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Science China Chemistry 2025年第1期68卷 394-402页

作者： Zhiqiang Ding Mingqian Wang Zijing zhou Bin Wang Yuesheng Li Tianjin Key Laboratory of Composite & Functional Materials School of Materials Science and Engineering Tianjin University

Living/controlled cationic ring-opening polymerization （ROP） of L-lactide is a promising approach to isotactic-rich and crystalline poly（L-lactide）.In contrast with the unsubstituted lactones,L-LA can not be polymerized by organic Lewis acids or carbenium ions,and the state of the art in this field is the cationic ROP of L-LA catalyzed by Br?nsted acid/alcohol system via activated monomer ***,we reported the first example of controlled cationic ROP of L-LA by using Meerweintype ion pair[Me3O]+[B（C6F5）4]-as the catalyst.[Me3O]+[B（C6F5）4]-promoted rapid L-LA cationic polymerization in the absence of alcohol,producing isotactic-rich and crystalline PLLA without transesterification and epimerization side *** activated chain end mechanism,involving twice SN2 substitution and configuration-inversion （S→R→S） with the assistance of released Me2O,was proposed and further verified by density functional theory and control *** work expands the catalytic toolbox of isotactic-rich and crystalline polylactide *** represents a unique example of cationic-controlled polymerization of L-LA catalyzed by an organic ion pair.

关键词： organic ion pair controlled cationic ring-opening polymerization activated chain end mechanism isotactic-rich polylactide

Gradient maturation experiment on hairs implies taphonomic changes in fossil hairs

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Science China Earth Sciences 2025年第1期68卷 62-73页

作者： Xin LI Yibo zhou Tao ZHAO Xingjian HE Yanhong PAN State Key Laboratory for Mineral Deposits Research Center for Critical Earth Material Cycling Centre for Research and Education on Biological Evolution and Environment and Frontiers Science School of Earth Sciences and Engineering Nanjing University Institute of Palaeontology Yunnan Key Laboratory of Earth System Science Yunnan Key Laboratory for PalaeobiologyYunnan University

Mammalian hair, as a key feature related to endothermy, physical protection, and camouflage, has a long geohistorical record that dates back even to the Mesozoic. However, the limited information on the taphonomy of hair hinders the understanding of its evolutionary significance in deep time. To address this, we conducted taphonomic experiments to simulate the transformation process of black hair. The changes in the morphological structure, microscopic characteristics, and chemical composition of hair during the simulated fossilization process were documented by scanning electron microscopy, Fourier transform infrared(FTIR) spectroscopy, and Raman spectroscopy. Our results revealed that damage to the morphology of hair began at a mild temperature(150–175°C), and hair transformed into a fluid-like mass at a relatively high temperature(200°C). In addition, the morphological structure of melanosomes had relatively greater preservation potential than keratins did, and the microscopic features of melanosomes were persistently stable. The Raman and FTIR spectra indicated that the characteristic melanin and keratin peaks changed as the temperature increased. Although the chemical signals were not lost completely, the variations in the characteristic amide bands in the FTIR spectra indicate that the keratins severely degraded at high temperatures(>200°C), whereas the characteristic melanin bands in the Raman spectra suggested that melanin signals were still recognizable, even at high temperatures(>200°C). These results were confirmed by principal component analysis(PCA) and principal component analysis linear discriminant analysis(PCA–LDA). In addition, the Raman signals of all the samples in the simulated experiments were distinguished from the signals of common geological carbonaceous materials(humic acid), which suggested that Raman spectroscopy can be used to detect melanin in fossils.

关键词： Mammalian hair Melanin Keratin Fossilization Experimental taphonomy

Prussian Blue Analogue‑Templated Nanocomposites for Alkali‑Ion Batteries:Progress and Perspective

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Nano-Micro Letters 2025年第1期17卷 216-261页

作者： Jian‑En zhou Yilin Li Xiaoming Lin Jiaye Ye Key Laboratory of Theoretical Chemistry of Environment Ministry of EducationSchool of ChemistrySouth China Normal UniversityGuangzhou 510006People’s Republic of China School of Chemistry and Physics Faculty of ScienceQueensland University of Technology2 George StreetBrisbaneQLD 4000Australia Centre for Materials Science Queensland University of Technology2 George StreetBrisbaneQLD 4000Australia

Lithium-ion batteries(LIBs)have dominated the portable electronic and electrochemical energy markets since their commercialisation,whose high cost and lithium scarcity have prompted the development of other alkali-ion batteries(AIBs)including sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs).Owing to larger ion sizes of Na^(+)and K^(+)compared with Li^(+),nanocomposites with excellent crystallinity orientation and well-developed porosity show unprecedented potential for advanced lithium/sodium/potassium *** enticing open rigid framework structures,Prussian blue analogues(PBAs)remain promising self-sacrificial templates for the preparation of various nanocomposites,whose appeal originates from the well-retained porous structures and exceptional electrochemical activities after thermal *** review focuses on the recent progress of PBA-derived nanocomposites from their fabrication,lithium/sodium/potassium storage mechanism,and applications in AIBs(LIBs,SIBs,and PIBs).To distinguish various PBA derivatives,the working mechanism and applications of PBA-templated metal oxides,metal chalcogenides,metal phosphides,and other nanocomposites are systematically evaluated,facilitating the establishment of a structure–activity correlation for these *** on the fruitful achievements of PBA-derived nanocomposites,perspectives for their future development are envisioned,aiming to narrow down the gap between laboratory study and industrial reality.

关键词： Prussian blue analogues Self-sacrificial template Lithium-ion batteries Sodium-ion batteries Potassium-ion batteries

日青威盆地桃林地区白垩纪热流体活动特征及其对储层物性的影响

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海洋地质前沿 2023年第2期39卷 38-48页

作者：刘汉青周瑶琪陈彤彤穆宏玉刘英杰页岩油气富集机理与有效开发国家重点实验室北京102206 中国石化油气成藏重点实验室无锡214126 中国石油大学(华东)地球科学与技术学院青岛266580

山东东部日青威盆地为近年来新发现的裂陷盆地,盆内广泛发育深水重力沉积岩并且有机质含量丰富,具有非常规油气勘探远景。为了查明盆地内热流体活动的发育特征及其对储层物性的改造作用,以桃林地区长玢岩及其围岩为研究对象,通过岩相学... 详细信息

山东东部日青威盆地为近年来新发现的裂陷盆地,盆内广泛发育深水重力沉积岩并且有机质含量丰富,具有非常规油气勘探远景。为了查明盆地内热流体活动的发育特征及其对储层物性的改造作用,以桃林地区长玢岩及其围岩为研究对象,通过岩相学观察及X-射线衍射、流体包裹体、物性测试等实验分析方法,探讨了热流体活动特征及其对储层物性的影响。研究结果表明:闪长玢岩与围岩的岩性组合主要有2种类型:闪长玢岩+砂岩(下部)、闪长玢岩+角砾岩+火山碎屑岩+砂岩+粉砂岩(上部);热流体活动对围岩的影响主要体现在独特的脉体特征、碎屑颗粒的热液蚀变、黏土矿物出现异常变化、流体包裹体均一温度出现异常高值4个方面;桃林地区热流体活动在砂岩储层中以横向运移为主,随着距离侵入体距离的增加,热流体对储层物性的影响减弱,但在地层中部出现物性相对好的区域,推测是多期次热流体以及次生断裂作为运移通道的叠加结果。

关键词：日青威盆地桃林地区热流体耦合作用储层改造

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临清坳陷东部高古4井煤成气藏成藏特征

煤田地质与勘探 2016年第4期44卷 46-53页

作者：梁钊周瑶琪王瑞刘晨光朱之锦张德彬中国石油大学地球科学与技术学院山东青岛266580 中国石化胜利油田股份有限公司地质科学研究院山东东营257051 中国石化胜利油田股份有限公司孤岛采油厂山东东营257231

为了查明临清坳陷东部上古生界煤成气藏的勘探潜力,通过多种方法对其成藏条件进行研究并对高古4井煤成气藏进行解剖。结果表明:该区主要发育煤岩和砂泥岩互层沉积,其中煤岩和泥岩可作为烃源岩,干酪根类型多为Ⅲ型和Ⅱ2型,生气为主,砂体... 详细信息

为了查明临清坳陷东部上古生界煤成气藏的勘探潜力,通过多种方法对其成藏条件进行研究并对高古4井煤成气藏进行解剖。结果表明:该区主要发育煤岩和砂泥岩互层沉积,其中煤岩和泥岩可作为烃源岩,干酪根类型多为Ⅲ型和Ⅱ2型,生气为主,砂体可作为储层,与煤岩和泥岩形成储盖组合;高古4井太原组气藏中的天然气主要来源于本组煤岩,储集空间以溶蚀孔隙和微裂缝为主,上覆煤岩封盖和侧向泥岩遮挡形成断块圈闭,定型于新近纪,烃类聚集主要发生于新近纪之后,其它组段砂岩由于侧向遮挡条件不利而未成藏。高古4井煤成气成藏具有"近源自生自储、超晚期生烃成藏、断层侧向遮挡"的特点,发育类似成藏条件的区域应该成为该区今后勘探的重点。

关键词：上古生界煤成气高古4 井临清坳陷东部

四川广元上寺上二叠统硅质岩地球化学特征及成因分析

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矿物岩石 2017年第1期37卷 93-102页

作者：方雪周瑶琪姚旭刘美辰加娜提古丽.吾斯曼刘加召中国石油大学(华东)地球科学与技术学院山东青岛266000 山东省第八地质矿产勘查院山东日照276800

四川广元上寺剖面广泛发育条带状、层状、团块状、结核状硅质岩。通过对上寺上二叠统硅质岩野外观察、取样,室内手标本观察及对其中的8块硅质岩样品进行元素地球化学的分析,对上寺上二叠统共8块硅质岩样品进行岩石学及地球化学特征研究... 详细信息

四川广元上寺剖面广泛发育条带状、层状、团块状、结核状硅质岩。通过对上寺上二叠统硅质岩野外观察、取样,室内手标本观察及对其中的8块硅质岩样品进行元素地球化学的分析,对上寺上二叠统共8块硅质岩样品进行岩石学及地球化学特征研究,重点分析其成因。结果表明,硅质岩化学成分以SiO2为主,质量分数为73.05%~94.47%(平均87.1%),Fe,Mn含量较低,Al/(Al+Fe+Mn)值在0.54~0.70之间,平均值为0.63,在Al-Fe-Mn三角图解中,样品全部落在生物及非热液沉积区,MnO/TiO2值大部分小于0.5。硅质岩的大部分微量元素远远小于地壳克拉克值,V/(V+Ni)值均小于0.83,反映沉积环境为富氧;稀土元素总量较低,LREE/HREE平均值为5.84,δCe值变化范围0.20~1.30,为负异常且差异较大,δEu值变化范围1.01~4.10,较弱正异常,稀土元素北美页岩标准化曲线总体较平坦,略有右倾趋势。综合分析认为,硅质来源较复杂,生物来源为其主要来源,深部热水及火山作用为其次要来源,其中热液的注入与始于中二叠世的火山活动有关,硅质岩的形成以生物化学沉积为主,热水沉积为辅,硅质沉积环境为富氧的台盆相。

关键词：硅质岩地球化学成因晚二叠世上寺

Grid-Connected/Islanded Switching Control Strategy for Photovoltaic Storage Hybrid Inverters Based on Modified Chimpanzee Optimization Algorithm

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Energy Engineering 2025年第1期122卷 265-284页

作者： Chao zhou NarisuWang Fuyin Ni Wenchao Zhang School of Electrical and Information Engineering Jiangsu University of TechnologyChangzhou213001China Jiangsu Key Laboratory of Power Transmission&Distribution Equipment Technology Jiangsu University of TechnologyChangzhou213001China

Uneven power distribution,transient voltage,and frequency deviations are observed in the photovoltaic storage hybrid inverter during the switching between grid-connected and island *** response to these issues,this paper proposes a grid-connected/island switching control strategy for photovoltaic storage hybrid inverters based on the modified chimpanzee optimization *** proposed strategy incorporates coupling compensation and power differentiation elements based on the traditional droop ***,it combines the angular frequency and voltage amplitude adjustments provided by the phase-locked loop-free pre-synchronization control *** pre-synchronization is achieved by regulating the virtual current to zero and aligning the photovoltaic storage hybrid inverter with the grid ***,two novel operators,learning and emotional behaviors are introduced to enhance the optimization precision of the chimpanzee *** operators ensure high-precision and high-reliability optimization of the droop control parameters for photovoltaic storage hybrid inverters.A Simulink model was constructed for simulation analysis,which validated the optimized control strategy’s ability to evenly distribute power under load *** strategy effectively mitigated transient voltage and current surges during mode ***,seamless and efficient switching between gridconnected and island modes was achieved for the photovoltaic storage hybrid *** enhanced energy utilization efficiency,in turn,offers robust technical support for grid stability.

关键词： Photovoltaic storage hybrid inverters modified chimpanzee optimization algorithm droop control seamless switching

Interfacial Zn2+-solvation regulator towards reversible and stable Zn anode

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Journal of Energy Chemistry 2025年第1期100卷 684-692页

作者： Miao zhou Xiongbin Luo Hang Li Shan Guo Zhuang Tong Xiaotao zhou Xu Li Zhaohui Hou Shuquan Liang Guozhao Fang College of Mechanical Engineering Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials Hunan Institute of Science and Technology School of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province Central South University College of Materials and Metallurgy Guizhou University National Energy Metal Resources and New Materials Key Laboratory Central South University

Aqueous zinc-ion batteries （AZIBs） are fundamentally challenged by the instability of the electrode/electrolyte interface,predominantly due to irreversible zinc （Zn） deposition and hydrogen ***,the intricate mechanisms behind the electrochemical discrepancies induced by interfacial Zn2+-solvation and deposition behavior demand comprehensive *** molecules endowed with special functional groups （such as hydroxyl,carboxyl,etc.） have the potential to significantly optimize the solvation structure of Zn2+and regulate the interfacial electric double layer （EDL）.By increasing nucleation overpotential and decreasing interfacial free energy,these functional groups facilitate a lower critical nucleation radius,thereby forming an asymptotic nucleation model to promote uniform Zn ***,this study presents a pioneering approach by introducing trace amounts of n-butanol as solvation regulators to engineer the homogenized Zn （H-Zn） anode with a uniform and dense *** interfacial reaction and structure evolution are explored by in/ex-situ experimental techniques,indicating that the H-Zn anode exhibits dendrite-free growth,no by-products,and weak hydrogen evolution,in sharp contrast to the bare ***,the H-Zn anode achieves a remarkable Zn utilization rate of approximately 20% and simultaneously sustains a prolonged cycle life exceeding 500 ***,the H-Zn//NH4V4O10（NVO） full battery showcases exceptional cycle stability,retaining 95.04%capacity retention after 400 cycles at a large current density of 5 A *** study enlightens solvation-regulated additives to develop Zn anode with superior utilization efficiency and extended operational lifespan.

关键词： Solvation

Laser‑Induced Highly Stable Conductive Hydrogels for Robust Bioelectronics

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Nano-Micro Letters 2025年第3期17卷 117-120页

作者： Yibo Li Hao zhou Huayong Yang Kaichen Xu State Key Laboratory of Fluid Power and Mechatronic Systems School of Mechanical EngineeringZhejiang UniversityHangzhou 310058People’s Republic of China

Despite the promising progress in conductive hydrogels made with pure conducting polymer,great challenges remain in the interface adhesion and robustness in longterm *** address these challenges,*** Hwan Ko and Taek-Soo Kim’s team introduced a laserinduced phase separation and adhesion method for fabricating conductive hydrogels consisting of pure poly(3,4-ethylenedioxythiophene):polystyrene sulfonate on polymer *** laser-induced phase separation and adhesion treated conducting polymers can be selectively transformed into conductive hydrogels that exhibit wet conductivities of 101.4 S cm^(−1)with a spatial resolution down to 5μ***,they maintain impedance and charge-storage capacity even after 1 h of *** micropatterned electrode arrays demonstrate their potential in long-term in vivo signal recordings,highlighting their promising role in the field of bioelectronics.

关键词： Laser processing Conductive hydrogels Stable interface Bio-interfacing electrodes Bioelectronic application

Nanostructured ZnO/BiVO_(4)I-scheme heterojunctions for piezocatalytic degradation of organic dyes via harvesting ultrasonic vibration energy

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 488-497页

作者： Yiling Li Xiaoyao Yu Yingjie zhou Yao Lin Ying Wu Key Laboratory of the Ministry of Education for Advanced Catalysis Materials College of Chemistry and Materials ScienceZhejiang Normal UniversityJinhua 321004China

BiVO_(4)porous spheres modified by ZnO were designed and synthesized using a facile two-step *** resulting ZnO/BiVO_(4)composite catalysts have shown remarkable efficiency as piezoelectric catalysts for degrading Rhodamine B(RhB)unde mechanical vibrations,they exhibit superior activity compared to pure *** 40wt%ZnO/BiVO_(4)heterojunction composite displayed the highest activity,along with good stability and *** enhanced piezoelectric catalytic activity can be attributed to the form ation of an I-scheme heterojunction structure,which can effectively inhibit the electron-hole ***,hole(h+)and superoxide radical(·O_(2)^(-))are proved to be the primary active ***,ZnO/BiVO_(4)stands as an efficient and stable piezoelectric catalyst with broad potential application in the field of environmental water pollution treatment.

关键词： piezoelectric catalytic heterojunction dye degradation ultrasonic vibration