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Enhancing sustainability in phosphate ore processing:Performance of frying oil as alternative flotation collector for carbonate removal

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International Journal of Mining Science and Technology 2024年第4期34卷 557-571页

作者： Asmae El-bahi Yassine Taha Yassine ait-Khouia Abdellatif Elghali Mostafa Benzaazoua Geology&Sustainable Mining Institute(GSMI) Mohammed VI Polytechnic UniversityBen Guerir 43150Morocco

Recycling waste frying oils for the synthesis of flotation reagents presents a promising avenue for sustainable waste ***,it offers a cost-effective solution for crafting a specialized collector designed to efficiently remove carbonates and enhance phosphate enrichment in froth flotation *** study focuses on the synthesis of an anionic collector using the saponification reaction of a frying oil sample,subsequently applied to the flotation of calcite and *** elucidate the adsorption mechanisms of the frying oil collector(FrOC)and sodium oleate,a reference collector,on fluorapatite,calcite,dolomite,and quartz surfaces,comprehensive experiments were conducted,including zeta potential measurements and Fourier transform infrared *** revealed diverse adsorption affinities of the molecules towards these *** assess the practical performance of the collector,flotation tests were conducted using a natural phosphate ore mixture,employing a BoxBehnken experimental ***,under optimized conditions(pH 9,1000 g/t of FrOC,3.5 min of conditioning,and 6 min of flotation),FrOC exhibited excellent performance,with calcite and dolomite recoveries exceeding 80%,while apatite recovery in the concentrate fraction remained below 10%.This work exemplifies both circular economy practices and the distinctive approach to sustainable mineral processing.

关键词： Frying oils recycling Phosphate beneficiation Flotation separation Green surfactants Sustainability

Adsorption of Disperse Blue SBL dye by synthesized poorly crystalline hydroxyapatite

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Journal of Environmental Sciences 2008年第10期20卷 1268-1272页

作者： BARKA Noureddine QOURZAL Samir ASSABBANE Ali NOUNAH Abederrahman ait-ichou yhya Materials Photocatalysis and Environment Team Department of Chemistry Faculty of Sciences Agadir.BP: 8106 Hay Dakhla Agadir 80006 Morocco. Laboratory of Environmental Sciences Technology High School.BP.227 Sal-Mdina 11000 Morocco

The present study has been undertaken to evaluate the adsorption in batch mode of a disperse dye (Disperse Blue SBL) by poorly crystalline hydroxyapatite synthesized by coprecipitation between Ca(NO3)2and (NH4)2HPO4 reagents in aqueous solution at room temperature. The adsorption experiments were carried out to investigate the factors that influence the dye uptake by the adsorbent, such as the contact time under agitation, adsorbent dosage, initial dye concentration, solution temperature, and pH. The experimental results show that the percentage of dye removal increases with increasing the amount of adsorbent, until the total discoloration. The adsorption isotherms follow the model of Langmuir with a high adsorption capacity. The adsorption was pH and temperature dependent.

关键词： hydroxyapatite Disperse Blue SBL adsorption isotherm enthalpy of adsorption

Evaluation of phase change materials for a light-weight building in Morocco:Effect of building’s volume,window orientation&infiltration

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Energy and Built Environment 2024年第6期5卷 863-877页

作者： Imad ait Laasri Niima Es-sakali Abdelkader Outzourhit Mohamed Oualid Mghazli Laboratory(LaMEE) Faculty of Sciences SemlaliaCadi Ayyad UniversityMarrakeshMorocco Laboratory(LMAID) Rabat National School of MineRabatMorocco Green Energy Park(UM6P/IRESEN) km2 R206BenguerirMorocco ENTPE LTDS UMR CNRS 5513Universitéde LyonCedexVaulx-en-VelinFrance

In this study,we will model a light-weight building made of phase change materials(PCMs)to analyze the impact of the building volume,window orientation,and air infiltration on the PCM *** is done by calculating the energy savings attained by the use of PCM across all of ***’ll use the commercial Rubitherm panels with RT28HC as a phase change material in this ***,the EnergyPlus simulation engine is chosen to perform the *** impact of building volumes is also evaluated on the PCM activation for light-weight square buildings with different side lengths of 10 m,9 m,8 m,and 7 ***,we looked at how well the PCM performed in terms of energy savings and thermal regulation at different window orientation placements(south,north,west,and east)and various air infiltration rates(0.5,1,1.5,and 3 ACH).This paper’s primary objective is to determine the energy savings for the PCM-enhanced building in Morocco,as well as the effect of building volume,window orientation,and infiltration on the PCM capabilities for stabilizing the indoor room *** results show good indoor temperature stabilization during the summer,for the light-weight square building with a south-facing window and no air *** configuration was able to achieve a total fluctuation reduction of 1303.3℃for the 10 m building in a semi-arid ***,a high energy savings percentage of 69.56%was achieved for the PCM-enhanced building with the south-oriented window and air infiltration of 0.5 air change per hour.

关键词： Building energy efficiency Phase change materials Passive thermal regulation

Performance Evaluation of an Evaporative Cooling Pad for Humidification-Dehumidification Desalination

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Fluid Dynamics & Materials Processing 2024年第10期20卷 2323-2335页

作者： Ibtissam El Aouni Hicham Labrim Elhoussaine Ouabida Ahmed ait Errouhi Rachid El Bouayadi Driss Zejli Aouatif Saad Advanced Systems Engineering Laboratory National School of Applied SciencesIbn Tofail UniversityKenitra14000Morocco

The perfect combination of renewable energy and desalination technologies is the key to meeting water demands in a cost-effective,efficient and environmentally friendly *** desalination technique by humidificationdehumidification is non-conventional approach suitable for areas with low infrastructure(such as rural and decentralized regions)since it does not require permanent *** this study,this technology is implemented by using solar energy as a source of thermal power.A seawater desalination unit is considered,which consists of a chamber with two evaporators(humidifiers),a wetted porous material made of a corrugated cellulose cardboard and a condenser(dehumidifier).The evaporation system is tested with dry bulb temperature and relative air humidity *** results of numerical simulations indicate that higher inlet air velocities(from 0.75 to 3 m/s)lead to a decrease in theΔT,ΔRH,and *** the air remaining within the evaporator for 30 cm,the temperature differential increases to 5.7°C,accompanied by a 39%rise in relative humidity *** changes result in a significant enhancement in humidification efficiency,achieving a remarkable efficiency level of 78%.However,a wettability value of 630 m^(2)/m^(3)leads to a smaller reduction of these *** the pad thickness,particularly to 0.3 m,improves performance by boostingΔT,ΔRH,and effectiveness,especially for pads with a wettability of 630 m^(2)/m^(3),for which superior performances are predicted by the numerical tests.

关键词： Desalination humidification dehumidification porous material solar energy evaporator

Capparis spinosa L waste activated carbon as an efficient adsorbent for crystal violet toxic dye removal: Modeling, optimization by experimental design, and ecological analysis

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Chinese Journal of Chemical Engineering 2024年第7期71卷 283-302页

作者： Mohammed Benjelloun Youssef Miyah Salma Ssouni Soulaiman Iaich Mohamed El-habacha Salek Lagdali Khadija Saka El Mustafa Iboustaten Abdelaziz ait Addi Sanae Lairini Rabia Bouslamti Laboratory of Materials ProcessesCatalysisand EnvironmentHigher School of TechnologySidi Mohamed Ben Abdellah UniversityFez 30070Morocco Ministry of Health and Social Protection Higher Institute of Nursing Professions and Health TechniquesFez/Meknes 30070Morocco Laboratory of Biochemistry Faculty of MedicinePharmacy and DentistrySidi Mohamed Ben Abdellah UniversityFez 30070Morocco Laboratory of Applied Chemistry and Environment Faculty of SciencesIbnou Zohr UniversityAgadir 80322Morocco Research Team of Energy and Sustainable Development Higher School of TechnologyIbnou Zohr UniversityGuelmim 81000Morocco Organic Chemistry and Physical Chemistry Laboratory Faculty of SciencesIbnou Zohr UniversityAgadir 80322Morocco

Textile dyes are dramatic sources of pollution and non-aesthetic disturbance of aquatic life and therefore represent a potential risk of bioaccumulation that can affect living *** is imperative to reduce or eliminate these dyes from liquid effluents with innovative biomaterials and ***,this research aims to highlight the performance of Capparis spinosa L waste-activated carbon(CSLW-AC)adsorbent to remove crystal violet(CV)from an aqueous *** mechanism of CV adsorption on CSLW-AC was evaluated based on the coupling of experimental data and different characterization *** efficiency of the CSLW-AC material reflected by the equilibrium adsorption capacity of CV could reach more than 195.671 mg·g^(–1) when 0.5 g·L^(–1) of CSLW-AC(Particle size≤250μm)is introduced into the CV of initial concentration of 100 mg·L^(–1) at pH 6 and temperature 65℃ and in the presence of potassium ions after 60 min of contact time according to the one parameter at a time *** adsorption behavior of CV on CSLW-AC was found to be consistent with the pseudo-second-order kinetic model and Frumkin's linear isothermal *** thermodynamic aspects indicate that the process is physical,spontaneous,and *** optimization of the process by the Box Behnken design of experiments resulted in an adsorption capacity approaching 183.544 mg·g^(–1)([CV]=100 mg·L^(–1) and[CSLW-AC]=0.5 g·L^(–1) at 35 min).The results of the Lactuca sativa seeds germination in treated CV(70%),adsorbent solvent and thermal regeneration(more than 5 cycles),and process cost analysis(1.0484 USD·L^(–1))tests are encouraging and promising for future exploitations of the CSLW-AC material in different industrial fields.

关键词： Box Behnken Capparis spinosa L waste-activated carbon Cost analysis Isotherm Kinetic Regeneration

Metastatic clear cell sarcoma of the pancreas:An overview

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World Journal of Clinical Cases 2024年第29期12卷 6262-6265页

作者： Rachid ait Addi Department of Biology Independent Senior ResearcherMarrakesh 41020Morocco

Clear cell sarcoma(CCS)is a rare soft-tissue sarcoma that accounts for less than 1%of all cases and was originally reported in *** incidence of CCS is estimated to be approximately 0.014/100000 depending on the surveillance,epidemiology and end results *** is a highly invasive type that mainly metastasizes to the lungs,followed by the bones and brain;however,pancreatic metastasis is relatively *** has a high probability of recurrence or metastasis and has a poor prognosis with a high mortality ***,even after recovery,it is fundamental to keep regular postoperative follow-up for CCS patients.

关键词： Clear cell sarcoma Pancreas Metastasis Follow-up Case report

摩洛哥民用建筑保温性建筑材料评价 ——以马拉喀什和伊夫兰地区为例

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摩洛哥民用建筑保温性建筑材料评价 ——以马拉喀什和伊夫兰地区...

作者： ait ALLA YASSINE 燕山大学

学位级别：硕士

An Affordable and Easily Accessible Approach for Acrylonitrile Monomer Purification through a Simple Column Technique

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Journal of Materials Science and Chemical Engineering 2024年第4期12卷 18-28页

作者： Rawdah Whba Mohd Sukor Su’ait Azizan Ahmad Department of Chemistry Faculty of Applied Sciences Taiz University Taiz Yemen Department of Engineering Physics Istanbul Medeniyet University Istanbul Türkiye Solar Energy Research Institute (SERI) Universiti Kebangsaan Malaysia Bangi Malaysia Department of Chemical Sciences Universiti Kebangsaan Malaysia Bangi Malaysia Department of Physics Faculty of Science and Technology Airlangga University (Campus C) Surabaya Indonesia

This manuscript presents a dataset detailing a method for purifying monomers. Purification plays a crucial role in every chemical process, as it leads to an improvement in product quality through the removal of impurities. The primary method for monomer purification, like acrylonitrile (AN), is the distillation technique. However, this technique is unsafe and hard to set up or handle. A straightforward, risk-free, low-cost method like the column technique resolves these issues. A simple column technique demonstrated the successful execution of purifying AN. Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) analyses confirmed that AN was successfully purified, with purity reaching 99.8%. FTIR spectra revealed changes in the position and intensity of the stretching vibration peaks after purification. Also, the functional groups of the inhibitor monomethyl ether of hydroquinone (MeHQ) were undetected after purification. Furthermore, after purification, NMR spectra revealed the absence of aromatic protons and carbons associated with MeHQ. In conclusion, the column technique is a successful and inexpensive way to purify AN monomers. This makes it useful for a wide range of applications, especially in polymerization reactions where MeHQ needs to be removed to prevent self-polymerization during the initiation process.

关键词： Liquid Monomers Acrylonitrile Purification Inhibitor Simple Column

Juvenile Systemic Sclerosis: About 9 Cases

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Open Journal of Pediatrics 2024年第2期14卷 320-326页

作者： Kaoutar Danaoui Houda Nassih Khadija Oujennane Rabiy El Qadiry Aicha Bourrahouat Said Amal Imane ait Sab B Pediatric Ward Mohammed VI University Hospital Center Marrakesh Morocco Dermatology Ward Mohammed VI University Hospital Center Marrakesh Morocco

Scleroderma is a rare disease with two primary forms: localized scleroderma (LS) and systemic sclerosis (SSc). Both are chronic conditions that can manifest in various patterns (subtypes) and are linked to extracutaneous involvement in pediatric patients. Juvenile SSc poses a higher risk of morbidity and mortality, with patients facing life-threatening complications such as lung, heart, and visceral organ fibrosis, and vasculopathy. In contrast, mortality is extremely rare in juvenile LS, but patients are susceptible to significant morbidity, leading to severe disfigurement and functional impairment. Treatment for scleroderma aims to control inflammation and address specific issues. An early diagnosis significantly enhances the overall outcome. This study conducts a retrospective descriptive analysis aiming to document the clinical manifestations, management approaches, and outcomes of systemic sclerosis in a cohort of nine children receiving treatment for juvenile systemic sclerosis at Pediatric B department of Mohammed VI University, Hospital Center in Marrakech, Morocco.

关键词： Scleroderma Systemic Sclerosis Children Pediatric