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Preparation of 3D graphene-based architectures and their applications in supercapacitors

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Progress in Natural Science:Materials International 2015年第6期25卷 554-562页

作者： Zhuxian Yang Sakineh Chabi yongde xia Yanqiu Zhu College of Engineering Mathematics and Physical SciencesUniversity of Exeter

Three dimensional(3D) graphene-based architectures such as 3D graphene-based hydrogels,aerogels,foams,and sponges have attracted huge attention owing to the combination of the structural interconnectivities and the outstanding properties of graphene which offer these interesting structures with low density,high porosity,large surface area,stable mechanical properties,fast mass and electron *** have been extensively studied for a wide range of applications including capacitors,batteries,sensors,catalyst,*** are several reviews focusing on the 3D graphene-based architectures and their *** this work,we only summarise the latest development on the preparation of 3D graphene-based architectures and their applications in supercapacitors,with emphasis on the preparation strategies.

关键词： 3D-graphene Supercapacitor Electrode architecture

Ultralight three-dimensional,carbon-based nanocomposites for thermal energy storage

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Journal of Materials Science & Technology 2020年第1期36卷 70-78页

作者： Oluwafunmilola Ola Yu Chen Qijian Niu yongde xia Tapas Mallick Yanqiu Zhu College of Engineering Mathematics and Physical SciencesUniversity of ExeterEX44QFUnited Kingdom Key Laboratory of Carbon Fiber and Functional Polymers.Ministry of Education Changzhou Institute of Advanced Materials ResearchBeijing University of Chemical TechnologyBeijing100029China

Polymer based nanocomposites consisting of elastic three-dimensional(3 D)carbon foam(CF),paraffin wax and graphene nanoplatelets(GNPs)have been created and evaluated for thermal energy *** ultralight,highly porous(~98.6%porosity),and flexible CFs with densities of2.84-5.26 mg/cm^3 have been used as the backbone skeleton to accommodate phase change wax and nanoscale thermal conductive enhancer,*** level of defects and the ordered sp2 configuration allow the resulting CFs to exhibit excellent cyclic compressive behavior at strains up to 95%,while retaining part of their elastic properties even after 100 cycles of *** dispersing the highly conductive GNP nanofillers in paraffin wax and infiltrating them into the flexible CFs,the resultant nanocomposites were observed to possess enhanced overall thermal conductivity up to 0.76 W/(m K),representing an impressive improvement of226%,which is highly desirable for thermal engineering.

关键词： Nanocomposites Foam Thermal properties Compressive properties

Bimetallic Fe-Mo sulfide/carbon nanocomposites derived from phosphomolybdic acid encapsulated MOF for efficient hydrogen generation

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Journal of Materials Science & Technology 2021年第25期84卷 76-85页

作者： Zheng Huang Zhuxian Yang Mian Zahid Hussain Quanli Jia Yanqiu Zhu yongde xia College of Engineering Mathematics and Physical SciencesUniversity of ExeterExeter EX44QFUK Hennan Key Laboratory of High Temperature Functional Ceramics Zhengzhou UniversityZhengzhou450052China

To tackle the energy crisis and achieve more sustainable development,hydrogen as a clean and renewable energy resource has attracted great *** for cheap but efficient catalysts for hydrogen production from water splitting is urgently *** this report,bimetallic Fe-Mo sulfide/carbon nanocomposites that derived from a polyoxometalate phosphomolybdic acid encapsulated metal-organic framework MIL-100(PMA@MIL-100)have been generated and their applications in electrocatalytic hydrogen generation were *** PMA@MIL-100 precursor is formed via a simple one-pot hydrothermal synthesis method and the bimetallic Fe-Mo sulfide/carbon nanocomposites were obtained by chemical vapor sulfurization of PMA@MIL-100 at high *** nanocomposite samples were fully characterized by a series of techniques including X-ray diffraction,Fourier-transform infrared analysis,thermogravimetric analysis,N2 gas sorption,scanning electron microscopy,transmission electron microscopy,X-ray photoelectron spectroscopy,and were further investigated as electrocatalysts for hydrogen production from water *** hydrogen production activity of the best performed bimetallic Fe-Mo sulfide/carbon nanocomposite exhibits an overpotential of-0.321 V at 10 m A cm^(-2)and a Tafel slope of 62 m V dec^(-1)with a 53%reduction in overpotential compared to Mo-free counterpart *** dramatic improvement in catalytic performance of the Fe-Mo sulfide/carbon composite is attributed to the homogeneous distribution of the nanosized iron sulfide,MoS_(2)particles,and the formation of Fe-Mo-S phases in the S-doped porous carbon *** work has demonstrated a potential approach to fabricate complex heterogeneous catalytic materials for different applications.

关键词： MOF Nanocomposite Encapsulation Metal sulfide Hydrogen generation

Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient multifunctional electrocatalysts

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Frontiers of Chemical Science and Engineering 2021年第6期15卷 1487-1499页

作者： Laicong Deng Zhuxian Yang Rong Li Binling Chen Quanli Jia Yanqiu Zhu yongde xia College of Engineering Mathematics and Physical SciencesUniversity of ExeterExeterEX44QFUK Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province College of Chemistry and Chemical EngineeringChina West Normal UniversityNanchong637000China Henan Key Laboratory of High Temperature Functional Ceramics Zhengzhou UniversityZhengzhou450052China

Developing cost-effective electrocatalysts for oxygen reduction reaction(ORR),oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)is vital in energy conversion and storage ***,we report a simple method for the synthesis of graphene-reinforced CoS/C nanocomposites and the evaluation of their electrocatalytic performance for typical electrocatalytic *** of CoS embedded in N,S co-doped porous carbon and graphene(CoS@C/Graphene)were generated via simultaneous sulfurization and carbonization of one-pot synthesized graphite oxide-ZIF-67 *** obtained CoS@C/Graphene nanocomposites were characterized by X-ray diffraction,Raman spectroscopy,thermogravimetric analysis-mass spectroscopy,scanning electronic microscopy,transmission electronic microscopy,X-ray photoelectron spectroscopy and gas *** is found that CoS nanoparticles homogenously dispersed in the in situ formed N,S co-doped porous carbon/graphene *** CoS@C/10Graphene composite not only shows excellent electrocatalytic activity toward ORR with high onset potential of 0.89 V,four-electron pathway and superior durability of maintaining 98%of current after continuously running for around 5 h,but also exhibits good performance for OER and HER,due to the improved electrical conductivity,increased catalytic active sites and connectivity between the electrocatalytic active CoS and the carbon *** work offers a new approach for the development of novel multifunctional nanocomposites for the next generation of energy conversion and storage applications.

关键词： MOF derivative graphene electrocatalyst oxygen reduction reaction oxygen evolution reaction hydrogen evolution reaction

n -BUTANE ISOMERIZATION OVER PERSULFATE MODIFIED Al2O3 ZrO2 CATALYSTS

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Chinese Journal of Catalysis 1999年第5期20卷 487-488页

作者： xia yongde, Hua Weiming, Gao Zi (Department of Chemistry, Fudan University, Shanghai 200433) 复旦大学化学系上海 200433

The conversion of n-butane to isobutane over strong acid catalysts is an important process in the petrochemical refining industry, because isobutane is a valuable precursor to methyl-tert-butyl ether and other fuel additives. Many reports dealing with sulfate promoted zirconia as catalysts for n-butane isomerization have appeared[1, 2].

关键词： ywords n butane isomerization persulfated zirconia alumina acid strength distribution

Construction of hydrangea-like core-shell SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi microspheres for tunable electromagnetic wave absorbers

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Journal of Advanced Ceramics 2023年第4期12卷 711-723页

作者： Huanhuan Niu Xuewen Jiang yongde xia Hailong Wang Rui Zhang Hongxia Li Bingbing Fan Yanchun Zhoua School of Material Science&Engineering Zhengzhou UniversityZhengzhou 450001China Department of Engineering University of ExeterExeter EX44SBUK School of Materials Science and Engineering Luoyang Institute of Science and TechnologyLuoyang 471023China Sinostel Luoyang Institute of Refractories Research Co. Ltd.Luoyang 471039China

Ti_(3)C_(2)T_(x)MXene shows great potential in the application as microwave absorbers due to its high attenuation ***,excessively high permittivity and self-stacking are the main obstacles that constrain its wide range of *** tackle these problems,herein,the microspheres of SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi with the hydrangea-like core-shell structure were designed and prepared by a combinatorial electrostatic assembly and hydrothermal reaction *** microspheres are constructed by an outside layer of CoNi nanosheets and intermediate Ti_(3)C_(2)T_(x)MXene nanosheets wrapping on the core of modified SiO_(2),engendering both homogenous and heterogeneous *** trilayer SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi microspheres are“magnetic microsize supercapacitors”that can not only induce dielectric loss and magnetic loss but also provide multilayer interfaces to enhance the interfacial *** optimized impedance matching and core-shell structure could boost the reflection loss(RL)by electromagnetic *** synthesized SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi microspheres demonstrate outstanding microwave absorption(MA)performance benefited from these *** obtained RL value was-63.95 dB at an ultra-thin thickness of 1.2 mm,corresponding to an effective absorption bandwidth(EAB)of 4.56 *** work demonstrates that the trilayer core-shell structure designing strategy is highly efficient for tuning the MA performance of MXene-based microspheres.

关键词： SiO_(2)@Ti_(3)C_(2)T_(x)@CoNi hydrangea-like core-shell structure spherical capacitor high-performance microwave absorption(MA) interfacial polarization impedance match

Metal-organic framework derived multi-functionalized and co-doped TiO_(2)/C nanocomposites for excellent visible-light photocatalysis

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Journal of Materials Science & Technology 2022年第6期101卷 49-59页

作者： Mian Zahid Hussain Zhuxian Yang Ahmed M.E.Khalil Shahzad Hussain Saif Ullah Awan Quanli Jia Roland A.Fischer Yanqiu Zhu yongde xia College of Engineering Mathematics and Physical SciencesUniversity of ExeterExeter EX44QFUnited Kingdom Department of Chemistry and Catalysis Research Centre Technical University of MunichGarching85748Germany Department of Chemical Engineering Faculty of EngineeringCairo UniversityGiza 12613Egypt Department of Physics COMSATS University Islamabad45550 Pakistan Department of Electrical Engineering National University of Sciences and TechnologyIslamabadPakistan Henan Key Laboratory of High Temperature Functional Ceramics Zhengzhou UniversityZhengzhou 450052China

Multi-functionalized and co-doped TiO_(2)/C nanocomposites were derived from the pyrolysis of Ti-MOFs at 800℃under different gaseous atmospheres and their photocatalytic performance were *** gaseous atmosphere during pyrolysis plays a critical role in determining the structural,textural,optical and physicochemical properties of the derived TiO_(2)/C composites due to the synergistic effect of nitrogen-containing species,carboxylate and sulfur functionalized porous carbon as well as N/S co-doped TiO_(2)*** the Ti-MOFs derived TiO_(2)/C composites exclusively possess homogeneously distributed TiO_(2)nanoparticles in a functionalized disc-like porous carbon matrix and demonstrate much enhanced adsorption and photodegradation performance than commercial TiO_(2)under the same *** adsorption of methylene blue(MB)in dark on these TiO_(2)/C composites are dominated with pseudo second-order kinetic model and the high adsorption capacity of MB in dark on composite TiO_(2)/C derived from MIL-125(Ti)in argon is due to its high surface area with predominant mesoporous carbon matrix in the *** composite N-O-TiO_(2)/C derived from NH2-MIL-125(Ti)in water vapor exhibited the highest photodegradation activity with 99.7%MB removal in 3 h under visible light due to the optimal anatase/rutile phasejunction,together with the formation of photoactive oxygen-rich N-O like interstitial/intraband states above the valence band of TiO_(2),as well as the presence of N-containing species and-OH/-COOH multi-functional groups with superhydrophilic nature of the *** simple one-step and easily modifiable approach can be further employed to modulate homogeneously dispersed multi-functionalized and co-doped metal oxide/carbon nanocomposites for various environment and energy-related applications.

关键词： Nanocomposite MOF derivative TiO_(2) Porous carbon Photocatalysis

Surface functionalized N-C-TiO_(2)/C nanocomposites derived from metal-organic framework in water vapour for enhanced photocatalytic H generation

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Journal of Energy Chemistry 2021年第6期30卷 485-495,I0012页

作者： Mian Zahid Hussain Zhuxian Yang Bart van der Linden Zheng Huang Quanli Jia Erik Cerrato Roland A.Fischer Freek Kapteijn Yanqiu Zhu yongde xia College of Engineering Mathematics and Physical SciencesUniversity of ExeterExeter EX44QFUnited Kingdom Department of Chemistry and Catalysis Research Center Technical University of MunichGarching 85748Germany Catalysis Engineering Chemical Engineering DepartmentDelft University of Technologyvan der Maasweg92629 HZ DelftNetherlands Henan Key Laboratory of High Temperature Functional Ceramics Zhengzhou UniversityZhengzhou 450052HenanChina Department of Chemistry University of TurinVia P.Giuria710125 TurinItaly

Surface-functionalized nitrogen/carbon co-doped polymorphic TiO_(2) phase junction nanoparticles uniformly distributed in porous carbon matrix were synthesized by a simple one-step pyrolysis of titanium based metal-organic framework(MOF),NH_(2)-MIL^(-1)25(Ti) at 700℃ under water vapour *** water vapour during the pyrolysis of NH_(2)-MIL^(-1)25(Ti) not only functionalizes the derived porous carbon matrix with carboxyl groups but also forms additional oxygen-rich N like interstitial/intraband states lying above the valence band of TiO2 along with the self-doped carbo n,which further narrows the energy band gaps of polymorphic TiO2 nanoparticles that enhance photocatalytic charge transfer *** co-catalyst,sample N-C-TiO2/CArW demonstrates H_(2) evolution activity of 426 μmol gcat-1h^(-1),which remarkably outperforms commercial TiO_(2)(P-25) and N-C-TiO_(2)/CAr with a 5-fold and 3-fold H_(2) generation,*** study clearly shows that water vapour atmosphere during the pyrolysis increases the hydrophilicity of the Ti-MOF derived composites by functionalizing porous carbon matrix with carboxylic groups,as well as enhancing the electrical conductivity and charge transfer efficiency due to the formation of additional localized oxygen-rich N like interstitial/intraband *** work also demonstrates that by optimizing the anatase-rutile phase composition of the TiO2 polymorphs,tuning the energy band gaps by N/C co-doping and functionalizing the porous carbon matrix in the N-C-TiO2/C nanocomposites,the photocatalytic H_(2) generation activity can be further enhanced.

关键词： Metal-organic framework TiO_(2) Porous carbon Nanocomposite Photocatalysis Hydrogen generation

Functional Nanoporous Carbon Materials for Energy Gases Storage

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Functional Nanoporous Carbon Materials for Energy Gases Stor...