检索结果-南通市图书馆

Fabrication of Molecularly Imprinted Electrospun Nanofibers with Mono-amidoxime Functional Ligand for Efficient Decontamination of Toxic Organophosphates

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Polymer Science 2024年第4期42卷 446-456页

作者： Lan Wang Peng Jiang Ya-Lin Niu Jun-Peng Cao Tian-ying guo Key Laboratory of Functional Polymer Materials Ministry of EducationInstitute of Polymer ChemistryCollege of Chemistry and Frontier Science Center for the Creation of New Organic SubstancesNankai UniversityTianjin300071China

There is an urgent imperative to discover practical and efficacious artificial catalysts for the expeditious decontamination of toxic organophosphates. Herein, we propose a novel molecularly imprinted approach utilizing electrospun fiber scaffolds. Specifically, an amidoxime-based functional polymer (PMAOX) has been synthesized, which contains amidoxime groups that can act as nucleophiles and ligands for the formation of catalytic active sites. This polymer was blended with polyacrylonitrile (PAN), a well-processable material, to prepare a nanofiber mat using electrospinning techniques. Then, the amidoxime side groups on fiber surface were further cross-linked after the molecular coordination of templates to complete the molecularly imprinting process. This approach can not only enhance the content of functional molecularly imprinted polymers without affecting structural stability, but also combines surface MI technology to fully expose and leverage the advantages of active sites. The as prepared molecularly imprinted electrospun nanofibers MIF-Zn-PMAOX/PAN-6/4 catalyzes the degradation of paraoxon with a half-life of 32 min, and MIF-Ag-PMAOX/PAN catalyzes the degradation of parathion with a half-life of 18 min. The maximum catalytic rate evidence rate enhancements nearly 3700-fold of the self-hydrolysis. Thus, the mono-amidoxime based molecularly imprinted fibers demonstrate the versatility and superiority as self-detoxifying for organophosphates.

关键词： Organophosphateshydrolysis Electrospinning Molecular imprinting

N-doping offering higher photodegradation performance of dissolved black carbon for organic pollutants: experimental and theoretical studies

在线全文

学校读者我要写书评

暂无评论

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2024年第4期25卷 340-356页

作者： Yong guo Mengxia CHEN Ting CHEN ying guo Zixuan XU guowei XU Soukthakhane SINSONESACK Keophoungeun KANMANY Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes Ministry of EducationCollege of EnvironmentHohai UniversityNanjing 210093China Key Laboratory of Environmental Engineering of Jiangsu Province Jiangsu Provincial Academy of Environmental ScienceNanjing 210036China State Key Laboratory of Pollution Control and Resource Reuse Nanjing UniversityNanjing 210023China Central Environmental Laboratory Natural Resources and Environment Research InstituteMinistry of Natural Resources and EnvironmentVientiane 999012Laos

We investigated the influence mechanism of N-doping for dissolved black carbon(DBC)photodegradation of organic *** degradation performance of N-doped dissolved black carbon(NDBC)for tetracycline(TC)(71%)is better than that for methylene blue(MB)(28%)under *** levels are both better than DBC degradation performances for TC(68%)and MB(18%)under *** species quenching experiments suggest that h and-O,are the main reactive species for NDBC photodegraded TC,while-OH and h*are the main reactive species for NDBC photodegraded MB.-OH is not observed during DBC photodegradation of *** is likely because N-doping increases valence-band(VB)energy from 1.55 eV in DBC to 2.04 eV in NDBC;the latter is strong enough to oxidize water to ***,N-doping increases the DBC band gap of 2.29 to 2.62 eV in NDBC,resulting in a higher separation efficiency of photo-generated electrons-holes in NDBC than in *** these factors give NDBC stronger photodegradation performance for TC and MB than ***-performance liquid chromatography-mass spectrometry(HPLC-MS)characterization and toxicity evaluation with the quantitative structure-activity relationship(QSAR)method suggest that TC photodegradation intermediates produced by NDBC have less aromatic structure and are less toxic than those produced by *** adopted a theoretical approach to clarify the relationship between the surface groups of NDBC and the photoactive species *** results add to the understanding of the photochemical behavior of NDBC.

关键词： Dissolved black carbon(DBC) N-doping Organic pollutants Band gap Photodegradation

Recent progress in hair follicle stem cell markers and their regulatory roles

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

World Journal of Stem Cells 2024年第2期16卷 126-136页

作者： Yi-Zhan Xing Hai-ying guo Fei Xiang Yu-Hong Li Department of Cell Biology Army Medical UniversityChongqing 400038China Institute of Burn Research Southwest HospitalArmy Medical UniversityChongqing 400038China

Hair follicle stem cells(HFSCs)in the bulge are a multipotent adult stem cell *** can periodically give rise to new HFs and even regenerate the epidermis and sebaceous glands during wound *** increasing number of biomarkers have been used to isolate,label,and trace HFSCs in recent *** more detailed data from single-cell transcriptomics technology,we mainly focus on the important HFSC molecular markers and their regulatory roles in this review.

关键词： Hair follicle stem cells Bulge Secondary hair germ Marker Single-cell RNA-sequencing

The current situation of semen analysis in China,based on a survey of 296 laboratories

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Asian Journal of Andrology 2024年第2期26卷 220-221页

作者： Long-Long Fu ying Liu Xiao-Wei Wang Fang Zhou ying guo Wen-Hong Lu Yi-Qun Gu National Health Commission Key Laboratory of Male Reproductive Health Reproductive Health Research CenterNational Research Institute for Family PlanningBeijing 100081China Institute of Pediatric Research Children's Hospitalof Soochow UniversitySuzhou 215025China

Dear Editor,Semen analysis is a basic test to assess male fertility and is a fundamental test in assisted reproductive *** the first publication of World Health Organization(WHO)Laboratory Manual of Human Semen and Sperm-Cervical Mucus Interaction in 1980,to the publication of the WHO Manual,6th edition in 2021,these 40 years have been recognized as providing a global standard that is widely used in research and clinical laboratories *** WHO Manual,6th edition in Chinese,which we have been authorized by the WHO to translate,will be published soon.

关键词： technology. analysis translate

An Opposition-Based Learning-Based Search Mechanism for Flying Foxes Optimization Algorithm

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Computers, Materials & Continua 2024年第6期79卷 5201-5223页

作者： Chen Zhang Liming Liu Yufei Yang Yu Sun Jiaxu Ning Yu Zhang Changsheng Zhang ying guo Software College Northeastern UniversityShenyang110169China School of Information Science and Engineering Shenyang Ligong UniversityShenyang110159China China Telecom Digital Intelligence Technology Co. Ltd.Beijing100035China College of Computer Science and Engineering Ningxia Institute of Science and TechnologyShizuishan753000China

The flying foxes optimization(FFO)algorithm,as a newly introduced metaheuristic algorithm,is inspired by the survival tactics of flying foxes in heat wave *** preferentially selects the best-performing *** tendency will cause the newly generated solution to remain closely tied to the candidate optimal in the search *** address this issue,the paper introduces an opposition-based learning-based search mechanism for FFO algorithm(IFFO).Firstly,this paper introduces niching techniques to improve the survival list method,which not only focuses on the adaptability of individuals but also considers the population’s crowding degree to enhance the global search ***,an initialization strategy of opposition-based learning is used to perturb the initial population and elevate its ***,to verify the superiority of the improved search mechanism,IFFO,FFO and the cutting-edge metaheuristic algorithms are compared and analyzed using a set of test *** results prove that compared with other algorithms,IFFO is characterized by its rapid convergence,precise results and robust stability.

关键词： Flying foxes optimization(FFO)algorithm opposition-based learning niching techniques swarm intelligence metaheuristics evolutionary algorithms

Differential distribution of fibrovascular proliferative membranes in 25-gauge vitrectomy for proliferative diabetic retinopathy

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

International Journal of Ophthalmology(English edition) 2024年第8期17卷 1462-1468页

作者： Nan Lu Shi-Lin Yang Shuo guo Dong-Ni Yang Li Liu Chun-Hui Fan ying guo Jian Liu Wei Zhao Department of Ophthalmology the First Hospital of QinhuangdaoQinhuangdao 066000Hebei ProvinceChina School of Control Engineering Northeastern University at QinhuangdaoQinhuangdao 066004Hebei ProvinceChina

AIM:To analyze the distribution of fibrovascular proliferative membranes(FVPMs)in proliferative diabetic retinopathy(PDR)patients that treated with pars plana vitrectomy(PPV),and to evaluate the outcomes ***:This was a retrospective and cross-sectional *** 25-gauge(25-G)PPV cases operated for PDR from May 2018 to April *** to the FVPMs images outlined after operations,subjects were assigned into three groups:arcade type group,juxtapapillary type group,and central type *** patients were followed up for over one *** characteristics,operation-related variables,postoperative parameters and complications were ***:Among 103 eyes recruited,the FVPMs distribution of nasotemporal and inferiosuperioral was significantly different(both P<0.01),with 95(92.23%)FVPMs located in the nasal quadrants,and 74(71.84%)in the *** eyes with a central FVPM required the longest operation time,with silicon oil used in most patients,generally combined with tractional retinal detachment(RD)and rhegmatogenous RD,the worst postoperative bestcorrected visual acuity(BCVA)and the highest rates of recurrent RD(all P<0.05).FVPM type,age of onset diabetes mellitus,preoperative BCVA,and combined with tractional RD and rhegmatogenous RD were significantly associated with BCVA improvement(all P<0.05).Compared with the central type group,the arcade type group had higher rates of BCVA ***:FVPMs are more commonly found in the nasal and inferior mid-peripheral retina in addition to the area of arcade *** 25-G PPV for treating PDR eyes with central FVPM have relatively worse prognosis.

关键词： proliferative diabetic retinopathy fibrovascular proliferative membrane 25-gauge pars plana vitrectomy

黄色系硅化造礁石珊瑚的结构特征及颜色成因研究

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

岩石矿物学杂志 2024年第3期43卷 663-672页

作者：郭逸琳郭颖中国地质大学(北京)珠宝学院北京100083

近些年,黄色系硅化造礁石珊瑚以其独特的花纹和美丽的颜色受到了人们的关注和喜爱。为充分认识硅化造礁石珊瑚的结构特征及颜色成因,本文采用X射线粉末衍射仪、偏光显微镜、热场发射扫描电子显微镜、紫外-可见光分光光度计和拉曼光谱仪... 详细信息

近些年,黄色系硅化造礁石珊瑚以其独特的花纹和美丽的颜色受到了人们的关注和喜爱。为充分认识硅化造礁石珊瑚的结构特征及颜色成因,本文采用X射线粉末衍射仪、偏光显微镜、热场发射扫描电子显微镜、紫外-可见光分光光度计和拉曼光谱仪对3块天然黄色系硅化造礁石珊瑚进行了研究。结果表明:所研究的硅化造礁石珊瑚空腔区与隔片区石英颗粒的形态、种类及分布特征不同。当隔片和体壁所围成的空腔或是共骨之间的空腔足够大时,沿空腔内壁到中心,石英颗粒的种类和形态从不规则的细粒→他形的中粒→他形-半自形粗粒;当空腔受到挤压时,石英颗粒主要为他形或似纤维状的细粒石英。隔片区的石英颗粒主要为细粒石英。在偏光显微镜下观察到的黄色-褐红色的矿物经证实为针铁矿和赤铁矿,其中赤铁矿是黄色系硅化造礁石珊瑚的主要致色矿物。受造礁石珊瑚骨骼结构的影响,微观上针铁矿和赤铁矿总是以色素点的方式存在于极细粒或细粒石英颗粒的间隙,宏观上富集于隔片区和空腔边缘。

关键词：硅化造礁石珊瑚石英质玉二氧化硅结构特征颜色成因

AF-RetinaNet:一种基于自适应融合与特征细化的微小行人检测算法

在线全文

学校读者我要写书评

暂无评论

控制与决策 2024年第3期39卷 939-946页

作者：邵香迎郭颖王友伟南京信息工程大学江苏省大气环境与装备技术协同创新中心南京210044 南京信息工程大学自动化学院南京210044

为解决目前目标检测算法在微小行人的识别与定位过程中准确率较低的问题,提高微小行人检测能力,提出一种基于自适应融合与特征细化的微小行人检测算法AF-RetinaNet.首先,将特征增强模块与ResNet相结合构建特征提取网络,采用并行结构获... 详细信息

为解决目前目标检测算法在微小行人的识别与定位过程中准确率较低的问题,提高微小行人检测能力,提出一种基于自适应融合与特征细化的微小行人检测算法AF-RetinaNet.首先,将特征增强模块与ResNet相结合构建特征提取网络,采用并行结构获得增强特征;其次,使用上下文自适应学习模块,通过获得目标上下文的特征信息,从而关注相似特征的差异性,缓解误检问题;最后,构造具有图像超分思想的特征细化模块,对目标特征信息进行放大重构,优化小目标的特征表达能力,缓解漏检问题.在TinyPerson数据集上, AF-RetinaNet算法的检测精度达到56.78%,漏检率达到85.38%.与基于RetinaNet算法的研究基准相比,检测精度提高5.57%,漏检率降低3.67%.实验结果表明,该模型能有效提高对微小行人的检测和识别精度.

关键词：机器视觉微小行人小目标检测特征增强上下文信息特征细化

Author correction to“Identification of the dietary supplement capsaicin as an inhibitor of Lassa virus entry”[Acta Pharmaceutica Sinica B 10(2020)789-798]

在线全文

学校读者我要写书评

暂无评论

Acta Pharmaceutica Sinica B 2024年第7期14卷 3294-3294页

作者： Ke Tang Xiaoyu Zhang ying guo State Key Laboratory of Bioactive Substance and Function of Natural Medicines Institute of Materia MedicaChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100050China Department of Pharmacology Institute of Materia MedicaChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing 100050China

The authors regret that there is an error in Fig.2B(Page 793),in which the fluorescence image of the“DMSO(Before&during low pH treatment)”group was mistakenly pasted in the process of assembling *** correction does not significantly impact the findings and conclusions of the *** authors would like to assure readers that the corrected image does not alter the validity of the *** original data of these figures have been provided to the Editorial Office,and the corresponding authors or the Editorial Office can be contacted for original data access.

关键词： correction figures image