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Double-confined nanoheterostructure Sb/Sb_(2)S_(3)@Ti_(3)C_(2)T_(x)@C toward ultra-stable Li-/Na-ion batteries

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Rare Metals 2024年第5期43卷 2067-2079页

作者： Dan Wang Qun Ma Huan He Zhi-Yuan Wang Run-guo Zheng Hong-Yu Sun yan-guo liu Chun-Li liu School of Materials Science and Engineering Northeastern UniversityShenyang110819China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004China Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province Qinhuangdao 066004China Department of Physics and Oxide Research Center Hankuk University of Foreign StudiesYongin 17035Korea

Antimony-based materials with high capacities and moderate potentials are promising anodes for lithium-/-sodium-ion ***,their tremendous volume expansion and inferior conductivity lead to poor structural stability and sluggish reaction ***,a doubleconfined nanoheterostructure Sb/Sb_(2)S_(3)@Ti_(3)C_(2)T_(x)@C has been fabricated through a solvothermal method followed by low-temperature heat *** dual protection of“MXene”and“carbon”can better accommodate the volume expansion of Sb/Sb_(2)S_(3).The strong covalent bond(Ti-S,Ti-O-Sb,C-O-Sb)can firmly integrate Sb-based material with Ti_(3)C_(2)T_(x)and carbon,which significantly improves the structure *** addition,the carbon layer can restrain the oxidation of MXenes,and the nano-Sb/Sb_(2)S_(3)can facilitate electron/ion transport and suppress the restacking of *** heterogeneous interface between Sb and Sb_(2)S_(3)can further promote interfacial charge *** MXene-Sb/Sb_(2)S_(3)@C-1 with the optimal Sb content shows high specific capacities,comparable rate properties and ultra-stable cycling performances(250 m Ah·g^(-1)after 2500 cycles at 1 A·g^(-1)for sodium-ion batteries).Ex situ X-ray diffractometer(XRD)test reveals the storage mechanism including the conversion and alloying process of MXene-Sb/Sb_(2)S_(3)@*** voltammetry(CV)test results demonstrate that the pseudocapacitance behavior is dominant in MXene-Sb/Sb_(2)S_(3)@C-1,especially at large *** design paves the way for exploring high-performance alloy-based/conversion-type anode for energy storage devices.

关键词： Sb/Sb_(2)S_(3) MXene Carbon Anode Lithium-ion batteries Sodium-ion batteries

Hydrothermal in situ Ligand Synthesis from 1,10-Phenanthroline-5,6-dione and Characterization of 1D Coordination Polymers [Co(bpdc)(H_2O)_3]·H_2O and [Cu(bpy)V_2O_6]

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Chemical Research in Chinese Universities 2007年第3期23卷 250-253页

作者： WANG Xiu-li BI yan-feng LIN Hong-yan liu guo-cheng Faculty of Chemistry and Chemical Engineering Bohai University Jinzhou 121000 P. R. China

Hydrothermal treatment of MCl2 （ M = Co or Cu ） , NH4 VO3, and 1,10-phenanthroline-5,6-dione （pdon） resulted in the formation of a duplex coordination polymer [ Co （ bpdc ）（ H2O ） 3 ] · H2O （ bpdc = 2,2＇-bipyridine-3,3＇-dicarboxylate） and a chain-like coordination polymer [ Cu （bpy） V2O6 ] （ bpy = 2,2＇-bipyridine ）. X-ray single-crystal structural analysis shows that under hydrothermal conditions and in the presence of different transition metals, the organic reagent pdon was transformed in situ into bpdc and bpy, respectively. Mechanism of the in situ ligand synthesis reaction has been discussed.

关键词： Hydrothermal synthesis In situ Ligand synthesis Coordination polymer Mechanism

Phenanthroline-based Fluorescent Chemosensor for Selective Detection of Zn^(2+) in DMF Buffer Solution

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Chemical Research in Chinese Universities 2010年第6期26卷 884-887页

作者： WANG Xlu-li ZHENG Wen-yan LIN Hong-yan liu guo-cheng Faculty of Chemistry and Chemical Engineering Key Laboratory of Applied Chemistry of Liaoning Province Bohai University Jinzhou 121000 P. R. China

A simple ＂off-on＂ fluorescent chemosensor with high selectivity to zinc ions based on 1,10-phenanthro-line receptor dipyrido[3,2-d：2＇,3＇-f]quinoxaline（L） was *** selectivity response of receptor L to zinc ion was demonstrated by UV-Vis absorption and fluorescence spectroscopies in DMF buffer *** experiment results show that the fluorescent chemosensor L exhibits the optimum response behavior to Zn2＋ in the range of pH 8.0―9.0 and shows excellent selectivity to Zn2＋ over other cations tested.

关键词： Fluorescence Chemosensor Phenanthroline-based Cation detection selectivity

Towards high-performance anodes:Design and construction of cobalt-based sulfide materials for sodium-ion batteries

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Journal of Energy Chemistry 2021年第3期30卷 680-698页

作者： Baole Guan Si-Yu Qi Ying Li Ting Sun yan-guo liu Ting-Feng Yi Department of Chemistry College of SciencesNortheastern UniversityShenyang 110819LiaoningChina School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004HebeiChina Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province Qinhuangdao 066004HebeiChina Institute of Advanced Electrochemical Energy&School of Materials Science and Engineering Xi’an University of TechnologyXi’an 710048ShaanxiChina

Sodium-ion batteries are increasingly becoming important in the energy storage field owing to their low cost and high natural abundance of ***-based sulfide materials have been extensively studied as anode materials owing to their remarkable Na storage ***,the application of cobalt-based sulfides is hampered by their serious capacity degradation and unsatisfactory cycling stability due to severe structural changes during ***,it is important to comprehensively summarize advances in the understanding and modification of cobalt-based sulfides from various *** the present review,recent advances on various cobalt-based sulfides,such as CoS,CoS_(2),Co_(3)S_(4),Co_(9)S_(8),NiCo_(2)S_(4),CUCo_(2)S_(4),and SnCoS_(4),are outlined with particular attention paid to strategies that improve their sodium storage ***,the mechanisms of charge storage are ***,the key barriers to their extensive application and corresponding strategies for designing high-performance cobalt-based sulfide anode materials are ***,key developments are summarized and future research directions are proposed based on recent advancements,aiming to offer possible fascinating strategies for the future promotion of cobalt-based sulfides as anode materials applied in sodium-ion batteries.

关键词： Cobalt sulfides Sodium-ion battery Anode material Nanoengineering

Synthesis, DNA-binding, and Photocleavage of 2,3-Di-2-pyridylquinoxaline-silver(Ⅰ) Complex

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Chemical Research in Chinese Universities 2008年第1期24卷 15-19页

作者： WANG Xiu-li FANG Jia-ni BI yan-feng LIN Hong-yan liu guo-cheng Faculty of Chemistry and Chemical Engineering Liaoning Key Laboratry of Applied Chemistry Bohai University Jinzhou 121000 P. R. China

A new dinuclear complex, [Ag（L）（CH3CN）]2（ClO4）2·2H2O（L=2,3-di-2-pyridylquinoxaline）, was prepared and characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction analyses. The interaction of the complex with calf thymus DNA（CT-DNA） was investigated by absorption, fluorescence spectroscopies, and viscosity measurement. The results suggested that the complex was bound to DNA via an intercalative mode. The intrinsic binding constant value Kb was found to be approximately 1.48×10^3 L·mol^-1. Moreover, the Ag（I） complex could cleave the plasmid pUC19 DNA from the supercoiled Form Ⅰto the nicked FormⅡ under irradiation at 365 nm.

关键词： DNA Ag-Polypyridyl complex Interaction Fluorescence Cleavage

Ultrafine nano-scale Cu_(2)Sb alloy confined in three-dimensional porous carbon as an anode for sodium-ion and potassium-ion batteries

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International Journal of Minerals,Metallurgy and Materials 2021年第10期28卷 1666-1674页

作者： Dan Wang Qun Ma Kang-hui Tian Chan-Qin Duan Zhi-yuan Wang yan-guo liu School of Materials Science and Engineering Northeastern UniversityShenyang 110819China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004China Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province Qinhuangdao 066004China

Ultrafine nano-scale Cu2Sb alloy confined in a three-dimensional porous carbon was synthesized using NaCl template-assisted vacuum freeze-drying followed by high-temperature sintering and was evaluated as an anode for sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs).The alloy exerts excellent cycling durability(the capacity can be maintained at 328.3 mA·h·g^(-1) after 100 cycles for SIBs and 260 mA·h·g^(-1) for PIBs)and rate capability(199 mA·h·g^(-1) at 5 A·g^(-1) for SIBs and 148 mA·h·g^(-1) at 5 A·g^(-1) for PIBs)because of the smooth electron transport path,fast Na/K ion diffusion rate,and restricted volume changes from the synergistic effect of three-dimensional porous carbon networks and the ultrafine bimetallic *** study provides an ingenious design route and a simple preparation method toward exploring a high-property electrode for K-ion and Na-ion batteries,and it also introduces broad application prospects for other electrochemical applications.

关键词： copper-antimony alloy anode porous carbon potassium-ion batteries sodium-ion batteries

Measurement of GaN/Ge（001） Heterojunction Valence Band Offset by X-Ray Photoelectron Spectroscopy

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Chinese Physics Letters 2010年第6期27卷 183-186页

作者： guo yan liu Xiang-Lin SONG Hua-Ping yanG An-Li ZHENG Gao-Lin WEI Hong-Yuan yanG Shao-yan ZHU Qin-Sheng WANG Zhan-guo Key Laboratory of Semiconductor Materials Science Institute of Semiconductors Chinese Academy of Sciences PO Box 912 Beijing 100083

X-ray photoelectron spectroscopy has been used to measure the valence band offset （VBO） at the GaN/Ge heterostructure interface. The VBO is directly determined to be 1.13 ±0.19 eV, according to the relationship between the conduction band offset AEc and the valence band offset △Ev：△Ec =EgGaN -EgGe - △Ev, and taking the room-temperature band-gaps as 3.4 and 0.67eV for GaN and Ge, respectively. The conduction band offset is deduced to be 1.6±0.19 eV, which indicates a type-I band alignment for GaN/Ge. Accurate determination of the valence and conduction band offsets is important for the use of GaN/Ge based devices.

关键词： Measurement Photoelectron Spectroscopy

In situ synthesis of Co_(3)O_(4)nanoparticles confined in 3D nitrogendoped porous carbon as an efficient bifunctional oxygen electrocatalyst

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Rare Metals 2020年第12期39卷 1383-1394页

作者： Zhi-Yuan Wang Shun-Da Jiang Chan-Qin Duan Dan Wang Shao-Hua Luo yan-guo liu School of Materials Science and Engineering Northeastern UniversityShenyang 110819China Key Laboratory of Dielectric and Electrolyte Functional Material-Hebei Province Qinhuangdao 066004China

The rational exploitation of non-precious metal catalyst with high activity,strong durability and low cost for the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is of vital importance for metalair ***,a composite of Co_(3)O_(4)nanoparticles confined in three-dimensional(3 D)N-doped porous carbon(Co-NpCs)was prepared by a simple freeze-drying and in situ pyrolysis *** effect of different dosages of Co(NO_(3))_(2)on the catalytic performance was *** Co-NpC-12%exhibits the best catalytic performance(E_(1/2)=0.78 V,better stability than 20%Pt/C)in ORR and in OER among all the as-synthesized ***,it also exhibits the best bifunctional activity(ΔE=0.849 V).The excellent properties of Co-NpCs are mainly due to the synergy between Co_(3)O_(4)and ***,a high Co_(3)O_(4)loading amount can boost the defect level of the N-doped hierarchical porous carbon and expose more active ***,the unique in situ pyrolysis guarantees a largearea contact between Co_(3)O_(4)and carbon as well as a strong C-O-Co bonding,which promotes charge transfer,avoids the peeling of Co_(3)O_(4)nanoparticles and effectively improves the stability of the *** work is expected to offer a feasible strategy to produce metal oxide/carbon nanocomposite and push forward the development of bifunctional electrocatalyst with high activity and stability.

关键词： Bifunctional electrocatalyst Co_(3)O_(4) Nitrogendoped porous carbon In situ synthesis

A lithium–tin fluoride anode enabled by ionic/electronic conductive paths for garnet-based solid-state lithium metal batteries

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Rare Metals 2024年第2期43卷 575-587页

作者： Lei Zhang Qian-Kun Meng Xiang-Ping Feng Ming Shen Yu-Qing Zhang Quan-Chao Zhuang Run-guo Zheng Zhi-Yuan Wang yan-Hua Cui Hong-Yu Sun yan-guo liu School of Materials Science and Engineering Northeastern UniversityShenyang110819China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao066004China School of Materials and Physics China University of Mining&TechnologyXuzhou221116China Institute of Electronic Engineering China Academy of Engineering PhysicsMianyang621900China

The high energy density and stability of solid-state lithium metal batteries(SSLMBs)have garnered great ***-type oxides,especially Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO),with high ionic conductivity,wide electrochemical window,and stability to Li metal anode,are promising solid-state electrolyte(SSEs)materials for ***,Li/LLZTO interface issues including high interface resistance,inhomogeneous Li deposition,and Li dendrite growth have hindered the practical application of ***,a multi-functional Li–SnF_(2) composite anode with Li,LiF,and Li-Sn alloy was specifically designed and *** composite anode improves the wettability to LLZTO,constructing an intimate contact interface between it and ***,ionic/electronic conductive paths in situ formed at the interface can effectively uniform Li deposition and suppress Li *** solid-state symmetric cell exhibits low interface resistance(11Ω·cm^(2)) and high critical current density(1.3 mA·cm^(−2))at 25℃.The full SSLMB based on LiFePO_(4) or LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode also shows stable cycling performance and high rate *** work provides a new composite anode strategy for achieving high-energy density and high-safety SSLMBs.

关键词： Solid-state lithium metal batteries(SSLMBs) Lithium-tin fluoride anode Ionic/electronic conductive Interface resistance Lithium dendrite