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Flexural behavior of textile reinforced mortar-autoclaved lightweight aerated concrete composite panels

Frontiers of Structural and Civil Engineering 2024年第5期18卷 776-787页

作者： Liying GUO Mingke DENG Wei zhang Tong LI yangxi zhang Mengyu CAO Xian HU Department of Civil Engineering Xi’an University of Architecture and TechnologyXi’an 710055China Key Lab of Structural Engineering and Earthquake Resistance Ministry of Education(XAUAT)Xi’an 710055China Scene engineering design institute Xi’an 710016China Dahua Group Shang hai 200062China

To improve the deficiencies of prefabricated autoclaved lightweight aerated concrete(ALC)panel such as susceptibility to cracking and low load-bearing capacity,a textile-reinforced mortar-autoclaved lightweight aerated concrete(TRM-ALC)composite panel was developed in this *** group of reference ALC panels and five groups of TRM-ALC panels were fabricated and subjected to four-point flexural *** was applied on the tensile side of the ALC panels to create *** variable parameters were the plies of textile(one or two),type of textile(basalt or carbon),and whether the matrix(without textile)was applied on the compression side of *** results showed that a bonding only 8-mm-thick TRM layer on the surface of the ALC panel could increase the cracking load by 180%−520%.The flexural capacity of the TRM-ALC panel increased as the number of textile layers *** reinforcement of the matrix on the compressive side could further enhance the stiffness and ultimate loadbearing capacity of the TRM-ALC *** panels with basalt textile failed in flexural mode,with the rupture of fabric *** with carbon textile failed in shear mode due to the ultra-high tensile strength of *** addition,analytical models related to the different failure modes were presented to estimate the ultimate load-carrying capacity of the TRM-ALC panels.

关键词： prefabricated autoclaved lightweight aerated concrete panel textile-reinforced mortar cracking load flexural capacity stiffness

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纤维特征参数对HES-HDC单轴拉伸性能的影响及拉伸韧性评价方法

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湖南大学学报（自然科学版） 2024年第3期51卷 130-140页

作者：杨家盛邓明科张晴晴邓友生张阳玺范洪侃西安建筑科技大学土木工程学院陕西西安710055 西安科技大学建筑与土木工程学院陕西西安710054 西安五和建筑科技研究院有限公司陕西西安710055

为探究高早强高延性混凝土(HES-HDC)在不同PE纤维直径与体积率下的单轴拉伸力学性能,设计了17组薄板试件进行单轴拉伸试验,研究PE纤维直径(22μm和25μm)及体积率(1.00%、1.25%和1.50%)对不同龄期(2 h、24 h、7 d、28 d和56 d)HES-HDC应... 详细信息

为探究高早强高延性混凝土(HES-HDC)在不同PE纤维直径与体积率下的单轴拉伸力学性能,设计了17组薄板试件进行单轴拉伸试验,研究PE纤维直径(22μm和25μm)及体积率(1.00%、1.25%和1.50%)对不同龄期(2 h、24 h、7 d、28 d和56 d)HES-HDC应力-应变曲线、拉伸强度和应变的影响;根据试验结果提出了HDC拉伸韧性评价方法.结果表明:在拉伸荷载作用下,HES-HDC应力-应变曲线展示出应变强化特性,破坏过程呈多裂缝开展;2 h龄期时,HES-HDC拉伸强度与应变达到3.29 MPa和0.88%以上;28 d时,HES-HDC拉伸应变可保持在1.28%以上;当纤维体积率为1.00%时,小直径纤维对试件拉伸应变有利,而大直径纤维对试件拉伸强度有利;综合大直径纤维试件拉伸强度与应变,纤维最佳体积率为1.25%.提出的拉伸韧性评价方法可评价HDC薄板受拉全过程的韧性.随龄期的增长,HES-HDC拉伸韧性指数降低,而拉伸强度系数提高;小直径纤维试件的拉伸韧性高于大直径纤维试件;纤维体积率为1.25%时试件拉伸韧性最大.

关键词：高早强高延性混凝土纤维直径纤维体积率单轴拉伸抗拉强度拉伸韧性

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Optimizing piezoelectric performance of complex perovskite through increasing diversity of B-site cations

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Journal of Materials Science & Technology 2024年第3期170卷 78-86页

作者： Mengdi Cheng Dongyan zhang yangxi Yan Zhimin Li Pangpang Wang Ri-ichi Murakami School of Advanced Materials and Nanotechnology Xidian UniversityXi’an 710126China Nanomaterials Group Institute of SystemInformation Technologies and Nanotechnologies(ISIT)Fukuoka Industry-Academia Symphonicity(FiaS)4-1 KyudaishinmachiNishi-kuFukuoka 819-0388Japan School of Mechanical Engineering Chengdu UniversityChengdu 610106China

Piezoelectric materials with unique properties are hugely appealing for high sensitivity sensors and ultrasonic ***,Pb(Ni_(1/3)Nb_(2/3))O_(3)-Pb(Yb_(1/2)Nb_(1/2))O_(3)-PbTiO_(3)piezoelectric system was designed and investigated in *** optimized piezoelectric response(d_(33)=826 pC/N,d_(33)∗=1017 pm/V)together with good temperature stability and negligible performance degradation up to 10^(6) cycles was achieved in 0.58PNN-0.10PYN-0.32PT *** analysis revealed the amplification of intrinsic and extrinsic contributions in MPB region due to more spontaneous polarization orientations and an increase in chemical disorder of system after the introduction of *** origin of high piezoelectric response was investigated through the combination of scanning electron microscopy and piezoresponse force *** diversity of B-site cations was shown to enhance local structural heterogeneity,weaken long-range ferroelectric ordered domains,and lower free energy barrier via the formation of nanodomain configuration that promoted polarization rotation,thereby improving piezoelectric properties of the ***,it is suggested that increasing the diversity of B-site cations is an effective strategy for achieving outstanding piezoelectric performance.

关键词： PNN-PYN-PT ceramics Piezoelectricity enhancement Relaxation behavior Domain structure

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半对数线图在流行病学研究中的应用

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疾病监测 2020年第2期35卷 182-183页

作者：章扬熙辽宁省疾病预防控制中心辽宁沈阳110005

介绍半对数线图的结构和用途,并应用该方法研究我国新型冠状病毒肺炎(COVID-19)疫情的时间分布及其流行速度变化。通过对2020年1月下旬COVID-19确诊患者和疑似患者时间分布的分析发现,COVID-19患者的传播速度在明显下降,半对数线逐渐走... 详细信息

介绍半对数线图的结构和用途,并应用该方法研究我国新型冠状病毒肺炎(COVID-19)疫情的时间分布及其流行速度变化。通过对2020年1月下旬COVID-19确诊患者和疑似患者时间分布的分析发现,COVID-19患者的传播速度在明显下降,半对数线逐渐走平,日环比值(DLR)已经趋近于1,目前防控措施很有效。如果春节返程的人口流动期间防控得当,疫情有望逐渐下降。半对数线图是研究疫情消长规律的重要工具。

关键词：半对数线图新型冠状病毒肺炎日环比值流行病学

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引入盾构技术开发利用深层地热能

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城市地质 2019年第2期14卷 12-17页

作者：张英群张延夕河北省地矿局地质矿产科技处河北石家庄050081 河北省地质调查院河北石家庄050081

探索分析引入盾构技术直接开发利用基础地热能的可行性。地热梯度及地热资源的分布特点揭示,只要有足够的深度就能获得足够的地温。传统的地热勘查和地热开发技术受到多种因素制约,使地热资源的开发利用受到了极大的限制,引入盾构技术... 详细信息

探索分析引入盾构技术直接开发利用基础地热能的可行性。地热梯度及地热资源的分布特点揭示,只要有足够的深度就能获得足够的地温。传统的地热勘查和地热开发技术受到多种因素制约,使地热资源的开发利用受到了极大的限制,引入盾构技术开发利用深部基础地热资源,将是一种颠覆性和革命性的地热开发技术。本文通过分析地热资源的分布特征,结合盾构技术的特点,探索一种广泛利用基础地热能的技术、方法和可能性。

关键词：深层地热干热岩清洁能源盾构技术地热开发利用

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Diatomic Pd catalyst with conjugated backbone for synergistic electrochemical CO_(2)reduction

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Nano Research 2024年第6期17卷 4850-4855页

作者： Wenxuan zhang Mengran zhang Hongjuan Wang Wen zhang Min zhang MOE International Joint Laboratory of Materials Microstructure Institute for New Energy Materials and Low Carbon TechnologiesSchool of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical EngineeringTianjin University of TechnologyTianjin 300384China

Double-site catalysts have attracted widespread attention in the field of electrocatalysis due to their high metal loading,adjustable active centres,and electronic valence ***,the development of bimetallic sites catalysts that coordinate with definite atoms is still in the exploratory ***,we designed and synthesized a bimetallic palladium complex(BPB-Pd_(2))with conjugated *** supported BPB-Pd_(2)was applied to electrochemical CO_(2)reduction reaction(CO_(2)RR)for the first *** as-obtained BPB-Pd_(2)gives an exceptional Faradaic efficiency of CO(FECO)of 94.4%at−0.80 V *** hydrogen electrode(RHE),which is significantly superior to monoatomic palladium catalyst(BPB-Pd1).The density functional theory(DFT)calculations revealed that the essential reason for the outstanding activity of BPB-Pd_(2)toward CO_(2)RR was that the electronic effect between diatomic palladium reduces the free energy change for CO_(2)RR ***,BPB-Pd_(2)exhibits moderate free energy change to form COOH*intermediate,which was beneficial for the generation of CO in CO_(2)RR.

关键词： synthesis electrocatalysis CO_(2)reduction bimetallic palladium complex synergistic catalysis

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N-doped graphene quantum dot-decorated N-TiO2/P-doped porous hollow g-C_(3)N_(4) nanotube composite photocatalysts for antibiotic photodegradation and H2 production

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International Journal of Minerals,Metallurgy and Materials 2024年第1期31卷 165-178页

作者： Jingshu Yuan Yao zhang Xiaoyan zhang Junjie zhang Shen’gen zhang Institute for Advanced Materials and Technology University of Science and Technology BeijingBeijing 100083China Xi’an Fanyi University Xi’an 710105China Shunde Graduate School of University of Science and Technology Beijing Foshan 528399China State Key Laboratory of Lunar and Planetary Sciences Macao University of Science and TechnologyMacao SAR 820000China

Exclusive responsiveness to ultraviolet light (~3.2 eV) and high photogenerated charge recombination rate are the two primary drawbacks of pure TiO_(2). We combined N-doped graphene quantum dots (N-GQDs), morphology regulation, and heterojunction construction strategies to synthesize N-GQD/N-doped TiO_(2)/P-doped porous hollow g-C_(3)N_(4) nanotube (PCN) composite photocatalysts (denoted as G-TPCN). The optimal sample (G-TPCN doped with 0.1wt% N-GQD, denoted as 0.1% G-TPCN) exhibits significantly enhanced photoabsorption, which is attributed to the change in bandgap caused by elemental doping (P and N), the improved light-harvesting resulting from the tube structure, and the upconversion effect of N-GQDs. In addition, the internal charge separation and transfer capability of0.1% G-TPCN are dramatically boosted, and its carrier concentration is 3.7, 2.3, and 1.9 times that of N-TiO_(2), PCN, and N-TiO_(2)/PCN(TPCN-1), respectively. This phenomenon is attributed to the formation of Z-scheme heterojunction between N-TiO_(2) and PCNs, the excellent electron conduction ability of N-GQDs, and the short transfer distance caused by the porous nanotube structure. Compared with those of N-TiO_(2), PCNs, and TPCN-1, the H2 production activity of 0.1%G-TPCN under visible light is enhanced by 12.4, 2.3, and 1.4times, respectively, and its ciprofloxacin (CIP) degradation rate is increased by 7.9, 5.7, and 2.9 times, respectively. The optimized performance benefits from excellent photoresponsiveness and improved carrier separation and migration efficiencies. Finally, the photocatalytic mechanism of 0.1% G-TPCN and five possible degradation pathways of CIP are proposed. This study clarifies the mechanism of multiple modification strategies to synergistically improve the photocatalytic performance of 0.1% G-TPCN and provides a potential strategy for rationally designing novel photocatalysts for environmental remediation and solar energy conversion.

关键词： N-doped TiO_(2) N-doped graphene quantum dots P-doped g-C_(3)N_(4) porous hollow nanotube heterojunction photocatalysis

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Reversing free-electron transfer of sulfide cocatalyst for exceptional photocatalytic H_(2)evolution

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Journal of Materials Science & Technology 2024年第4期171卷 147-149页

作者： Yanfeng zhang Zhenyi zhang National Experimental Chemistry Teaching Center Hebei Key Laboratory of Inorganic Nano-materialsCollege of Chemistry and Materials ScienceHebei Normal UniversityShijiazhuang 050024China Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission Key Laboratory of Photosensitive Materials and Devices of Liaoning ProvinceSchool of Physics and Materials EngineeringDalian Minzu UniversityDalian 116600China

Recently,Yu and co-workers deeply explore the potential impact of free electron transfer between co-catalysts and photocatalyst carriers on H_(2)evolution efficiency of active sites over MoS_(2+x).They pro-pose an electron-reversal tactics to evade the unexpected electron transfer and synchronously regulate the above transfer in a beneficial orientation for weakening hydrogen adsorption on S ***,this highlight not only discusses and summarizes the essences of electron reversal and the optimized H ad-sorption/desorption mechanism,but also emphasizes the significance of femtosecond transient absorp-tion spectroscopy(fs-TAS)and in-situ irradiated X-ray photoelectron spectroscopy(ISI-XPS)for revealing charge transfer dynamics and *** anticipate that this highlight can disseminate a new per-spective on the roles of photocatalyst carriers in improving cocatalytic H_(2)-production kinetics.

关键词： Photocatalysis Cocatalyst Electron reversal Antibonding-orbital occupancy S–H bonds

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一种石墨烯热电器件的圆片级制备工艺

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微纳电子技术 2014年第7期51卷 458-464页

作者：赵琦张扬熙刘冠东高成臣郝一龙北京大学微电子学研究院北京100871 北京大学深圳研究生院信息工程学院广东深圳518055 中国科学院传感技术国家重点实验室北京100083

石墨烯器件的规模制备是石墨烯材料从实验室研究走向市场应用的关键技术。基于大面积化学气相淀积(CVD)石墨烯,结合微加工技术,对石墨烯圆片级制备工艺进行了初步研究。优化了光学光刻和反应离子刻蚀(RIE)等工艺参数,设计了一套适用于4... 详细信息

石墨烯器件的规模制备是石墨烯材料从实验室研究走向市场应用的关键技术。基于大面积化学气相淀积(CVD)石墨烯,结合微加工技术,对石墨烯圆片级制备工艺进行了初步研究。优化了光学光刻和反应离子刻蚀(RIE)等工艺参数,设计了一套适用于4英寸(1英寸=2.54 cm)硅衬底圆片级制备石墨烯器件的完整工艺流程,可以减少光刻次数,降低工艺成本。测试结果表明,单个圆片的器件成品率可达90.6%,圆片内器件具有较好的均一性,制备的石墨烯热电单元阵列在冷热端温差为5.2℃时,输出电压可达3.52 mV,高于已报道的同类石墨烯器件。

关键词：石墨烯化学气相淀积(CVD) 圆片级微加工技术热电器件

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Friction as energy dissipation process associated with superlubricity of solids

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Friction 2024年第9期12卷 2083-2088页

作者： Bo zhang Saga University Saga-shi 840-8502Japan

The paper shows that work in a quantum system is quantized with energy;the quantum work is equivalent to the highest eigenenergy(the Debye energy)of the system and the superlubricity of solids is derived from the quantum *** prerequisite for the superlubricity is that the lateral force at contact surfaces in sliding is less than the Debye force so that the phonon of the solids is not excited.

关键词： superlubricity phonon friction Plank law Debye frequency

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