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齿轮钢中非金属夹杂物检测方法对比及其对疲劳性能的影响

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轨道交通材料 2024年第1期3卷 61-65页

作者：周明明姜永升肖英杰中车福伊特传动技术(北京)有限公司北京102202

为了更全面和准确地确定齿轮钢中非金属夹杂物的含量,对现行的两种钢中非金属夹杂物含量的测定方法(传统的标准评级图显微检验法和极值分析法),进行对比检测分析,结果表明,极值分析法评价出的钢中非金属夹杂物的含量较为精准。同时,通... 详细信息

为了更全面和准确地确定齿轮钢中非金属夹杂物的含量,对现行的两种钢中非金属夹杂物含量的测定方法(传统的标准评级图显微检验法和极值分析法),进行对比检测分析,结果表明,极值分析法评价出的钢中非金属夹杂物的含量较为精准。同时,通过旋转弯曲疲劳试验测定齿轮钢锻坯的疲劳性能,得到与用极值分析法评价的齿轮锻坯中非金属夹杂物的最大预测尺寸L max所对应的齿轮钢的疲劳极限,当非金属夹杂物的最大预测尺寸L_(max)=67.47μm时,钢的疲劳极限为701 MPa;L_(max)=48.90μm时,钢的疲劳极限为1011 MPa;L_(max)=35.88μm时,钢的疲劳极限为1070 MPa,得出通过极值分析法测定的钢中非金属夹杂物的最大预测尺寸L_(max)越小,所对应的钢的疲劳极限值越高。当受疲劳试验时间和试验条件等因素限制而无法进行钢材的疲劳试验时,可通过极值分析法评价钢材中非金属夹杂物的最大预测尺寸L max的值来初步判断所选用钢材的疲劳强度是否能达到要求。

关键词：非金属夹杂物极值分析法疲劳性能齿轮钢

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赣江中游鱼类群落结构及多样性

江西科学 2024年第3期42卷 490-497页

作者：肖莹洁张洁徐鹏邹晓焰毛艳邹武赣江中游水文水资源监测中心江西吉安343000 鄱阳湖水文生态监测研究重点实验室南昌330000 修河水文水资源监测中心江西九江332000

赣江是鄱阳湖第一大支流,也是鱼类重要栖息和繁殖场所。随着赣江梯级枢纽的逐步建成运行,鱼类栖息繁殖的生境条件发生一定变化。为掌握赣江中游鱼类群落结构特征,了解主要梯级峡江水利枢纽对鱼类资源的影响,也为即将实施的赣江干流全面... 详细信息

赣江是鄱阳湖第一大支流,也是鱼类重要栖息和繁殖场所。随着赣江梯级枢纽的逐步建成运行,鱼类栖息繁殖的生境条件发生一定变化。为掌握赣江中游鱼类群落结构特征,了解主要梯级峡江水利枢纽对鱼类资源的影响,也为即将实施的赣江干流全面禁捕积累基础资料,于2022年在赣江中游开展鱼类资源调查。研究共调查到鱼类77种,隶属5目11科49属,其中,鲤科鱼类物种数量最多,占比64.94%。主要优势种为银鮈、鳙、似鳊和鳊。不同水域鱼类群落差异明显,整体上,峡江坝下江段鱼类多样性水平最高,主要得益于该江段紧邻已全面实施禁捕的峡江段四大家鱼种质资源保护区,同时该河段在大部分时段仍保持自然流水特征,能够满足不同类型鱼类栖息繁殖需求,建议重点保护。

关键词：鱼类群落环境影响因子鱼类多样性赣江中游

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Controlling secondary flow in high-lift low-pressure turbine using boundary-layer slot suction

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Chinese Journal of Aeronautics 2024年第3期37卷 21-33页

作者： xiao QU Liunan LI yingjie ZHANG Xingen LU Junqiang ZHU Yanfeng ZHANG School of Mechanical Engineering Beijing Institute of TechnologyBeijing 100081China Key Laboratory of Light-Duty Gas-Turbine Institute of Engineering ThermophysicsChinese Academy of SciencesBeijing 100190China School of Aeronautics and Astronautics University of Chinese Academy of SciencesBeijing 100190China

The design of high-lift Low-Pressure Turbines(LPTs)causes the separation of the boundary layer on the suction side of the blade and leads to a strong secondary *** present study aims to minimize secondary losses through endwall slot suction and incoming wakes in a front-loaded high-lift LPT cascade with Zweifel of 1.58 under low Reynolds number of *** slotted schemes for the boundary layer of the endwall were designed(Plan A and Plan B),and the effects of suction mass flow on secondary flow were *** underlying physics of the endwall boundary layer of the suction and secondary flow under unsteady wakes was *** results show that slot suction at the endwall boundary layer can significantly suppress the secondary flow by removing low-momentum *** A and B significantly reduced the secondary kinetic energy by 44.2%and 36.9%,respectively,compared with the baseline cascade at the suction mass flow ratios of 1%.With an increase in the mass flow ratio of suction,the secondary flow was gradually reduced in both Plans A and *** is more beneficial to control the secondary flow to destroy the intersection of the pressure side and suction side of the horseshoe vortex before it develops into a passage *** unsteady wakes,the combined effects of incoming wakes and endwall boundary layer suction can further suppress the secondary flow at the suction mass flow ratios of 2%for Plan A,because the positive and negative vorticity inside upstream wakes accelerated the mixing of the main flow and secondary flow and thus increased the energy of secondary vortices.

关键词： Low-pressure turbine Secondary flow Flow control Boundary-layer suction Incoming wake

Senome-wide Association Studies in Maize： Praise and Stargaze

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Molecular Plant 2017年第3期10卷 359-374页

作者： yingjie xiao Haijun Liu Liuji Wu Marilyn Warburton Jianbing Yan National Key Laboratory of Crop Genetic Improvement Huaz.hong Agricultural University Wuhan 430070 China Synergetic Innovation Center of Henan Grain Crops Henan Agricultural University Zhengzhou 450002 China United States of Department of Agriculture Agricultural Research Service Corn Host Plant Resistance Research Unit Box 9555 MS 39762 Mississippi USA These authors contributed equally to this article

Genome-wide association study （GWAS） has become a widely accepted strategy for decoding genotype- phenotype associations in many species thanks to advances in next-generation sequencing （NGS） technol- ogies. Maize is an ideal crop for GWAS and significant progress has been made in the last decade. This review summarizes current GWAS efforts in maize functional genomics research and discusses future prospects in the omics era. The general goal of GWAS is to link genotypic variations to corresponding dif- ferences in phenotype using the most appropriate statistical model in a given population. The current re- view also presents perspectives for optimizing GWAS design and analysis. GWAS analysis of data from RNA, protein, and metabolite-based omics studies is discussed, along with new models and new popula- tion designs that will identify causes of phenotypic variation that have been hidden to date. The joint and continuous efforts of the whole community will enhance our understanding of maize quantitative traits and boost crop molecular breeding designs.

关键词： GWAS omics mixed model population design functional genomics Zea mays

Structure-regulated fluorine-containing additives to improve the performance of perovskite solar cells

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Nano Research 2024年第7期17卷 6080-6086页

作者： Peiya Chen xiaoman Bi Hao Yan yingjie Zhao Yihao Liu Zhuo Huang Qian xiao Yongpeng Yang Shasha Zhang Yiqiang Zhang Yanlin Song Henan Institute of Advanced Technology College of ChemistrySchool of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China Key Laboratory of Green Printing CAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of Sciences(ICCAS)Beijing Engineering Research Center of Nanomaterials for Green Printing TechnologyNational Laboratory for Molecular Sciences(BNLMS)Beijing 100190China

Perovskite solar cells(PSCs)have seen remarkable progress in recent years,largely attributed to various additives that enhance both efficiency and *** these,fluorine-containing additives have garnered significant interest because of their unique hydrophobic properties,effective defect passivation,and regulation capability on the crystallization ***,a targeted structural approach to design such additives is necessary to further enhance the performance of ***,fluoroalkyl ethylene with different fluoroalkyl chain lengths(CH_(2)CH(CF_(2))nCF_(3),n=3,5,and 7)as liquid additives is used to investigate influences of fluoroalkyl chain lengths on crystallization regulation and defect *** findings indicate that optimizing the quantity of F groups plays a crucial role in regulating the electron cloud distribution within the additive *** optimization fosters strong hydrogen bonds and coordination effects with FA+and uncoordinated Pb^(2+),ultimately enhancing crystal quality and device ***,1H,1H,2H-perfluoro-1-hexene(PF_(3))with the optimal number of F presents the most effective modulation effect.A PSC utilizing PF_(3)achieves an efficiency of 24.05%,and exhibits exceptional stability against humidity and thermal *** work sheds light on the importance of tailored structure designs in additives for achieving high-performance PSCs.

关键词： perovskite solar cells fluorine number additive structure crystallization regulation defect passivation

Introducing sulfur to nickel-iron selenide for high-efficiency alkaline seawater electrolysis

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Science China Chemistry 2024年第8期67卷 2747-2754页

作者： Xuanwa Chen Yanhui Yu Xingqi Han Huan Wang yingjie Hua Daoxiong Wu Peilin Deng Juanxiu xiao Xinlong Tian Jing Li School of Marine Science and Engineering Hainan Provincial Key Lab of Fine ChemistrySchool of Chemistry and Chemical EngineeringHainan UniversityHaikou 570228China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) College of ChemistryNankai UniversityTianjin 300071China Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan Province School of Chemistry and Chemical EngineeringHainan Normal UniversityHaikou 571158China

Seawater electrolysis is an effective way to obtain hydrogen(H_(2))in a sustainable ***,the lack of electrocatalysts with high activity,stability,and selectivity for oxygen evolution reaction(OER)severely hinders the development of seawater electrolysis ***,sulfur-doped nickel-iron selenide nanosheets(S-NiFeSe_(2))were prepared by an ion-exchange strategy and served as highly active OER electrocatalyst for alkaline seawater *** overpotential is 367 m V,and it can run stably for over 50 h at 100 m A cm^(-2).Excitingly,the S-NiFeSe_(2)||Pt/C pair exhibits cell voltage of 1.54 V at 10 m A cm^(-2)under alkaline seawater conditions,which can run smoothly for 100 h without decay,and the efficiency of electricity-tohydrogen(ETH)energy conversion reaches more than 80%.Such electrode,with abundant accessible reactive sites and good corrosion resistance,is a good candidate for seawater ***,density functional theory calculations reveal that the surface sulfur atoms can activate the adjacent Ni sites and decrease the free energy changes of the associated intermediates at the adjacent Ni sites for OER,and the step of~*OH→~*O is the potential rate-limiting *** this work,the true reactive site in nickel-iron selenides is the Ni sites,but not the Fe sites as commonly believed.

关键词： S-doping nickel-iron selenide electrocatalysts oxygen evolution reaction alkaline seawater electrolysis

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Bioinspired zinc-mediated umpolung thiolation of alkyl electrophiles: reaction development, scope and mechanism

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Science China Chemistry 2024年第3期67卷 898-907页

作者： Yuenian Xu Yan Zhang Yong Liu Wen-Wu Sun Jie Huang Hui He yingjie Wu Wen Liu Shao-Fei Ni Xu-Qiong xiao Xinxin Shao College of Material Chemistry and Chemical EngineeringKey Laboratory of Organosilicon Chemistry and Material Technology of Ministry of EducationHangzhou Normal UniversityHangzhou 311121China School of Pharmaceutical Sciences South-Central Minzu UniversityWuhan 430074China Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guang-dong Province Shantou UniversityShantou 515063China

Zinc-promoted umpolung thiolation of alkyl electrophiles with masked sulfur transfer reagents in the absence of nickel or copper catalysis is described. This protocol proceeds via a SET process of Zn to electrophilic sulfur reagent followed by insertion of Zn into disulfide and nucleophilic thiolation, providing straightforward access to a wide range of alkyl sulfides with broad substrate scope. A neutral TMEDA-ligated four-coordinated zinc thiolate with tetrahedra geometry was synthesized, isolated and fully characterized by NMR, IR and X-ray analysis. More importantly, the chemical reactivity of this active intermediate has been investigated, enabling the construction of C-Se, C-Te, Sb-S and Bi-S bonds to prepare valuable sulfur-containing molecules and beyond.

关键词： umpolung thiolation C(sp^(3))-S bond formation masked sulfur reagents reductive coupling

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A heavy metal transporter gene ZmHMA3a promises safe agricultural production on cadmium-polluted arable land

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Journal of Genetics and Genomics 2023年第2期50卷 130-134页

作者： Yuanyuan Chen Zhen-Fei Chao Min Jin Ya-Ling Wang Yaoyao Li Jia-Chen Wu yingjie xiao Yong Peng Qiao-Yan Lv Songtao Gui Xiaqing Wang Mei-Ling Han Alisdair R.Fernie Dai-Yin Chao Jianbing Yan National Key Laboratory of Crop Genetic Improvement Huazhong Agricultural UniversityWuhanHubei 430070China National Key Laboratory of Plant Molecular Genetics CAS Center for Excellence in Molecular Plant SciencesShanghai Institute of Plant Physiology and EcologyChinese Academy of SciencesShanghai 200032China University of Chinese Academy of Sciences Beijing 100049China School of Life Sciences State Key Laboratory for Conservation and Utilization of Subtropical Agro-BioresourcesSouth China Agricultural UniversityGuangzhouGuangdong 510642China Hubei Hongshan Laboratory WuhanHubei 430070China Beijing Key Laboratory of Maize DNA Fingerprinting and Molecular Breeding Maize Research CenterBeijing Academy of Agriculture&Forestry Sciences(BAAFS)Beijing 100097China Department of Molecular Physiology Max-Planck-Institute of Molecular Plant PhysiologyAm Mühlenberg 114476 Potsdam-GolmGermany National Key Laboratory of Crop Genetic Improvement Huazhong Agricultural UniversityWuhanHubei 430070China Hubei Hongshan LaboratoryWuhanHubei 430070China

In China,19%of agricultural soils contain harmful heavy metal pollutants at levels exceeding environmentally recommended standards,whilst around 3 million hectares of arable land are too polluted to grow crops on(Zhao et al.,2015;Hu et al.,2016).Among the deleterious heavy metals,cadmium(Cd)is the most bioavailable toxic metallic pollutant and is rapidly transferable through the food chain(Wang et al.,2019).Concerning the current dilemma of the enhanced food demands of a rising population and decreasing availability of arable land,it is promising to cultivate field crops that produce enough safe foods for human consumption and simultaneously remove the pollutants from contaminated arable lands.

关键词： arable crops cadmium

Total glucosides of paeony alleviates cGAS-STING-mediated diseases by blocking the STING-IRF3 interaction

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Chinese Journal of Natural Medicines 2024年第5期22卷 402-415页

作者： XIU Ye WANG Sihao ZHANG Ping LI Chengwei WU Zhixin WEN Jincai XU yingjie LV Guiji ZHAO xiaomei DONG Xu CHEN Yichong LI Junjie WANG Yan ZOU Liang xiao xiaohe BAI Zhaofang School of Pharmacy Fujian University of Traditional Chinese MedicineFuzhou 350122China Department of Hepatology The Fifth Medical Center of PLA General HospitalBeijing 100039China China Military Institute of Chinese Materia Fifth Medical Center of Chinese PLA General HospitalBeijing 100039China Department of Pharmacy Medical Supplies Center of PLA General HospitalBeijing 100039China School of Food and Biological Engineering Chengdu UniversityChengdu 610106China National Key Laboratory of Kidney Diseases Chinese PLA General HospitalBeijing 100039China

In the realm of autoimmune and inflammatory diseases,the cyclic GMP-AMP synthase(cGAS)stimulator of interferon genes(STING)signaling pathway has been thoroughly investigated and *** this,the clinical approval of drugs targeting the cGAS-STING pathway has been *** Total glucosides of paeony(TGP)is highly anti-inflammatory and is commonly used in the treatment of rheumatoid arthritis(RA),emerged as a subject of our *** found that the TGP markedly reduced the activation of the cGAS-STING signaling pathway,triggered by various cGAS-STING agonists,in mouse bone marrow-derived macrophages(BMDMs)and Tohoku Hospital Pediatrics-1(THP-1)*** inhibition was noted alongside the suppression of interferon regulatory factor 3(IRF3)phosphorylation and the expression of interferon-beta(IFN-β),C-X-C motif chemokine ligand 10(CXCL10),and inflammatory mediators such as tumor necrosis factor-alpha(TNF-α)and interleukin-6(IL-6).The mechanism of action appeared to involve the TGP’s attenuation of the STING-IRF3 interaction,without affecting STING oligomerization,thereby inhibiting the activation of downstream signaling *** vivo,the TGP hindered the initiation of the cGAS-STING pathway by the STING agonist dimethylxanthenone-4-acetic acid(DMXAA)and exhibited promising therapeutic effects in a model of acute liver injury induced by lipopolysaccharide(LPS)and D-galactosamine(D-GalN).Our findings underscore the potential of the TGP as an effective inhibitor of the cGAS-STING pathway,offering a new treatment avenue for inflammatory and autoimmune diseases mediated by this pathway.

关键词： Total glucosides of gaeony cGAS-STING pathway Inflammation LPS/D-GalN STING inhibitor