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Immobilized CeO_(2)@C-N Heterogenous Structures with Enhanced Dual Modal Photodynamic/Photothermal Bacterial Inactivation Under NIR Laser Irradiation

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Journal of Analysis and Testing 2023年第3期7卷 189-203页

作者： yijun pang Zhiquan Chen Didi Yang Xuke Fan Zhenda Liang Yongtao Xu Sheng Ye Jiancong Liu Li Zhou Institute of Environmental Research at Great Bay Area Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou UniversityGuangzhou 510006China School of Pharmacy Hubei University of Science and TechnologyXianning 437100China

Non-antibiotic fungicides are urgently needed due to the potential threat of drug-resistant bacteria to human *** this research,a novel antibacterial nanoplatform based on CeO_(2)@C-N has been developed to achieve rapid near-infrared(NIR)laser-induced *** prepared CeO_(2)@C-N hybrid material exhibited a nanowire-like structure,with dispersed CeO_(2)nanoparticles averaging 5 nm in size within the heterogeneous configuration.X-ray photoelectron spectroscopy(XPS)and Raman spectra revealed that the heterogenous structures have a significant amount of oxygen vacancies and ***,CeO_(2)@C-N has a narrower band gap than CeO_(2),which allows for broader absorbance extending to the NIR *** these unique physiochemical properties,CeO_(2)@C-N could inactivate *** and MRSA at a low concentration(20 mg/L)under 808 nm NIR laser(1 W/cm^(2))*** excellent bactericidal activity of CeO_(2)@C-N is attributed to the combination of photodynamic and photo thermal processes,based on its excellent photo-thermal conversion property,detection of reactive oxygen species(ROS)(^(1)O_(2)and·OH)under light irradiation,and scavenger quenching experiment *** study offers a feasible and efficient way to fabricate a highly effective antibacterial candidate.

关键词： Photothermal Photodynamic Heterogenous structure Antibacterial Cerium Carbon

Removal of Cr(Ⅵ)by glutaraldehyde-crosslinked chitosan encapsulating microscale zero-valent iron:Synthesis,mechanism,and longevity

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Journal of Environmental Sciences 2024年第8期142卷 115-128页

作者： yijun Duan Fang Liu Xiang Liu Miao Li School of Environment Tsinghua UniversityBeijing 100084China Transportation Institute of Inner Mongolia University Hohhot 010070China

Microscale zero-valent iron(mZVI)has shown great potential for groundwater Cr(Ⅵ)***,low Cr(Ⅵ)removal capacity caused by passivation restricted the wide use of *** prepared mZVI/GCS by encapsulating mZVI in a porous glutaraldehydecrosslinked chitosan matrix,and the formation of the passivation layer was alleviated by reducing the contact between zero-valent iron *** average pore diameter of mZVI/GCS was 8.775 nm,which confirmed the mesoporous characteristic of this *** of batch experiments demonstrated that mZVI/GCS exhibited high Cr(Ⅵ)removal efficiency in a wide range of pH(2-10)and temperature(5-35℃).Common groundwater coexisting ions slightly affected m ZVI/*** material showed great reusability,and the average Cr(Ⅵ)removal efficiency was 90.41%during eight *** this study,we also conducted kinetics and isotherms ***-second-order model was the most matched kinetics *** Cr(Ⅵ)adsorption process was fitted by both Langmuir and Freundlich isotherms models,and the maximum Langmuir adsorption capacity of m ZVI/GCS reached243.63 mg/g,which is higher than the adsorption capacities of materials reported in most of the previous ***,the column capacity for Cr(Ⅵ)removal of a mZVI/GCS-packed column was 6.4 times higher than that of a mZVI-packed column in a 50-day ***,mZVI/GCS with a porous structure effectively relieved passivation problems of mZVI and showed practical application prospects as groundwater Cr(Ⅵ)remediation material with practical application prospects.

关键词： Chitosan Glutaraldehyde mZVI Cr(Ⅵ) Groundwater

Core-shell structured Ru-Ni@SiO_2: Active for partial oxidation of methane with tunable H_2/CO ratio

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Journal of Energy Chemistry 2018年第3期27卷 883-889页

作者： Yixuan Dou yijun pang Lingli Gu Yifan Ding Wu Jiang Xinzhen Feng Weijie Ji Chak-Tong Au Key Laboratory of Mesoscopic Chemistry MOE School of Chemistry and Chemical Engineering Nanjing University Department of Chemistry Hong Kong Baptist University

This study demonstrated that a Ru-Ni bimetallic core-shell catalyst（0.6%Ru-Ni）@Si O2with a proper surface Ru concentration is superior in achieving better catalytic activity and tunable H2/CO ratio at a comparatively lower reaction temperature（700℃）.Compared to the impregnation method,the hydrothermal approach leads to a highly uniform Ru distribution throughout the core *** Ru distribution would result in a proper surface Ru concentration as well as more direct Ru-Ni interaction,accounting for better catalyst *** surface Ru species hinders surface carbon deposition,but also declines overall activity and H2/CO ratio,meanwhile likely enhances Ni oxidation to certain degree under the applied reaction *** the current（m%Ru-Ni）@Si O2catalyst,the formation of fibrous carbon species is suppressed,which accounts for good stability of catalyst within a TOS of 10 h.

关键词： Ruthenium Nicolet Bimetallic Core-shell structure Partial oxidation of methane

High-efficiency crystalline white organic lightemitting diodes

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Light(Science & Applications) 2024年第4期13卷 747-759页

作者： yijun Liu Feng Zhu Yue Wang Donghang Yan State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China. School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei 230026China. State Key Laboratory of Supramolecular Structure and Materials Jilin UniversityChangchun 130012China

Crystalline white organic light-emitting diodes(C-WOLEDs)are promising candidates for lighting and display *** is urgently necessary,however,to develop energy-saving and high-efficiency C-WOLEDs that have stable and powerful emission to meet commercial ***,we report a crystalline host matrix(CHM)with embedded nanoaggregates(NA)structure for developing high-performance C-WOLEDs by employing a thermally activated delayed fluorescence(TADF)material and orange phosphorescent dopants(Phos.-D).The CHM-TADFNA-D WOLED exhibit a remarkable EQE of 12.8%,which is the highest performance WOLEDs based on crystalline *** device has a quick formation of excitons and a well-designed energy transfer process,and possesses a fast ramping of luminance and current *** to recently reported high-performance WOLEDs based on amorphous material route,the C-WOLED achieves a low series-resistance Joule-heat loss ratio and an enhanced photon output,demonstrating its significant potential in developing the next-generation WOLEDs.

关键词： diodes dopant crystalline

Heterophilic Graph Neural Network Based on Spatial and Frequency Domain Adaptive Embedding Mechanism

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Computer Modeling in Engineering & Sciences 2024年第5期139卷 1701-1731页

作者： Lanze Zhang yijun Gu Jingjie Peng College of Information and Cyber Security People’s Public Security University of ChinaBeijing100038China

Graph Neural Networks(GNNs)play a significant role in tasks related to homophilic *** GNNs,based on the assumption of homophily,employ low-pass filters for neighboring nodes to achieve information aggregation and ***,in heterophilic graphs,nodes from different categories often establish connections,while nodes of the same category are located further apart in the graph *** characteristic poses challenges to traditional GNNs,leading to issues of“distant node modeling deficiency”and“failure of the homophily assumption”.In response,this paper introduces the Spatial-Frequency domain Adaptive Heterophilic Graph Neural Networks(SFA-HGNN),which integrates adaptive embedding mechanisms for both spatial and frequency domains to address the aforementioned ***,for the first problem,we propose the“Distant Spatial Embedding Module”,aiming to select and aggregate distant nodes through high-order randomwalk transition probabilities to enhance modeling *** the second issue,we design the“Proximal Frequency Domain Embedding Module”,constructing adaptive filters to separate high and low-frequency signals of nodes,and introduce frequency-domain guided attention mechanisms to fuse the relevant information,thereby reducing the noise introduced by the failure of the homophily *** deploy the SFA-HGNN on six publicly available heterophilic networks,achieving state-of-the-art results in four of ***,we elaborate on the hyperparameter selection mechanism and validate the performance of each module through experimentation,demonstrating a positive correlation between“node structural similarity”,“node attribute vector similarity”,and“node homophily”in heterophilic networks.

关键词： Heterophilic graph graph neural network graph representation learning failure of the homophily assumption

An ensemble learning method to retrieve sea ice roughness from Sentinel-1 SAR images

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Acta Oceanologica Sinica 2024年第5期43卷 78-90页

作者： Pengyi Chen Zhongbiao Chen Runxia Sun yijun He School of Marine Sciences Nanjing University of Information Science&TechnologyNanjing 210044China East Sea Information Center of State Oceanic Administration Shanghai 200136China

Sea ice surface roughness(SIR)affects the energy transfer between the atmosphere and the ocean,and it is also an important indicator for sea ice *** obtain a small-scale SIR with high spatial resolution,a novel method is proposed to retrieve SIR from Sentinel-1 synthetic aperture radar(SAR)images,utilizing an ensemble learning ***,the two-dimensional continuous wavelet transform is applied to obtain the spatial information of sea ice,including the scale and direction of ice ***,a model is developed using the Adaboost Regression model to establish a relationship among SIR,radar backscatter and the spatial information of sea *** proposed method is validated by using the SIR retrieved from SAR images and comparing it to the measurements obtained by the Airborne Topographic Mapper(ATM)in the summer Beaufort *** determination of coefficient,mean absolute error,root-mean-square error and mean absolute percentage error of the testing data are 0.91,1.71 cm,2.82 cm,and 36.37%,respectively,which are ***,K-fold cross-validation and learning curves are analyzed,which also demonstrate the method’s applicability in retrieving SIR from SAR images.

关键词： 2-D Cauchy continuous wavelet transform(CWT) Adaboost Regression sea ice sea ice surface roughness

Enhanced High-Temperature Cycling Stability of Garnet-Based All Solid-State Lithium Battery Using a Multi-Functional Catholyte Buffer Layer

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Nano-Micro Letters 2024年第7期16卷 59-73页

作者： Leqi Zhao yijun Zhong Chencheng Cao Tony Tang Zongping Shao WA School of Mines:Minerals Energy and Chemical EngineeringCurtin UniversityPerthWA 6102Australia

The pursuit of safer and high-performance lithium-ion batteries(LIBs)has triggered extensive research activities on solid-state batteries,while challenges related to the unstable electrode-electrolyte interface hinder their practical *** has been used extensively to improve the cathode-electrolyte interface in garnet-based all-solid-state LIBs(ASSLBs),while it introduces new concerns about thermal *** this study,we propose the incorporation of a multi-functional flame-retardant triphenyl phos-phate additive into poly(ethylene oxide),acting as a thin buffer layer between LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)cathode and garnet *** electrochemical stability tests,cycling performance evaluations,interfacial thermal stability analysis and flammability tests,improved thermal stability(capacity retention of 98.5%after 100 cycles at 60℃,and 89.6%after 50 cycles at 80℃)and safety characteristics(safe and stable cycling up to 100℃)are *** on various materials characterizations,the mechanism for the improved thermal stability of the interface is *** results highlight the potential of multi-functional flame-retardant additives to address the challenges associated with the electrode-electrolyte interface in ASSLBs at high *** thermal modification in ASSLBs operating at elevated temperatures is also essential for enabling large-scale energy storage with safety being the primary concern.

关键词： Solid-state battery Cathode electrolyte interlayer Flame-retardant additive Cycling stability Interfacial stability

Recent progress and prospects of electrolytes for electrocatalytic nitrogen reduction toward ammonia

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Chinese Chemical Letters 2024年第4期35卷 3-16页

作者： Sajid Mahmood Haiyan Wang Fang Chen yijun Zhong Yong Hu Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Department of ChemistryZhejiang Normal UniversityJinhua 321004China The Center for Applied Mathematics and Bioinformatics(CAMB) Gulf University for Science and TechnologyMishref 32093Kuwait Hangzhou Institute of Advanced Studies Zhejiang Normal UniversityHangzhou 311231China

Electrochemical nitrogen reduction reaction(ENRR) provides a promising strategy to achieve sustainable synthesis of ammonia. However, despite great efforts devoted to this research field, the problems such as low energy efficiency and weak selectivity still impede its practical implementation. Most of the research to date has been concentrated on creating sophisticated electrocatalysts, and adequate knowledge of electrolytes is still lacking. Herein, the recent progress in electrolytes for ENRR, including alkaline, neutral,acidic, water-in-salt, organic, ionic liquid, and mixed water-organic electrolytes, is thoroughly reviewed to obtain an in-depth understanding of their effects on electrocatalytic performance. Recently developed representative electrocatalysts in various types of electrolytes are also introduced, and future research priorities of different electrolytes are proposed to develop new and efficient ENRR systems.

关键词： Electrocatalytic nitrogen reduction Ammonia Electrolytes Production rate Faradaic efficiency

Evaluation of the intracellular lipid-lowering effect of polyphenols extract from highland barley in HepG2 cells

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Food Science and Human Wellness 2024年第1期13卷 454-461页

作者： yijun Yao Zhifang Li Bowen Qin Xingrong Ju Lifeng Wang College of Food Science and Engineering/Collaborative Innovation Centre for Modern Grain Circulation and Safety Nanjing University of Finance and EconomicsNanjing 210023China

Active ingredients from highland barley have received considerable attention as natural products for developing treatments and dietary supplements against *** practical application,the research of food combinations is more significant than a specific food *** study investigated the lipid-lowering effect of highland barley polyphenols via lipase assay in vitro and HepG2 cells induced by oleic acid(OA).Five indexes,triglyceride(TG),total cholesterol(T-CHO),low density lipoprotein-cholesterol(LDL-C),aspartate aminotransferase(AST),and alanine aminotransferase(ALT),were used to evaluate the lipidlowering effect of highland barley *** also preliminary studied the lipid-lowering mechanism by Realtime fluorescent quantitative polymerase chain reaction(q PCR).The results indicated that highland barley extract contains many components with lipid-lowering effects,such as hyperoside and *** vitro,the lipase assay showed an 18.4%lipase inhibition rate when the additive contents of highland barley extract were 100μg/m *** intracellular lipid-lowering effect of highland barley extract was examined using 0.25 mmol/L OA-induced HepG2 *** results showed that intracellular TG,LDL-C,and T-CHO content decreased by 34.4%,51.2%,and 18.4%,*** and AST decreased by 51.6%and 20.7%compared with the untreated hyperlipidemic HepG2 cells.q PCR results showed that highland barley polyphenols could up-regulation the expression of lipid metabolism-related genes such as PPARγand Fabp4.

关键词： Highland barley Polyphenols extract Lipid-lowering effect HepG2 cells