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A dual-site Fe-based catalyst for efficient ammonia synthesis under mild conditions

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Science China Chemistry 2025年

作者： Shiyong Zhang Mingyuan Zhang Tianhua Zhang Jizhen Sun Jiaxin Li Kailin Su Ruishao Mao yanliang zhou Xuanbei Peng yangyu Zhang Jun Ni Bingyu Lin Xiuyun wang Lilong Jiang National Engineering Research Center of Chemical Fertilizer Catalyst Fuzhou University Qingyuan Innovation Laboratory

Achieving green ammonia （NH3） synthesis requires developing effective catalysts under mild ***,the competitive adsorption of N2and H2,as well as the strong binding of N-containing intermediates on the catalyst,greatly inhibits the active sites for efficient ***,we constructed a series of ZrH2-modified Fe catalysts with dual active sites to address these issues and realized efficient NH3synthesis under mild *** study shows that ZrH2can not only provide active sites for H2activation but also transfer electrons to Fe sites for accelerating *** interaction between Fe and ZrH2over 40ZrH2-Fe leads to a decrease in work function and a downward shift of the d-band center,which is conducive to N2activation and NH3desorption,*** utilization of distinct sites for activating different reactants can avoid the competitive adsorption of N2and H2,leading to excellent NH3synthesis activity of the 40 wt.%ZrH2-mediated Fe *** a result,40ZrH2-Fe exhibits a high NH3synthesis rate of 23.3 mmol g-1cath-1at 400°C and 1 MPa and robust stability during100 h time-on-stream.

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Fabrication of Waterproof Artificial Compound Eyes with Variable Field of View Based on the Bioinspiration from Natural Hierarchical Micro–Nanostructures

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Nano-Micro Letters 2020年第12期12卷 13-28页

作者： Peilin zhou Haibo Yu ya Zhong Wuhao Zou Zhidong wang Lianqing Liu State Key Laboratory of Robotics Shenyang Institute of AutomationChinese Academy of SciencesShenyang 110016People’s Republic of China Institutes for Robotics and Intelligent Manufacturing Chinese Academy of SciencesShenyang 110169People’s Republic of China University of Chinese Academy of Sciences Beijing 100049People’s Republic of China Department of Advanced Robotics Chiba Institute of TechnologyChiba 275‑0016Japan

Planar and curved microlens arrays(MLAs)are the key components of miniaturized microoptical *** order to meet the requirements for advanced and multipurpose applications in microoptical field,a simple manufacturing method is urgently required for fabricating MLAs with unique properties,such as waterproofness and variable field-of-view(FOV)*** properties are beneficial for the production of advanced artificial compound eyes for the significant applications in complex microcavity environments with high humidity,for instance,miniature medical ***,the simple and effective fabrication of advanced artificial compound eyes still presents significant *** this paper,bioinspired by the natural superhydrophobic surface of lotus leaf,we propose a novel method for the fabrication of waterproof artificial compound *** jet printing was used to fabricate hierarchical MLAs and nanolens arrays(NLAs)on polydimethylsiloxane *** flexible film of MLAs hybridized with NLAs exhibited excellent superhydrophobic property with a water contact angle of 158°.The MLAs film was deformed using a microfluidics chip to create artificial compound eyes with variable FOV,which ranged from 0°to 160°.

关键词： Bioinspired Hierarchical MLAs and NLAs Waterproof artificial compound eyes E-jet printing Microfluidics chip

Einstein Probe discovery of EP240408a: A peculiar X-ray transient with an intermediate timescale

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Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 222-240页

作者： Wenda Zhang Weimin Yuan Zhixing Ling Yong Chen Nanda Rea Arne Rau Zhiming Cai Huaqing Cheng Francesco Coti Zelati Lixin Dai Jingwei Hu Shumei Jia Chichuan Jin Dongyue Li Paul O’Brien Rongfeng Shen Xinwen Shu Shengli Sun Xiaojin Sun Xiaofeng wang Lei yang Bing Zhang Chen Zhang Shuang-Nan Zhang Yonghe Zhang Jie An David Buckley Alexis Coleiro Bertrand Cordier Liming Dou Rob Eyles-Ferris zhou Fan Hua Feng Shaoyu Fu Johan P.U.Fynbo Lluis Galbany Saurabh W.Jha Shuaiqing Jiang Albert Kong Erik Kuulkers Weihua Lei Wenxiong Li Bifang Liu Mingjun Liu Xing Liu Yuan Liu Zhu Liu Chandreyee Maitra Alessio Marino Itumeleng Monageng Kirpal Nandra Jeremy Sanders Roberto Soria Lian Tao Junfeng wang Song wang Tinggui wang Zhongxiang wang Qingwen Wu Xuefeng Wu Dong Xu yanjun Xu Suijian Xue Yongquan Xue Zijian Zhang Zipei Zhu Hu Zou Congying Bao Fansheng Chen Houlei Chen Tianxiang Chen Wei Chen Yehai Chen Yifan Chen Chenzhou Cui Weiwei Cui yanfeng Dai Dongwei Fan Ju Guan Dawei Han Dongjie Hou Haibo Hu Maohai Huang Jia Huo Zhenqing Jia Bowen Jiang Ge Jin Chengkui Li Junfei Li Longhui Li Maoshun Li Wei Li Zhengda Li Tianying Lian Congzhan Liu Heyang Liu Huaqiu Liu Fangjun Lu Laidan Luo Jia Ma Xuan Mao Haiwu Pan Xin Pan Liming Song Hui Sun Yunyin Tan Qingjun Tang Yihan Tao Hao wang Juan wang Lei wang Wenxin wang Yilong wang Yusa wang Qinyu Wu Haitao Xu Jingjing Xu Xinpeng Xu Yunfei Xu Zhao Xu Changbin Xue Yulong Xue Ailiang yan Haonan yang Xiongtao yang yanji yang Juan Zhang Mo Zhang Wenjie Zhang Zhen Zhang Zhen Zhang Ziliang Zhang Donghua Zhao Haisheng Zhao Xiaofan Zhao Zijian Zhao Hongyan zhou Yilin zhou Yuxuan Zhu Zhencai Zhu National Astronomical Observatories Chinese Academy of Sciences School of Astronomy and Space Sciences University of Chinese Academy of Sciences Key Laboratory of Particle Astrophysics Institute of High Energy Physics Chinese Academy of Sciences Institute of Space Sciences (ICE) CSIC Institut d’Estudis Espacials de Catalunya (IEEC) Max Planck Institute for Extraterrestrial Physics Innovation Academy for Microsatellites Chinese Academy of Sciences Department of Physics University of Hong Kong School of Physics and Astronomy University of Leicester School of Physics and Astronomy Sun yat-sen University Department of Physics Anhui Normal University Shanghai Institute of Technical Physics Chinese Academy of Sciences Physics Department Tsinghua University Nevada Center for Astrophysics University of Nevada Las Vegas Department of Physics and Astronomy University of Nevada Las Vegas South African Astronomical Observatory Department of Astronomy University of Cape Town Department of Physics University of the Free State Université Paris Cité CNRS Astroparticule et Cosmologie Université Paris Cité CEA Paris-Saclay IRFU/DAp-AIM Department of Astronomy Guangzhou University Cosmic Dawn Center (DAWN) Niels Bohr Institute University of Copenhagen Department of Physics and Astronomy Rutgers the State University of New Jersey Institute for Cosmic Ray Research The University of Tokyo ESA/ESTEC Department of Astronomy School of Physics Huazhong University of Science and Technology INAF-Osservatorio Astrofisico di Torino Sydney Institute for Astronomy School of Physics The University of Sydney Department of Astronomy Xiamen University Institute for Frontiers in Astronomy and Astrophysics Beijing Normal University Department of Astronomy University of Science and Technology School of Astronomy and Space Sciences University of Science and Technology of China Institute of Deep Space Sciences Deep Space Exploration Laboratory Department of Astronomy School of Physics and Astronomy Yunnan University Shanghai Astronomical Observatory Chi

We report the discovery of a peculiar X-ray transient,EP240408a,by Einstein Probe （EP） and follow-up studies made with EP,Swift,NICER,GROND,ATCA and other ground-based multiwavelength *** new transient was first detected with Wide-field X-ray Telescope （WXT） on board EP on April 8th,2024,manifested in an intense yet brief X-ray flare lasting for *** flare reached a peak flux of 3.9×10-9erg cm-2s-1in 0.5-4 ke V,～300 times brighter than the underlying X-ray emission detected throughout the *** and more precise follow-up observations by EP/FXT,Swift and NICER confirmed the finding of this new *** X-ray spectrum is non-thermal in 0.5-10 ke V,with a power-law photon index varying *** X-ray light curve shows a plateau lasting for ～4 d,followed by a steep decay till becoming undetectable ～10 d after the initial *** on its temporal property and constraints from previous EP observations,an unusual timescale in the range of 7-23 d is found for EP240408a,which is intermediate between the commonly found fast and long-term *** counterparts have been found in optical and near-infrared,with the earliest observation at 17 h after the initial X-ray detection,suggestive of intrinsically weak emission in these *** demonstrate that the remarkable properties of EP240408a are inconsistent with any of the transient types known so far,by comparison with,in particular,jetted tidal disruption events,gamma-ray bursts,X-ray binaries and fast blue optical *** nature of EP240408a thus remains an *** suggest that EP240408a may represent a new type of transients with intermediate timescales of the order of～10 *** detection and follow-ups of more of such objects are essential for revealing their origin.

关键词： X-ray transients ${\bm~{Einstein~~Probe}}$

Probabilistic Response and Short-Term Extreme Load Estimation of Offshore Monopile Wind Turbine Towers by Probability Density Evolution Method

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China Ocean Engineering 2022年第3期36卷 363-371页

作者： ZHANG Hui XU ya-zhou School of Building Services Science and Engineering Xi’an University of Architecture and TechnologyXi’an 710055China School of Civil Engineering Xi’an University of Architecture and TechnologyXi’an 710055China

A new analysis framework based on probability density evolution method(PDEM)and its Chebyshev collocation solution are introduced to predict the dynamic response and short-term extreme load of offshore wind turbine(OWT)towers subjected to random sea *** regard to the stochastic responses,random function method is employed to generate samples of sea elevation,the probability density evolution equation(PDEE)is solved to calculate time-variant probability density functions of structural *** the probabilistic load estimation,a FAST model of NREL 5MW offshore turbine is established to obtain samples of bending moment at the tower *** equivalent extreme event theory is used to construct a virtual stochastic process(VSP)to assess the short-term extreme *** results indicate that the proposed approach can predict time-variant probability density functions of the structural responses,and shows good agreement with Monte Carlo ***,the predicted short-term extreme load can capture the fluctuation at the tail of the extreme value distribution,thus is more rational than results from the typical distribution ***,the proposed method shows good adaptation,precision and efficiency for the dynamic response analysis and load estimation of OWT towers.

关键词： offshore wind turbine probability density evolution method Chebyshev collocation matrix exponential Monte Carlo

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枸杞多糖对小鼠免疫功能的调节作用

宁夏医学院学报 1994年第4期16卷 304-306页

作者：黎雪如周娅王琦薛筱芳

本文研究枸杞多糖对正常小鼠及用氢化可的松造成的免疫功能受抑小鼠的免疫调节作用。将ＢＡＬＢ／ｃ小鼠分成４组，即空白对照组、枸杞多糖组、氢化可的松组和枸杞多糖调节组。结果显示枸杞多糖能增加小鼠胸腺的重量和白细胞数量，能提... 详细信息

本文研究枸杞多糖对正常小鼠及用氢化可的松造成的免疫功能受抑小鼠的免疫调节作用。将ＢＡＬＢ／ｃ小鼠分成４组，即空白对照组、枸杞多糖组、氢化可的松组和枸杞多糖调节组。结果显示枸杞多糖能增加小鼠胸腺的重量和白细胞数量，能提高特异性抗体的效价和细胞免疫功能。对氢化可的松抑制的免疫功能有调节升高作用。

关键词：枸杞多糖细胞免疫功能 BALB/c小鼠氢化可的松免疫调节作用特异性抗体升高重量抑制显示

Hexagonal MBenes-Supported Single Atom as Electrocatalysts for the Nitrogen Reduction Reaction

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Energy Material Advances 2023年第1期4卷 331-343页

作者： ya Gao Erpeng wang yazhuo Zheng Jian zhou Zhimei Sun School of Materials Science and Engineering Beihang UniversityBeijing 100191China

The electrocatalytic nitrogen reduction reaction(NRR)is currently constrained by sluggish reaction kinetics and poor selectivity because of the difficulties in activating inert N≡N triple bonds and the existence of competing hydrogen evolution reaction(HER).Therefore,electrocatalysts with high activity,selectivity,and stability are highly ***,by means of first-principles calculations,we investigated the electrocatalytic NRR performance of a series of transition metal atoms(e.g.,3d,4d,and 5d)embedded in defective hexagonal MBene nanosheets[h-Zr(Hf)_(2)B_(2)O_(2)]and identified that h-Zr(Hf)_(2)B_(2)O_(2) could be an excellent platform for electrocatalytic *** the basis of our proposed screening criteria,16 candidates are efficiently selected out from 50 systems,among which,Zr_(2)B_(2)O_(2)-Cr stands out with high selectivity to NRR against HER and the ultralow limiting potential(−0.10 V).The value is much lower than that of the well-established stepped Ru(0001)surface(−0.43 V).The origin of the high activity toward NRR is attributed to the synergistic effect of the single atom(SA)and the M atoms in the *** impressively,a composition descriptor is further proposed on the basis of the inherent characteristics of the catalysts[number of valence electrons of SA and electronegativity of the SA and Zr(Hf)atoms],which helps to better predict the catalytic *** work not only contributes to the development of highly efficient NRR electrocatalysts but also extend the application of h-MBenes in electrocatalysis.

关键词： selectivity bonds kinetics

Bioinspired polydopamine coated nanopore nanofluidic unijunction transistor exhibiting negative differential resistance and ion current oscillation

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Nano Research 2024年第11期17卷 10026-10033页

作者： Yong wang Wenting Guo Bo wang ya zhou Ping Hu Jiangtao Ren Erkang wang Yongdong Jin State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun 130022 China School of Applied Chemistry and Engineering University of Science and Technology of China Hefei 230026 China Guangdong Key Laboratory of Biomedical Measurements and Ultrasound Imaging School of Biomedical Engineering Shenzhen University Medical School Shenzhen University Shenzhen 518060 China Quality and Safety Engineering Institute of Food and Drug Zhejiang Gongshang University Hangzhou 310018 China

Nanofluidic devices have turned out to be exemplary systems for investigating fluidic transport properties in a highly restricted area, where the electrostatic interactions or chemical reactions between nanochannel and flowing species strongly dominate the ions and flow transport. Numerous nanofluidic devices have recently been explored to manipulate ion currents and construct electronic devices. Enlightened by electronic field effect transistors, utilizing the electric field effect of nanopore nanochannels has also been adopted to develop versatile nanofluidic devices. Here, we report a nanopore-based nanofluidic unijunction transistor composed of a conical glass nanopipette with the biomaterial polydopamine (PDA) coated at its outer surface. The asfabricated nanofluidic device exhibited negative differential resistance (NDR) and ion current oscillation (ICO) in ionic transport. The pre-doped copper ions in the PDA moved toward the tip as increasing the potential, having a robust shielding effect on the charge of the tip, thus affecting the surface charge density of the nanopore in the working zone. Finite element simulation based on a continuum model coupled with Stokes-Brinkman and Poisson-Nernst-Planck (PNP) equations revealed that the fluctuations in charge density remarkably affect the transport of ionic current in the nanofluidic device. The as-prepared nanofluidic semiconductor device was a ready-to-use equipment that required no additional external conditions. Our work provides a versatile and convenient way to construct nanofluidic electronic components;we believe by taking advantage of advanced surface modification methods, the oscillation frequency of the unijunction transistors could be controlled on demand, and more nanofluidic devices with resourceful functions would be exploited.

关键词： polydopamine nanopore unijunction transistor negative differential resistance ion current oscillation

An alternative aqueous synthetic route to preparing CdTe quantum dots with tunable photoluminescence

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Chinese Chemical Letters 2012年第3期23卷 359-362页

作者： Yi Lin wang Sheng yan Liu Li ya zhou School of Chemistry and Chemical Engineering Guangxi UniversityNanning 530004China

An aqueous synthetic route has been developed for the preparation of mercaptosuccinic acid（MSA）-capped CdTe quantum dots （QDs） using TeO_2 as tellurium source and sodium borohydride as *** size and the emission color of CdTe QDs can be tuned by varying the reflux *** obtained QDs were characterized by photoluminescence（PL） spectroscopy,X-ray powder diffraction（XRD） and high-resolution transmission electron microscopy（HRTEM）.The results show that the CdTe QDs were of zinc-blende crystal structure in a sphere-like shape.

关键词： Cadmium telluride Quantum dots Synthesis Photoluminescence

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研究生教育促进新质生产力的机制研究

黑龙江高教研究 2025年第1期43卷 91-97页

作者：周均旭王涛广西大学广西南宁530004

基于2011一2020年我国30个省份的面板数据,运用双向固定效应模型、中介效应模型和门槛效应模型探究了研究生教育对新质生产力的影响效应。结果表明:在全国层面,研究生教育能够有效促进新质生产力发展,经过一系列稳健性检验结论依然成立... 详细信息

基于2011一2020年我国30个省份的面板数据,运用双向固定效应模型、中介效应模型和门槛效应模型探究了研究生教育对新质生产力的影响效应。结果表明:在全国层面,研究生教育能够有效促进新质生产力发展,经过一系列稳健性检验结论依然成立;科技创新在研究生教育促进新质生产力发展的影响过程中发挥部分中介作用;研究生教育在促进新质生产力发展过程中存在产学研合作的门槛效应;区域异质性分析表明,研究生教育显著促进东部地区新质生产力发展,中西部地区次之,东北地区则不显著。对此,应聚焦研究生教育高质量发展,重视科技创新机制转化作用,充分发挥产学研合作调节效应,优化研究生教育布局结构,促进区域新质生产力形成与协调发展。

关键词：新质生产力研究生教育科技创新产学研合作