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Chinese Journal of Structural Chemistry 2006年第7期25卷 854-860页

作者： RAO Yi-Jian YUAN Cai BIAN Chuan-Bing HOU Xiao-Min LI Yong-Dong ZHAO Geng-Xiang ye Xiao-ming huang Zi-Xiang huang ming-Dong State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China

Sarl is a small GTPase involved in COPⅡ vesicle transport. Previous studies showed that H79G mutation of Sarl can lock Sarl in its GTP-bound active conformation, stabilize coat assembly, and prevent the disassembly of COP Ⅱ vesicle coats by reducing Sec23/24 GAP- stimulated hydrolysis. We show here that the replacement of His79 by glycine induces a large conformation change in switch Ⅱ and results in the lost of hydrogen bond between His79 and its associated nucleophilic water molecule that was hypothesized to reduce the GAP-stimulated hydrolysis during the COP Ⅱ assembly and disassembly. These results confirm that the switch Ⅱ conformation is important for COP Ⅱ disassembly through coat-controlled GTP hydrolysis.

关键词： Sarl switch Ⅱ COP Ⅱ disassembly crystal structure

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Fabrication of alginate-based microspheres with cellular structure for tuning ammonium dinitramide performance

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Defence Technology（防务技术） 2023年第10期28卷 111-120页

作者： Dun-ju Wang Xu Zhou Yao-feng Mao Xin Wang ye-ming huang Rui-hao Wang Da-wei Zheng Co-Innovation Center for New Energetic Materials Southwest University of Science and TechnologyMianyang621010China China Academy of Engineering Physics Institute of Chemical MaterialsMianyang621900PR China

Recently,an emerging category green of energetic material ammonium dinitramide(ADN)has exhibited promising application in propellants due to its outstanding merits in energy release and environmental *** can be considered to substitute traditional oxidizer of ammonium perchlorate(AP)in military systems and *** this paper,a novel spherical energetic composite ADN/copper alginate(CA)with a microporous structure was designed and prepared by the W/O gel emulsion method,and a desirable porous microsphere structure was *** characterization techniques were used to investigate the structure and properties of ADN/CA *** results showed that ADN crystals were homogeneously encapsulated in an alginate-gel *** decomposition temperature was reduced to 151.7℃compared to ADN,while the activation energy of them was reduced from 129.73 k J/mol(ADN)to 107.50 k J/mol(ADN/CA-4).In addition,as-prepared samples had lower impact and frictional sensitivity than *** mechanism of sensitivity reduction and decomposition are also ***-volume combustion tests show that peak pressure of the ADN/CA-4 achieves 253.4 k Pa and pressurization rate of 2750.4 k Pa/***,this has a promising application in improving the combustion performance and safety performance of solid propellants.

关键词： Ammonium dinitramide Sodium alginate Microspheres High reactivity Energetic materials

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Understanding and probing progression of localized corrosion on inner walls of steel pipelines:an overview

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Journal of Iron and Steel Research International 2025年第1期32卷 1-18页

作者： ming-yu Wang Hai-yuan Yao Yong-fei Liu ye-sen Zhu Wan-bin Chen Yun-ze Xu Yi huang School of Naval Architecture and Ocean Engineering Dalian University of TechnologyDalian 116024LiaoningChina China National Offshore Oil Corporation Research Institute Co. Ltd.Beijing 100028China State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentDalian University of TechnologyDalian 116024LiaoningChina

Corrosion poses a major threat to the safety of transportation ***,it is crucial to have an in-depth understanding of corrosion mechanisms in pipeline steels for the effective management of pipeline *** research on corrosion mechanisms relies on the use of efficient and reliable corrosion monitoring and analysis *** advancements in corrosion monitoring techniques specifically designed for the localized corrosion monitoring were aimed to be introduced,and a comprehensive overview of recent progress in understanding the localized corrosion mechanisms in pipeline steels was *** on the different corrosive environments encountered,the localized corrosion issues inside pipelines are classified into two categories:localized corrosion primarily influenced by electrochemical processes and localized corrosion controlled by both electrochemical and mechanical ***,a thorough analysis of the synergistic effects between micro-cell and macro-cell currents,as well as the interplay of mechanics and electrochemistry is ***,recommendations for future research on the mechanisms of internal localized corrosion in pipelines are provided.

关键词： Pipeline steel Localized corrosion Corrosion type Corrosion monitoring Corrosion mechanism

Biisoindolylidene solvatochromic fluorophores: Synthesis and photophysical properties

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Chinese Chemical Letters 2025年第2期36卷 394-399页

作者： Xiaoyu Chen Jiahao Hu Jingyi Lin Haiyang huang Changqing ye Hongli Bao College of Chemistry Fuzhou University State Key Laboratory of Structural Chemistry Key Laboratory of Coal to Ethylene Glycol and Its Related TechnologyCenter for Excellence in Molecular SynthesisFujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fujian College University of Chinese Academy of SciencesFuzhou 350002China dUniversity of Chinese Academy of Sciences

Environment-sensitive fluorescent probes are commonly utilized in various fields, including fluorescence sensing and imaging. This paper describes the synthesis and photophysical properties of a novel class of solvatochromic fluorophores that incorporate biisoindolylidene as the core backbone. This study investigates the structure-property relationships of these newly developed fluorophores. The central biisoindolylidene acts as an efficient electron acceptor, and by modifying the aryl ring substituent at the 3,3 position, the photophysical properties of the fluorophores can be significantly enhanced, particularly in terms of photoluminescence quantum efficiency. Furthermore, when an electron-donor group replaces the aryl ring at the 3,3 position, intriguing solvatochromic behavior is observed. This leads to a red-shift in the maximum emission wavelength and an increase in the Stokes shift with increasing solvent polarity. In solvent dimethyl sulfoxide(DMSO), the maximum emission wavelength can reach up to 750 nm,with a Stokes shift of approximately 150 nm. Finally, the potential application of the fluorophore in the detection of volatile acids is explored in a preliminary manner.

关键词： Acid sensitive Biisoindolylidene Electron receptor New fluorophores Solvatochromic

Unintentional emissions of polychlorinated naphthalenes in China:Sources,composition,and historical trends

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Journal of Environmental Sciences 2025年第2期148卷 221-229页

作者： ye huang Lin huang Ying Li Nazupar Sidikjan Yunshan Zhang Yan Chen Yangmin Chen ye Li Wei Du Long Chen YanWu Shanshan Zhang Jing Yang Wenjun Meng Guofeng Shen Min Liu Shu Tao Key Laboratory of Geographic Information Science of the Ministry of Education School of Geographic SciencesEast China Normal UniversityShanghai 200241China Yunnan Provincial Key Laboratory of Soil Carbon Sequestration and Pollution Control Faculty of Environmental Science&EngineeringKunming University of Science&TechnologyKunming 650500China Laboratory of Earth Surface Processes College of Urban and Environmental SciencePeking UniversityBeijing 100871China

Polychlorinated naphthalenes(PCNs)are detrimental to human health and the *** the commercial production of PCNs banned,unintentional releases have emerged as a significant environmental ***,relevant information is still *** this study,provincial emissions for eight PCNs homologues from 37 sources in the Chinese mainland during the period of 1960-2019 were estimated based on a source-specific and time-varying emission factor *** results showed that the total PCNs emissions in 2019 reached 757.0 kg with Hebei ranked at the top among all the provinces and iron&steel industry as the biggest ***-chlorinated PCNs comprised 90%of emissions by mass,while highly chlorinated PCNs dominated in terms of toxicity,highlighting divergent priorities for mitigating emissions and safeguarding human *** emissions showed an overall upward trend from 1960 to 2019 driven by emission increase from iron&steel industry in terms of source,and from North China and East China in terms of geographic ***-capita emissions followed an inverted U-shaped environmental Kuznets curvewhile emission intensities decreased with increasing per-capita Gross Domestic Product(GDP)following a nearly linear pattern when log-transformed.

关键词： PCNs Emission inventory Emission factor Composition profile Emission intensity Chinese mainland

Highly efficient catalytic transfer hydrogenation for the conversion of nitrobenzene to aniline over PdO/TiO_(2):The key role of in situ switching from PdO to Pd

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Journal of Environmental Sciences 2025年第2期148卷 515-528页

作者： Anqi Lu Xiaokang Xiang ming Lei Shuangshuang huang Bingbing Liang Siyu Zhao Lihua Zhu Heqing Tang College of Resources and Environmental Science South-Central Minzu UniversityWuhan 430074China School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074China School of Physics and Technology Center for Electron MicroscopyMOE Key Laboratory of Artificial Micro-and Nano-Structuresand Institute for Advance StudiesWuhan UniversityWuhan 430072China

The reduction of nitrobenzene to aniline is very important for both pollution control and chemical ***,difficulties still remain in developing a catalytic system having high efficiency and selectivity for the production of ***,it was found that PdO nanoparticles highly dispersed on TiO_(2)support(PdO/TiO_(2))functioned as a highly efficient catalyst for the reduction of nitrobenzene in the presence of *** favorable conditions,95%of the added nitrobenzene(1 mmol/L)was reduced within 1 min with an ultra-low apparent activation energy of 10.8 kJ/mol by using 0.5%PdO/TiO_(2)as catalysts and 2 mmol/L of NaBH4 as reductants,and the selectivity to aniline even reached up to 98%.The active hydrogen specieswere perceived as dominant species during the hydrogenation of nitrobenzene by the results of isotope labeling experiments and ESR spectroscopic.A mechanismwas proposed as follows:PdO activates the nitro groups and leads to in-situ generation of Pd,and the generated Pd acts as the reduction sites to produce active hydrogen *** this catalytic system,nitrobenzene prefers to be adsorbed on the PdO nanoparticles of the PdO/TiO_(2)***,the addition of NaBH4 results in in-situ generation of a Pd/PdO/TiO_(2)composite from the PdO/TiO_(2)composite,and the Pd nanoclusters would activate NaBH4 to generate active hydrogen species to attack the adsorbed nitro *** work will open up a new approach for the catalytic transfer hydrogenation of nitrobenzene to aniline in green chemistry.

关键词： Catalytic transfer hydrogenation Reduction Pd Nitrobenzene Aniline

Investigating the p-Ω interactions and correlation functions

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Science China(Physics,Mechanics & Astronomy) 2025年

作者： ye Yan Qi huang Youchang Yang Hongxia huang Jialun Ping Department of Physics Nanjing Normal University School of Science Guizhou University of Engineering Science

Motivated by experimental measurements, we investigate the p-Ω correlation functions and interactions on the basis of a quark model. By solving the inverse scattering problem with channel coupling, we renormalize the coupling to other channels into an effective single-channel p-Ω potentials. The effects of Coulomb interaction and spin-averaging are also discussed. According to our results, the depletion of the p-Ω correlation functions, which is attributed to the JP= 2+bound state not observed in the ALICE Collaboration's measurements(Nature 588, 232（2020）), can be explained by the contribution of the attractive JP= 1+component in spin-averaging. So far, we have provided a consistent description of the p-Ω system from the perspective of the quark model, including the energy spectrum, scattering phase shifts, and correlation functions. The existence of the p-Ω bound state has been supported by all three aspects. Additionally, a sign of the p-Ω correlation function's subtle sub-unity part can be seen in experimental measurements, which warrants more precise verification in the future.

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Investigating the p-Ω interactions and correlation functions

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SCIENCE CHINA-PHYSICS MECHANICS & ASTRONOMY 2025年第3期68卷 1-12页

作者： Yan, ye huang, Qi Yang, Youchang huang, Hongxia Ping, Jialun Nanjing Normal Univ Dept Phys Nanjing 210023 Peoples R China Guizhou Univ Engn Sci Sch Sci Bijie 551700 Peoples R China

Motivated by experimental measurements, we investigate the p-Omega correlation functions and interactions on the basis of a quark model. By solving the inverse scattering problem with channel coupling, we renormalize the coupling to other channels into an effective single-channel p-Omega potentials. The effects of Coulomb interaction and spin-averaging are also discussed. According to our results, the depletion of the p-Omega correlation functions, which is attributed to the JP = 2+ bound state not observed in the ALICE Collaboration's measurements (Nature 588, 232 (2020)), can be explained by the contribution of the attractive JP = 1+ component in spin-averaging. So far, we have provided a consistent description of the p-Omega system from the perspective of the quark model, including the energy spectrum, scattering phase shifts, and correlation functions. The existence of the p-Omega bound state has been supported by all three aspects. Additionally, a sign of the p-Omega correlation function's subtle sub-unity part can be seen in experimental measurements, which warrants more precise verification in the future.

关键词： correlation function p-Omega dibaryon quark delocalization color screening model

Dual-phase interface engineering via parallel modulation strategy for highly reversible Zn metal batteries

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Journal of Energy Chemistry 2025年第2期101卷 163-174页

作者： Zhean Bao Yang Wang Kun Zhang Guosheng Duan Leilei Sun Sinan Zheng Bin Luo Zhizhen ye Jingyun huang School of Materials Science and Engineering State Key Laboratory of Silicon and Advanced Semiconductor Materials Zhejiang University Institute of Wenzhou Zhejiang University Institute of Thermal Science and Power Systems Zhejiang University Longmen Laboratory of Luoyang

The reversibility and stability of aqueous Zn metal batteries（AZMBs） are largely limited by Zn dendrites and interfacial parasitic ***,we propose a parallel modulation strategy to boost the reversibility of the Zn anode by introducing N,N,N',N'-tetramethylchloroformamidinium hexafluorophosphate（TCFH） as an additive in the *** is composed of PF6-and TN+with opposite ***6-can spontaneously induce the in-situ generation of ZnF2solid electrolyte interface（SEI） on the anode,which can improve the transport kinetics of Zn2+at the interface,thus promoting the rapid and uniform deposition of Zn as well as inhibiting the growth of *** addition,TN+is enriched at the anode surface during Zn deposition through the anchoring effect,which brings a reconfiguration of the ion/molecule *** anchored-TN+reduces the concentrations of H2O and SO42-,sufficiently restraining the parasitic *** to the dual-phase interface engineering constructed of PF6-and TN+in parallel,the symmetric cell with the proposed electrolyte survives long cycling stability over750 h at 20 mA cm-2,10 mAh *** study offers a distinct viewpoint to the multidimensional optimization of Zn anodes for high-performance AZMBs.

关键词： Anchoring effect Aqueous Zn metal batteries Electrolyte additive Solid electrolyte interface Zn anode

Source apportionment of black carbon using an advanced Aethalometer model in a typical industrial city of China

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Journal of Environmental Sciences 2025年第5期151卷 42-53页

作者： Xingxing Fan Sihang ye huang Zheng Bin Han Guotao Zhang Zhensen Zheng Xueyan Zhao Shaofei Kong Xiaoli Wang Wen Yang Chinese Research Academy of Environmental Sciences Beijing 100012China School of Environmental Science and Safety Engineering Tianjin University of TechnologyTianjin 300380China Service Center Ministry of Ecology and Environment of the People’s Republic of China Beijing 100032China Department of Atmospheric Sciences School of Environmental StudiesChina University of Geosciences(Wuhan)Wuhan 430074China

Black carbon(BC)aerosol can lead to adverse health effects and drive climate change;therefore,the characteristic research and identification of BC sources are essential for lowering *** this study,equivalent black carbon(eBC)measurement was performed using a seven-wavelength Aethalometer(AE33)at an urban site in a typical industrial city(Zibo)of Northern China for the first *** monitoring was performed from February 2021 to January *** mass absorption cross-section(MAC)of AE33 was optimised using the online elemental carbon(EC)data,and eBC was corrected using the *** corrected annual BC concentration was 1.72±1.18μg/m^(3).The diurnal variation of BC depicted a bimodal ***,the BC concentration on weekends was 18%lower than on *** diurnal variation and weekend effect reflect the critical contributions of traffic emission to BC *** source apportionment of BC was calculated by a constraining Aethalometer model,which restricted theÅngstrom exponent using the online potassium *** results revealed that BC was not significantly affected by biomass burning(BC_(bb))in *** relative contribution of BC_(bb)was higher in winter than in other *** daily morning peak of BC was primarily influenced by traffic sources,whereas the contribution of biomass burning increased after 17:00 in the evening *** findings suggest that it is more important to control fossil fuel sources for BC emission reduction in Zibo,while it is necessary to strengthen the control of biomass combustion sources in winter.

关键词： Black carbon(BC) Aethalometer AbsorptionÅngstrom exponent(AAE) Aethalometer model Fossil fuels Biomass burning Source apportionment