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Chinese Chemical Letters 2024年第3期35卷 538-543页

作者： Yini Mao Yong jiang Hao Liu yimin jiang Ming Li Wei Su Rongxing He Key Laboratory of Luminescence Analysis and Molecular Sensing(Southwest University) Ministry of EducationCollege of Chemistry and Chemical EngineeringSouthwest UniversityChongqing 400715China Key Laboratory of Beibu Gulf Environment Change and Resources Utilization(Nanning Normal University) Ministry of EducationCollege of Chemistry and Life ScienceNanning Normal UniversityNanning 530000China

Urea plays a vital role in the sustainable development of mankind as it is one of the most important nitrogen fertilizers.Conventional synthesis of urea is accompanied by a high level of energy consumption while electrocatalytic methods suffer from low yields and poor selectivity.Our work achieves efficient synthesis of urea by designing the graphene-In_(2)O_(3)electrocatalysts for the co-activated reduction of nitrate and carbon dioxide,where the formation rate of urea,Faraday efficiency(FE)and carbon selectivity at-0.35 V vs.RHE can reach 357.47μg mg^(-1)h^(-1),10.46%and~100%,respectively.Herein,the key intermediates in the C–N coupling reaction are demonstrated to be*NH_(2)and*CO_(2),which is of novelty compared to previous reports.This work may provide inspiration for subsequent studies on the reaction mechanism of the electrochemical synthesis of urea,as well as theoretical guidance for the sustainable synthesis of some other important chemical substances.

关键词： Graphene-supported In_(2)O_(3) Dispersion effect Efficient C-N coupling Key intermediate Urea

Transcription factor OsSPL10 interacts with OsJAmyb to regulate blast resistance in rice

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The Crop Journal 2024年第1期12卷 301-307页

作者： Zaofa Zhong Lijing Zhong Xiang Zhu yimin jiang Yihong Zheng Tao Lan Haitao Cui College of Life Science Fujian Agriculture and Forestry UniversityFuzhou 350002FujianChina Key Laboratory of Genetics Breeding and Multiple Utilization of CropsMinistry of EducationCollege of AgricultureFujian Agriculture and Forestry UniversityFuzhou 350002FujianChina Fujian Provincial Key Laboratory of Crop Breeding by Design Fujian Agriculture and Forestry UniversityFuzhou 350002FujianChina College of Plant Protection Shandong Agricultural UniversityTai’an 271018ShandongChina

Transcription factors(TFs)play essential roles in transcriptional reprogramming during activation of plant immune responses to pathogens.OsSPL10(SQUAMOSA promoter binding protein-like10)is an important TF regulating trichome development and salt tolerance in rice.Here we report that knockout of OsSPL10 reduces whereas its overexpression enhances rice resistance to blast disease.OsSPL10 positively regulates chitin-induced immune responses including reactive oxygen species(ROS)burst and callose deposition.We show that OsSPL10 physically associates with OsJAmyb,an important TF involved in jasmonic acid(JA)signaling,and positively regulates its protein stability.We then prove that OsJAmyb positively regulates resistance to blast.Our results reveal a molecular module consisting of OsSPL10 and OsJAmyb that positively regulates blast resistance.

关键词： Immunity Jasmonate Oryza sativa OsSPL10 Transcription factor

Enhancing the electrocatalytic performance of nitrate reduction to ammonia by in-situ nitrogen leaching

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Chinese Chemical Letters 2024年第2期35卷 564-569页

作者： Mimi Fu Yini Mao Hua Wang Wei Luo yimin jiang Wei Shen Ming Li Rongxing He College of Chemistry and Chemical Engineering Southwest UniversityChongqing 400715China

Electrochemical nitrate reduction reaction (NITRR) is regarded as a “two birds-one stone” method for the treatment of nitrate contaminant in polluted water and the synthesis of valuable ammonia, which is retarded by the lack of highly reactive and selective electrocatalysts .Herein, for the first time, nickel foam supported Co_(4) N was designed as a high-performance NITRR catalyst by an in-situ nonmetal leaching-induced strategy.At the optimal potential, the Co_(4) N/NF catalyst achieves ultra-high Faraday efficiency and NH_(3) selectivity of 95.4% and 99.4%, respectively.Ex situ X-ray absorption spectroscopy (XAS), together with other experiments powerfully reveal that the nitrogen vacancies produced by nitrogen leaching are stable and play a key role in boosting nitrate reduction to ammonia.Theoretical calculations confirm that Co_(4) N with abundant nitrogen vacancies can optimize the adsorption energies of NO_(3)^(-) and intermediates, lower the free energy (Δ G ) of the potential-determining step (*NH_(3) to NH_(3) ) and inhibit the formation of N-containing byproducts.In addition, we also conclude that the nitrogen vacancies can stabilize the adsorbed hydrogen, making H_(2) quite difficult to produce, and lowering ΔG from *NO to *NOH, which facilitates the selective reduction of nitrate.This study reveals significant insights about the in-situ nonmetal leaching to enhance the NITRR activity.

关键词： Co4N Nitrate reduction In-situ nonmetal leaching Nitrogen vacancy Mechanism

Interface engineering of FeCo LDH@NiCoP nanowire heterostructures for highly efficient and stable overall water splitting

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Chinese Chemical Letters 2022年第8期33卷 4003-4007页

作者： Yong jiang Yurong Li yimin jiang Xiaorui Liu Wei Shen Ming Li Rongxing He College of Chemistry and Chemical Engineering Southwest UniversityChongqing 400715China

Developing efficient and inexpensive OER electrocatalysts is a challenge for overall water splitting.Herein,the heterostructured Fe Co LDH@NiCoP/NF nanowire arrays with high performance were rationally designed and prepared using an interface engineering strategy.Benefitting from the special heterostructure between Fe Co LDH and Ni Co P,the as-synthesized Fe Co LDH@Ni Co P/NF electrocatalyst exhibits outstanding OER performance with an exceptionally low overpotential of 206 mV to achieve 20 mA/cm^(2)current density in an alkaline electrolyte.Importantly,a cell constructed using the FeCo LDH@NiCoP/NF electrocatalyst as cathode and anode just needs a voltage of 1.48 V at 10 mA/cm^(2),and shows excellent stability over 80 h.Experimental and theoretical results verified that the introduction of Ni Co P efficiently regulates the electronic structure of Fe Co LDH,which tremendously boosts the conductivity and intrinsic catalytic activity of FeCo LDH@NiCoP/NF electrocatalyst.The present work provides guidance for the preparation of other efficient and cheap electrocatalytic materials.

关键词： OER Heterostructure Interface engineering Water-splitting DFT

Electrochemistry enabled selective vicinal fluorosulfenylation and fluorosulfoxidation of alkenes

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Chinese Chemical Letters 2022年第4期33卷 2009-2014页

作者： Yi Yu yimin jiang Shaofen Wu Zhaojiang Shi Jinnan Wu Yaofeng Yuan Keyin Ye Key Laboratory of Molecule Synthesis and Function Discovery(Fujian Province University) College of ChemistryFuzhou UniversityFuzhou 350108china State Key Laboratory of Physical Chemistry of Solid Surfaces Xiamen UniversityXiamen 361005china

Both sulfur and fluorine play important roles in organic synthesis, the life science, and materials science.The direct incorporation of these elements into organic scaffolds with precise control of the oxidation states of sulfur moieties is of great significance. Herein, we report the highly selective electrochemical vicinal fluorosulfenylation and fluorosulfoxidation reactions of alkenes, which were enabled by the unique ability of electrochemistry to dial in the potentials on demand. Preliminary mechanistic investigations revealed that the fluorosulfenylation reaction proceeded through a radical-polar crossover mechanism involving a key episulfonium ion intermediate. Subsequent electrochemical oxidation of fluorosulfides to fluorosulfoxides were readily achieved under a higher applied potential with the adventitious H;O in the reaction mixture.

关键词： Alkene Chemoselectivity Electrochemistry Fluorine Sulfur

The Tibetan Plateau bridge:Influence of remote teleconnections from extratropical and tropical forcings on climate anomalies

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Atmospheric and Oceanic Science Letters 2024年第1期17卷 28-33页

作者： yimin Liu Wei Yu Jilan jiang Tingting Ma jiangyu Mao Guoxiong Wu State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics Institute of Atmospheric PhysicsChinese Academy of SciencesBeijingChina University of Chinese Academy of Sciences BeijingChina School of Atmospheric Sciences Sun Yat-sen UniversitySouthern Marine Science and Engineering Guangdong Laboratory(Zhuhai)ZhuhaiChina Guangdong Province Key Laboratory for Climate Change and Natural Disaster Studies Sun Yat-sen UniversityZhuhaiChina

本文回顾了青藏高原桥梁作用方面的最新研究进展,涉及北大西洋气候异常对春,夏亚洲季风和厄尔尼诺-南方涛动(ENSO)事件的遥相关影响,热带海洋异常和中国东部极端气候异常之间的联系以及华南春雨的季节内变化等.介绍了年际时间尺度上,冬... 详细信息

本文回顾了青藏高原桥梁作用方面的最新研究进展,涉及北大西洋气候异常对春,夏亚洲季风和厄尔尼诺-南方涛动(ENSO)事件的遥相关影响,热带海洋异常和中国东部极端气候异常之间的联系以及华南春雨的季节内变化等.介绍了年际时间尺度上,冬-春季北大西洋海表温度强迫如何影响南亚季风的季节性转变以及随后ENSO事件的触发.5月份青藏高原上空显著的负感热斜压结构,为北大西洋影响亚洲季风和ENSO提供了桥梁效应,夏季北大西洋涛动与华东夏季降水变化显著相关,高原潜热在这一关系中起着桥梁作用.另一方面,这种高原桥梁效应也存在于从热带海洋异常到东亚夏季极端降水事件的连接中,以及从中纬度波列到华南春雨准双周振荡的联系中.

关键词：青藏高原桥梁作用遥相关北大西洋厄尔尼诺-南方涛动热带对流气候异常和极端事件

Formation of mono-dispersed droplets with electric periodic dripping regime in electrohydrodynamic(EHD) atomization

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Chinese Journal of Chemical Engineering 2020年第5期28卷 1241-1249页

作者： Zhentao Wang Qisi Wang Yaosheng Zhang yimin jiang Lei Xia School of Energy and Power Engineering Jiangsu UniversityZhenjiang 212013China

The formation of controllable size and dripping frequency in electrohydrodynamic(EHD)atomization with electric periodic dripping regime are of much interest and importance because of significant and wide applications,such as micro-encapsulation and ink-printing.In the present study,the experimental and theoretical works were carried out to explore droplet formation in periodic dripping regime in presence of an electric field.The dimensionless electric charge carried by each droplet produced is smaller than the 50%of critical value of the Rayleigh limit,where charge-to-mass ratio of droplets was obtained through the deflection distance in the presence of an electric field.The droplet in electric periodic dripping regime usually undergoes oscillating deformation,and finally forms a spherical droplet below the tip no more than ten times out diameter of tube.The droplet size tens of microns to one hundreds of microns decreases with an increase in applied potential.In the electric dripping mode,droplets size is independent of flow rate and affected by flow rate due to adsorption of surface active species in micro-dripping.The simplified model to predict droplets size was derived from the balance of electric,surface tension and gravity forces.The droplets size calculated in good agreement with the experiments.Meanwhile,the dripping frequency of droplets with rang of a few to several hundred hertz obtained from timeresolved images is highly dependent of liquid flow rate and electric potential.The largest dripping frequency was predicted and in reasonable agreement with the experimental results.In electric periodic dripping regime drop-on-demand droplets in size and dripping frequency further our understanding on the formation of identical droplets and are beneficial to many practical applications.

关键词： Electric field Electric periodic dripping Formation Diameter Dripping frequency

Prevalence of bacteria, fungi, and virus coinfections with SARS-CoV-2 Omicron variant among patients with severe COVID-19 in Guangzhou, China, winter 2022

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Biosafety and Health 2024年第2期6卷 92-97页

作者： Qinghong Fan Mengling jiang Jun Zhang Guofang Tang Ming Gao Yingfen Wen Xizi Deng Jun Dai Honghao Lai Peng Qian Yaqing Lin Ruiying He Liya Li Yueping Li Zhengtu Li Xuesong Liu yimin Li Na Yu Yun Lan Fengyu Hu Feng Li Institute of Infectious Diseases Guangzhou Eighth People's HospitalGuangzhou Medical UniversityGuangzhou 510440China State Key Laboratory of Respiratory Disease National Clinical Research Center for Respiratory DiseaseGuangzhou Institute of Respiratory Healththe First Affliated Hospital of GuangzhouMedicalUniversityGuangzhou510120China Guangzhou Laboratory Guangzhou 510700China

The status of coinfection during the national outbreak of severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)Omicron BA.5.2 or BF.7 in China in the winter of 2022,which is suspected to contribute substan-tially to the overloaded severe cases,needs to be investigated.We analyzed the coinfection status of 385 severe patients infected with the Omicron variant in Guangzhou using metagenomic sequencing.We found that 317(82.3%)patients were coinfected with at least one additional pathogen(s),including bacteria(58.7%),fungi(27.1%)and viruses(73.5%).Pseudomonas aeruginosa(P.aeruginosa)(24.2%),Staphylococcus aureus(S.aur-eus)(14.0%),and Klebsiella pneumoniae(K.pneumonia)(13.4%)ranked as the top three coinfected bacteria.Aspergillus fumigatus(A.fumigatus)(39.5%),Pneumocystis jiroveci(P.jiroveci)(24.4%)and Canidia albicans(C.albicans)(22.1%)were the top three coinfected fungi.Epstein-Barr virus(EBV)(63.1%),Human herpesvirus 7(HHV-7)(34.8%),and Herpes simplex virus 1(HSV-1)(32.6%)were the top three coinfected viruses.Of note,the detection of multiple coinfections of potential pathogenic bacteria,fungi,and viruses,despite lacking con-sistent patterns,highlighted a complicated synergistic contribution to disease severity.Our study presents the most comprehensive spectrum of bacterial,fungal,and viral coinfections in Omicron-associated severe coron-avirus disease 2019(COVID-19),implying that the coinfection of conditional pathogens might synergistically deteriorate the Omicron infection outcomes.

关键词： SARS-CoV-2 Omicron BA.5.2 Omicron BF.7 Coinfection Severeinfection

基于逆系统解耦的三电平Buck变换器反步滑模控制

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电源学报 2024年第2期22卷 73-80页

作者：蒋经纬陆益民广西大学电气工程学院南宁530004

多电平变换器因其可以降低开关管承受的电压应力、减小滤波电感和滤波电容体积,被广泛应用在直流微电网中。三电平Buck变换器的飞跨电容电压和输出电压存在耦合,是一个多输入多输出、强耦合的非线性系统。针对这一问题,提出一种逆系统... 详细信息

多电平变换器因其可以降低开关管承受的电压应力、减小滤波电感和滤波电容体积,被广泛应用在直流微电网中。三电平Buck变换器的飞跨电容电压和输出电压存在耦合,是一个多输入多输出、强耦合的非线性系统。针对这一问题,提出一种逆系统解耦反步滑模控制方法。采用逆系统方法实现输出电压控制和飞跨电容电压控制的解耦,采用反步滑模法控制保证输出电压的稳定性和鲁棒性,通过状态反馈控制将飞跨电容电压平衡在输入电压的1/2处。仿真和实验结果表明,所提控制策略能使得飞跨电容电压和输出电压均具有良好的稳态和动态特性。

关键词：三电平Buck变换器多输入多输出系统解耦控制反步滑模控制

A novel ball-in-ball hollow oxygen-incorporating cobalt sulfide spheres as high-efficient electrocatalyst for oxygen evolution reaction

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Chinese Chemical Letters 2021年第2期32卷 755-760页

作者： Yurong Li Qifei Guo yimin jiang Wei Shen Ming Li Rongxing He College of Chemistry and Chemical Engineering Southwest UniversityChongqing 400715China

Transition-metal chalcogenides with hollow nanostructure,especially cobalt sulfides,are considered as the most pro mising non-precious metal catalysts for oxygen evolution reactio n.However,it is difficult to synthesize oxygen-containing cobalt sulphides with hollow structure due to the different physical/chemical properties between metal sulfides and metal cobalts.Herein,we report a novel oxygencontaining amorphous cobalt sulfide ball-in-ball hollow sphere s(Co-S-O BBHS) synthesized by an anion exchange method.Taking advantage of the ball-in-ball hollow structure,the amorphous Co-S-O BBHS shows supe rior oxygen evolution reaction(OER) electrocatalytic performance with a low overpotentiat of285 mV at 10 mA/cm2,small Tafel slope of 49.67 mV/dec,high Faraday efficiency of 96%,and satisfied durability.Experiments and DFT calculations demonstrate that the introduction of oxygen and sulfur modulates the electronic structure of Co-S-O BBHS,thus enhancing the adsorption of *0(adsorbed 0 species on catalyst surface) intermediate,which greatly boosts the catalytic activity towards OER.This work provides a new strategy for controllable synthe sis of complex hollow structures of transition-metal chalcogenides for OER.

关键词： Oxygen doped Sulfides Kirkendall effect Oxygen evolution reaction Electrocatalyst