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A perspective on high-entropy two-dimensional materials

SusMat 2022年第1期2卷 65-75页

作者： yanglansen cui Yongzheng Zhang Zhenjiang Cao Jianan Gu Zhiguo Du Bin Li Shubin Yang School of Materials Science and Engineering Beihang UniversityBeijingP.R.China

In past decades,high-entropy(HE)materials,containing five or more elements with approximately equal atomic ratio,are extensively investigated due to their desirable properties in a series of applications.Recently,HE two-dimensional(2D)materials have become promising materials,which not only endow the advantages from their bulk form but also exhibit unusual properties due to their 2D features.So far,the HE 2D transition metal carbides(MXenes),dichalcogenides(TMDs),hydrotalcites(LDHs),and oxides have been successfully synthesized and performed well in different electrochemical reactions,which is originated from the synergistic effect of multicomponents and atomic thin characteristics.Here,the challenges on processing,characterization,and property predictions of HE 2D materials are emphasized.Finally,viable strategies,advanced processing,fundamental understanding,in-depth characterization of new HE 2D materials are proposed.

关键词： 2D materials high-entropy lattice distortions MXenes strong stress

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Harnessing the Unique Features of 2D Materials toward Dendrite-free Metal Anodes

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Energy & Environmental Materials 2022年第1期5卷 45-67页

作者： Zhenjiang Cao Yongzheng Zhang yanglansen cui Jianan Gu Zhiguo Du Yongzheng Shi Kai Shen Hao Chen Bin Li Shubin Yang School of Materials Science and Engineering Beihang UniversityBeijing 100191China

Electrochemically active metal anodes,such as lithium,sodium,potassium,and zinc,have attracted great research interests in the advanced rechargeable batteries owing to their superior theoretical energy densities.Unfortunately,the metal anodes suffer from the huge volume changes with loss of active materials during the plating and stripping processes,resulting in fast capacity decay.Moreover,the random growth of dendrites on the metal anodes will penetrate the separator,causing severe safety issues.Engineering metal anodes by introducing the 2D materials are widely investigated to alleviate these issues.Benefitting from the ultrathin structure feature and unique electrical properties,2D materials are regarded as one of the best host of metal anodes.Besides,the tunable active sites on basal plane enable 2D materials to achieve favorable interaction with metal anodes.Moreover,some 2D materials exhibit good mechanical strength and flexibility,serving as building block for the artificial solid electrolyte interphase.In this review,we mainly disclosed the correlations between the intrinsic properties of 2D materials and their functions in guiding uniform nucleation,controlling the growth of metals,and accommodating the volume change.Also,the challenges of 2D materials in metal anodes are well discussed.Finally,the future directions to develop highperformance metal anodes by taking advantage of these unique features of 2D materials are proposed.

关键词： 2D materials metal anodes dendrite-free nucleation high-energy density

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Temperature difference-enhanced salinity gradient energy conversion enabled by thermostable hydrogel membrane with anti-swelling property

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Nano Research 2023年第8期16卷 11288-11295页

作者： Zhehua Zhang Teng Zhou Xiang-Yu Kong Yadong Wu Weiwen Xin yanglansen cui Linsen Yang Tingyang Li Xin Li Qingchen Wang Weipeng Chen Lei Jiang Liping Wen Key Laboratory of Bio-inspired Materials and Interfacial Science Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100049China School of Future Technology University of Chinese Academy of SciencesBeijing 100049PChina College of Mechanical and Electrical Engineering Hainan UniversityHaikou 570228China Binzhou Institute of Technology Binzhou 256600China

Coupling low-grade heat(LGH)with salinity gradient is an effective approach to increase the efficiency of the nanofluidic-membrane-based power generator.However,it is a challenge to fabricate membranes with high charge density that ensures ion permselectivity,while maintaining chemical and mechanical stability in this composite environment.Here,we develop a bis[2-(methacryloyloxy)ethyl]phosphate(BMAP)hydrogel membrane with good thermal stability and anti-swelling property through self-crosslinking of the selected monomer.By taking advantage of negative space charge and three-dimensional(3D)interconnected nanochannels,salinity gradient energy conversion efficiency is substantially enhanced by temperature difference.Theoretical and experimental results verify that LGH can largely weaken the concentration polarization,promoting transmembrane ion transport.As a result,such a hydrogel membrane delivers high-performance energy conversion with a power density of 11.53 W·m^(−2)under a negative temperature difference(NTD),showing a 193%increase compared with that without NTD.

关键词： ion transport temperature difference-enhanced salinity gradient energy self-crosslinking hydrogel membranes space charge

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Atomic insights of electronic states engineering of GaN nanowires by Cu cation substitution for highly efficient lithium ion battery

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Journal of Energy Chemistry 2022年第4期31卷 46-54页

作者： Zhenjiang Li Kesheng Gao Ying Han Shiqi Ding yanglansen cui Minmin Hu Jian Zhao Meng Zhang Alan Meng Jimmy Yun Zhiming Liu Da-Wei Wang Changlong Sun College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina School of Chemical Engineering The University of New South WalesSydneyNSW 2052Australia Shandong Engineering Laboratory for Preparation and Application of High-performance Carbon-Materials College of Electromechanical EngineeringQingdao University of Science and TechnologyQingdao 266061ShandongChina Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science MOECollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042ShandongChina Qingdao International Academician Park Research Institute QingdaoShandong 266000China School of Materials Science and Engineering Beihang University100191 BeijingChina School of Materials Science and Engineering Xi’an Jiaotong UniversityXi’an 710049ShaanxiChina

Electronic engineering of gallium nitride(Ga N) is critical for enhancement of its electrode performance.In this work, copper(Cu) cation substituted Ga N(Cu-Ga N) nanowires were fabricated to understand the electronically engineered electrochemical performance for Li ion storage. Cu cation substitution was revealed at atomic level by combination of X-ray photoelectron spectroscopy(XPS), X-ray absorption fine structure(XAFS), density functional theory(DFT) simulation, and so forth. The Cu-Ga N electrode delivered high capacity of 813.2 m A h g^(-1) at 0.1 A g^(-1) after 200 cycles, increased by 66% relative to the unsubstituted Ga N electrode. After 2000 cycles at 10 A g^(-1),the reversible capacity was still maintained at326.7 m A h g^(-1). The DFT calculations revealed that Cu substitution introduced the impurity electronic states and efficient interatomic electron migration, which can enhance the charge transfer efficiency and reduce the Li ion adsorption energy on the Cu-Ga N electrode. The ex-situ SEM, TEM, HRTEM, and SAED analyses demonstrated the reversible intercalation Li ion storage mechanism and good structural stability. The concept of atomic-arrangement-assisted electronic engineering strategy is anticipated to open up opportunities for advanced energy storage applications.

关键词： Cu cation substitution Electronic states engineering GaN nanowires Lithium-ion batteries DFT

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Carbon-supported layered double hydroxide nanodots for efficient oxygen evolution: Active site identification and activity enhancement

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Nano Research 2021年第9期14卷 3329-3336页

作者： Shenlong Zhao Detao Zhang Shuai Jiang yanglansen cui Haijing Li Juncai Dong Zhirun Xie Da-Wei Wang Rose Amal Zhenhai Xia Liming Dai Australian Carbon Materials Centre(A-CMC) School of Chemical EngineeringThe University of New South WalesSydneyNSW 2052Australia Center of Advanced Science and Engineering for Carbon(Case4Carbon) Department of Macromolecular Science and EngineeringCase Western Reserve University(CWRU)10900 Euclid AvenueClevelandOH 44106USA School of Chemical and Biomolecular Engineering The University of SydneySydneyNSW 2006Australia Department of Materials Science and Engineering University of North TexasDentonTX 76203USA Beijing Synchrotron Radiation Facility Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China School of Chemical Engineering The University of New South WalesSydneyNSW 2052Australia

In this study,we developed a novel confinement-synthesis approach to layered double hydroxide nanodots(LDH-NDs)anchored on carbon nanoparticles,which formed a three-dimensional(3D)interconnected network within a porous carbon support derived from pyrolysis of metal-organic frameworks(C-MOF).The resultant LDH-NDs@C-MOF nonprecious metal catalysts were demonstrated to exhibit super-high catalytic performance for oxygen evolution reaction(OER)with excellent operation stability and low overpotential(-230 mV)at an exchange current density of 10 mA·cm^(-2).The observed overpotential for the LDH-NDs@C-MOF is much lower than that of large-sized LDH nanosheets(321 mV),pure carbonized MOF(411 mV),and even commercial RuO_(2)(281 mV).X-ray absorption measurements and density functional theory(DFT)calculations revealed partial charge transfer from Fe^(3+)through an O bridge to Ni^(2+)at the edge of LDH-NDs supported by C-MOF to produce the optimal binding energies for OER intermediates.This,coupled with a large number of exposed active sides and efficient charge and electrolyte/reactant/product transports associated with the porous 3D C-MOF support,significantly boosted the OER performance of the LDH-ND catalyst with respect to its nanosheet counterpart.Apart from the fact that this is the first active side identification for LDH-ND OER catalysts,this work provides a general strategy to enhance activities of nanosheet catalysts by converting them into edge-rich nanodots to be supported by 3D porous carbon architectures.

关键词： carbon nanomaterials layered double hydroxide(LDH)nanodots metal-organic framework(MOF)derivatives oxygen evolution reaction

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