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Lithium sulfide nanocrystals as cathode materials for advanced batteries

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Journal of Energy Chemistry 2021年第12期30卷 138-169,I0004页

作者： Fengming Wan Liran Fang Xin Zhang Colin A.Wolden yongan yang Institute of Molecular Plus Tianjin UniversityTianjin 300072China Department of Chemical and Biological Engineering Colorado School of Mines1613 Illinois StreetGoldenCO 80401United States

The ever-increasing need for sustainable development requires advanced battery techniques beyond the current generation of lithium ion *** all candidates being explored,lithium-sulfur batteries are a very promising system to be commercialized in the near *** this end,the development of lithium sulfide(Li_(2)S)nanocrystal-based cathodes has received tremendous effort and witnessed multiple *** from the focus on performance improvement in previous reviews,this review summarizes the research progress in line with the approaches of materials synthesis and electrode *** key chemistry,operation procedure,materials characterizations and performance assessments are all given a balanced ***,all approaches are collectively analyzed along the lines of six criteria towards practical applications,i.e.,electrode performance,materials quality,resources sustainability,production cost,operation procedure,and consumed ***,some perspective viewpoints on the future research directions are offered.

关键词： Lithium sulfide Nanocrystals Cathode materials Advanced batteries

Design and realization of a novel multitask TT&C operation pattern

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Journal of Systems Engineering and Electronics 2008年第6期19卷 1243-1249页

作者： yang yongan Han Minzhang Feng Zuren Fan Henghai Bai Jian Xi'an Jiaotong Univ. Xi'an 710049 P. R. China Xi'an Satellite Control Center Xi'an 710043 P. R. China

With the sharp increase of China＇s in-orbit spacecraft and the constraint TT＆C resources, a mathematical model for optimal TT＆C resource allocation is proposed, and the TT＆C facility remote monitoring function is designed to achieve the multitask operation pattern under the unified management of the network management center. With this pattern, the TT＆C network management and the spacecraft management are separated, which is quite different from the previous pattern. Further, a novel spacecraft TT＆C technique based on spacecraft control language is developed, and the telecommanding pattern is designed to address the spacecraft operation problems. The engineering application shows that this pattern fundamentally improves the TT＆C network capability, increases the resource efficiency, and satisfies the efficient, accurate, and flexible operation of spacecraft.

关键词： spacecraft TT&C network multitask TT&C administration design and realization.

1D/2D composite subnanometer channels for ion transport:The role of confined water

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Nano Research 2023年第8期16卷 10913-10921页

作者： Yuhao Li Xiaorui Jin Xinhai Yan Xinyu Ai Xin yang Zi-Jian Zheng Kun Huang Gaofeng Zhao yongan yang Meiling Wu Kai-Ge Zhou Institute of Molecular Plus Department of ChemistryTianjin UniversityTianjin 300072China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials Hubei Key Laboratory of Polymer MaterialsHubei UniversityWuhan 430062China School of Chemical Engineering and Analytical Science National Graphene InstituteUniversity of ManchesterManchesterM139PLUK School of Civil Engineering Tianjin UniversityTianjin 300072China

As a mass transport media,water is an alternative of organic solvent applied in rechargeable batteries,due to its unique properties,including fast ionic migration,easy-processibility,economic/environmental friendliness,and flame ***,due to the high activity of water molecules in aqueous electrolytes,the corrosion of metal anode,side reactions,and inferior metal electrodeposition behavior leads to unstable cycling performance,poor Coulombic efficiency(CE),and early-staged failure of *** several attempts to regulate the activity of water,migration of ions is sacrificed,due to the limited methods to control the water ***,we developed a subnanoscale confinement strategy based on a nacre-like structure to modulate the activity of water in the solid *** tuning the ratio between the two-dimensional(2D)vermiculite and one-dimensional(1D)cellulose nanofibers(CNFs),the capillary size in the 1D/2D structure is altered to achieve a fast Zn^(2+)*** dielectric relaxation and molecular dynamics studies indicate that the enhanced Zn^(2+)conductivity is attributed to the fast water relaxation in the precisely defined 1D/2D *** advantage of the regulated activity of the confined water in 2D capillary,the composite vermiculite membrane can suppress the corrosion and side reactions between Zn electrode and water molecular,endowing a reversible Zn^(2+)stripping/plating behavior and a stable cycling performance for 900 *** on our confinement strategy to control the water states by 1D/2D structures,this work will open an avenue toward aqueous energy storage devices with excellent reversibility,high safety,and long-term stability.

关键词： ion transport subnanometer channels confined water aqueous electrolyte limited side reactions

A universal performance-enhancing method for Li-S batteries:the cathode material of Li_(2)S@Li_(2)S_(2)@Li_(2)S_(6) double-shell structure

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Science China Chemistry 2024年第4期67卷 1229-1241页

作者： Shunjin yang Yujiang Sun Qiaran Zhang Xiaohu Hu Xing Chen Guoran Li Xiao Sun Yuzhe Zhang Shijie Xu Xinyu Wang yongan yang Institute of Molecular Plus School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China College of Materials Science and Engineering Nankai UniversityTianjin 300350China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage Tianjin 300072China

Lithium sulfide(Li_(2)S)as a cathode material for lithium-sulfur(Li-S)batteries,one of the most promising advanced batteries in the future,has received tremendous attention in the past ***,developing the practical Li_(2)S cathode confronts challenges of low conductivity for Li-ions and electrons,high sensitivity to environmental moisture,big overpotential barrier to electrochemical activation,and poor cyclability due to the shuttle effect of intermediate *** article herein reports a simple and effective strategy for making Li_(2)S@Li_(2)S_(2)@Li_(2)S_(6) double-shelled microparticles,which can significantly mitigate these *** are synthesized by dissolving Li2S together with S in dimethoxyethane,then drying off the solvent,and finally calcining the collected *** with pure Li_(2)S,such a double-shell material presents a 26.7% improvement in cycling capacity,0.5 V lower in activation overpotential,and prolonged tolerance in the ambient *** density functional theory calculation shows that the performance enhancement lies in the higher stability of Li2S6in contact with moisture and some autocatalytic effect of Li_(2)S_(2)@Li_(2)S_(6).Such a double-shell structure becomes a universal performanceenhancing approach when being combined with other means,such as cathodes composited with catalytic MoS_(2),separators modified with selenium-doped sulfurized-polyacrylonitrile/montmorillonite,electrolytes containing fluorenone additive,and Li anodes coated with a layer of Li_(3)*** corresponding capacity retention shows up to 80%improvement compared with pure Li_(2)S.

关键词： lithium-sulfur batteries lithium sulfide lithium polysulfides cathode performance double shell structure

Moderate sewage sludge biochar application on alkaline soil for corn growth:a field study

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Biochar 2021年第2期3卷 135-147页

作者： Shengyu Xie Guangwei Yu Ruqing Jiang Jianli Ma Xiaofu Shang Gang Wang Yin Wang yongan yang Chunxing Li CAS Key Laboratory of Urban Pollutant Conversion Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Graduate School of Environmental Studies Tohoku University6‑6‑07 AobaAramaki‑azaAoba‑kuSendaiMiyagi 980‑8579Japan Tianjin Academy of Environmental Sciences Tianjin 300191China Tianjin High Quality Agricultural Products Development Demonstration Center Tianjin 301508China Department of Environmental Engineering Technical University of Denmark2800 Kongens LyngbyDenmark

In view of the risks induced by the inhibitory effects of applying impracticably large amounts of sewage sludge biochar(SSB)to the alkaline soil,this field study investigated the influence of moderate biochar amendments(0,1500,4500,and 9000 kg/hm2)on corn growth,alkaline soil properties,and the uptake of potentially toxic elements(PTEs).The results showed that applying more SSB would decrease the ammonium nitrogen concentration and increase the available phosphorus and potassium concentrations,which inhibited corn plant growth because of high background nutrient levels of the alkaline *** the alkaline soil was amended with 1500 kg/hm2 SSB,the dry weight of 100 niblets increased from 32.11 g in the control to 35.07 *** was no significant variation in the total concentration of PTEs in the *** concentrations of Mn,Ni,Cu,and Zn in niblets decreased from 5.54,0.83,2.26,and 27.15 mg/kg in the control to 4.47,0.62,1.30,and 23.45 mg/kg,***,the health risk from corn consumption was significantly ***,the combination of SSB and fertilizer improved corn growth and reduced the risk of consumption of ***,considering the increase in corn fruit yield and the decrease in consumption risk,applying 1500 kg/hm2 of biochar to alkaline soils is a realistically achievable rate,which can broaden the utilization of SSB for remediation of different types of soil.

关键词： Sewage sludge biochar Alkaline soil Corn growth Soil property Potentially toxic elements Soil remediation

Fluorine-Doped High-Performance Li_(6)PS_(5)Cl Electrolyte by Lithium Fluoride Nanoparticles for All-Solid-State Lithium-Metal Batteries

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Transactions of Tianjin University 2024年第3期30卷 250-261页

作者： Xiaorou Cao Shijie Xu Yuzhe Zhang Xiaohu Hu Yifan Yan Yanru Wang Haoran Qian Jiakai Wang Haolong Chang Fangyi Cheng yongan yang Institute of Molecular Plus School of Chemical Engineering and TechnologyTianjin UniversityTianjin 300072China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China

All-solid-state lithium-metal batteries(ASSLMBs)are widely considered as the ultimately advanced lithium batteries owing to their improved energy density and enhanced safety *** various solid electrolytes,sulfide solid electrolyte(SSE)Li_(6)PS_(5)Cl has garnered significant ***,its application is limited by its poor cyclability and low critical current density(CCD).In this study,we introduce a novel approach to enhance the performance of Li_(6)PS_(5)Cl by doping it with fluorine,using lithium fluoride nanoparticles(LiFs)as the doping *** F-doped electrolyte Li_(6)PS_(5)Cl-0.2LiF(nano)shows a doubled CCD,from 0.5 to 1.0 mA/cm^(2) without compromising the ionic conductivity;in fact,conductivity is enhanced from 2.82 to 3.30 mS/cm,contrary to the typical performance decline seen in conventionally doped Li_(6)PS_(5)Cl *** symmetric Li|SSE|Li cells,the lifetime of Li_(6)PS_(5)Cl-0.2LiF(nano)is 4 times longer than that of Li_(6)PS_(5)Cl,achieving 1500 h vs.371 h under a charging/discharging current density of 0.2 mA/cm^(2).In Li|SSE|LiNbO_(3)@NCM721 full cells,which are tested under a cycling rate of 0.1 C at 30℃,the lifetime of Li_(6)PS_(5)Cl-0.2LiF(nano)is four times that of Li_(6)PS_(5)Cl,reaching 100 cycles vs.26 ***,the doping of nano-LiF off ers a promising approach to developing high-performance Li_(6)PS_(5)Cl for ASSLMBs.

关键词： Sulfide solid electrolyte All-solid-state lithium batteries Li_(6)PS_(5)Cl Lithium fluoride F-doping

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TC18钛合金绝热剪切带晶粒细化机制

稀有金属材料与工程 2011年第8期40卷 1454-1457页

作者：徐媛孙坤杨永安楚雄师范学院云南楚雄675000

采用分离式霍普金森压杆,对TC18钛合金试样进行室温高应变率(103s-1)剪切试验,通过光学显微镜、扫描电镜及透射电镜观察绝热剪切带微结构,研究高应变率变形条件下TC18钛合金中所形成绝热剪切带的晶粒细化机制。TEM观察表明:绝热剪切带... 详细信息

采用分离式霍普金森压杆,对TC18钛合金试样进行室温高应变率(103s-1)剪切试验,通过光学显微镜、扫描电镜及透射电镜观察绝热剪切带微结构,研究高应变率变形条件下TC18钛合金中所形成绝热剪切带的晶粒细化机制。TEM观察表明:绝热剪切带中晶粒细化是由3种机制共同作用的结果。第1种机制是由于变形晶粒中位错快速增殖、快速运动、塞积,塞积处产生巨大应力集中,导致形成裂纹并最终断裂形成细小晶粒;第2种机制为本研究提出的细小晶粒由拉长晶粒的"内颈缩"方式形成;第3种机制——细小晶粒由动态再结晶形成。

关键词： TC18钛合金绝热剪切带晶粒细化机制内颈缩

Characterization and Mitigation of BeiDou Triple-Frequency Code Multipath Bias

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Characterization and Mitigation of BeiDou Triple-Frequency C...

第九届中国卫星导航学术年会

作者： Xing Wang Guoqiang Zhao Feng Zhang yongan yang State Key Laboratory of Astronautic Dynamics

Regarding the problem of systematic multipath bias on Bei Dou navigation system code observations, ten days Bei Dou triple-frequency observations of multi-stations were collected, the relationships between the characteristic of multipath bias and the type of the satellite, the signal frequency and the satellite elevation angle were analyse d. In order to solve this problem, a modified sidereal filtering based on zero-phase filter was proposed to mitigate the multipath bias on GEO and IGSO satellites code observations, and elevation-angle correction method was introduced to decrease the multipath bias of IGSO and MEO satellite code observations. The experimental results show that the modified sidereal filtering can decrease the multipath bias of B1, B2 and B3 frequencies code observations for GEO and IGSO satellites over 17.0, 18.6 and 10.5%, respectively, and the elevation-angle correction method can reduce the multipath bias of IGSO and MEO satellite B1, B2 and B3 frequencies code measurements by 5.0, 6.8, and 4.1%, respectively. After mitigating the multipath bias of Bei Dou code observations, the precision of single point position for east, north and up directions can be improved about 34, 45 and 51%, respectively.

关键词： BeiDou navigation system Triple-frequency multipath bias on code observations Modified sidereal filtering Elevation-angle correction

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-60℃水冷自复叠制冷系统研究

制冷学报 2015年第2期36卷 52-58页

作者：杨永安杨昭刘斌天津大学热能研究所天津300072 天津市制冷技术重点实验室天津商业大学天津300134

提出一种新型水冷自复叠制冷循环方式,用冷凝分离器代替传统循环的冷凝器和相分离器,在冷凝分离器中同时完成了高沸点工质的冷凝及高沸点工质与低沸点工质的分离。对采用这种冷凝分离器的水冷自复叠制冷循环方式的R22/R23、R290/R170、R... 详细信息

提出一种新型水冷自复叠制冷循环方式,用冷凝分离器代替传统循环的冷凝器和相分离器,在冷凝分离器中同时完成了高沸点工质的冷凝及高沸点工质与低沸点工质的分离。对采用这种冷凝分离器的水冷自复叠制冷循环方式的R22/R23、R290/R170、R134a/R23、R134a/R170四种工质对进行了循环特性研究。在自行搭建的水冷自复叠制冷系统实验台上进行了R22/R23、R134a/R23两种工质对的实验研究。结果表明,在相同工况下,R22/R23自复叠制冷系统的COP要高于R134a/R23自复叠制冷系统;和传统的自复叠系统相比,采用冷凝分离器的水冷自复叠制冷循环COP明显提高,提升率达到60%-100%。

关键词：混合工质自复叠制冷循环冷凝分离器