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Construction of Naphthalenediimide Lanthanide(Ⅲ)-MOFs and Composites Incorporated Electron-Rich Pyrene Derivative as Multifunctional Fluorescence Sensing for Nitro Aromatic Compounds and Aldehydes

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Chinese Journal of Chemistry 2024年第3期42卷 283-293页

作者： Rong Huo Ting Zhang Guang Zeng chen Wang yong Heng Xing Feng Ying Bai College of Chemistry and Chemical Engineering Liaoning Normal UniversityDalianLiaoning116029 China State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianLiaoning116023 China

The development of host-guest MOF luminescent composites has attracted considerable attention. However,it is still a challenge to reasonably design large scale conjugated polycarboxylic acids metal-organic framework (MOF) and modulate donor-acceptor interaction. Herein,a series of isostructural 3D porous lanthanide MOF [Ln_(2)(BINDI)0.5(NO_(3))(DMA)(H_(2)O)]∙DMA∙2.5H_(2)O (Ln = La (1),Ce (2),Pr (3) and Nd (4);H_(4)BINDI (N,N’-bis(5-isophthalic acid)-1,4,5,8-naphthalenediimide) were synthesized. Considering the electron-deficient performances of Ln-BINDI MOFs,D-A type composites Ln-MOFs (1—4@H_(4)TBAPy) were prepared via the incorporation of electron-rich H_(4)TBAPy (1,3,6,8-tetrakis(p-benzoic acid) pyrene),which more improved the luminescence performance of complexes 1—4 and can be used as fluorescence sensors for the detection of nitro compounds and aldehydes. High sensitivity of 1@H_(4)TBAPy towards pNBA,pNA PNP,DNP,and TNP could be achieved through hydrogen bond interactions between MOF and analytes,as well as the π-π interaction between H_(4)TBAPy and the naphthalene ring of BINDI,thus the fluorescence quenching efficiency of 1@H_(4)TBAPy was better than that of the complex 1. In addition,it is found that 1@H_(4)TBAPy has high selectivity and sensitivity to aromatic aldehyde SA,5-Mesal and HMBA. Such strategy to enhance the emission of NDI based Ln-BINDI MOFs,will open up an avenue to obtain more fluorescent MOFs for sensing.

关键词： Ln-MOF Pyrene molecule NACs Aldehydes Fluorescence sensing Carboxylate ligands Charge transfer Donor-acceptor systems

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Privacy-Preserving Federated Mobility Prediction with Compound Data and Model Perturbation Mechanism

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China Communications 2024年第3期21卷 160-173页

作者： Long Qingyue Wang Huandong chen Huiming Jin Depeng Zhu Lin Yu Li Li yong Beijing National Research Center for Information Science and Technology(BNRist) Department of Electronic EngineeringTsinghua UniversityBeijing 100084China China Mobile Research Beijing 100032China

Human mobility prediction is important for many ***,training an accurate mobility prediction model requires a large scale of human trajectories,where privacy issues become an important *** rising federated learning provides us with a promising solution to this problem,which enables mobile devices to collaboratively learn a shared prediction model while keeping all the training data on the device,decoupling the ability to do machine learning from the need to store the data in the ***,existing federated learningbased methods either do not provide privacy guarantees or have vulnerability in terms of privacy *** this paper,we combine the techniques of data perturbation and model perturbation mechanisms and propose a privacy-preserving mobility prediction algorithm,where we add noise to the transmitted model and the raw data collaboratively to protect user privacy and keep the mobility prediction *** experimental results show that our proposed method significantly outperforms the existing stateof-the-art mobility prediction method in terms of defensive performance against practical attacks while having comparable mobility prediction performance,demonstrating its effectiveness.

关键词： federated learning mobility prediction privacy

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Development and validation of a nomogram model for predicting the risk of gallstone recurrence after gallbladder-preserving surgery

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Hepatobiliary & Pancreatic Diseases International 2024年第3期23卷 288-292页

作者： Peng Liu yong-Wei chen Che Liu Yin-Tao Wu Wen-Chao Zhao Jian-yong Zhu Yang An Nian-Xin Xia Faculty of Hepato-Pancreato-Biliary Surgery the First Medical CenterChinese PLA General HospitalBeijing 100853China Institute of Hepatobiliary Surgery of Chinese PLA Beijing 100853China Key Laboratory of Digital Hepetobiliary Surgery of Chinese PLA Beijing 100853China

Background:The high incidence of gallstone recurrence was a major concern for laparoscopic gallbladderpreserving *** study aimed to investigate the risk factors for gallstone recurrence after gallbladder-preserving surgery and to establish an individualized nomogram model to predict the risk of gallstone ***:The clinicopathological and follow-up data of 183 patients who were initially diagnosed with gallstones and treated with gallbladder-preserving surgery at our hospital from January 2012 to January 2019 were retrospectively *** independent predictive factors for gallstone recurrence following gallbladder-preserving surgery were identified by multivariate logistic regression analysis.A nomogram model for the prediction of gallstone recurrence was constructed based on the selected *** C-index,receiver operating characteristic(ROC)curve and calibration curve were used to evaluate the predictive power of the nomogram model for gallstone ***:During the follow-up period,a total of 65 patients experienced gallstone recurrence,and the recurrence rate was 35.5%.Multivariate logistic regression analysis revealed that the course of gallstones>2 years[odds ratio(OR)=2.567,95%confidence interval(CI):1.270-5.187,P=0.009],symptomatic gallstones(OR=2.589,95%CI:1.059-6.329,P=0.037),multiple gallstones(OR=2.436,95%CI:1.133-5.237,P=0.023),history of acute cholecystitis(OR=2.778,95%CI:1.178-6.549,P=0.020)and a greasy diet(OR=2.319,95%CI:1.186-4.535,P=0.014)were independent risk factors for gallstone recurrence after gallbladder-preserving surgery.A nomogram model for predicting the recurrence of gallstones was established based on the above five *** results showed that the C-index of the nomogram model was 0.692,suggesting it was valuable to predict gallstone ***,the calibration curve showed good consistency between the predicted probability and actual ***:The nomogram model for

关键词： Gallstone Gallbladder-preserving surgery Recurrence Risk factors Nomogram

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Excessive level of dietary insect protein negatively changed growth metabolomic and transcriptomic profiles of largemouth bass(Micropterus salmoides)

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Animal Nutrition 2024年第2期17卷 397-407页

作者： Hao Sun Wenjing Dong Guanglun He yong Long Yuanfa He yongjun chen Shimei Lin College of Fisheries Southwest University College of Fisheries Key Laboratory of Freshwater Fish Reproduction and Development (Ministry of Education) Southwest University State Key Laboratory of Freshwater Ecology and Biotechnology Institute of Hydrobiology Chinese Academy of Sciences

Hermetia illucens(HI) meal is a promising substitute for fish meal(FM) in the feeds of farmed ***, the impacts of dietary HI meal on largemouth bass(LMB) remain unknown. In this study, we formulated three isonitrogenous and isolipid diets with 0%(HI0, control), 20%(HI20) and 40%(HI40) of FM substituted by HI meal. A total of 270 juvenile largemouth bass with an initial body weight of10.02 ± 0.03 g were used(30 fish per tank). After an 80-day feeding trial, the fish fed with the HI40 diet demonstrated decreased growth performance and protein efficiency ratio(PER), and increased liver oxidative indices and lipid accumulation compared to the control(P < 0.05). Transcriptomic analysis revealed the effects of high dietary HI meal on liver gene expression. Consistent with the reduced growth and disturbed liver oxidative status, the upregulated genes were enriched in the biological processes associated with protein catabolism and endoplasmic reticulum(ER) stress; while the downregulated genes were enriched in cellular proliferation, growth, metabolism, immunity and maintenance of tissue homeostasis. Differential metabolites in the liver samples were also identified by untargeted metabolomic assay. The results of joint transcriptomic-metabolomic analyses revealed that the pathways such as one carbon pool by folate, propanoate metabolism and alpha-linolenic acid metabolism were disturbed by high dietary HI meal. In summary, our data revealed the candidate genes, metabolites and biological pathways that account for the adverse effects of high HI meal diet on the growth and health of LMB.

关键词： Hermetia illucens Growth Transcriptome Metabolomic effect Micropterus salmoides

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Investigation on photonic crystal nanobeam cavity based on mixed diamond–circular holes

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Nanotechnology and Precision Engineering 2024年第1期7卷 63-70页

作者： Jingtong Bin Kerui Feng Shang Ma Ke Liu yong cheng Jing chen Qifa Liu College of Telecommunication and Information Engineering Nanjing University of Posts and TelecommunicationsNanjing 210003China College of Electronic and Optical Engineering and College of Flexible Electronics(Future Technology) Nanjing University of Posts and TelecommunicationsNanjing 210003China State Key Laboratory of Advanced Optical Communication Systems and Networks Shanghai Jiao Tong UniversityShanghai 200240China

A photonic crystal nanobeam cavity(M-PCNC)with a structure incorporating a mixture of diamond-shaped and circular air holes is *** performance of the cavity is simulated and studied *** theﬁnite-difference time-domain method,the parameters of the M-PCNC,including cavity thickness and width,lattice constant,and radii and numbers of holes,are optimized,with the quality factor Q and mode volume Vm as performance *** modulation of the lattice constant and hole radius enable the proposed M-PCNC to realize outstanding *** optimized cavity possesses a high quality factor Q 1.45105 and an ultra-small mode=×volume Vm 0.01(λ/n)[Zeng et al.,Opt Lett 2023:48;3981–3984]in the telecommunications wavelength *** can be progres-=sively squeezed in both the propagation direction and the perpendicular in-plane direction by a series of interlocked anti-slots and slots in the diamond-shaped hole ***,the energy can be conﬁned within a small mode volume to achieve an ultra-high Q/Vm ratio.

关键词： Photonic crystal nanobeam cavity Mixed diamond–circular holes Slots and anti-slots FDTD simulation Quality factor Mode volume

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Numerical Simulations of Wave Impact Forces on the Open-Type Sea Access Road Using A Two-Phase SPH Model

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China Ocean Engineering 2024年第5期38卷 755-770页

作者： chen yong-kun Domenico D.MERINGOLO LIU yong Shandong Provincial Key Laboratory of Ocean Engineering Ocean University of China Dipartimento D.I.C.E.A.M. Università degli Studi Mediterranea di Reggio Calabria

A numerical study based on a two-dimensional two-phase SPH(Smoothed Particle Hydrodynamics) model to analyze the action of water waves on open-type sea access roads is presented. The study is a continuation of the analyses presented by chen et al.(2022), in which the sea access roads are semi-immersed. In this new configuration, the sea access roads are placed above the still water level, therefore the presence of the air phase becomes a relevant issue in the determination of the wave forces acting on the structures. Indeed, the comparison of wave forces on the open-type sea access roads obtained from the single and two-phase SPH models with the experimental results shows that the latter are in much better agreement. So in the numerical simulations, a two-phase δ-SPH model is adopted to investigate the dynamical problems. Based on the numerical results, the maximum horizontal and uplifting wave forces acting on the sea access roads are analyzed by considering different wave conditions and geometries of the structures. In particular, the presence of the girder is analyzed and the differences in the wave forces due to the air cushion effects which are created below the structure are highlighted.

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Monolithic integrated optoelectronic chip for vector force detection

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Microsystems & Nanoengineering 2024年第3期10卷 245-257页

作者： Jiansong Feng Zhongqi Wang Mengyuan Zhanghu Xu Zhang yong Shen Jing Yang Zhibin Li Bin chen Taihong Wang Xiaolong chen Zhaojun Liu Department of Electrical and Electronic Engineering Southern University of Science and TechnologyShenzhen 518055China Department of Electrical and Electronic Engineering The University of Hong KongHong KongChina

Sensors with a small footprint and real-time detection capabilities are crucial in robotic surgery and smart wearable *** device footprint while maintaining its high performance is a major challenge and a significant limitation to their ***,we proposed a monolithic integrated micro-scale sensor,which can be used for vector force *** sensor combines an optical source,four photodetectors,and a hemispherical silicone elastomer component on the same sapphire-based AlGaInP *** chip-scale optical coupling is achieved by employing the laser lift-off techniques and the flip-chip bonding to a processed sapphire *** hemispherical structure device can detect normal and shear forces as low as 1mN within a measurement range of 0–220 mN for normal force and 0–15 mN for shear *** packaging,the sensor is capable of detecting forces over a broader range,with measurement capabilities extending up to 10 N for normal forces and 0.2 N for shear *** has an accuracy of detecting a minimum normal force of 25 mN and a minimum shear force of 20 ***,this sensor has been validated to have a compact footprint of approximately 1.5 mm^(2),while maintaining high real-time *** also demonstrate its promising potential by combining this sensor with fine surface texture perception in the fields of compact medical robot interaction and wearable devices.

关键词： robot force smart

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A novel Ce_(0.485)Zr_(0.485)Y_(0.03)O_(2) composite oxide with surface doping of Y and its application in Pd-only three-way catalyst

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Rare Metals 2024年第2期43卷 749-757页

作者： Zheng Zhao Wei-Xin Zhao yong-Qi Zhang Mei-Sheng Cui yong-Ke Hou Dong-Ming chen Juan-Yu Yang Zong-Yu Feng Xiao-Wei Huang National Engineering Research Center for Rare Earth Grirem Advanced Materials Co.Ltd.GRINM Group Corporation LimitedBeijing100088China Griem Hi-Tech Co.Ltd. Langfang065000China Rare Earth Functional Materials(Xiong’an)Innovation Venter Co.Ltd. Baoding071700China

The ceria-zirconia compound oxide-supported noble metal Pd(Pd@CZ)is widely used in three-way ***,the surface structure of CZ plays an important role in catalytic activity of ***,how to regulate the surface structure of CZ and clarify the structure–activity relationship is still a *** this paper,a strategy is proposed to develop high activity Pd@CZ nanocatalysts by tuning Y doping sites in *** precipitate-deposition method is developed to prepare the novel Ce_(0.485)Zr_(0.485)Y_(0.03)O_(2) composite with surface doping of Y(CZ-Y-S).In addition,the Pd@CZ-Y-S(Pd supported on CZ-Y-S)exhibits superior catalytic activity for HC,CO,and NO oxide,wherein,for CO and C_(3)H_(6) oxidation,the low-temperature activity of Pd@CZ-Y-S is still 20%higher than that of Pd@CZ-Y-B(Y bulk doping)and commercial Pd@CZ after 1000℃/4 h *** effect mechanism is further studied by density functional theory(DFT)*** with Pd@CZ-Y-B,Pd@CZ-Y-S shows the lower CO oxide reaction energy barriers due to the weaker adsorption strength of *** Y surface doping strategy could provide valuable insights for the development of highly efficient Pd@CZ catalyst with extensive applications.

关键词： Rare earth Ceria-zirconia-supported Pd Surface doping Experiment and theory Catalytic application

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Ultra-robust informational metasurfaces based on spatial coherence structures engineering

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Light(Science & Applications) 2024年第7期13卷 1310-1319页

作者： Leixin Liu Wenwei Liu Fei Wang Xiaofeng Peng Duk-yong Choi Hua cheng Yangjian Cai Shuqi chen Shandong Provincial Engineering and Technical Center of Light Manipulations Collaborative Innovation Center of Light Manipulation and ApplicationsShandong Provincial Key Laboratory of Optics and Photonic DeviceSchool of Physics and ElectronicsShandong Normal UniversityJinan 250014China. The Key Laboratory of Weak Light Nonlinear Photonics Ministry of EducationSchool of PhysicsSchool of Materials Science and EngineeringSmart Sensing Interdisciplinary Science CenterNankai UniversityTianjin 300071China. School of Physical Science and Technology Soochow UniversitySuzhou 215006China. Laser Physics Centre Research School of PhysicsAustralian National UniversityCanberraACT 2601Australia. The Collaborative Innovation Center of Extreme Optics Shanxi UniversityTaiyuanShanxi 030006China

Optical information transmission is vital in modern optics and photonics due to its concurrent and multi-dimensional nature,leading to tremendous applications such as optical microscopy,holography,and optical *** optical information transmission technologies suffer from bulky optical setup and information loss/crosstalk when meeting scatterers or obstacles in the light ***,we theoretically propose and experimentally realize the simultaneous manipulation of the coherence lengths and coherence structures of the light beams with the disordered *** ultra-robust optical information transmission and self-reconstruction can be realized by the generated partially coherent beam with modulated coherence structure even 93%of light is recklessly obstructed during light transmission,which brings new light to robust optical information transmission with a single *** method provides a generic principle for the generalized coherence manipulation on the photonic platform and displays a variety of functionalities advancing capabilities in optical information transmission such as meta-holography and imaging in disordered and perturbative media.

关键词： optics coherent holography

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Research of caged dynamics of clusters center atoms in Pd_(82)Si_(18) amorphous alloy

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Chinese Physics B 2024年第4期33卷 623-629页

作者：邓永和陈贝祁清华李兵兵高明文大东王小云彭平 School of Computational Science and Electronics Hunan Institute of EngineeringXiangtan 411104China School of Physics and Mechanical&Electrical Engineering Jishou UniversityJishou 416000China School of Materials Science and Engineering Hunan UniversityChangsha 410082China

To date,there is still a lack of a comprehensive explanation for caged dynamics which is regarded as one of the intricate dynamic behaviors in amorphous *** study focuses on Pd_(82)Si_(18)as the research object to further elucidate the underlying mechanism of caged dynamics from multiple perspectives,including the cage's lifetime,atomic local environment,and atomic potential *** results reveal that Si atoms exhibit a pronounced cage effect due to the hindrance of Pd atoms,resulting in an anomalous peak in the non-Gaussian *** in-depth investigation was conducted on the caged dynamics differences between fast and slow Si *** comparison to fast Si atoms,slow Si atoms were surrounded by more Pd atoms and occupied lower potential energy states,resulting in smaller diffusion displacements for the slow Si ***,slow Si atoms tend to be in the centers of smaller clusters with coordination numbers of 9 and *** the isothermal relaxation process,clusters with coordination numbers 9 and 10 have longer lifetimes,suggesting that the escape of slow Si atoms from their cages is more *** findings mentioned above hold significant implications for understanding the caged dynamics.

关键词： caged dynamics Pd_(82)Si_(18) amorphous alloy fast and slow atoms clusters lifetime

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