检索结果-南通市图书馆

Label-free quantification of peptides in solution by disposable patterned hydrophilic chip based MALDI imaging

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2016年第6期27卷 901-904页

作者： Ting Wu Xiao-Hui Yang Chuan-Jing Zhang Zhen-ping Wang yi-ping du Shanghai Key Laboratory of Functional Materials Chemistry Research Centre of Analysis and Test East China University of Science and Technology

Quantification of a mixture of peptides in solution was achieved by disposable patterned hydrophilic chip based matrix-assisted laser desorption/ionization mass spectrometric imaging（MALDI MSI）.Compared with other quantitative methods for peptides in solution, this method is label-free and does not require separation of the multiple components of the solution before analysis. Uniform hydrophilic spots and high mass accuracy measurements provided confident identification and quantitative analysis of imaged compounds. The linear correlation between concentration and grayscale of image in the range of 5 fmol/μ L to 1 pmol/μ L was obtained for all four peptides. Good sensitivity and excellent reproducibility were also achieved. The method expands the application of MALDI MSI from tissues to solutions.

关键词： MALDI imaging Quantitative analysis Label-free Microarray Patterned hydrophilic chip

An enrichment device of silica-based monolithic material and its application to determine micro-carbaryl by NIRS

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2009年第4期20卷 469-472页

作者： yi ping du Xue Mei Wei Hong ping Xie Zi Xia Huang Juan Juan Fang Center of Analysis and Test East China University of Science and Technology Shanghai 200237 China School of Medicine Suzhou University Suzhou 215123 China

Silica-based monolithic column material was synthesized and an enrichment device was fabricated with the material by assembling the material inside a glass column. The enrichment device was applied for the determination of micro-carbaryl with near-infrared spectroscopy （NIRS）. The aqueous solutions of carbaryl passed through the device and the carbaryl was enriched on the surface of the material where diffuse reflection NIR spectra were measured. These procedures of enrichment and measurement ensured to concentrate analytes for the measurement, so that the sensitivity of determination of MRS could be improved. NIR spectra of carbaryl solutions （0.01-1.00μg mL^-1）, measured after the application of the enrichment device, were pretreated with multiplicative scatter correction （MSC） and regressed against the concentrations of the carbaryl solutions with partial least squares （PLS） method. The results showed that the minimum value of root-mean-square error of prediction （RMSEP） was 0.1771 μg mL^-1 when the number of latent variables was 3 of PLS regression. Therefore, the number of latent variables 3 was selected as the optimum value. RMSEP was not very low but acceptable considering that NIRS is commonly used in macro amount analysis and it is quite difficult for NIRS to determine micro amount analytes, especially, less than 1 μg mL^-1.

关键词： Near-infrared spectroscopy (NIRS) Pesticide Monolithic column Enrichment

Determination of primary aromatic amines using immobilized nanoparticles based surface-enhanced Raman spectroscopy

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2016年第5期27卷 745-748页

作者： Ting Wu Hai-Ting Wang Bo Shen yi-ping du Xuan Wang Zhen-ping Wang Chuan-Jing Zhang Wen-Bin Miu Shanghai Key Laboratory of Functional Materials Chemistry and Research Centre of Analysis and TestEast China University of Science and TechnologyShanghai 200237China Technical Center for Industrial Products and Raw Materials Inspection and Testing Shanghai Entry-Exit Inspection&Inspection and Quarantine Bureau Shanghai 200135China

Primary aromatic amines （PAAs） are substances with toxicity and suspected human carcinogenicity. A facile method for highly sensitive detection of PAAs using surface-enhanced Raman spectroscopy （SERS） is reported. The immobilization of Au nanoparticles （AuNPs） on the glycidyl methacrylate-ethylene dimethacrylate （GMA-EDMA） materials makes the suhstrate a closely packed but not aggregated Au NP arrays which provides a prominent SERS enhancement. Four PAAs with different substituent groups, namely, p-toluidine, p-nitroaniline, benzidine and 4,4-methylene-bis-（2-chloroaniline） have been successfully identified and quantified. High sensitivity and good linear relationship between SERS signals and concentrations of PAAs are obtained for all four PAAs.

关键词： Aromatic amines Surface-enhanced Raman spectroscopy(SERS) Immobilization Au nanoparticles

Surface enhanced Raman spectroscopy signals of mixed pesticides and their identification

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2011年第12期22卷 1477-1484页

作者： Hui Rong Tang Qing Qing Li Yu Lan Ren Jin Pei Geng Peng Cao Tao Sui Xuan Wang yi ping du Shanghai Key Laboratory of Functional Materials Chemistry and Research Centre of Analysis and Test East China University of Science and TechnologyShanghai 200237China Mudanjiang Normal University Mudanjiang 157012China Yantai Entry-Exit Inspection and Quarantine Bureau Yantai 264000 China

A rapid and sensitive method to identify and analyze mixed pesticides of tricyclazole,paraquat and flusilazole by surface-enhanced Raman scattering has been *** samples can be detected by SERS in low concentrations of 0.01 mg/L, 0.1 mg/L and 2.85 mg/L for individual tricyclazole,paraquat and flusilazole *** mixing the three pesticides in the low concentrations,their characteristic peaks can still be identified from the SERS spectrum of the mixture.

关键词： Surface-enhanced Raman scattering(SERS) Pesticide Mixed pesticides Identification

Rapid and sensitive detection of pesticides by surface-enhanced Raman spectroscopy technique based on glycidyl methacrylate-ethylene dimethacrylate(GMA-EDMA) porous material

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2013年第4期24卷 332-334页

作者： Qing-Qing Li yi-ping du ying Xu Xuan Wang Shi-Qian Ma Jin-Pei Geng Peng Cao Tao Sui Shanghai Key Laboratory of Functional Materials Chemistry & Research Centre of Analysis and Test East China University of Science and Technology Yantai Entry-Exit Inspection and Quarantine Bureau

A novel method of fast and sensitive SERS detection using GMA-EDMA porous material combined with a miniature device was reported in this study. A 100 μL solution containing sample, silver colloid and NaC1 was evenly mixed to ensure the sample molecules would adsorb onto silver nanoparticles. Then the mixture was added onto the porous material surface slowly, so that the aggregation of silver colloid would stay on the surface while the liquid components would flow away. This technology can improve the sensitivity of SERS detection. By this method, two pesticides tricyclazole and paraquat were successfully detected at concentrations of 5 × 10 3 mg/L and I × 10-3 mg/L, respectively.

关键词： rSurface-enhanced Raman spectroscopyGMA-EDMA porous materialTricyclazoleParaquat

Low Surface Brightness Galaxies from BASS+MzLS with Machine Learning

在线全文

学校读者我要写书评

暂无评论

Research in Astronomy and Astrophysics 2024年第5期24卷 185-197页

作者： Peng-Liang du Wei du Bing-Qing Zhang Zhen-ping yi Min He Hong Wu Key Laboratory of Optical Astronomy National Astronomical ObservatoriesChinese Academy of SciencesBeijing 100101China School of Astronomy and Space Science University of Chinese Academy of SciencesBeijing 100049China School of Mechanical Electrical and Information EngineeringShandong UniversityWeihai 264209China

From ∼5000 deg^(2) of the combination of the Beijing–Arizona Sky Survey and Mayall z-band Legacy Survey which is also the northern sky region of the Dark Energy Spectroscopic Instrument (DESI) Legacy Imaging Surveys, we selected a sample of 31,825 candidates of low surface brightness galaxies (LSBGs) with the mean effective surface brightness 24.2 0.60) LSBGs. The blue LSBGs appear spiral, disk or irregular while the red LSBGs are spheroidal or elliptical and spatially clustered. This trend shows that the color has a strong correlation with galaxy morphology for LSBGs. In the spatial distribution, the blue LSBGs are more uniformly distributed while the red ones are highly clustered, indicating that red LSBGs preferentially populate a denser environment than the blue LSBGs. Besides, both populations have a consistent distribution of ellipticity (median ∈∼ 0.3), half-light radius (median r_(eff) ∼ 4″) and Sérsic index (median n=1), implying the dominance of the full sample by the round and disk galaxies. This sample has definitely extended the studies of LSBGs to a regime of lower surface brightness, fainter magnitude and broader other properties than the previously Sloan Digital Sky Survey-based samples.

关键词： catalogs-galaxies fundamental parameters-galaxies statistics-techniques photometric

Optimal Cooperative Secondary Control for Islanded DC Microgrids via a Fully Actuated Approach

在线全文

学校读者我要写书评

暂无评论

IEEE/CAA Journal of Automatica Sinica 2024年第2期11卷 405-417页

作者： yi Yu Guo-ping Liu yi Huang Peng Shi IEEE Shenzhen Key Laboratory of Control Theory and Intelligent Systems Southern University of Science and TechnologyShenzhen 518055China School of Electrical Engineering and Automation Wuhan UniversityWuhan 430072China School of Electrical and Mechanical Engineering the University of AdelaideSA 5005Australia Research and Innovation Centre Obuda University1034 BudapestHungary

DC-DC converter-based multi-bus DC microgrids(MGs) in series have received much attention, where the conflict between voltage recovery and current balancing has been a hot topic. The lack of models that accurately portray the electrical characteristics of actual MGs while is controller design-friendly has kept the issue active. To this end, this paper establishes a large-signal model containing the comprehensive dynamical behavior of the DC MGs based on the theory of high-order fully actuated systems, and proposes distributed optimal control based on this. The proposed secondary control method can achieve the two goals of voltage recovery and current sharing for multi-bus DC MGs. Additionally, the simple structure of the proposed approach is similar to one based on droop control, which allows this control technique to be easily implemented in a variety of modern microgrids with different configurations. In contrast to existing studies, the process of controller design in this paper is closely tied to the actual dynamics of the MGs. It is a prominent feature that enables engineers to customize the performance metrics of the system. In addition, the analysis of the stability of the closed-loop DC microgrid system, as well as the optimality and consensus of current sharing are given. Finally, a scaled-down solar and battery-based microgrid prototype with maximum power point tracking controller is developed in the laboratory to experimentally test the efficacy of the proposed control method.

关键词： DC microgrids distributed control high-order fully actuated system approach linear quadratic regulator microgrid modeling secondary control

A universal polymer-assisted route to fabricate Zr-doped TiO2 nanocomposite: boosting reactive desulfurization

在线全文

学校读者我要写书评

暂无评论

Tungsten 2024年第3期6卷 596-609页

作者： Yue du ping Li Zhi-yi Zhong Wen-Xue Chen yi-Si Liu Yun-Long Xie Li-Na Zhou Kai Wang Hubei Key Laboratory of Photoelectric Materials and Devices College of Material Science and Engineering Hubei Normal University National Laboratory of Solid State Microstructures Nanjing University College of Urban and Environmental Sciences Huangshi Key Laboratory of Prevention and Control of Soil Pollution Hubei Normal University School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University

A series of transition metal ion-doped TiO2composites were prepared by polyethyleneimine-assisted solvent-free *** to the similar electronegativity and ionic radius of Ti and Zr ions,the introduction of Zr element to TiO2can effectively improve its surface acidity and introduce more defect sites on the ***-fabricated Zr-doped TiO2nanocomposite exhibits the formation of Zr-Ti bond,strong surface acidity,connected mesoporous channels,and relatively high *** remarkable properties contribute to its adsorption-oxidation-desulfurization capacity toward thiophene-type sulfides,which can remove 500 ×10-6dibenzothiophene from the model fuel within 100 min at low reaction *** polymer-induced self-assembly method can reduce organic solvent usage,pollutant emissions,and energy consumption,which provides an efficient and practical way to prepare porous metal oxide-based catalysts in future.

关键词： Oxidative desulfurization Transition metal ion-doped TiO 2 nanocomposite Dibenzothiophene Solvent-free self-assembly method

Stepwise colloidal lithography toward scalable and various planar chiral metamaterials

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Rare Metals 2024年第2期43卷 723-735页

作者： Xiu Yang Yong Liu Fei-Liang Chen Qian-Qi Lin Rohit Chikkaraddy Shan-Shan Huang Shi-Lin Xian yi-Dong Hou Jing-Lei du Liang-ping Xia Chun-Lei du School of Electronic Science and Engineering University of Electronic Science and Technology of ChinaChengdu610054China School of Optoelectronic Science and Engineering University of Electronic Science and Technology of ChinaChengdu610054China Zhuhai Multiscale Optoelectronics Technology Co. Ltd.Zhuhai915060China Hybrid Materials for Opto-Electronics Group Department of Molecules and MaterialsMESA+Institute for NanotechnologyMolecules Center and Center for Brain-Inspired Nano SystemsFaculty of Science and TechnologyUniversity of Twente7500 AEEnschedeThe Netherlands School of Physics and Astronomy University of BirminghamBirminghamB152TTUK College of Physics Sichuan UniversityChengdu610065China Key Laboratory of Micro Nano Optoelectronic Devices and Intelligent Perception Systems Yangtze Normal UniversityChongqing408100China

Chiral metamaterials(CMs)composed by artificial chiral resonators have attracted great attentions in the recent decades due to their strong chiroptical resonance and identifiable interaction with chiral materials,facilitating practical applications in chiral biosensing,chiral emission,and display ***,the complex geometry of CMs improves the fabrication difficulty and hinders their scalable fabrication for practical applications,especially in the visible and ultraviolet *** potential strategy is the colloidal lithography that enables parallel fabrication for scalable and various planar ***,we demonstrate a stepwise colloidal lithography technique that uses sequential deposition from multiple CMs and expand their variety and *** geometry and optical chirality of building blocks from single deposition are systematically investigated,and their combination enables a significant extension of the range of chiral patterns by multiple-step *** approach resulted in a myriad of complex designs with different characteristic sizes,compositions,and shapes,which are particularly beneficial for the development of nanophotonic *** addition,we designed a flexible chiral device based on PDMS,which exhibits a good CD value and excellent stability even after multiple inward and outward *** excellent compatibility to various substrates makes the planar CMs more flexible in practical applications in microfluidic biosensing.

关键词： Chiral metamaterials Colloidal lithography Nanophotonics Metasurfaces Plasmonics Nanofabrications Flexible devices