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Graphene oxide wrapped-silica microspheres humidity sensor with fast response/recovery,high sensitivity,and selectivity for pig respiratory rate monitoring

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Science China(Technological Sciences) 2025年第2期68卷 86-96页

作者： Jing LI bo LI Ziqi LIAO Yunhui DUAN Xinglan FU Yuehua huang Guanglin LI College of Engineering and Technology Southwest UniversityChongqing 400715China Modern Agricultural Equipment Research Institute Xihua UniversityChengdu 610039China

Respiratory rate monitoring is of great significance in pig healthy breeding for the early detection and timely prevention of respiratory *** sensing is an important noncontact method to monitor pig respiration,which does not cause direct harm to pigs and meets the requirements of animal *** paper proposes a humidity sensor based on graphene oxide wrapped-silica microspheres(GO@SiO_(2)).First,the sensor shows fast response/recovery performances of 0.24/0.73 *** demonstrate that the wrapped microsphere structure can inhibit water *** is speculated that the wrapped microsphere structure can inhibit the stacking of GO,and its curved surface can promote the evaporation of water ***,the sensor shows a high sensitivity of 1.2%/%RH-4.2%/%RH in 11%-95%RH *** can be attributed to different sensing mechanisms,from hopping transport to increasing ion transport,leading to a significant change in the sensor’s ***,the sensor shows selectivity to water molecules due to the hydrophilic characteristic of GO and the significant increase in conductivity by ion ***,the sensor is applied to realize the respiratory rate monitoring of adult pigs and piglets.

关键词： pig respiratory monitoring GO@SiO_(2)humidity sensor fast response/recovery high sensitivity selectivity

Small modifications of endo-functionalized cavities lead to large changes in molecular interaction in water

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Science China Chemistry 2025年第1期68卷 369-376页

作者： Song-Meng Wang Hao Nian Yan-Fang Wang Li-Shuo Zheng Yu-Tao Zheng yi-Wei Dong Liping huang Xiaoping Wang Wei Jiang Liu-Pan Yang Department of Chemistry Southern University of Science and TechnologyShenzhen 518055China School of Pharmaceutical Science Hengyang Medical SchoolUniversity of South ChinaHengyang 421001China School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal ResourcesGuangxi Normal UniversityGuilin 541004China

Studying molecular recognition in aqueous environments is crucial for understanding biological ***,we present a series of N-doped endo-functionalized anthracene-based cavities by introducing inward-directed pyridine *** subtle modifications can significantly affect the binding properties of these receptors,which is similar to the mutations in biological *** theoretical calculations and molecular recognition experiments demonstrated that these“mutations”have an impact on the hydrophobicity and charge distribution of the hosts,consequently significantly influencing molecular *** is crucial for understanding the intricate mechanisms of molecular-level interactions in biological receptors.

关键词： host-guest interaction hydrophobic effect endo-functionalized cavity mutation pyridine

Exploring the performance of large language models on hepatitis B infection-related questions:A comparative study

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World Journal of Gastroenterology 2025年第3期31卷 103-112页

作者： Yu Li Chen-Kai huang yi Hu Xiao-Dong Zhou Cong He Jia-Wei Zhong Department of Gastroenterology Jiangxi Provincial Key Laboratory of Digestive DiseasesJiangxi Clinical Research Center for GastroenterologyDigestive Disease HospitalThe First Affiliated HospitalJiangxi Medical CollegeNanchang UniversityNanchang 330006Jiangxi ProvinceChina HuanKui Academy Nanchang UniversityNanchang 330006Jiangxi ProvinceChina

BACKGROUND Patients with hepatitis B virus(HBV)infection require chronic and personalized care to improve *** language models(LLMs)can potentially provide medical information for *** To examine the performance of three LLMs,ChatGPT-3.5,ChatGPT-4.0,and Google Gemini,in answering HBV-related *** LLMs’responses to HBV-related questions were independently graded by two medical professionals using a four-point accuracy scale,and disagreements were resolved by a third *** question was run three times using three *** was assessed via the Gunning Fog index and Flesch-Kincaid grade *** Overall,all three LLM chatbots achieved high average accuracy scores for subjective questions(ChatGPT-3.5:3.50;ChatGPT-4.0:3.69;Google Gemini:3.53,out of a maximum score of 4).With respect to objective questions,ChatGPT-4.0 achieved an 80.8%accuracy rate,compared with 62.9%for ChatGPT-3.5 and 73.1%for Google *** the six domains,ChatGPT-4.0 performed better in terms of diagnosis,whereas Google Gemini demonstrated excellent clinical ***,in the readability analysis,the mean Gunning Fog index and Flesch-Kincaid grade level scores of the three LLM chatbots were significantly higher than the standard level eight,far exceeding the reading level of the normal *** Our results highlight the potential of LLMs,especially ChatGPT-4.0,for delivering responses to HBV-related *** may be an adjunctive informational tool for patients and physicians to improve ***,current LLMs should not replace personalized treatment recommendations from physicians in the management of HBV infection.

关键词： ChatGPT-3.5 ChatGPT-4.0 Google Gemini Hepatitis B infection Accuracy

Perceived Social Support and Symptoms of Depression and Anxiety among Chinese Adolescents:A Moderated Chain Mediation Model

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International Journal of Mental Health Promotion 2025年第1期27卷 29-40页

作者： Le-Qing Jin Chen-Wei Pan Chun-Hua Zhao Dan-Lin Li yi-bo Wu Tian-Yang Zhang School of Public Health Suzhou Medical CollegeSoochow UniversitySuzhou215123China Department of General Medicine and Big Data Center The Affiliated Suzhou Hospital of Nanjing Medical UniversitySuzhou215008China School of Public Health Peking UniversityBeijing100191China Graduate School of Interdisciplinary Science and Engineering in Health Systems Okayama UniversityOkayama700-8530Japan

Background:Although previous studies indicate that perceived social support might be associated with adolescent psychological problems,the specific mechanism has not been thoroughly *** on theoretical and empirical research on problematic Internet use(PIU)and sleep quality,this study explored whether they play a mediating role between perceived social support and symptoms of depression and anxiety among ***,we investigated whether these relationships varied by place of ***:A sample of 2115 Chinese adolescents was included,and analyzed data related to perceived social support,PIU,sleep quality,symptoms of depression and anxiety,and sociodemographic *** analysis,mediation,and moderation analysis were mainly ***:Perceived social support was negatively correlated with depressive symptoms(r=−0.22,p<0.001)and anxiety symptoms(r=−0.20,p<0.001)among *** and sleep quality played a chain mediating role in the relationship between perceived social support and symptoms of depression and anxiety in ***,the place of residence moderated the relationships between perceived social support and PIU and symptoms of depression and *** social support was a significant negative predictor of PIU and symptoms of depression and anxiety among adolescents in urban areas but not in rural ***:The findings suggest that low levels of perceived social support may lead to more PIU and poorer sleep quality,which may further increase the risk of symptoms of depression and anxiety in adolescents,especially in urban areas.

关键词： Perceived social support psychological problems problematic internet use sleep quality urban-rural difference

Disruption of Energy Metabolism and Reactive Oxygen Species Homeostasis in Honglian Type-Cytoplasmic Male Sterility(HL-CMS)Rice Pollen

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Rice science 2025年第1期32卷 81-93,I0056-I0058页

作者： WANG Mingyue ZHAO Weibo FENG Xiaoya CHEN yi LI Junhao FU Jinmei YAN yingchun CHU Zhaohui huang Wenchao State Key Laboratory of Hybrid Rice Key Laboratory for Research and Utilization of Heterosis in Indica Ricethe Ministry of Agriculture and Rural Affairs/Department of GeneticsCollege of Life SciencesWuhan UniversityWuhan 430072China

Honglian type-cytoplasmic male sterility(HL-CMS)is caused by the inter-communication between the nucleus and ***,the mechanisms by which sterility genes regulate metabolic alterations and changes in mitochondrial morphology in the pollen of HL-CMS remain *** this study,we compared the morphological differences between the pollen of the male sterile line YA and the near-isogenic line NIL-Rf6 using hematoxylin-eosin staining and 4ʹ,6-diamidino-2-phenylindole(DAPI)***-CMS is characterized by gametophytic sterility,where the aborted pollen grains are empty,and the tapetal layer remains *** electron microscopy was employed to observe mitochondrial morphological changes at the microspore stage,revealing significant mitochondrial alterations,characterized by the formation of'large spherical mitochondria',occurred at the binucleate stage in the YA ***,metabolomics analysis revealed decreased levels of metabolites associated with the carbohydrate and flavonoid ***,the decrease in flavonoids was found to contribute to an elevation in reactive oxygen species(ROS)***,we propose a model in which rice fertility is modulated by the levels of pollen carbohydrates and flavonoid metabolites,with impaired mitochondrial energy production and reduced flavonoid biosynthesis as the main causes of ROS accumulation and pollen abortion in rice.

关键词： cytoplasmic male sterility pollen reactive oxygen species rice mitochondrial metabolite

Predictive value of a constructed artificial neural network model for microvascular invasion in hepatocellular carcinoma:A retrospective study

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World Journal of Gastrointestinal Oncology 2025年第1期17卷 88-100页

作者： Hai-Yang Nong Yong-yi Cen Shan-Jin Lu Rui-Sui huang Qiong Chen Li-Feng huang Jian-Ning huang Xue Wei Man-Rong Liu Lin Li Ke Ding Department of Radiology The Third Affiliated Hospital of Guangxi Medical UniversityNanning 530031Guangxi Zhuang Autonomous RegionChina Department of Radiology Affiliated Hospital of Youjiang Medical University for NationalitiesBaise 533000Guangxi Zhuang Autonomous RegionChina Guangxi Clinical Medical Research Center for Hepatobiliary Diseases Affiliated Hospital of Youiiang Medical University for NationalitiesBaise 533000Guangxi Zhuang Autonomous RegionChina Department of Ultrasound The Third Affiliated Hospital of Guangxi Medical UniversityNanning 530031Guangxi Zhuang Autonomous RegionChina Department of Hepatobiliary Surgery The Third Affiliated Hospital of Guangxi Medical UniversityNanning 530031Guangxi Zhuang Autonomous RegionChina

BACKGROUND Microvascular invasion(MVI)is a significant risk factor for recurrence and metastasis following hepatocellular carcinoma(HCC)***,there is a paucity of preoperative evaluation approaches for *** To investigate the predictive value of texture features and radiological signs based on multiparametric magnetic resonance imaging in the non-invasive preoperative prediction of MVI in *** Clinical data from 97 HCC patients were retrospectively collected from January 2019 to July 2022 at our *** were classified into two groups:MVI-positive(n=57)and MVI-negative(n=40),based on postoperative pathological *** correlation between relevant radiological signs and MVI status was ***4.6 software and the mutual information method were employed to identify the top 10 dominant texture features,which were combined with radiological signs to construct artificial neural network(ANN)models for MVI *** predictive performance of the ANN models was evaluated using area under the curve,sensitivity,and *** models with relatively high predictive performance were screened using the DeLong test,and the regression model of multilayer feedforward ANN with backpropagation and error backpropagation learning method was used to evaluate the models’*** The absence of a pseudocapsule,an incomplete pseudocapsule,and the presence of tumor blood vessels were identified as independent predictors of HCC *** ANN model constructed using the dominant features of the combined group(pseudocapsule status+tumor blood vessels+arterial phase+venous phase)demonstrated the best predictive performance for MVI status and was found to be automated,highly operable,and very *** The ANN model constructed using the dominant features of the combined group can be recommended as a noninvasive method for preoperative prediction of HCC MVI status.

关键词： Hepatocellular carcinoma Texture analysis Magnetic resonance imaging Microvascular invasion Pseudocapsule Tumor blood vessels

Effect of h-BN rods on high-temperature properties of alumina-carbon refractory

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Journal of Iron and Steel Research International 2025年第1期32卷 115-128页

作者： Ya-ge Li Shuai-bing Wu Feng Liang Zhong huang Tu Long Long Dong Jun-yi Lv Hong-juan Duan Biao Wen Yong Liu Hai-jun Zhang The State Key Laboratory of Refractories and Metallurgy Wuhan University of Science and TechnologyWuhan430081HubeiChina Sinosteel Luoyang Institute of Refractories Research Co. Ltd.Luoyang471039HenanChina

h-BN rods modified low-carbon alumina-carbon(Al_(2)O_(3)-C)refractories were prepared,and the effect of h-BN rod addition on the high-temperature properties was investigated and compared with commercial h-BN flake,carbon black,and carbon nanotubes *** results demonstrated that Al_(2)O_(3)-C refractories containing h-BN rods exhibited optimal high-temperature service performances,including 25%higher hot modulus of rupture,21.3%higher thermal shock strength residual ratio,20.9%lower in oxidation and 44.3%less in slag corrosion,compared to the counterpart specimens without ***,benefiting from the synergistic enhancement of the rod-like h-BN and in-situ generated SiC whiskers,the high-temperature service performances of h-BN rods containing specimens outperformed counterpart specimens containing commercial h-BN flake,carbon black,and carbon nanotubes,respectively.

关键词： Al_(2)O_(3)-C refractory h-BN rod Microstructure High-temperature service performance

Stretchable All-Small-Molecule Organic Solar Cells Enabled by Polymer Elastomer Confinement

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Chinese Journal of Polymer Science 2025年第2期43卷 271-277页

作者： Chen-yi Zhang Yu-Qiang Liu Hong-Xiang Li Xin-Yue Cui Zheng-Dong Wei Yue-Heng Liu Ming-Hua Li An-Dong Zhang Pei Cheng Zhi-Shan bo College of Textiles&Clothing State Key Laboratory of Bio-fibers and Eco-textilesQingdao UniversityQingdao266071China State Key Laboratory of Polymer Materials Engineering College of Polymer Science and EngineeringSichuan UniversityChengdu610065China College of Materials Science and Engineering Qingdao UniversityQingdao266071China Beijing Key Laboratory of Energy Conversion and Storage Materials College of ChemistryBeijing Normal UniversityBeijing100875China

Intrinsic stretchability is a promising attribute of polymer organic solar cells(OSCs).However,rigid molecular blocks typically exhibit poor tensile properties,rendering polymers vulnerable to mechanical *** this study,we introduce a different approach utilizing all-small-molecule donors and acceptors to fabricate stretchable *** elastomer,styrene-b-ethylene-butylene-styrene(SEBS),was embedded to modulate film crystallization and *** effectively confines the growth process of donors and acceptors,leading to enhancement of the crystallization quality,thus contributing to enhanced device ***,SEBS can absorb and release mechanical stress during stretching,thereby preventing mechanical degradation of donors and *** mechanical properties of the OSCs were significantly improved by the incorporation of ***,the crack-onset strain increased from 1.03% to 5.99% with SEBS *** findings present a straightforward strategy for achieving stretchable OSCs using all small molecules,offering a different perspective for realizing stretchable devices.

关键词： All-small-molecule Organic solar cells Elastomer Stretchability Flexibility

Phase field modeling of the aspect ratio dependent functional properties of NiTi shape memory alloys with different grain sizes

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Acta Mechanica Sinica 2025年第1期41卷 22-41页

作者： bo Xu Beihai huang Chong Wang Qingyuan Wang Failure Mechanics and Engineering Disaster Prevention Key Laboratory of Sichuan ProvinceSichuan UniversityChengdu 610065China Department of Mechanical Science and Engineering College of Architecture and EnvironmentSichuan UniversityChengdu 610065China Key Laboratory of Deep Underground Science and Engineering(Sichuan University) Ministry of EducationChengdu 610065China

It is well known that coarse-grained super-elastic NiTi shape memory alloys(SMAs)exhibit localized rather than homogeneous martensite transformation(MT),which,however,can be strongly influenced by either internal size(grain size,GS)or the external size(geometric size).The coupled effect of GS and geometric size on the functional properties has not been clearly understood *** this work,the super-elasticity,one-way,and stress-assisted two-way shape memory effects of the polycrystalline NiTi SMAs with different aspect ratios(length/width for the gauge section)and different GSs are investigated based on the phase field *** coupled effect of the aspect ratio and GS on the functional properties is adequately *** simulated results indicate that when the aspect ratio is lower than about 4:1,the stress biaxiality and stress heterogeneity in the gauge section of the sample become more and more obvious with decreasing the aspect ratio,which can significantly influence the microstructure evolution in the process involving external ***,the corresponding functional property is strongly dependent on the aspect *** decreasing the GS and the aspect ratio(to be lower than 4:1),both the aspect ratio and GS can affect the MT or martensite reorientation in each grain and the interaction among ***,due to the strong internal constraint(i.e.,the constraint of grain boundary)and the external constraint(i.e.,the constraint of geometric boundary),the capabilities of the functional properties of NiTi SMAs are gradually weakened and highly dependent on these two factors.

关键词： Phase field modeling NiTi Aspect ratio Grain size Functional property