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The dynamic catalysis of Ga/ZSM-5 catalysts for propane-CO_(2) coupling conversion to aromatics and syngas

Journal of Energy Chemistry 2024年第10期97卷 513-519,I0011页

作者： yonggui Song Zhong-Pan Hu Haohao Feng Enze Chen Le Lv Yimo Wu Zhen Liu yong jiang Xiaozhi Su Feifei Xu Mingchang Zhu Jingfeng Han Yingxu Wei Svetlana Mintova Zhongmin Liu The Key Laboratory of the Inorganic Molecule-Based Chemistry of Liaoning Province and Laboratory of Coordination Chemistry Shenyang University of Chemical TechnologyShenyang110142LiaoningChina National Engineering Research Center of Lower-Carbon Catalysis Technology Dalian National Laboratory for Clean EnergyiChEM(Collaborative Innovation Center of Chemistry for Energy Materials)Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201203China Normandie University Laboratory of Catalysis and Spectrochemistry(LCS)NSICAENUNICAENCNRSCaen 1450France

Alkane coupling with CO_(2) by metal-containing zeolites catalysis is found to be a promising way to produce aromatics and syngas in recent years,but the real active sites and the role of CO_(2) are still unclear owing to the quick evolution of the metallic active sites and the complex reaction processes including direct propane aromatization,CO_(2) hydrogenation,reverse water-gas shift reaction,and propane-CO_(2) coupling ***,Ga/ZSM-5 catalysts were constructed to study the dynamic evolution of the metallic active sites and the role of CO_(2) during the propane and CO_(2) coupling *** optimizing the reaction conditions,a notable propane conversion rate of 97.9%and an impressive aromatics selectivity of 80.6%in hydrocarbons can be achieved at the conditions of 550℃and CO_(2)/C_(3)H_(8) of 4.^(13)CO_(2)isotope experiments illustrate that C-atoms of CO_(2) can enter into CO(86.5%)and aromatics(10.8%)during the propane-CO_(2) coupling reaction *** situ XANES and FTIR spectroscopies at 550℃and H_(2)/C_(3)H_(8) atmosphere reveal that GaO_(x) species can be gradually dispersed into[GaH_(2)]^(+)/[GaH]^(2+)on the Bronsted acid sites of ZSM-5 zeolite during H_(2) and/or C_(3)H_(8) treatment,which are the real active sites for propane-CO_(2) coupling *** situ CO_(2)-FTIR experiments demonstrate that the[GaH_(2)]^(+)/[GaH]^(2+)species can react with CO_(2) and accelerate the propane and CO_(2) coupling *** work not only presents a cost-effective avenue for CO_(2) utilization,but also contributes to the active site design for improved alkane and CO_(2) activation in coupling reaction system.

关键词： Carbon dioxide Propane aromatization Ga/ZSM-5 Gallium hydride Spectroscopy

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四轮毂驱动电动车辆横向稳定与侧倾预防协同控制策略

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吉林大学学报（工学版） 2024年第2期54卷 540-549页

作者：江和耀王永海吴幼冬王萍中国船舶集团有限公司第七一三研究所郑州450015 吉林大学通信工程学院长春130022

针对四轮轮毂驱动电动汽车在模型预测控制的框架下协同车辆的侧向、横摆运动与侧倾行为,提出一种集成车辆侧向稳定及防侧倾功能的控制策略。首先,为保证预测模型精度,采用非线性轮胎侧向力模型,对车辆未来侧向、横摆及侧倾状态进行预测... 详细信息

针对四轮轮毂驱动电动汽车在模型预测控制的框架下协同车辆的侧向、横摆运动与侧倾行为,提出一种集成车辆侧向稳定及防侧倾功能的控制策略。首先,为保证预测模型精度,采用非线性轮胎侧向力模型,对车辆未来侧向、横摆及侧倾状态进行预测;然后,基于模型预测控制方法设计控制器,将提高操纵性能、横向稳定性、抑制侧倾、平顺性和安全性等多个控制需求在控制器中集成考虑;最后,仿真实验结果表明:提出的控制器能有效改善车辆在高速急转向时的操纵稳定及侧向稳定性,并有效降低车辆侧倾风险。对于车辆质量增大及质心高度增加引起的高侧倾风险情况,即使控制器面对未知的车辆变化,亦可及时有效地调整车辆姿态防止车辆侧翻,保证行驶安全。

关键词：模型预测控制车辆稳定性控制防侧倾控制紧急转向行驶

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Highly reversible photomodulated hydrosoluble stiff-stilbene supramolecular luminophor induced by cucurbituril

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Chinese Chemical Letters 2024年第8期35卷 235-239页

作者： Guoxing Liu Yixin Li Changming Tian yongmei Xiao Lijie Liu Zhanqi Cao Song jiang Xin Zheng Caoyuan Niu Yun-Lai Ren Liangru Yang Xianfu Zheng yong Chen College of Science Henan Agricultural UniversityZhengzhou 450002China College of Chemistry and Chemical Engineering Henan University of TechnologyZhengzhou 450001China College of Chemistry State Key Laboratory of Elemento-Organic ChemistryNankai UniversityTianjin 300071China

A photochromic molecular rotor based on stiff-stilbene(SSB-FMR)was handily prepared through coupled reaction,and further self-assembled with cucurbit[8]uril(CB[8])to form a 2:2 quaternary supramolecu-lar complex(SSB-FMR/CB[8]).Significantly,the intervention of CB[8]on SSB-FMR achieved dual functions that assembly-induced emission enhancement and assembly-induced improvement of photoisomerized performance(especially reversibility)of stiff-stilbene molecular *** supramolecular strategy further facilitated the assembly as a photoresponsive fluorescence switch with outstanding fatigue resis-tance,which was expediently applied in high-security-level QR code anti-counterfeiting and controllable lysosome targeted *** study unprecedentedly provides a supramolecular method for highly effi-ciently improving photoisomerized performance especially reversibility of molecular photoswitches based on stiff-stilbene,and is of vital significance for the construction of intelligent materials with excellent ca-pability.

关键词： Host-guest complexation Cucurbituril Fluorescence switch Stiff-stilbene Fluorescence enhancement

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10B-doped MCP detector developed for neutron resonance imaging at Back-n white neutron source

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Nuclear Science and Techniques 2024年第8期35卷 58-68页

作者： Qiang Li Li‑Jiao wang Jing‑Yu Tang Xiang‑Biao Qiu Zhen Chen Mao‑Yuan Zhao Chang‑Jun Ning Kai Pan Wei Xu Tao Li Su‑Peng Lu Han Yi Rui‑Rui Fan Chang‑Qing Feng Rong Zhang Xiao‑Yang Sun Qi An Hao‑Fan Bai jiang‑Bo Bai Jie Bao Ping Cao Qi‑Ping Chen yong‑Hao Chen Zeng‑Qi Cui An‑Chuan Fan Fan‑Zhen Feng Min‑Hao Gu Chang‑Cai Han Zi‑Jie Han Guo‑Zhu He yong‑Cheng He Yang Hong Yi‑Wei Hu Han‑Xiong Huang Wei jiang Zhi‑Jie jiang Zheng‑Yao Jin Ling Kang Bo Li Gong Li Xiao Li Yang Li Jie Liu Rong Liu Shu‑Bin Liu Yi‑Na Liu Guang‑Yuan Luan Jie Ren Zhi‑Zhou Ren Xi‑Chao Ruan Zhao‑Hui Song Kang Sun Zhi‑Xin Tan Sheng‑Da Tang Jin‑Cheng wang Peng‑Cheng wang Zhao‑Hui wang Zhong‑Wei Wen Xiao‑Guang Wu Xuan Wu Cong Xia yong‑Ji Yu Guo‑Hui Zhang Hang‑Chang Zhang Lin‑Hao Zhang Qi‑Wei Zhang Xian‑Peng Zhang Yu‑Liang Zhang Yue Zhang Zhi‑yong Zhang Zhi‑Hao Zhou Ke‑Jun Zhu Chong Zou Institute of High Energy Physics Chinese Academy of Sciences(CAS)Beijing 100049China Spallation Neutron Source Science Center Dongguan 523803China State Key Laboratory of Particle Detection and Electronics Institute of High Energy Physics Chinese Academy of SciencesBeijing 100049China Dongguan Songshan Lake Future School Dongguan 523808China School of Nuclear Science and Technology University of Science and Technology of ChinaHefei 230027China State Key Laboratory of Particle Detection and Electronics University of Science and Technology of ChinaHefei 230026China North Night Vision Science and Technology(Nanjing)Research Institute Co.Ltd Nanjing 211106China Department of Modern Physics University of Science and Technology of ChinaHefei 230026China State Key Laboratory of Nuclear Physics and Technology School of PhysicsPeking UniversityBeijing 100871China Institute of Modern Physics Fudan UniversityShanghai 200433China Key Laboratory of Nuclear Data China Institute of Atomic EnergyBeijing 102413China China Academy of Engineering Physics Institute of Nuclear Physics and ChemistryMianyang 621900China USTC archaeometry lab University of Science and Technology of ChinaHefei 230026China Northwest Institute of Nuclear Technology Xi’an 710024China University of Chinese Academy of Sciences Beijing 100049China China Shipbuilding Trading Co. LtdBeijing 100044China

Neutron resonance imaging(NRI)has recently emerged as an appealing technique for neutron *** complexity surpasses that of conventional transmission imaging,as it requires a high demand for both a neutron source and ***,the progression of NRI technology has been sluggish since its inception in the 1980s,particularly considering the limited studies analyzing the neutron energy range above *** white neutron source(Back-n)at the China Spallation Neutron Source(CSNS)provides favorable beam conditions for the development of the NRI technique over a wide neutron energy range from eV to ***-sensitive microchannel plates(MCP)have emerged as a cutting-edge tool in the field of neutron detection owing to their high temporal and spatial resolutions,high detection efficiency,and low *** this study,we report the development of a 10B-doped MCP detector,along with its associated electronics,data processing system,and NRI experiments at the *** heavy elements such as gold,silver,tungsten,and indium can be easily identified in the transmission images by their characteristic resonance peaks in the 1–100 eV energy range;the more difficult medium-weight elements such as iron,copper,and aluminum with resonance peaks in the 1–100 keV energy range can also be *** particular,results in the neutron energy range of dozens of keV(Aluminum)are reported here for the first time.

关键词： Neutron resonance imaging 10B doped MCP detector White neutron source Sample nuclide identification

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Measurement of atmospheric non-reciprocity effects for satellite-based two-way time-frequency transfer

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Photonics Research 2024年第6期12卷 1274-1282页

作者： TING ZENG QI SHEN YUAN CAO JIAN-YU GUAN MENG-ZHE LIAN JIN-JIAN HAN LEI HOU JIAN LU XIN-XIN PENG MIN LI WEI-YUE LIU JIN-CAI WU yong wang JUAN YIN JI-GANG REN HAI-FENG jiang QIANG ZHANG CHENG-ZHI PENG JIAN-WEI PAN Hefei National Research Center for Physical Sciences at the Microscale and School of Physical Sciences University of Science and Technology of ChinaHefei 230026China Shanghai Research Center for Quantum Science and CAS Center for Excellence in Quantum Information and Quantum Physics University of Science and Technology of ChinaShanghai 201315China Hefei National Laboratory University of Science and Technology of ChinaHefei 230094China Faculty of Information Science and Engineering Ningbo UniversityNingbo 315211China Key Laboratory of Space Active Opto-Electronic Technology Shanghai Institute of Technical PhysicsChinese Academy of SciencesShanghai 200083China Xinjiang Astronomical Observatory Chinese Academy of SciencesUrumqi 830011China

Future optical clock networks will require high-precision optical time-frequency transfer between satellites and ground ***,due to atmospheric turbulence,satellite motion and time delay between the satellite–ground transmission links will cause spatial and temporal variations,respectively,resulting in the breakdown of the time-of-flight reciprocity on which optical two-way time-frequency transfer is ***,we experimentally simulate the atmospheric effects by two-way spatio-temporally separated links between two stationary terminals located 113 km apart and measure the effects for optical two-way time-frequency *** experiment shows that the effect on the link instability is less than 2.3×10^(−19) at 10,000 *** indicates that when the link instability of satellite-ground optical time-frequency transfer is on the order of 10^(−19),it is not necessary to consider the atmospheric non-reciprocity effects.

关键词： breakdown transfer satellite

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Gene cloning,protein expression,and enzymatic characterization of a double-stranded RNA degrading enzyme in Apolygus lucorum

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Insect Science 2024年第1期31卷 119-133页

作者： Jie-Yu Zhang Jing Zhao Keyan Zhu-Salzman Qin-Qin Ji Yi-Ping jiang Liu-Bin Xiao De-Jin Xu Guang-Chun Xu Lin-Quan Ge yong-An Tan College of Plant Protection Yangzhou UniversityYangzhouJiangsu ProvinceChina Institute of Plant Protection Jiangsu Academy of Agricultural SciencesNanjingJiangsu ProvinceChina Department of Entomology Texas A&M UniversityCollege StationTXUSA Taizhou Customs of the People's Republic of China TaizhouJiangsu ProvinceChina

RNA interference(RNAi)is a powerful tool that post-transcriptionally silences target genes in eukaryotic ***,silencing efficacy varies greatly among different insect ***,we met with little success when attempting to knock down genes in the mirid bug Apolygus lucorum via dsRNA *** disappearance of double-stranded RNA(dsRNA)could be a potential factor that restricts RNAi ***,we found that dsRNA can be degraded in midgut fluids,and a dsRNase of ***(AldsRNase)was identified and *** alignment indicated that its 6 key amino acid residues and the Mg2+-binding site were similar to those of other insects’*** signal peptide and endonuclease non-specific domain shared high sequence identity with the brown-winged green stinkbug Plautia stali *** showed high salivary gland and midgut expression and was continuously expressed through the whole life cycle,with peaks at the 4th instar ecdysis in the whole *** purified AldsRNase protein obtained by heterologously expressed can rapidly degrade *** comparing the substrate specificity of AldsRNase,3 specific substrates(dsRNA,small interfering RNA,and dsDNA)were all degraded,and the most efficient degradation is ***,immunofluorescence revealed that AldsRNase was expressed in the cytoplasm of midgut *** cloning and functional study of AldsRNase,the enzyme activity and substrate specificity of the recombinant protein,as well as the subcellular localization of nuclease,the reason for the disappearance of dsRNA was explained,which was useful in improving RNAi efficiency in *** and related species.

关键词： Apolygus lucorum cloning dsRNase enzymatic activity protein expression

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经管类虚拟仿真实验室建设路径与实践

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实验室研究与探索 2024年第1期43卷 238-245页

作者：江勇中国地质大学(北京)经济管理学院北京100083

虚拟仿真实验室是推进高校人才培养改革的重要载体。在数字化、网络化、智能化深入发展和“新文科”的大背景下,经管虚拟仿真协同实验平台需要结合不同企业场景、不同的学科交叉、不同的课程设计,建立多场景、多学科、多课程深入融合的... 详细信息

虚拟仿真实验室是推进高校人才培养改革的重要载体。在数字化、网络化、智能化深入发展和“新文科”的大背景下,经管虚拟仿真协同实验平台需要结合不同企业场景、不同的学科交叉、不同的课程设计,建立多场景、多学科、多课程深入融合的实验平台,推进经管实验教学的深入融合改革。基于协同理论,提出了经管类虚拟仿真实验室建设的协同理论框架、三大协同机制、序参量管理等实验室建设路径;同时,以本校经济管理实验中心为示范,构建了一个目标、一个平台、三大机制、多个场景、多个学科与多门课程交叉融合的经管虚拟仿真协同实验平台,提出了经管类虚拟仿真实验教学平台建设对策与建议。

关键词：协同理论经管虚拟仿真实验室建设机制路径研究

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大数据侦查中的算法权力构造及其规制路径

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中国人民公安大学学报（社会科学版） 2024年第3期40卷 33-42页

作者：蒋勇兰州大学甘肃兰州730000 智慧警务与国家安全风险治理重点实验室四川泸州646000

算法与大数据侦查的共振极大提升了算法权力的外部效用,算法通过隐私计算整合了数据关系,聚合了侦查的监控能力。通过预测犯罪延伸了侦查的时空触角,追诉行为出现预防化特征。通过自动化决策将基于警察个体的经验法则运用概率化,加强了... 详细信息

算法与大数据侦查的共振极大提升了算法权力的外部效用,算法通过隐私计算整合了数据关系,聚合了侦查的监控能力。通过预测犯罪延伸了侦查的时空触角,追诉行为出现预防化特征。通过自动化决策将基于警察个体的经验法则运用概率化,加强了算法决策的专断性。算法的外部效用形塑了算法权力的内部构造,大数据侦查中数据分析型职权的成型、预防性职权的渗透以及数字化的决策程序成为算法权力形态。面对算法权力的扩张,程序法上应当更新规制框架,包括构建以限制算力为核心的数据分析型职权规制框架,确立以场景为标准的警察预防性职权与侦查权的界分点,构建以线索生成为取向的算法决策边界。

关键词：大数据侦查算法权力数据分析型职权预防性职权规制路径

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Bose–Einstein distribution temperature features of quasiparticles around magnetopolaron in Gaussian quantum wells of alkali halogen ions

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Chinese Physics B 2024年第9期33卷 521-526页

作者： Xin Zhang Sarengaowa Shuang Han Ran An Xin-Xue Zhang Xin-Ying Ji Hong-Xu jiang Xin-Jun Ma Pei-Fang Li yong Sun College of Physics and Electronic Information Inner Mongolia Minzu UniversityTongliao028000China Institute of Condensed Matter Physics Inner Mongolia Minzu UniversityTongliao 028000China

We have applied strong coupling unitary transformation method combined with Bose–Einstein statistical law to investigate magnetopolaron energy level temperature effects in halogen ion crystal quantum *** obtained results showed that under magnetic field effect,magnetopolaron quasiparticle was formed through the interaction of electrons and surrounding *** the same time,magnetopolaron was influenced by phonon temperature statistical law and important energy level shifts down and binding energy *** revealed that lattice temperature and magnetic field could easily affect magnetopolaron and the above results could play key roles in exploring thermoelectric conversion and conductivity of crystal materials.

关键词： temperature effect quantum well asymmetric Gaussian potential magnetopolaron

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Manipulation of Na_(3)V_(2)(PO_(4))_(2)F_(3) via aluminum doping to alter local electron states toward an advanced cathode for sodiumion batteries

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Rare Metals 2024年第9期43卷 4253-4262页

作者： Shi-Min wang Jin-Qi Li Li Xu Meng-Jiao Sun Wen-Jin Huang Qing Liu Fu-Tong Ren yong-jiang Sun Ling-Yan Duan Hang Ma Hong Guo International Joint Research Center for Advanced Energy Materials of Yunnan Province Yunnan Key Laboratory of Carbon Neutrality and Green Low-Carbon TechnologiesSchool of Materials and EnergyYunnan UniversityKunming 650091China College of Environmental and Chemical Engineering Metallurgy CollegeKunming 650033China R&D Center Yunnan Yuntianhua Co.LtdKunming 650228China Southwest United Graduate School Kunming 650091China

With its unique 3D skeleton structure and exceptional cyclic stability,the Na^(+)superionic conducto(NASICON)-type Na_(3)V_(2)(PO_(4))_(2)F_(3)(NVPF)has been con sidered as a competitive cathode material for advanced Na ion ***,the release of fluorine during th heat treatment leads to the formation of an additional phas Na_(3)V_(2)(PO_(4))_(3)(NVP),which results in a low-voltage plateau and compromises the energy ***,we modulat the local electronic states of the V site by aluminum sub stitution to strengthen the stability of *** results confirm that the aluminum introduction not only changes the loca electron states of V sites,significantly reducing the for mation of NVP by-product from 6.71 wt%to 1.01 wt%but also effectively reduces the band gap,improving th electronic conductivity of *** optimized Na_(3)V_(1.9)Al_(0.1)(PO_(4))_(2)F_(3)exhibits higher energy density of 340 Wh·kg^(-1)and excellent rate performance of 106.7 mAh·g^(-1)at 10C compared with the pristine cathode.

关键词： Sodium-ion energy storage batteries Cathode NASICON Doping Electrochemistry

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