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Low-Temperature Fabrication of Stable Black-Phase CsPbI₃ Perovskite Flexible Photodetectors Toward Wearable Health Monitoring

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NANO-MICRO LETTERS 2025年第1期17卷 1-14页

作者： Zhao, yingjie Sun, yicheng Pei, Chaoxin yin, Xing Li, Xinyi Hao, yi Zhang, Mengru Yuan, Meng Zhou, Jinglin chen, Yu Song, Yanlin Zhengzhou Univ Coll Chem Zhengzhou 450001 Peoples R China Zhengzhou Univ Pingyuan Lab Zhengzhou 450001 Peoples R China Chinese Acad Sci Inst Chem Key Lab Green Printing Beijing 100190 Peoples R China Chinese Acad Sci Tech Inst Phys & Chem Key Lab Bioinspired Mat & Interfacial Sci Beijing 100190 Peoples R China Chinese Acad Sci Inst High Energy Phys Beijing 100049 Peoples R China

Low-temperature fabrication of black-phase CsPbI3 perovskite films is first demonstrated by using diphenylphosphinic chloride additive under 30-50 degrees C, arising from the steric effect and chloride insertion ***-area high-quality all-inorganic perovskite films with fewer defects enhanced crystallographic orientation, and excellent environmental stability is *** record performances are demonstrated for flexible wearable photodetectors with a responsivity of 42.1 A W-1, a detectivity of 1.3 x 1014 Jones, high-fidelity image, photoplethysmography sensor functions, and high mechanical stability. Flexible wearable optoelectronic devices fabricated from organic-inorganic hybrid perovskites significantly accelerate the development of portable energy, biomedicine, and sensing fields, but their poor thermal stability hinders further applications. Conversely, all-inorganic perovskites possess excellent thermal stability, but black-phase all-inorganic perovskite film usually requires high-temperature annealing steps, which increases energy consumption and is not conducive to the fabrication of flexible wearable devices. In this work, an unprecedented low-temperature fabrication of stable black-phase CsPbI3 perovskite films is demonstrated by the in situ hydrolysis reaction of diphenylphosphinic chloride additive. The released diphenyl phosphate and chloride ions during the hydrolysis reaction significantly lower the phase transition temperature and effectively passivate the defects in the perovskite films, yielding high-performance photodetectors with a responsivity of 42.1 A W-1 and a detectivity of 1.3 x 1014 Jones. Furthermore, high-fidelity image and photoplethysmography sensors are demonstrated based on the fabricated flexible wearable photodetectors. This work provides a new perspective for the low-temperature fabrication of large-area all-inorganic perovskite flexible optoelectronic devices.

关键词： In situ hydrolyzation Low-temperature processing All-inorganic perovskite Flexible photodetectors Health monitoring

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Exosomes:the next-generation therapeutic platform for ischemic stroke

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Neural Regeneration Research 2025年第5期20卷 1221-1235页

作者： Wenjing yin Hongyin Ma Yang Qu Jiaxin Ren yingying Sun Zhen-Ni Guo yi Yang Stroke Center Department of NeurologyFirst Hospital of Jilin UniversityChangchunJilin ProvinceChina Neuroscience Research Center Department of NeurologyFirst Hospital of Jilin UniversityChangchunJilin ProvinceChina

Current therapeutic strategies for ischemic stroke fall short of the desired objective of neurological functional ***,there is an urgent need to develop new methods for the treatment of this *** are natural cell-derived vesicles that mediate signal transduction between cells under physiological and pathological *** have low immunogenicity,good stability,high delivery efficiency,and the ability to cross the blood–brain *** physiological properties of exosomes have the potential to lead to new breakthroughs in the treatment of ischemic *** rapid development of nanotechnology has advanced the application of engineered exosomes,which can effectively improve targeting ability,enhance therapeutic efficacy,and minimize the dosages *** in technology have also driven clinical translational research on *** this review,we describe the therapeutic effects of exosomes and their positive roles in current treatment strategies for ischemic stroke,including their antiinflammation,anti-apoptosis,autophagy-regulation,angiogenesis,neurogenesis,and glial scar formation reduction ***,it is worth noting that,despite their significant therapeutic potential,there remains a dearth of standardized characterization methods and efficient isolation techniques capable of producing highly purified *** optimization strategies should prioritize the exploration of suitable isolation techniques and the establishment of unified workflows to effectively harness exosomes for diagnostic or therapeutic applications in ischemic ***,our review aims to summarize our understanding of exosome-based treatment prospects in ischemic stroke and foster innovative ideas for the development of exosome-based therapies.

关键词： blood–brain barrier electroacupuncture engineering exercise exosomes ischemic stroke mesenchymal stem cells microglia neuroprotection stents

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尿素态氮水平对烤烟漂浮育苗中营养生长和生理特性的影响

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华北农学报 2008年第1期23卷 128-132页

作者：习向银陈益银刘国顺时向东西南大学资源环境学院重庆400715 河南农业大学河南郑州450002

2001-2002年,在河南农业大学试验站采用漂浮育苗方式研究了不同尿素态氮水平对烤烟烟苗营养生长和生理特性的影响。结果表明,尿素态氮为15%,对烤烟漂浮育苗营养生长和生理特性无不良影响。与对照相比,当尿素态氮为75%时,烟苗的生长受到... 详细信息

2001-2002年,在河南农业大学试验站采用漂浮育苗方式研究了不同尿素态氮水平对烤烟烟苗营养生长和生理特性的影响。结果表明,尿素态氮为15%,对烤烟漂浮育苗营养生长和生理特性无不良影响。与对照相比,当尿素态氮为75%时,烟苗的生长受到明显抑制,叶片的光合特性和NR活性降低,根系吸收能力下降。

关键词：烤烟漂浮育苗尿素态氮生理特性

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二茂二氯化钛存在下炔烃的还原反应

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化学学报 1988年第7期46卷 703-705页

作者：刘以寅陈美文南开大学元素有机化学研究所天津

Sato等曾研究了异丁基溴化镁借助二茂二氯化钛(Cp_(2)TiCl_(2))的催化作用,于温和条件下对若干炔烃的还原过程[1].反应结果生成高选择性的顺式烯烃.反应起始于二茂钛氢化物[Cp_(2)TiH]的形成.

关键词：炔烃氢化产物异构体脂肪族不饱和烃烯烃取代乙炔

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Magneto‑Dielectric Synergy and Multiscale Hierarchical Structure Design Enable Flexible Multipurpose Microwave Absorption and Infrared Stealth Compatibility

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Nano-Micro Letters 2025年第2期17卷 401-416页

作者： chen Li Leilei Liang Baoshan Zhang yi Yang Guangbin Ji School of Electronic Science and Engineering Nanjing UniversityNanjing 210093People’s Republic of China College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 210016People’s Republic of China

Developing advanced stealth devices to cope with radar-infrared(IR)fusion detection and diverse application scenarios is increasingly demanded,which faces significant challenges due to conflicting microwave and IR cloaking mechanisms and functional integration ***,we propose a multiscale hierarchical structure design,integrating wrinkled MXene IR shielding layer and flexible Fe_(3)O_(4)@C/PDMS microwave absorption *** top wrinkled MXene layer induces the intensive diffuse reflection effect,shielding IR radiation signals while allowing microwave to pass ***,the permeable microwaves are assimilated into the bottom Fe_(3)O_(4)@C/PDMS layer via strong magneto-electric *** theoretical and experimental optimization,the assembled stealth devices realize a near-perfect stealth capability in both X-band(8–12 GHz)and long-wave infrared(8–14μm)wavelength ***,it delivers a radar cross-section reduction of−20 dB m^(2),a large apparent temperature modulation range(ΔT=70℃),and a low average IR emissivity of ***,the optimal device demonstrates exceptional curved surface conformability,self-cleaning capability(contact angle≈129°),and abrasion resistance(recovery time≈5 s).This design strategy promotes the development of multispectral stealth technology and reinforces its applicability and durability in complex and hostile environments.

关键词： Microwave absorption Radar-infrared compatible stealth Wrinkled MXene Magneto-dielectric synergy Multifunction

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磷对烤烟漂浮育苗生长和生理特性的影响

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河南农业科学 2008年第1期37卷 33-36页

作者：习向银陈益银刘国顺陈永生西南大学资源环境学院重庆400715 河南农业大学河南郑州450002 红塔集团长春卷烟厂吉林长春130031

2001-2002年，以NC89为供试烟草品种，采用叶县烟草公司所产的商品基质和育苗专用肥，在河南农业大学试验站进行了磷对烤烟漂浮育苗生长和生理特性的影响。结果表明，施磷处理烟苗长势好，叶片中矿质元素含量丰富，叶绿素含量、NR活性... 详细信息

2001-2002年，以NC89为供试烟草品种，采用叶县烟草公司所产的商品基质和育苗专用肥，在河南农业大学试验站进行了磷对烤烟漂浮育苗生长和生理特性的影响。结果表明，施磷处理烟苗长势好，叶片中矿质元素含量丰富，叶绿素含量、NR活性、根系活力均高于未施磷处理；且营养液中磷浓度以100-150mg／L为佳。

关键词：烤烟漂浮育苗生长发育生理特性磷素

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经历科学探究提升核心素养——以“瞬时加速度”习题课的教学为例

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物理教学探讨 2024年第1期42卷 29-32页

作者：陈一垠浙江省桐庐中学浙江桐庐311500

高中物理新课标把“科学探究”作为物理学科核心素养的一个重要维度。以“瞬时加速度”这节习题课为例,通过科学探究的形式对教学难点展开教学,借助手机、DIS传感器和电脑等现代化技术设备突破学生思维难点,从而提升学生的科学思维和科... 详细信息

高中物理新课标把“科学探究”作为物理学科核心素养的一个重要维度。以“瞬时加速度”这节习题课为例,通过科学探究的形式对教学难点展开教学,借助手机、DIS传感器和电脑等现代化技术设备突破学生思维难点,从而提升学生的科学思维和科学探究能力。

关键词：模型建构科学探究科学思维核心素养瞬时加速度

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经钛环中间体合成三芳基乙烯

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化学学报 1985年第6期43卷 539-545页

作者：刘以寅陈美文王积涛南开大学元素有机化学研究所南开大学化学系南开大学化学系天津

通过连续反应,合并操作等途径对 Masai-Rausch 反应进行了改进,提高了烯烃收率,并扩大了合成的适用范围,使其成为某些专一几何构型三芳基乙烯的合成方法之一.用改进方法合成了一些立体专一性的三芳基乙烯,收率一般为50～70％.产物除经... 详细信息

通过连续反应,合并操作等途径对 Masai-Rausch 反应进行了改进,提高了烯烃收率,并扩大了合成的适用范围,使其成为某些专一几何构型三芳基乙烯的合成方法之一.用改进方法合成了一些立体专一性的三芳基乙烯,收率一般为50～70％.产物除经常规分析外,还通过钛环中间体的分离与分析、比较烯烃异构化前后的波谱变化、烯烃氧化产物的制备以及反应历程分析,确定了它们的结构.

关键词：三芳基钛环乙烯烯烃烯烃异构化中间体

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Tuning the interfacial reaction environment via pH-dependent and induced ions to understand C–N bonds coupling performance in NO3- integrated CO2 reduction to carbon and nitrogen compounds over dual Cu-based N-doped carbon catalyst

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Journal of Energy Chemistry 2025年第1期100卷 273-285页

作者： Tianhang Zhou chen Shen Zhenghao Wu Xingying Lan yi Xiao College of Carbon Neutrality Future Technology State Key Laboratory of Heavy Oil Processing China University of Petroleum (Beijing) Institute of Materials Science TU Darmstadt Department of Chemistry Xi'an Jiaotong-Liverpool University Department of Mechanical and Mechatronics Engineering and Waterloo Institute of Nanotechnology University of Waterloo Waterloo

Dual atomic catalysts （DAC）,particularly copper （Cu2）-based nitrogen （N） doped graphene,show great potential to effectively convert CO2and nitrate （NO3-） into important industrial chemicals such as ethylene,glycol,acetamide,and urea through an efficient catalytical process that involves C–C and C–N ***,the origin of the coupling activity remained unclear,which substantially hinders the rational design of Cu-based catalysts for the N-integrated CO2reduction reaction （CO2RR）.To address this challenge,this work performed advanced density functional theory calculations incorporating explicit solvation based on a Cu2-based N-doped carbon (Cu2N6C10) catalyst for *** calculations are aimed to gain insight into the reaction mechanisms for the synthesis of ethylene,acetamide,and urea via coupling in the interfacial reaction *** to the sluggishness of CO2,the formation of a solvation electric layer by anions （F-,Cl-,Br-,and I-） and cations (Na+,Mg2+,K+,and Ca2+) leads to electron transfer towards the Cu *** process significantly accelerates the reduction of *** results reveal that*CO intermediates play a pivotal role in N-integrated ***,the Cu2-based N-doped carbon catalyst examined in this study has demonstrated the most potential for C–N coupling to *** findings reveal that through the process of a condensation reaction between*CO and NH2OH for urea synthesis,*NO3-is reduced to*NH3,and*CO2to*CCO at dual Cu atom *** dual-site reduction facilitates the synthesis of acetamide through a nucleophilic reaction between NH3and the ketene ***,we found that the I-and Mg2+ions,influenced by pH,were highly effective for acetamide and ammonia synthesis,except when F-and Ca2+were ***,the mechanisms of C–N bond formation were investigated via ab-initio molecular dynamics simulations,and we found that adjusting the micro-environment can change the dominant side reaction,shift

关键词： pH-dependent micro-environments C–N coupling Dual Cu-based nitrogen carbon catalysts Explicit solvation model Ion stabilizer AIMD

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Mesospheric tide comparisons at low latitudes observed by two collocated meteor radars

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Earth and Planetary Physics 2025年第1期9卷 54-68页

作者： Jian Li Wen yi XiangHui Xue Jie Zeng HaiLun Ye JianYuan Wang JinSong chen Na Li TingDi chen Chinese Academy of Sciences(CAS)Key Laboratory of Geospace Environment Department of Geophysics and Planetary SciencesUniversity of Science and Technology of ChinaHefei 230026China CAS Center for Excellence in Comparative Planetology Anhui Mengcheng Geophysics National Observation and Research StationUniversity of Science and Technology of ChinaHefei 230026China Hefei National Laboratory University of Science and Technology of ChinaHefei 230026China Collaborative Innovation Center of Astronautical Science and Technology Harbin 150001China National Key Laboratory of Electromagnetic Environment China Research Institute of Radiowave PropagationQingdao 266107China Yunnan Kunming Electromagnetic Environment National Observation and Research Station Qujing Kunming 655000China

Accurate knowledge of mesospheric winds and waves is essential for studying the dynamics and climate in the mesosphere and lower thermosphere(MLT)*** this study,we conduct a comparative analysis of the mesosphere tidal results obtained from two adjacent meteor radars at low latitudes in Kunming,China,from November 2013 to December *** two radars operate at different frequencies of 37.5 MHz and 53.1 MHz,***,overall good agreement is observed between the two radars in terms of horizontal winds and tide *** results show that the dominant tidal waves of the zonal and meridional winds are diurnal and semidiurnal ***,we conduct an exhaustive statistical analysis to compare the tidal amplitudes and vertical wavelengths recorded by the dual radar systems,which reveals a high degree of alignment in tidal *** investigation includes variances and covariances of tidal amplitudes,which demonstrate remarkable consistency across measurements from both *** finding highlights clear uniformity in the mesospheric tidal patterns observed at low latitudes by the two neighboring meteor *** of the comparative analysis specifically underscore the significant correlation in vertical wavelength measurements,validating the robustness of radar observations for tidal research.

关键词： mesosphere and lower thermosphere region meteor radar mesospheric winds tides

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