检索结果-南通市图书馆

Wettability,reactivity,and interface structure in Mg/Ni system

journal of Magnesium and Alloys 2024年第2期12卷 659-672页

作者： s.Terlicka N.sobczak Ł.Maj P.Darłak j.j.s.bczak Institute of Metallurgy and Materials science Polish Academy of Sciences25 Reymonta Str.KrakowPoland Faculty of Foundry Engineering AGH University23 Reymonta Str.KrakowPoland

The sessile drop method was applied to the experimental investigation of the wetting and spreading behaviors of liquid Mg drops on pure Ni *** comparison,the experiments were performed in two variants:(1)using the Capillary Purification(CP)procedure,which allows the non-contact heating and squeezing of a pure oxide-free Mg drop;(2)by classical Contact Heating(CH)*** high-temperature tests were performed under isothermal conditions(CP:760℃for 30 s;CH:715℃for 300 s)using Ar+5 wt%H_(2) *** the sessile drop tests,images of the Mg/Ni couples were recorded by CCD cameras(57 fps),which were then applied to calculate the contact angles of metal/substrate *** and transmission electron microscopy analyses,both coupled with energy-dispersive X-ray spectroscopy,were used for detailed structural characterization of the solidified *** was found that an oxide-free Mg drop obtained by the CP procedure showed a wetting phenomenon on the Ni substrate(an average contact angleθs),followed by fast spreading and good wetting over the Ni substrate(θ_((CP))~20°in 5 s)to form a final contact angle ofθ_(f(CP))~18°.In contrast,a different wetting behavior was observed for the CH procedure,where the unavoidable primary oxide film on the Mg surface blocked the spreading of liquid Mg showing apparently non-wetting behavior after 300 s contact at the test ***,in both cases,the deep craters formed in the Ni substrates under the Mg drops and significant change in the structure of initially pure Mg drops to Mg-Ni alloys suggest a strong dissolution of Ni in liquid Mg and apparent values of the final contact angles measured for the Mg/Ni system.

关键词： Magnesium-based alloys sessile drop tests Capillary purification procedure Wettability Reactivity Contact angle

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Dynamic-based model for calculating the boulder impact force in debris flow

引用

journal of Mountain science 2024年第6期21卷 1930-1940页

作者： yang Chaoping ZHANG shaojie YIN Yueping yang Hongjuan WEI Fangqiang state Key Laboratory of Mountain Hazards and Engineering Resilience Institute of Mountain Hazards and EnvironmentChinese Academy of SciencesChengdu 610299China University of Chinese Academy of sciences Beijing 100049China China Institute of Geological Environment Monitoring Beijing 100081China Chongqing Institute of Green and Intelligent Technology Chinese Academy of SciencesChongqing 400714China Chongqing school University of Chinese Academy of SciencesChongqing 400714China

The boulder impact force in debris flow is generally calculated by static methods such as the cantilever beam ***,these methods cannot describe the dynamic scenario of boulder collision on structures,so the inertia and damping effects of the structures are not involved causing an overestimation on the boulder impact *** order to address this issue,a dynamic-based model for calculating the boulder impact force of a debris flow was proposed in this study,and the dynamic characteristics of a cantilever beam with multiple degrees of freedom under boulder collision were *** using the drop-weight method to simulate boulders within debris flow,seven experiments of drop-weight impacting the cantilever beam were used to calibrate the error of the dynamicbased *** indicate that the dynamic-based model is able to reconstruct the impact force history on the cantilever beam during impact time and the error of dynamic-based model is 15.3%in calculating boulder impact force,significantly outperforming the cantilever beam model’s error of 285%.Therefore,the dynamic-based model can overcome the drawbacks of the static-based models and provide a more reliable theoretical foundation for the engineering design of debris flow control structures.

关键词： Debris flow Impact force Boulder collision Dynamic-based model Engineering design

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

stabilization and detection of labile reaction intermediates in supramolecular containers

引用

Chinese Chemical Letters 2024年第6期35卷 47-52页

作者： Rui Wang yang Liang julius Rebek jr. yang Yu Center for supramolecular Chemistry&Catalysis and Department of Chemistry College of ScienceShanghai UniversityShanghai 200444China skaggs Institute for Chemical Biology and Department of Chemistry The Scripps Research InstituteLa JollaCA 92037United States

Detection and observation of reactive intermediates is an essential step in investigation of reaction ***,most reactive intermediates are unstable and present at low concentrations;their short lifetimes make them difficult to detect and *** containers offer opportunities for the stabilization and characterization of those labile species,through isolation from the media and protection inside the cavity of the *** this review,we summarize the examples of labile reaction intermediates that are stabilized and characterized with the help of supramolecular *** container compounds include carcerands,deep cavitands and amide *** focus on unstable guest species-cyclobutadiene,benzocyclopropenone,o-benzyne,1,2,4,6-cycloheptatetraene,anti-Bredt's olefin,fluorophenoxycarbene,O-acylisoamide,and hemiaminalthat act as intermediates in certain organic reactions.

关键词： supramolecular containers Reaction intermediates Labile species stabilization short-lived species detection supramolecular chemistry

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Thermo-kinetic characteristics on stabilizing hetero-phase interface of metal matrix composites by crystal plasticity finite element method

引用

journal of Materials science & Technology 2024年第2期169卷 53-67页

作者： Y.B.Zhang s.j.s.ng F.Liu state Key Laboratory of solidification Processing Northwestern Polytechnical UniversityXi’an 710072China Analytical&Testing Center Northwestern Polytechnical UniversityXi’an 710072China

Using dislocation-based constitutive modeling in three-dimension crystal plasticity finite element(3D CPFE)simulations,co-deformation and instability of hetero-phase interface in different material systems were herein studied for polycrystalline metal matrix composites(MMCs).Local stress and strain fields in two types of 3layer MMCs such as fcc/fcc Cu-Ag and fcc/bcc Cu-Nb have been predicted under simple compressive ***,more severe strain-induced interface instability can be observed in the fcc/bcc systems than in the fcc/fcc systems upon refining to metallic nanolayered composites(MNCs).By detailed analysis of stress and strain localization,it has been demonstrated that the interface instability is always accompanied by high-stress concentration,i.e.,thermodynamic characteristics,or high strain prevention i.e.,kinetic characteristics,at the hetero-phase *** then follows that the thermodynamic driving forceG and the kinetic energy barrier Q during dislocation and shear banding can be adopted to classify the deformation modes,following the so-called thermo-kinetic *** by inserting a high density of high-energy interfaces into the Cu-Nb composites,such thermo-kinetic integration at the hetero-phase interface allows a successful establishment of MMCs with the high△G-high Q deformation mode,which ensures high hardening and uniform strain distri-bution,thus efficiently suppressing the shear band,stabilizing the hetero-phase interface,and obtaining an exceptional combination in strength and *** hetero-phase interface chosen by a couple of thermodynamics and kinetics can be defined as breaking the thermo-kinetic correlation and has been proposed for artificially designing MNCs.

关键词： Thermodynamics and kinetics Physics-based constitutive modeling Hetero-phase interface Crystal plasticity finite element

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Design and modification of metal sulfide-based catalysts for lithiumsulfur batteries

引用

Particuology 2024年第3期86卷 86-100页

作者： Yufei Zhao Chuannan Geng Li Wang Haotian yang Wei Lv Quan-Hong yang Nanoyang Group State Key Laboratory of Chemical EngineeringSchool of Chemical Engineering and TechnologyNational Industry-Education Integration Platform of Energy Storageand Collaborative Innovation Center of Chemical Science and Engineering(Tianjin)Tianjin UniversityTianjin300072China shenzhen Geim Graphene Center Engineering Laboratory for Functionalized Carbon MaterialsTsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen518055China Haihe Laboratory of sustainable Chemical Transformations Tianjin300192China joint school of National University of singapore and Tianjin University International Campus of Tianjin UniversityFuzhou350207China

Metal sulfide(Ms)have good conductivity,strong adsorption ability,and excellent catalytic activity for the conversion of sulfur species,and thus,show great promise as the catalysts in Lies ***,the relationship between their properties and electrochemical performance is still ***,further in-depth discussions are required to improve their design in Li-s *** review systematically summarizes the basic structural and electrochemical properties of Mss and highlights the advantages that guarantee them as high-performance catalysts in Li-s ***,various modification strategies for Mss to enhance the catalytic activity,efficiency,and stability are also *** last,future opportunities for Ms catalysts in Li-s batteries are proposed.

关键词： Lithium-sulfur battery Metal sulfide Catalysis

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

LsTM Network-Based Adaptation Approach for Dynamic Integration in Intelligent End-Edge-Cloud systems

引用

Tsinghua science and Technology 2024年第4期29卷 1219-1231页

作者： Xuan yang james A.Esquivel Graduate school Angeles University FoundationAngeles City 2009Philippinesand also with Shandong Provincial University Laboratory for Protected HorticultureWeifang University of Science and TechnologyWeifang 262700China Graduate school Angeles University FoundationAngeles City 2009Philippines

Edge computing, which migrates compute-intensive tasks to run on the storage resources of edge devices, efficiently reduces data transmission loss and protects data privacy. However, due to limited computing resources and storage capacity, edge devices fail to support real-time streaming data query and processing. To address this challenge, first, we propose a Long short-Term Memory (LsTM) network-based adaptive approach in the intelligent end-edge-cloud system. specifically, we maximize the Quality of Experience (QoE) of users by automatically adapting their resource requirements to the storage capacity of edge devices through an event mechanism. second, to reduce the uncertainty and non-complete adaption of the edge device towards the user’s requirements, we use the LsTM network to analyze the storage capacity of the edge device in real time. Finally, the storage features of the edge devices are aggregated to the cloud to re-evaluate the comprehensive capability of the edge devices and ensure the fast response of the user devices during the dynamic adaptation matching process. A series of experimental results show that the proposed approach has superior performance compared with traditional centralized and matrix decomposition based approaches.

关键词： quality of experience data query end-edge-cloud Long short-Term Memory(LsTM)networks

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Photo-enhanced uranium recovery from spent fuel reprocessing wastewater via s-scheme 2D/0D C_(3)N_(5)/Fe_(2)O_(3) heterojunctions

引用

susMat 2024年第2期4卷 41-50页

作者： Qi Meng Linzhen Wu Xiaoyong yang Ying Xiong Fanpeng Kong Tao Duan state Key Laboratory of Environment-friendly Energy Materials NuclearWaste and Environmental Safety Key Laboratory of DefenseSouthwest University of Science and TechnologyMianyangSichuanChina MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and storage Harbin Institute of TechnologyHarbinHeilongjiangChina Department of Materials science and Engineering KTH Royal Institute of TechnologyStockholmSweden

Re-extracting environmentally transportable hexavalent uranium from wastew-ater produced by spent fuel reprocessing using the photocatalytic technology is a crucial strategy to avoid uranium pollution and recover nuclear fuel strategic ***,we have designed s-scheme 2D/0D C_(3)N_(5)/Fe_(2)O_(3)heterojunction photocatalysts based on the built-in electric field and the energy band bend-ing theory,and have further revealed the immobilization process of hexavalent uranium conversion into relatively insoluble tetravalent uranium in terms of thermodynamics and *** to the results,the hexavalent uranium removal and recovery ratios in wastewater are as high as 93.38%and 83.58%,***,C_(3)N_(5)/Fe_(2)O_(3)heterojunctions also exhibit satisfactory cat-alytic activity and selectivity even in the presence of excessive impurity cations(including Na^(+),K^(+),Ca^(^(2+)),Mg^(2+),sr^(2+),and Eu^(3+))or various organics(such as xylene,tributylphosphate,pyridine,tannic acid,citric acid,and oxalic acid).It is believed that this work can provide a potential opportunity for s-scheme heterojunction photocatalysts to re-enrich uranium from spent fuel wastewater.

关键词： nuclear wastewater s-scheme heterostructure uranium recovery

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Accelerating Oxygen Electrocatalysis Kinetics on Metal-Organic Frameworks via Bond Length Optimization

引用

Nano-Micro Letters 2024年第9期16卷 279-290页

作者： Fan He Yingnan Liu Xiaoxuan yang Yaqi Chen Cheng‑Chieh yang Chung‑Li Dong Qinggang He Bin yang Zhongjian Li Yongbo Kuang Lecheng Lei Liming Dai yang Hou Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China Institute of Zhejiang University-Quzhou Quzhou 324000People’s Republic of China Ningbo Institute of Materials Technology and Engineering Chinese Academy of SciencesNingbo 315201People’s Republic of China school of Biological and Chemical Engineering NingboTech UniversityNingbo 315100People’s Republic of China Department of Physics Tamkang UniversityNew Taipei 25137TaiwanPeople’s Republic of China Australian Carbon Materials Centre(A‑CMC) School of Chemical EngineeringUniversity of New South WalesSydneyNSW 2051Australia

Metal-organic frameworks(MOFs)have been developed as an ideal platform for exploration of the relationship between intrinsic structure and catalytic activity,but the limited catalytic activity and stability has hampered their practical use in water ***,we develop a bond length adj.s.ment strategy for optimizing naphthalene-based MOFs that synthesized by acid etching Co-naphthalenedicarboxylic acid-based MOFs(donated as AE-CoNDA)to serve as efficient catalyst for water ***-CoNDA exhibits a low overpotential of 260 mV to reach 10 mA cm^(−2)and a small Tafel slope of 62 mV dec^(−1)with excellent stability over 100 *** integrated AE-CoNDA onto BiVO_(4),photocurrent density of 4.3 mA cm^(−2)is achieved at 1.23 *** investigations demonstrate that the stretched Co-O bond length was found to optimize the orbitals hybridization of Co 3d and O 2p,which accounts for the fast kinetics and high *** calculations reveal that the stretched Co-O bond length strengthens the adsorption of oxygen-contained intermediates at the Co active sites for highly efficient water splitting.

关键词： Metal-organic frameworks Bond length adj.s.ment spin state transition Orbitals hybridization Water splitting

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Acoustofluidics-enhanced biosensing with simultaneously high sensitivity and speed

引用

Microsystems & Nanoengineering 2024年第3期10卷 335-346页

作者： Yuang Li yang Zhao yang yang Wenchang Zhang Yun Zhang sheng sun Lingqian Zhang Mingxiao Li Hang Gao Chengjun Huang Institute of Microelectronics of the Chinese Academy of sciences Beijing 100029P.R.China University of Chinese Academy of sciences Beijing 101408P.R.China Department of Medicine Brigham and Women’s HospitalHarvard Medical SchoolBostonMA 02115USA

simultaneously achieving high sensitivity and detection speed with traditional solid-state biosensors is usually limited since the target molecules must passively diffuse to the sensor surface before they can be *** techniques have been applied to shorten the diffusion time by continuously moving molecules through the biosensing ***,the binding efficiencies of the biomolecules are still limited by the inherent laminar flow inside microscale *** this study,focused traveling surface acoustic waves were directed into an acoustic microfluidic chip,which could continuously enrich the target molecules into a constriction zone for immediate detection of the immune reactions,thus significantly improving the detection sensitivity and *** demonstrate the enhancement of biosensing,we first developed an acoustic microfluidic chip integrated with a focused interdigital transducer;this transducer had the ability to capture more than 91%of passed ***,polystyrene microbeads were pre-captured with human IgG molecules at different concentrations and loaded for detection on the *** representative results,~0.63,2.62,11.78,and 19.75 seconds were needed to accumulate significant numbers of microbeads pre-captured with human IgG molecules at concentrations of 100,10,1,and 0.1 ng/mL(~0.7 pM),respectively;this process was faster than the other methods at the hour level and more sensitive than the other methods at the nanomolar *** results indicated that the proposed method could significantly improve both the sensitivity and speed,revealing the importance of selective enrichment strategies for rapid biosensing of rare molecules.

关键词： fluid continuously simultaneous

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Transient Response and Ionic Dynamics in Organic Electrochemical Transistors

引用

Nano-Micro Letters 2024年第11期16卷 191-223页

作者： Chao Zhao jintao yang Wei Ma state Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi′an 710049People’s Republic of China

The rapid development of organic electrochemical transistors(OECTs)has ushered in a new era in organic electronics,distinguishing itself through its application in a variety of domains,from high-speed logic circuits to sensitive biosensors,and neuromorphic devices like artificial synapses and organic electrochemical random-access *** recent strides in enhancing OECT performance,driven by the demand for superior transient response capabilities,a comprehensive understanding of the complex interplay between charge and ion transport,alongside electron–ion interactions,as well as the optimization strategies,remains *** review aims to bridge this gap by providing a systematic overview on the fundamental working principles of OECT transient responses,emphasizing advancements in device physics and optimization *** review the critical aspect of transient ion dynamics in both volatile and non-volatile applications,as well as the impact of materials,morphology,device structure strategies on optimizing transient *** paper not only offers a detailed overview of the current state of the art,but also identifies promising avenues for future research,aiming to drive future performance advancements in diversified applications.

关键词： Organic electrochemical transistors Transient response Ion dynamics Electronic dynamics Volatility and non-volatility

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：