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Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries

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NANO-MICRO LETTERS 2025年第1期17卷 1-17页

作者： Zhou, Chengwang Ding, Zhezheng Ying, Shengzhe Jiang, Hao Wang, yan fang, Timing Zhang, You Sun, Bing Tang, Xiao Liu, Xiaomin Qingdao Univ Sch Text & Clothing Sch Chem & Chem Engn Qingdao 266071 Shandong Peoples R China Univ Technol Sydney Fac Sci Ctr Clean Energy Technol Sch Math & Phys Sci Ultimo NSW 2007 Australia Henan Normal Univ Sch Chem & Chem Engn Xinxiang 453007 Henan Peoples R China

A double-layered protective film based on zinc-based coordination compound and ZnF2-rich solid electrolyte interphase layer has been successfully fabricated on the zinc metal anode via electrode/electrolyte synergistic *** double-layered architecture can effectively modulate Zn2+ flux and suppress the zinc dendrite growth, thus facilitating the uniform zinc *** as-developed zinc-(dual) halogen batteries based on double-layered protective film can present high areal capacity and satisfactory cycling stability. Aqueous zinc-halogen batteries are promising candidates for large-scale energy storage due to their abundant resources, intrinsic safety, and high theoretical capacity. Nevertheless, the uncontrollable zinc dendrite growth and spontaneous shuttle effect of active species have prohibited their practical implementation. Herein, a double-layered protective film based on zinc-ethylenediamine tetramethylene phosphonic acid (ZEA) artificial film and ZnF2-rich solid electrolyte interphase (SEI) layer has been successfully fabricated on the zinc metal anode via electrode/electrolyte synergistic optimization. The ZEA-based artificial film shows strong affinity for the ZnF2-rich SEI layer, therefore effectively suppressing the SEI breakage and facilitating the construction of double-layered protective film on the zinc metal anode. Such double-layered architecture not only modulates Zn2+ flux and suppresses the zinc dendrite growth, but also blocks the direct contact between the metal anode and electrolyte, thus mitigating the corrosion from the active species. When employing optimized metal anodes and electrolytes, the as-developed zinc-(dual) halogen batteries present high areal capacity and satisfactory cycling stability. This work provides a new avenue for developing aqueous zinc-(dual) halogen batteries.

关键词： Zn metal anodes Double-layered protective film Electrode/electrolyte optimization Aqueous zinc-(dual) halogen batteries

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指向高质量课堂的听评课量表设计及其关键问题

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教学与管理 2025年第1期 24-28页

作者：户艳茹方妍清华大学教育研究院北京100084 清华大学附属中学北京100084

在建设高质量课堂的时代背景下,重新设计课堂听评课框架与维度,有助于倒逼教师专业成长,反促课堂提质增效。在深刻反思现有听评课量表存在不足、尤其是缺乏科学量化标准的前提下,重新设计的旨在提升课堂质量的听评课量表主要包括2个观... 详细信息

在建设高质量课堂的时代背景下,重新设计课堂听评课框架与维度,有助于倒逼教师专业成长,反促课堂提质增效。在深刻反思现有听评课量表存在不足、尤其是缺乏科学量化标准的前提下,重新设计的旨在提升课堂质量的听评课量表主要包括2个观察维度、6个观察要素、13个观察指标和26个观察点。在教学实践中应用这一听评课量表,需要注意凸显学生的主体性、全面性与个性化,构建民主平等的课堂生命共同体,展现时代风格与学校特色,形成良性教研文化和沟通合作机制。

关键词：高质量课堂听评课量表教研制度

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Small modifications of endo-functionalized cavities lead to large changes in molecular interaction in water

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Science China Chemistry 2025年第1期 369-376页

作者： Song-Meng Wang Hao Nian yan-fang Wang Li-Shuo Zheng Yu-Tao Zheng Yi-Wei Dong Liping Huang Xiaoping Wang Wei Jiang Liu-Pan yang Department of Chemistry Southern University of Science and Technology School of Chemistry and Pharmaceutical Sciences State Key Laboratory for Chemistry and Molecular Engineering of Medicinal ResourcesGuangxi Normal University School of Pharmaceutical Science Hengyang Medical School University of South China

Studying molecular recognition in aqueous environments is crucial for understanding biological processes. Herein, we present a series of N-doped endo-functionalized anthracene-based cavities by introducing inward-directed pyridine units. The subtle modifications can significantly affect the binding properties of these receptors, which is similar to the mutations in biological systems. Combining theoretical calculations and molecular recognition experiments demonstrated that these “mutations” have an impact on the hydrophobicity and charge distribution of the hosts, consequently significantly influencing molecular *** is crucial for understanding the intricate mechanisms of molecular-level interactions in biological receptors.

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Indelible Rules of Josephson Coupling Energy and Zero-Point Energy in High-Tc Cuprates

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Communications in Theoretical Physics 2004年第4期41卷 629-631页

作者： LIUFu-sui CHENWan-fang DepartmentofPhysics PekingUniversityBeijing100871China CCAST（WorldLaboratory） P.O.Box8730Beijing100080China

This paper shows that the Josephson coupling energy and the zero-point energy have indelible rules on the superfluid density and the superconductivity in the high-Tc cuprates. This paper also shows that the values of Tc at underdoped and overdoped regions are determined by the damage conditions of the phase coherence in the classical and the quantum XY-models, respectively.

关键词： high-T-c cuprates superfluid density Josephson coupling zero-point energy

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Absorption of electromagnetic waves by the dust particles in a plasma

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Science China(Technological Sciences) 2004年第4期47卷 461-469页

作者： LI fang LI Lianlin sui Qiang Institute of Electronics Chinese Academy of Sciences Beijing 100080 China Institute of Electronics Chinese Academy of Sciences Beijing 100080 China Institute of Electronics Chinese Academy of Sciences Beijing 100080 China

Absorption of electromagnetic waves by the dust particles in a plasma has been studied based on a Mie-Debye scattering mode. The longitudinal field of the Debye scattering has been derived and the wave energy loss from it has been calculated. It is shown that the lower the temperature of the plasma is and the higher the density of the plasma is, the larger the absorption cross section will be due to the longitudinal scattering. For the low frequency waves the electromagnetic waves scattered in a dusty plasma are mainly in the form of Debye scattering. In this case the energy loss due to the longitudinal scattering will affect the wave propagation seriously.

关键词： dusty plasma, Mie-Debye scatter, absorption cross section, total section.

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Surface engineering with ionic polymers on membranes for boron removal

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Frontiers of Chemical Science and Engineering 2024年第5期18卷 61-69页

作者： Xiting Zhang Chenyi fang J Paul Chen sui Zhang Department of Chemical and Biomolecular Engineering National University of SingaporeSingapore 117576Singapore Department of Civil and Environmental Engineering National University of SingaporeSingapore 119260Singapore College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060China

Removal of boric acid from seawater and wastewater using reverse osmosis membrane technologies is imperative and yet remains inadequately addressed by current commercial *** research efforts performed post-modification of reverse osmosis membranes to enhance boron rejection,which is usually accompanied by substantial sacrifice in water *** study delves into the surface engineering of low-pressure reverse osmosis membranes,aiming to elevate boron removal efficiency while maintaining optimal salt rejection and water *** were modified by the self-polymerization and co-deposition of dopamine and polystyrene sulfonate at varying ratios and *** surfaces became smoother and more hydrophilic after *** optimum membrane exhibited a water permeability of 9.2±0.1 L·m^(-2)·h^(-1)·bar^(-1),NaCl rejection of 95.8%±0.3%,and boron rejection of 49.7%±0.1% and 99.6%±0.3% at neutral and alkaline pH,*** water permeability is reduced by less than 15%,while the boron rejection is 3.7 times higher compared to the blank *** research provides a promising avenue for enhancing boron removal in reverse osmosis membranes and addressing water quality concerns in the desalination process.

关键词： membrane low-pressure reverse osmosis boron surface engineering

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Experimental Features of Gap Anisotropy in High-To Cuprates and Explanation

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Communications in Theoretical Physics 2003年第6X期40卷 739-741页

作者： LIUFu-sui CHENWan-fang PENGKuang-Ding DepartmentofPhysics PekingUniversityBeijing100871China CCAST(WorldLaboratory) P.O.Box8730Beijing100080China DepartmentofPhysics YunnanUniversityKunming650091China

This papersummarizes the experimental features of the gap anisotropy in the high-Tc cuprates, and use the composite d-wave to explain these features.

关键词：能隙各向异性铜酸盐临界温度 d-波费米面固体结构理论

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A revisit of the local scour around bridge piers under an ice-covered flow condition-An experimental study

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Journal of Hydrodynamics 2021年第5期33卷 928-937页

作者： Jun Wang Kui Wang Bi-he fang Jueyi sui School of Civil and Hydraulic Engineering Hefei University of TechnologyHefei 230009China School of Engineering University of Northern British ColumbiaPrince GeorgeBCCanada

In this study,by changing both pier diameters and particle sizes of sand bed in flume experiments,the scour process around cylindrical bridge piers under an ice-covered flow condition has been *** is found that the appearance of an ice cover on the water surface caused a deeper and wider scour hole in comparison with that in an open flow with identical flow rates,implying a larger volume of scour hole under an ice-covered flow *** to the scouring process at a bridge pier under an open flow condition,both the depth and volume of a scour hole increase with the flow velocity and pier *** with results under an open flow condition,for identical flow rates,the maximum depth of a scour hole under an ice-covered flow condition increased by about 20%-30%,and both the scour area and volume of a scour hole increased by about 40%-50%.A flow at Froude number of 0.15 is the demarcation point for assessing an obvious impact of an ice cover on the local scour around a bridge pier in this experimental *** data collected from laboratory experiments,equations have been developed to calculate the maximum scour depth,scour area and scour *** of present study have been compared with those of others.

关键词： Bridge pier ice cover local scour scour area scour depth scour volume

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Efficient synthesis of lithium rare-earth tetrafluoride nanocrystals via a continuous flow method

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Nano Research 2020年第10期13卷 2837-2846页

作者： Jinsong sui Junyu yan Kai Wang Guangsheng Luo The State Key Lab of Chemical Engineering Department of Chemical EngineeringTsinghua UniersityBeijing 100084China

As an important upconversion illuminant material, LiREF4 nanocrystals were efficiently synthesized in a continuous reactor with the assistant of a new precursor solution. The employed trioctylamine solvent in the solution had a strong interaction with HF, and helped to avoid the generation of unnecessary solid components as LiF and NH4REF4 during the reaction. A silicon carbide reactor was developed to carry out the synthesis reaction, where LiYF4:Yb,Er/Ho/Tm quickly nucleated in 5 min at 300℃. The reaction time to successfully prepare 15 nm sized nanocrystals was less than 30 min, and the space-time yield of the flow synthesis method was 14.8 times that of a control group batch reaction. The prepared nanocrystals had a strong illuminant ability, which could find its use in the area of security mark printing.

关键词： lithium rare earth tetrafluoride upconversion illuminant nanocyrstal silicon carbide reactor flow chemistry

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Novel degradable polymer networks containing acetal components

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Science China Chemistry 2011年第3期54卷 419-425页

作者： sui XinCe SHI yan FU ZhiFeng State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Beijing 100029 China

A novel copolymer network with acetal structure was prepared using bis[4-(vinyloxy)butyl](4-methyl-1,3-phenylene)biscarbamate(BECT)as the crosslinking ***,a tri-copolymer of maleic anhydride(MAn),n-butyl vinyl ether(BVE)and 4-hydroxybutyl vinyl ether(HBVE)was synthesized via free-radical polymerization with 2,2′-azobisisobutyronitrile as the *** tri-copolymer consisted of two sorts of alternating units,MAn-alt-BVE and *** linear copolymer Poly((MAn-alt-BVE)-co-(MAn-alt-HBVE))with pending hydroxyl groups was then combined with BECT in the presence of pyridinium p-toluenesulfonate,generating a copolymer network comprising acetal components in the crosslinking segment. This polymer network exhibited degradation in acid conditions.

关键词： alternating copolymerization maleic anhydride network degradation

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