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Rare Metals 2024年第2期43卷 749-757页

作者： Zheng Zhao Wei-Xin Zhao yong-Qi Zhang Mei-Sheng Cui yong-ke hou Dong-Ming Chen Juan-Yu Yang Zong-Yu Feng Xiao-Wei Huang National Engineering Research Center for Rare Earth Grirem Advanced Materials Co.Ltd.GRINM Group Corporation LimitedBeijing100088China Griem Hi-Tech Co.Ltd. Langfang065000China Rare Earth Functional Materials(Xiong’an)Innovation Venter Co.Ltd. Baoding071700China

The ceria-zirconia compound oxide-supported noble metal Pd(Pd@CZ)is widely used in three-way ***,the surface structure of CZ plays an important role in catalytic activity of ***,how to regulate the surface structure of CZ and clarify the structure–activity relationship is still a *** this paper,a strategy is proposed to develop high activity Pd@CZ nanocatalysts by tuning Y doping sites in *** precipitate-deposition method is developed to prepare the novel Ce_(0.485)Zr_(0.485)Y_(0.03)O_(2) composite with surface doping of Y(CZ-Y-S).In addition,the Pd@CZ-Y-S(Pd supported on CZ-Y-S)exhibits superior catalytic activity for HC,CO,and NO oxide,wherein,for CO and C_(3)H_(6) oxidation,the low-temperature activity of Pd@CZ-Y-S is still 20%higher than that of Pd@CZ-Y-B(Y bulk doping)and commercial Pd@CZ after 1000℃/4 h *** effect mechanism is further studied by density functional theory(DFT)*** with Pd@CZ-Y-B,Pd@CZ-Y-S shows the lower CO oxide reaction energy barriers due to the weaker adsorption strength of *** Y surface doping strategy could provide valuable insights for the development of highly efficient Pd@CZ catalyst with extensive applications.

关键词： Rare earth Ceria-zirconia-supported Pd Surface doping Experiment and theory Catalytic application

Experiments and modeling of microstructural and mechanical behaviors of laser-welded Ni-based superalloy at high temperatures

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Chinese Journal of Aeronautics 2025年第1期38卷 99-114页

作者： Ting hou yong LI Degang WANG Yuelin WANG Marko VILOTIC School of Mechanical Engineering and Automation Beihang UniversityBeijing 100191China Department of Structure Shenyang Aircraft Designand Research InstituteShenyang 110000China Engineering Center Shenyang Aircraft CorporationShenyang 110000China Faculty of Technical Science University of Novi SadNovi Sad 21102Serbia

The performance of welded Ni-based superalloys at high temperatures is essential to be evaluated due to their particular service environment for aero-engines and high-speed *** tensile properties and related microstructural evolutions such as the carbide precipitate and grain of a laser-welded Ni-based alloy were experimentally and numerically investigated at different temperatures(20,300,500,800℃).The results show that at room temperature,the strength of the Base Material(BM)was slightly smaller,with a difference of less than 1%,than the Welded Material(WM),which can be attributed to the more uniformly distributed needle-shaped carbide precipitates in the WM than those nonuniformly coarser spherical ones in the *** at 300℃ and 500℃,the strength of WM decreased more obviously compared with that of BM due to the more apparent growth of grain:13.52%loss in yield strength in WM alloys as compared with BM alloys at 300℃,and 16.57% at 500℃.At 800℃,the strength of BM and WM both decreased to a similar level due to Dynamic Recrystallization(DRX).However,a much higher elongation was observed for the BM than WM(less than 50%of BM),which can be attributed to the enhanced dislocation accumulation capability of the large spherical carbides along grain boundaries on the fracture surface in ***,a unified model considering the welding effects on both microstructures(dislocation,carbides,and grain)and mechanical properties evolutions at different temperatures was developed and *** on this model,the key temperature ranges(20–600℃)where apparent weakening of strength and uniform plasticity occurs for welded structures were identified,providing a direct guidance for potential structure and process design.

关键词： Ni-based superalloy Microstructure Mechanical properties Constitutive model High temperature

Viscosity and structure relationship with equimolar substitution of CaO with MgO in the CaO–MgO–Al_(2)O_(3)–SiO_(2)slag melts

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 70-79页

作者： yong hou Shuo Zhang Jie Dang Jia Guo Hanghang Zhou Xuewei Lü College of Materials Science and Engineering Chongqing UniversityChongqing 400044China Chongqing key Laboratory of Vanadium-Titanium Metallurgy and New Materials Chongqing UniversityChongqing 400044China

Currently,the Al_(2)O_(3)content in the high-alumina slag systems within blast furnaces is generally limited to 16wt%–18.5wt%,making it challenging to overcome this *** most studies that concentrated on managing the MgO/Al_(2)O_(3)ratio or basicity,this paper explored the effect of equimolar substitution of MgO for CaO on the viscosity and structure of a high-alumina CaO-MgO-Al_(2)O_(3)-SiO_(2)slag system,providing theoretical guidance and data to facilitate the application of high-alumina *** results revealed that the viscosity first decreased and then increased with higher MgO substitution,reaching a minimum at 15mol%MgO *** transform infrared spectroscopy(FTIR)results found that the depths of the troughs representing[SiO_(4)]tetrahedra,[AlO_(4)]tetrahedra,and Si-O-Al bending became progressively deeper with increased MgO *** of the Raman spectra showed that the average number of bridging oxygens per Si atom and the X_(Q^(3))/X_(Q^(2))(X_(Q^(i))is the molar fraction of Q^(i) unit,and i is the number of bridging oxygens in a[SiO_(4)]tetrahedral unit)ratio increased from 2.30 and 1.02 to 2.52 and 2.14,respectively,indicating a progressive polymerization of the silicate structure.X-ray photoelectron spectroscopy(XPS)results highlighted that non-bridging oxygen content decreased from 77.97mol% to 63.41mol% with increasing MgO concentration,whereas bridging oxygen and free oxygen contents *** analysis demonstrated a gradual increase in the polymerization degree of the tetrahedral structure with the increase in MgO ***,bond strength is another important factor affecting the slag *** occurrence of a viscosity minimum can be attributed to the complex evolution of bond strengths of non-bridging oxygens generated during depolymerization of the[SiO_(4)]and[AlO_(4)]tetrahedral structures by CaO and MgO.

关键词： aluminosilicate viscosity structure spectroscopy

Effects of co-precipitation temperature on structure and properties of La and Y doped cerium zirconium mixed oxides

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Transactions of Nonferrous Metals Society of China 2022年第2期32卷 618-628页

作者： Lian-jie ZHANG Mei-sheng CUI Hao WANG yong-ke hou Shi-lei CHEN Zhi-zhe ZHAI Zhi-qi LONG yong-qi ZHANG National Engineering Research Center for Rare Earth GRINM Group Co.Ltd.Beijing 100088China General Research Institute for Nonferrous Metals Beijing 100088China GRIREM Advanced Materials Co. Ltd.Beijing 100088China GRIREM Hi-Tech Co. Ltd.Langfang 065201China

Due to the oxygen storage and release properties,cerium zirconium mixed oxides are recognized as the key material in automotive three-way *** reveal the effects of co-precipitation temperature on structure,physical and chemical properties of multi-doped cerium zirconium mixed oxides,a series of La and Y doped cerium zirconium mixed oxides(CZLYs)were synthesized via a co-precipitation method,and the physical and chemical properties of CZLYs were systemically characterized by XRD,N_(2) adsorption−desorption,TEM,XPS,oxygen storage capacity(OSC)and hydrogen temperature programmed reduction(H_(2)-TPR).The results show that co-precipitation temperature is an important parameter to influence the crystal size,oxygen storage capacity and thermal stability of *** the co-precipitation temperature was 60℃,the best redox properties and thermal stability of CZLYs were *** thermal treatment at 1100℃for 10 h,the specific surface area and oxygen storage capacity of the corresponding aged sample were 15.42 m^(2)/g and 497.7μmol/g,*** addition,a mechanism was proposed to reveal the effects of co-precipitation temperature on the structure and properties of CZLYs.

关键词： La and Y doping cerium zirconium mixed oxides co-precipitation temperature crystal size thermal stability

Fe3+ ion quantification with reusable bioinspired nanopores

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Chinese Chemical Letters 2025年第2期36卷 207-212页

作者： Yanqiong Wang Yaqi hou Fengwei Huo Xu hou Institute of Flexible Electronics (IFE Future Technologies) Xiang’an Campus Xiamen University State key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University Institute of Artificial Intelligence Xiamen University Department of Physics Research Institute for Biomimetics and Soft Matter Fujian Provincial Key Laboratory for Soft Materials Research Jiujiang Research Institute College of Physical Science and Technology Xiamen University Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKkeM) Engineering Research Center of Electrochemical Technologies of Ministry of Education Xiamen University

Excessive Fe3+ion concentrations in wastewater pose a long-standing threat to human *** low-cost,high-efficiency quantification of Fe3+ion concentration in unknown solutions can guide environmental management decisions and optimize water treatment *** this study,by leveraging the rapid,real-time detection capabilities of nanopores and the specific chemical binding affinity of tannic acid to Fe3+,a linear relationship between the ion current and Fe3+ion concentration was *** this linear relationship,quantification of Fe3+ion concentration in unknown solutions was ***,ethylenediaminetetraacetic acid disodium salt was employed to displace Fe3+from the nanopores,allowing them to be restored to their initial conditions and reused for Fe3+ion *** reusable bioinspired nanopores remain functional over 330 days of *** recycling capability and the long-term stability of the nanopores contribute to a significant reduction in *** study provides a strategy for the quantification of unknown Fe3+concentration using nanopores,with potential applications in environmental assessment,health monitoring,and so forth.

关键词： Bioinspired nanopores Chemical binding affinity Fe3+ ion quantification Reusability Tannic acid

Effect of initial microstructure on microstructure evolution and mechanical properties of 0.12C martensitic steels during quenching and tempering

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Journal of Iron and Steel Research International 2025年第1期32卷 260-269页

作者： Ya-ru Wang Zi-yong hou He Yang Jun Zhao Zhi-yuan Chang Fan-mao Meng Ling Zhang Gui-lin Wu Xiao-xu Huang State key Laboratory of Vanadium and Titanium Resource Comprehensive Utilization Panzhihua 617000SichuanChina State key Laboratory of Advanced Special Steel Shanghai Key Laboratory of Advanced FerrometallurgySchool of Materials Science and EngineeringShanghai UniversityShanghai 200444China International Joint Laboratory for Light Alloys(Ministry of Education) College of Materials Science and EngineeringChongqing UniversityChongqing 400044China Institute of Steel Technology for Automobile and household Appliance Pangang Group Co.Ltd.Panzhihua 617000SichuanChina ATB Motor(Shanghai)Co. Ltd.Keen International CenterShanghai 200041China Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology BeijingBeijing 100083China

The microstructure evolution and mechanical properties of a Fe-0.12C-0.2Si-1.6Mn-0.3Cr-0.0025B(wt.%)steel with different initial microstructures,i.e.,hot rolled(HR)and cold rolled-annealed(CRA),were studied through optical microscopy,scanning electron microscopy,electron channeling contrast imaging,microhardness and room temperature uniaxial tensile *** water quenching from 930℃ to room temperature,a fully martensitic microstructure was obtained in both as-quenched HR and CRA specimens,which shows a microhardness of 480±5 HV,and no significant difference in microstructure and microhardness was *** test results show that the product of tensile strength and total elongation(UTS×TE)of the as-quenched HR specimen,i.e.,24.1 GPa%,is higher than that of the as-quenched CRA specimen,i.e.,18.9 GPa%.While,after being tempered at 300℃,the martensitic microstructures and mechanical properties of the two as-quenched specimens change significantly due to the synergy role of the matrix phase softening and the precipitation *** the maximum UTS×TE,it is 18.9 GPa%obtained in the as-quenched CRA one,while that is 24.4 GPa%obtained in the HR specimen after tempered at 300℃ for 5 min.

关键词： Initial microstructure Lath martensite Quenching Tempering Mechanical property

Marine dispersion of Fukushima-derived radiocesium in the North Pacific and its implications

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Science China Earth Sciences 2025年第2期68卷 389-406页

作者： Tong ZHANG Xiaolin hou Yukun FAN State key Laboratory of Loess and Quaternary Geology Shaanxi Key Laboratory of Accelerator Mass Spectrometry Technology and ApplicationXi’an AMS CenterInstitute of Earth EnvironmentChinese Academy of SciencesXi’an 710061China University of Chinese Academy of Sciences Beijing 100049China Xi’an Institute for Innovative Earth Environment Research Xi’an 710061China

A key scientific approach to addressing the environmental radiation risks from Fukushima nuclear contaminated water(FNCW) discharge into the ocean is understanding and predicting the marine dispersion of *** dispersion of radiocesium(CsF:134Cs,137Cs) from the Fukushima nuclear accident in the North Pacific and its marginal seas post-2011 was systematically summarized,focusing on pathways,vertical distribution changes,and transit *** research examined CsFdispersion through the Kuroshio Extension and denser central mode water(D-CMW) to the eastern North Pacific,as well as through subtropical mode water(STMW),lighter central mode water(L-CMW),and D-CMW to the subtropical western North Pacific,China Seas,and Sea of *** considered broader implications of CsFdispersion in light of ongoing FNCW *** this prolonged liquid discharge and Kuroshio Extension’s barrier effect,it is crucial to emphasize the role of CMW besides STMW in transporting FNCW to the subtropical western North Pacific and its marginal *** research should focus on the key mechanism and longitude range of CMW crossing the Kuroshio *** short-lived134Cs decays rapidly during the storage and dispersion of FNCW,long-lived135Cs and135Cs/137Cs ratios can serve as valuable tracers for detecting and quantifying ***,there is an urgent need for high-precision analysis of these key radionuclides and their characteristic *** promptly detect,assess,and respond to FNCW intrusion,continuous monitoring and identification of nuclear pollution sources in key ocean currents and straits are ***,interdisciplinary research integrating monitoring with marginal sea circulation dynamics and high-resolution numerical simulations should be a priority.

关键词： Fukushima nuclear accident Fukushima nuclear contaminated water Marine dispersion Mode water Kuroshio Extension

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Luminescence: a new perspective for investigating perovskite precursors

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Science China Materials 2025年第1期68卷 312-313页

作者： Haofeng Zheng Shaocong hou School of Electrical Engineering and Automation Wuhan UniversityWuhan 430072China Wuhan University Shenzhen Research Institute Shenzhen 518057China

In the past two decades, perovskite materials have made significant progress in optoelectronic semiconductors, emerging as formidable candidates for the next generation of commercial solar cells, light-emitting diodes (LEDs), and *** the fundamental solution chemistry and photophysics in solution-processed perovskite devices is crucial for comprehending to achieve highly efficient optoelectronic devices.

关键词： optoelectronic diodes perovskite

基于多李雅普诺夫函数的一般非线性系统渐近镇定

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自动化学报 2025年第1期51卷 197-209页

作者：杨可馨李永强侯忠生冯宇浙江工业大学信息工程学院杭州310000 青岛大学自动化学院青岛266071

针对离散时间非线性系统,提出一种基于多李雅普诺夫(Lyapunov)函数的控制器设计方法.该方法不仅能够保证闭环系统稳定性,还能够扩大闭环吸引域(Domain of attraction,DOA).首先,给出基于多Lyapunov函数下系统渐近稳定的充分条件.结果表... 详细信息

针对离散时间非线性系统,提出一种基于多李雅普诺夫(Lyapunov)函数的控制器设计方法.该方法不仅能够保证闭环系统稳定性,还能够扩大闭环吸引域(Domain of attraction,DOA).首先,给出基于多Lyapunov函数下系统渐近稳定的充分条件.结果表明,由多个Lyapunov函数的负定不变集构成的并集是一个稳定的控制集合,其从控制空间到状态空间的投影是闭环DOA的估计.随后,使用区间分析算法求解集合的内近似估计,基于此算法可以求解多Lyapunov函数的负定不变集的近似值和闭环DOA的估计值,并给出相应控制器的设计方法.最后,通过仿真算例验证了本文方法的有效性.

关键词：非线性系统多李雅普诺夫函数稳定性吸引域区间分析

Molecular dynamics simulation of quartz deformation under slow earthquake background

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Science China Earth Sciences 2025年第2期68卷 598-610页

作者： Jingxian SUN Qianqian GUO Quanlin hou College of Earth and Planetary Sciences University of Chinese Academy of SciencesKey Laboratory of Computational GeodynamicsCASBeijing 100049China

Slow earthquakes are the primary mechanism of slow energy release,and research on the focal mechanism has been *** have primarily focused on the friction law based on physical mechanisms and have suggested that slow earthquakes are caused by brittle ***,the focal strength and structural characteristics of slow earthquakes in subduction zones provide evidence of plastic *** is the role of plastic deformation in the focal mechanisms of slow earthquakes?Mechanochemical study have shown that mechanical forces can directly affect chemical *** this study,we examine the storage and release of chemical energy during plastic deformation and consider a mechanochemical process in the focal mechanism of slow *** with the Tersoff potential,molecular dynamics simulation on the shear deformation process of twoα-quartz crystals show that the shear modulus ofα-quartz is 18 GPa,and that the crystal model primarily exhibits atoms flowing and changing in the direction of chemical bonds during the steady-state flow *** molecular potential energy and stress vary in an oscillating up-and-down curve during shear,indicating that chemical energy can be stored and released during plastic *** is consistent with the energy variation during slow *** the initial simple-shear loading condition,α-quartz crystals undergo general shear deformation instead of plane strain and the angle between the longest instantaneous stretching axis(ISA_(1))and the shearing direction is approximately 30°,not 45°.Both the deformation type and direction of ISA_(1)are contrary to basic deformation theory,which may provide clues for future *** study reveals the process of quartz elastic-plastic shear deformation on an atomic *** information is useful for understanding focal mechanisms of slow *** study is part of a series of investigations on tectonic stress chemistry.

关键词： Slow earthquake α-quartz Plastic strain energy Tectonic stress chemistry Tersoff potential

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