmospheric tides:Revisited with new calculation

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Geodesy and Geodynamics 2019年第1期10卷 37-41页

作者： Sung-Ho Na Wenbin Shen Jungho Cho Kiweon Seo Young-Hong Shin Kwan-Dong Park Kookyoun Youm Sung-moon yoo KASI-SLR Observatory(on Leave from Ajou University) 276-73 Wolsangongdan-roSejong30060Republic of Korea Department of Geophysics School of Geodesy and GeomaticsKey Laboratory of Geospace Environment and Geodesy of Ministry of EducationWuhan UniversityWuhan430079China Korea Astronomy and Space Science 776 Daedeok-DaeroYuseong-GuDaejeon34055Republic of Korea Seoul National University Seoul08826Republic of Korea Korea Institute of Geoscience and Mineral Resources Republic of Korea Inha University 22207Republic of Korea

The global oceanic/atmospheric tides exert decelerating/accelerating secular torques on the Earth rotation. We developed new formulations to accurately calculate amounts of two kinds of secular tidal torques. After Melchior, we found that an additional factor 1+k-l = 1.216, which has been formerly neglected, must be multiplied unto the tidal torque integral. By using our refined formulations and the recent oceanic/atmospheric global tide models, we found that:(i) semidiurnal oceanic lunar/solar tides exert decelerating torques of about-4.462 × 10^(16)/-0.676 × 10^(16) Nm respectively and(ii) atmospheric S_2 tide exerts accelerating torque of 1.55 × 10^(15) Nm. Former estimates of the atmospheric S_2 tidal torque were twice as large as our estimate due to improper consideration of loading effect. We took the load Love number for atmospheric loading effect from Guo et al.(2004). For atmospheric loading of spherical harmonic degree two, the value of k′=-0.6031 is different from that for ocean loading as k′ =-0.3052,while the latter is currently used for both cases-ocean/atmospheric loading-without distinction. We discuss(i) the amount of solid Earth tidal dissipation(which has been left most uncertain) and(ii) secular changes of the dynamical state of the Earth-moon-Sun system. Our estimate of the solid Earth tidal torque is-4.94×10^(15) Nm.

关键词： Earth rotation Oceanic and atmospheric tides Tidal torque Secular deceleration and acceleration

UHPC键齿湿接缝直剪试验及湿接缝直剪承载力统一公式

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土木工程学报 2022年第6期55卷 79-91页

作者：冯峥李传习周佳乐董创文柯红军 yoo Doo-Yeol 长沙理工大学桥梁与建筑绿色建造与维护湖南省重点实验室湖南长沙410004 长沙理工大学桥梁工程安全控制教育部重点实验室湖南长沙410004 汉阳大学韩国首尔04763

为得到UHPC键齿湿接缝的直剪受力性能及直剪承载力统一公式,开展17个UHPC试件的直剪推出试验,考察键齿形状、侧向应力等对UHPC键齿湿接缝直剪破坏模式、裂纹发展情况、直剪强度以及剪切滑移性能的影响,并结合前期24个UHPC整体浇筑试件... 详细信息

为得到UHPC键齿湿接缝的直剪受力性能及直剪承载力统一公式,开展17个UHPC试件的直剪推出试验,考察键齿形状、侧向应力等对UHPC键齿湿接缝直剪破坏模式、裂纹发展情况、直剪强度以及剪切滑移性能的影响,并结合前期24个UHPC整体浇筑试件和24个UHPC平(湿)接缝试件的试验结果对UHPC界面直剪承载力计算方法进行研究。结果表明:UHPC键齿接缝试件的剪切破坏过程可分为线弹性阶段、裂纹发展阶段、破坏阶段和残余应力阶段;各键齿接缝直剪破坏界面与剪切界面几乎重合;梯形(键齿夹角113°)、矩形、倒梯形(键齿夹角65°)等三种键齿形式的直剪性能基本相同,为方便施工,工程中键齿宜选用梯形;键齿接缝试件的初裂强度、峰值强度提升值(相对于平接缝)与整体试件相应强度提升值之比远小于两者剪切面的整体面积之比;无侧向应力下,UHPC键齿接缝试件的剪切刚度和峰值强度均大于平接缝试件,逊于整体试件,且差距较大;键齿接缝试件峰值强度为整体试件的52.5%;在5MPa侧向应力下,平接缝试件与各键齿接缝试件剪切刚度已差别不大,峰值强度差值变小;键齿接缝试件的峰裂比(峰值强度与初裂强度之比)为1.173~1.319;键齿接缝试件的剪切刚度、延性系数、初裂强度、峰值强度及剪切滑移能力均随着侧向应力的增大而增大;UHPC湿接缝试件初裂强度和峰值强度随侧向应力的增长规律符合库伦准则,其摩擦系数可取1.26。最后,建立物理意义明确、形式简单、精度较高的可适用于未配抗剪钢筋UHPC整体界面、平湿接缝界面和键齿湿接缝界面的直剪承载力计算统一公式。

关键词：桥梁工程超高性能混凝土(UHPC) 直接剪切性能湿接缝界面键齿形状侧向应力直剪承载力

Direct synthesis of highly conductive poly（3,4- ethylenedioxythiophene）：poly（4-styrenesulfonate）（PEDOT：PSS）/graphene composites and their applications in energy harvesting systems

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Nano Research 2014年第5期7卷 717-730页

作者： Dohyuk yoo Jeonghun Kim Jung Hyun Kim Department of Chemical and Biomolecular Engineering Yonsei University 50 Yonsei-ro Seodaemun-gu Seou1120-749 Republic of Korea Electronic Materials Division R&D Center Dongjin Semichem Co. Ltd. 625-3 Yodang-Ri Yanggam-Myeon Hwaseong-Gun Gyeonggi-Do Republic of Korea

We report for the first time highly conductive poly(3,4-ethylenedioxythiophene): poly(4-styrenesulfonate) (PEDOT:PSS)/graphene composites fabricated by in situ polymerization and their applications in a thermoelectric device and a platinum (Pt)-free dye-sensitized solar cell (DSSC) as energy harvesting systems. Graphene was dispersed in a solution of poly(4-styrenesulfonate) (PSS) and polymerization was directly carried out by addition of 3,4-ethylenedioxythiophene (EDOT) monomer to the dispersion. The content of the graphene was varied and optimized to give the highest electrical conductivity. The composite solution was ready to use without any reduction process because reduced graphene oxide was used. The fabricated film had a conductivity of 637 S·cm−1, corresponding to an enhancement of 41%, after the introduction of 3 wt.% graphene without any further complicated reduction processes of graphene being required. The highly conductive composite films were employed in an organic thermoelectric device, and the device showed a power factor of 45.7 μW·m−1K−2 which is 93% higher than a device based on pristine PEDOT:PSS. In addition, the highly conductive composite films were used in Pt-free DSSCs, showing an energy conversion efficiency of 5.4%, which is 21% higher than that of a DSSC based on PEDOT:PSS.

关键词：石墨复合材料能量转换效率 PEDOT 高导电性器件应用采集系统 PSS 磺酸盐