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Aluminum foam as buffer layer used in soft rock tunnel with large deformation

Journal of Mountain Science 2025年第1期22卷 324-336页

作者： wu Faquan MIAO Binxin TIAN Yun ZHANG Fang ZHANG Chaoxuan School of Civil Engineering Shaoxing UniversityShaoxing 312000China Key Laboratory of Rock Mechanics and Geohazards of Zhejiang Province Shaoxing 312000China School of Civil Engineering and Architecture Taizhou UniversityTaizhou 318000China

The squeezing deformation of surrounding rock is an important factor restricting the safe construction and long-term operation of tunnels when a tunnel passes through soft strata with high ground *** such soft rock geological conditions,the large deformation of the surrounding rock can easily lead to the failure of supporting structures,including shotcrete cracks,spalling,and steel arch *** improve the lining support performance during the large deformation of squeezed surrounding rock,this work selects aluminum foam with densities of 0.25 g/cm3,0.42 g/cm3 and 0.61 g/cm3 as the buffer layer material and carries out uniaxial confined compression *** the evaluation and analysis of energy absorption and the comparison of the yield pressure of aluminum foam with those of other cushioning materials and yield pressure support systems,the strength,deformation and energy absorption of aluminum foam with a density of 0.25 g/cm3 meet the yield pressure performance *** numerical model of the buffer layer yielding support system is then established via the finite element analysis software ABAQUS,and the influence of the buffer layer setting on the lining support is *** with the conventional support scheme,the addition of an aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary *** maximum and minimum principal stresses of the primary support are reduced by 13%and 15%,*** maximum and minimum principal stresses of the secondary lining are reduced by 15%and 12%,respectively,and the displacement deformation of the secondary lining position is reduced by 15%.In summary,the application of aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining,improve the stress safety of the support and reduce the deformation of the support.

关键词： Soft rock tunnel Uniaxial confined compression Aluminum foam Buffer layer Yielding support

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Unveiling the Hidden Interactions Among Features:A Heterogeneous Graph Approach for Personality Prediction

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Machine Intelligence Research 2025年第1期22卷 91-100页

作者： Yuxuan Song Yilin wu Qiudan Li Liping Chen Daniel Zeng The State Key Laboratory of Multimodal Artificial Intelligence Systems Institute of AutomationChinese Academy of SciencesBeijing100190China The School of Artificial Intelligence University of Chinese Academy of SciencesBeijing100049China

Identifying personalities accurately helps merchants and management departments understand user needs in detail and improve the quality of service and decision-making *** research on text-based personality prediction mainly uses deep neural networks or pretrained language models to mine deep semantics,ignoring the dynamic interactions among personality *** paper presents a novel personality prediction method that simultaneously taps into the capability of graph neural networks to model the deep interactions among features and that of pretrained language models to learn latent semantics with a hierarchical aggregation ***,the proposed model leverages self-attention to capture the interaction relationships among POS tags,entities,personality tags,etc.,and considers the labels’cooccurrence *** efficacy of the proposed model is evaluated on the myPersonality and PANDORA *** research contributes to the personality prediction literature from the perspective of a multigranular personality feature learning perspective and provides business value for consuming predictive analytics.

关键词： Personality prediction graph representation learning pretrained models graph convolutional networks attention mechanism

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Efficient catalysis of FeNiCu-based multi-site alloys on magnesium-hydride for solid-state hydrogen storage

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Chinese Chemical Letters 2025年第1期36卷 603-609页

作者： Shuai Li Liuting Zhang Fuying wu Yiqun Jiang Xuebin Yu School of Energy and Power Instrumental Analysis CenterJiangsu University of Science and TechnologyZhenjiang 212003China Department of Materials Science Fudan UniversityShanghai 200433China Max Planck Institute for Iron Research Düsseldorf 40237Germany

Hydrogen,as a cheap,clean,and cost-effective secondary energy source,performs an essential role in optimizing today’s energy *** hydride(Mg H_(2))represents an attractive hydrogen carrier for storage and transportation,however,the kinetic behavior and operating temperature remain *** this work,a dual-phase multi-site alloy(Ms A)anchored on carbon substrates was designed,and its superior catalytic effects on the hydrogen storage properties of MgH_(2) were *** analysis identified that multi-site Fe Ni_(3)/Ni Cu nanoalloys synergistically served as intrinsic drivers for the striking de/hydrogenation performance of the MgH_(2)-Ms A ***,the unique multi-metallic site structure attached to the surface of MgH_(2)provided substantial reversible channels and accessible active sites conducive to the adsorption,activation,and nucleation of H *** addition,the coupling system formed by FeNi_(3) and NiCu dual-phase alloys further enhanced the reactivity between Mg/MgH_(2) and H ***,the onset dehydrogenation temperature of Mg H_(2)+5 wt%Ms A was reduced to 195℃ and the hydrogen desorption apparent activation energy was reduced to 83.6 k J/mol.5.08 wt%H_(2) could be released at 250℃ in 20 min,reaching a high dehydrogenation rate of 0.254 wt%H_(2)/min,yet that for MgH_(2) at a higher temperature of 335℃ was only 0.145 wt%H_(2)/***,the dehydrogenated Mg H_(2)-Ms A sample could absorb hydrogen from room temperature(30℃)and charge 3.93 wt%H_(2) at 100℃ within20 min under 3.0 MPa H_(2) *** from carbon substrates,the 5 wt%Ms A doped-MgH_(2) could still maintain 6.36 wt%hydrogen capacity after 20 *** conclusion,this work provides experimental rationale and new insights for the design of efficient catalysts for magnesium-based solid-state hydrogen storage materials.

关键词： Hydrogen storage Magnesium hydride Synergistic effect Catalysis Multi-site alloys

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Alumina supported platinum-ceria catalyst for reverse water gas shift reaction

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Journal of Rare Earths 2025年第2期43卷 284-294页

作者： Na Jiang Weiwei Wang Haoxin Liu Meiyao wu Chunjiang Jia Key Laboratory for Colloid and Interface Chemistry Key Laboratory of Special Aggregated MaterialsSchool of Chemistry and Chemical EngineeringShandong University

The activation of CO2molecules is a fundamental step for their effective *** highdensity oxygen vacancies on the surface of reducible oxides is pivotal for the activation of *** this work,we prepared a series of 0.5PtxCe/Al2O3（x=1,5,10,or 20） catalysts with varying Ce loading and 0.5 wt% of Pt for the reverse water gas shift（RWGS） *** size of CeO2particle increases with Ce ***,the 0.5Pt5Ce/Al2O3catalyst with an average CeO2particle size of 5.5 nm exhibits a very high CO2conversion rate(116.4×10-5molCO2/(gcat·s)) and CO selectivity（96.1%） at 600℃.Our experimental findings reveal that the small-size CeO2in 0.5Pt5Ce/Al2O3possesses a greater capacity to generate reactive oxygen vacancies,promoting the adsorption and activation of *** addition,the oxygen vacancies are cyclically generated and consumed during the reaction,which contributes to the elevated catalytic performance of the *** work provides a general strategy to construct rich oxygen vacancies on CeO2for designing high-performance catalysts in C1chemistry.

关键词： CO 2 activation Ceria Oxygen vacancies Size-effect Reverse water gas shift reaction Rare earths

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In situ measurement of environmental γ radiation dose rates of key nuclides for large radioactive surface sources

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Nuclear Science and Techniques 2025年第1期36卷 69-79页

作者： Ze-Qian wu Jian Sun Wei-Qi Huang Bai-Rong Wang Jin-Xing Cheng Jiang-Feng wu Yong-Hong Wang Biao Yuan Sheng Qi Kun Shan Institute of NBC Defence Beijing 102205China Beijing New-High Technology Academy Beijing 100094China

To monitor nuclear and radiation emergencies,it is crucial to obtain accurate in situ measurements of the environmentalγ radiation dose rate from key radionuclides,particularly for large radioactive surface *** methods currently used for measuring dose rates are inadequate for obtaining the dose rates of key radionuclides and have large angular response errors when monitoring surface *** address this practical problem,this study proposes three methods for measuring the dose rate:the weighted peak total ratio,mean value regression,and numerical integration *** methods are based on energy-spectrum measurement data,and they were theoretically derived and numerically ***,a 1-m-long hexagonal radioactive surface source was integrated into a larger surface *** situ measurement experiments were conducted on a large radioactive surface source using a dose-rate meter and a portable HPGespectrometer to analyze the errors of the three aforementioned methods and verify their validity.

关键词： Environmentalγradiation dose rate HPGespectrometer Key radionuclides Radioactive surface source

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Characteristics of catalytic destruction of dichloromethane and ethyl acetate mixture over HxPO4-RuOx/CeO2 catalyst

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Journal of Environmental Sciences 2025年第2期148卷 336-349页

作者： Jiawen Chen Qingjie Meng Feng Bi Jingkun Chen Xiaole Weng Zhongbiao wu Key Laboratory of Environment Remediation and Ecological Health Ministry of EducationCollege of Environmental and Resource SciencesZhejiang UniversityHangzhou 310058China School of Civil&Environmental Engineering and Geography Science Ningbo UniversityNingbo 315211China ZJU-Hangzhou Global Scientific and Technological Innovation Center Hangzhou 311200China Zhejiang Provincial Engineering Research Centre of Industrial Boiler&Furnace Flue Gas Pollution Control Hangzhou 310058China

Catalytic destruction is an ascendant technology for the abatement of volatile organic compounds(VOCs)originating fromsolvent-based industrial *** varied composition tends to influence each VOC’s catalytic behavior in the reaction *** investigated the catalytic destruction of multi-component VOCs including dichloromethane(DCM)and ethyl acetate(EA),as representatives from pharmaceutical waste gases,over co-supported HxPO_(4)-RuOx/CeO_(2) catalyst.A mutual inhibitory effect relating to concentrations because of competitive adsorption was verified in the binary VOCs oxidation and EA posed a more negative effect on DCM oxidation owing to EA’s superior adsorption *** adsorption of EA on acidic sites(HxPO_(4)/CeO_(2))promoted DCM activation on basic sites(O^(2−))and the dominating EA oxidation blocked DCM’s access to oxidation centers(RuOx/CeO_(2)),resulting in boosted monochloromethane yield and increased chlorine deposition for DCM *** impaired redox ability of Ru species owing to chlorine deposition in turn jeopardized deep oxidation of EA and its by-products,leading to increased gaseous by-products such as acetic acid originating fromEA ***,DCM at low concentration slightly promoted EA conversion at low temperatures with or without water,consistent with the enhanced EA adsorption in co-adsorption *** was mainly due to that DCM impeded the shielding effect of hydrolysate deposition from rapid EA hydrolysis depending on the decreased ***,water benefited EA hydrolysis but decreased CO_(2) selectivity while the generated water derived from EA was likely to affect DCM *** work may provide theoretical guidance for the promotion of applied catalysts toward industrial applications.

关键词： Catalytic destruction Multi-component VOCs Mixture effect Interaction mechanism

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Smart Gas Sensors:Recent Developments and Future Prospective

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Nano-Micro Letters 2025年第3期17卷 55-86页

作者： Boyang Zong Shufang wu Yuehong Yang Qiuju Li Tian Tao Shun Mao College of Environmental Science and Engineering Biomedical Multidisciplinary Innovation Research InstituteShanghai East HospitalState Key Laboratory of Pollution Control and Resource ReuseTongji University1239 Siping RoadShanghai 200092People’s Republic of China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092People’s Republic of China Microbiome Medicine Center Department of Laboratory MedicineZhujiang HospitalSouthern Medical UniversityGuangzhou 510280People’s Republic of China

Gas sensor is an indispensable part of modern society withwide applications in environmental monitoring,healthcare,food industry,public safety,*** the development of sensor technology,wireless communication,smart monitoring terminal,cloud storage/computing technology,and artificial intelligence,smart gas sensors represent the future of gassensing due to their merits of real-time multifunctional monitoring,earlywarning function,and intelligent and automated *** electronicand optoelectronic gas sensors have been developed for high-performancesmart gas *** the development of smart terminals and the maturityof integrated technology,flexible and wearable gas sensors play an increasingrole in gas *** review highlights recent advances of smart gassensors in diverse *** structural components and fundamentalprinciples of electronic and optoelectronic gas sensors are described,andflexible and wearable gas sensor devices are ***,sensorarray with artificial intelligence algorithms and smart gas sensors in“Internet of Things”paradigm are ***,the challengesand perspectives of smart gas sensors are discussed regarding the future need of gas sensors for smart city and healthy living.

关键词： Smart gas sensor Electronic sensor Optoelectronic sensor Flexible and wearable sensor Artificial intelligence

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Optimizing canopy-spacing configuration increases soybean yield under high planting density

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Crop Journal 2025年第1期13卷 233-245页

作者： Li, Ruidong Xu, Cailong wu, Zongsheng Xu, Yifan Sun, Shi Song, Wenwen wu, Cunxiang Institute of Crop Sciences Chinese Academy of Agricultural Sciences/National soybean Industrial Technology R & D Center Beijing 100081 China

Dense cropping increases crop yield but intensifies resource competition, which reduces single plant yield and limits potential yield growth. Optimizing canopy spacing could enhance resource utilization, support crop morphological development and increase yield. Here, a three-year study was performed to verify the feasibility of adjusting row spacing to further enhance yield in densely planted soybeans. Of three row-spacing configurations (40–40, 20–40, and 20–60 cm) and two planting densities (normal 180,000 plants ha−1 and high 270,000 plants ha−1). The differences in canopy structure, plant morphological development, photosynthetic capacity and their impact on yield were analyzed. Row spacing configurations have a significant effect on canopy transmittance (CT). The 20–60 cm row spacing configuration increased CT and creates a favorable canopy light environment, in which plant height is reduced, while branching is promoted. This approach reduces plant competition, optimizes the developments of leaf area per plant, specific leaf area, leaf area development rate, leaf area duration and photosynthetic physiological indices (Fv/Fm, ETR, Pn). The significant increase of 11.9%–34.2% in canopy apparent photosynthesis (CAP) is attributed to the significant optimization of plant growth and photosynthetic physiology through CT, an important contributing factor to yield increases. The yield in the 20–60 cm treatment is 4.0% higher than in equidistant planting under normal planting density, but 5.9% under high density, primarily driven by CAP and pod number. These findings suggest that suitable row spacing configurations optimize the light environment for plants, promote source-sink transformation in soybeans, and further improve yield. In practice, a 20–60 cm row spacing configuration could be employed for high-density soybean planting to achieve a more substantial yield gain. © 2024 Crop Science Society of China and In

关键词： Canopy transmittance Planting density Row-spacing configuration Soybean Yield

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A comprehensive review on wedelolactone: natural sources, total synthesis, and pharmacological activities

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Chinese Journal of Natural Medicines 2025年第02期23卷 169-181页

作者： Haiping Cai Yue wu Xiaojin Zhang State Key Laboratory of Natural Medicines Jiangsu Key Laboratory of Drug Design and Optimization and Department of Chemistry China Pharmaceutical University

Plant-derived natural products have long been a vital source for developing therapeutic drugs. Wedelolactone(WDL), a coumestan isolated from Eclipta prostrata, Wedelia calendulacea, Wedelia chinensis, and Sphagneticola trilobata, demonstrates a broad spectrum of therapeutic potential, including anticancer, anti-inflammatory, anti-obesity, anti-myotoxic,antimicrobial, anti-diabetic, and tissue-protective activities. This review synthesizes information on the isolation, total synthesis, pharmacological activity, underlying mechanisms, and pharmacokinetic properties of WDL. Additionally, it offers insights into potential clinical applications and future drug discovery avenues utilizing WDL or its derivatives, either independently or in combination with other pharmaceuticals.

关键词： Mechanism Natural product Pharmacological activity Synthesis Wedelolactone

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“陕西苹果”地理标志保护对甘肃林果产品地理标志保护的借鉴

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黑河学刊 2010年第3期 31-32页

作者：吴应珍李昂马卿雁骆团望甘肃农业大学人文学院甘肃兰州730070 兰州城市学院甘肃兰州730070 甘肃出入境检验检疫局甘肃兰州730020 静宁县细巷乡人民政府甘肃静宁743414

"陕西苹果"是我国目前保护面积最大的五星级农产品地理标志,其地理标志保护的一些经验对同处农业部苹果优势产业带的甘肃"静宁苹果"、"平凉金果"等地理标志的保护有借鉴意义。主要体现为:加强地方立法,重视农产品地理标志技术和法律宣传... 详细信息

"陕西苹果"是我国目前保护面积最大的五星级农产品地理标志,其地理标志保护的一些经验对同处农业部苹果优势产业带的甘肃"静宁苹果"、"平凉金果"等地理标志的保护有借鉴意义。主要体现为:加强地方立法,重视农产品地理标志技术和法律宣传,科技法律专家全方位进行技术支持。

关键词：地理标志地理标志保护借鉴 “陕西苹果” 甘肃林果

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