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Peracetic acid catalytic activation using Co3O4 nanocluster decorated graphitic carbon nitride for cefapirin degradation in water

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Science China Technological Sciences 2024年第10期67卷 3103-3115页

作者： yin shimei GAO YiXuan CHEN Long LI Fan LIU XiaoNa QI Fei LIU Wen Beijing Key Lab for Source Control Technology of Water Pollution College of Environmental Science and EngineeringBeijing Forestry University Key Laboratory of Water and Sediment Sciences (Ministry of Education) College of Environmental Sciences and EngineeringPeking University School of Environmental Science and Engineering Taiyuan University of Technology State Environmental Protection Key Laboratory of All Material Fluxes in River Ecosystems Peking University Beijing National Laboratory for Molecular Sciences Peking University

This study innovated cobalt-based catalytic nanocomposites（CCNs） for the heterogeneous activation of peracetic acid（PAA）,a green and efficient advanced oxidation process for removing antibiotics from *** Co3O4catalysts exhibit limited activity due to stable electronic *** overcome this,CCNs were synthesized using a one-step condensation method,incorporating a size control strategy that anchors Co3O4nanoclusters within 4-5 nm onto six-fold cavity of g-C3N4,simultaneously modifying the coordination environment of *** alteration significantly enhances the adsorption energy of PAA and catalytic activity compared to commercial *** improved performance of CCN2,in particular,is attributed to a shift in the cobalt d band center towards the Fermi level,facilitating electron delocalization and transfer,enhancing Co-O bonding,and accelerating PAA ***2's superior activity,with a cefapirin（CFP） degradation kinetic rate constant(k1=0.760 min-1)～11 times that of PAA direct oxidation(k1=0.070 min-1) and～5 times that of commercial Co3O4/PAA system(k1=0.164 min-1),is due to its ability to generate dominant reactive species for antibiotic degradation,including alkoxy radicals(CH3C（=O）OO·),high valence metal(CoⅣ（=O）2+),and singlet oxygen（1O2）,with the latter two being crucial for the degradation *** degradation of CFP involved three mechanisms,including direct oxidation by PAA,decarboxylation,and open-ring reactions at nitrogen *** research provides insights into developing high-activity catalysts for efficient PAA activation and antibiotic removal,leveraging the strategy of shifting the transition metal d band center.

关键词： peracetic acid Co3O4 nanocluster high valence metal singlet oxygen cefapirin

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Peracetic acid catalytic activation using CoOnanocluster decorated graphitic carbon nitride for cefapirin degradation in water

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Science China Technological Sciences 2024年

This study innovated cobalt-based catalytic nanocomposites （CCNs） for the heterogeneous activation of peracetic acid （PAA）,a green and efficient advanced oxidation process for removing antibiotics from *** Co3O4catalysts exhibit limited activity due to stable electronic *** overcome this,CCNs were synthesized using a one-step condensation method,incorporating a size control strategy that anchors Co3O4nanoclusters within 4?5 nm onto six-fold cavity of g-C3N4,simultaneously modifying the coordination environment of *** alteration significantly enhances the adsorption energy of PAA and catalytic activity compared to commercial *** improved performance of CCN2,in particular,is attributed to a shift in the cobalt d band center towards the Fermi level,facilitating electron delocalization and transfer,enhancing Co?O bonding,and accelerating PAA ***2’s superior activity,with a cefapirin （CFP） degradation kinetic rate constant (k1=0.760 min-1)～11 times that of PAA direct oxidation (k1=0.070 min-1) and～5 times that of commercial Co3O4/PAA system (k1=0.164 min-1),is due to its ability to generate dominant reactive species for antibiotic degradation,including alkoxy radicals(CH3C（=O）OO·),high valence metal (CoIV（=O）2+),and singlet oxygen （1O2）,with the latter two being crucial for the degradation *** degradation of CFP involved three mechanisms,including direct oxidation by PAA,decarboxylation,and open-ring reactions at nitrogen *** research provides insights into developing high-activity catalysts for efficient PAA activation and antibiotic removal,leveraging the strategy of shifting the transition metal d band center.

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“双高”建设背景下皮具专业课程教学改革探讨——以《手工皮具产品设计与制作工艺》课程为例

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皮革科学与工程 2022年第1期32卷 103-106,108页

作者：赵丹尹仕美上海工艺美术职业学院上海201808

“双高”建设背景下,针对高职艺术类院校学生在皮具手工制作课程学习中出现的厌学情绪、教学效率低等问题提出“DMOC”教学模式,以上海工艺美术职业学院的《手工皮具设计与工艺》课程进行教学实验,通过对学情分析,以提升学生自主学习能... 详细信息

“双高”建设背景下,针对高职艺术类院校学生在皮具手工制作课程学习中出现的厌学情绪、教学效率低等问题提出“DMOC”教学模式,以上海工艺美术职业学院的《手工皮具设计与工艺》课程进行教学实验,通过对学情分析,以提升学生自主学习能力和课程教学效果为目标,结合在线教学资源,从课前、课中、课后的教学组织及效果测试,论证“DMOC”教学模式的应用效果。为有效提高“手工皮具设计与工艺”课程教学质量,提供切实可行的理论借鉴与实践指导,进一步达到学校对于人才培养目标的要求,培养高质量的应用型技能人才。

关键词：高职院校手工皮具教学改革 “DMOC”教学模式

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生物炭和枯草芽孢杆菌对Cd污染土壤中萱草生长和土壤修复的影响

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分子植物育种 2023年第21期21卷 7201-7207页

作者：尹仕美胡春光上海工艺美术职业学院上海201808 云南林业职业技术学院昆明650000

本研究旨在探讨生物炭和枯草芽孢杆菌对Cd污染土壤中大花萱草生长和土壤修复的影响。研究设置了四个处理组:(1)对照组(CK),不添加任何改良剂;(2)生物炭组(B),土壤添加3%生物炭;(3)枯草芽孢杆菌组(BS),土壤添加4×10~9CFU/kg土壤的枯草... 详细信息

本研究旨在探讨生物炭和枯草芽孢杆菌对Cd污染土壤中大花萱草生长和土壤修复的影响。研究设置了四个处理组:(1)对照组(CK),不添加任何改良剂;(2)生物炭组(B),土壤添加3%生物炭;(3)枯草芽孢杆菌组(BS),土壤添加4×10~9CFU/kg土壤的枯草芽孢杆菌悬液;(4)生物炭+枯草芽孢杆菌组(B+BS),土壤同时添加3%生物炭和4×10~9CFU/kg土壤的枯草芽孢杆菌悬液。分别测定了各组大花萱草的农艺性状、净光合速率、蒸腾速率、生理指标、土壤p H、大花萱草中Cd含量以及土壤中有效态Cd含量。研究结果显示,相较于B组和BS组,B+BS组的大花萱草株高、叶面积、地上生物量和地下生物量显著增加(P<0.05)。与B组和BS组比较,B+BS组的净光合速率和蒸腾速率显著增加(P<0.05)。相较于B组和BS组,B+BS组的大花萱草含水量和叶绿素含量显著增加,而细胞膜透性、游离脯氨酸含量和可溶性糖含量显著降低(P<0.05)。与B组和BS组比较,B+BS组的土壤p H值显著增加(P<0.05)。与B组和BS组比较,B+BS组的大花萱草Cd含量和土壤中有效态Cd含量均显著降低(P<0.05)。综上所述,本研究表明,生物炭和枯草芽孢杆菌均能有效促进Cd污染土壤中大花萱草的生长,促进土壤修复,并且两者联用的效果最佳。

关键词：生物炭枯草芽孢杆菌 Cd污染土壤大花萱草(Hemerocallis fulva)

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Hydrogen and nitrogen absorption properties of Ce-added Zr_(2)(Fe_(1-x)Ni_(x)) alloys

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Journal of Rare Earths 2024年第6期42卷 1136-1141,I0005页

作者： Kai yin Xiaopeng Liu State Key Laboratory of Advanced Materials for Smart Sensing GRINM Group Co.Ltd.Beijing10088China GRIMAT Engineering Institute Co. Ltd.Beijing101407China General Research Institute of Nonferrous Metals Beijing100088China

To improve the nitriding resistance of Zr_(2)Fe alloy,the Ce-added Zr_(2)(Fe_(1-x)Ni_(x))(x=0,0.15,0.3,0.5)alloys were prepared by magnetic levitation melting *** effects of Ni substitution for Fe on the phase structure,hydrogen and nitrogen absorption properties of the alloys were investigated by X-ray diffraction,scanning electron microscopy and p-c isotherm *** experimental results show that Ni substitution can effectively inhibit the formation of both α-Zr and ZrFe_(2) phases and promote the formation of C16 structure Zr_(2)(Fe,Ni)phase,causing Ni-substituted alloys to exhibit low nitrogen absorption rate and *** 623 K under 0.5 MPa nitrogen pressure,the nitrogen absorption capacity of Ce-added Zr_(2)(Fe_(0.5)Ni_(0.5))alloy reaches to 0.8 mL/g,much lower than that of Zr_(2)Fe alloy(1.5 mL/g).Ni substitution decreases the crystal cell volume of the C_(16)Zr_(2)(Fe,Ni)phase,resulting in an increase in the hydrogen absorption equilibrium *** 623 K under 0.05 MPa hydrogen pressure,the hydrogen absorption capacity decreases from 1.46 wt%of Zr_(2)Fe alloy to 1.41 wt%of Ce-added Zr_(2)(Fe_(0.5)Ni_(0.5))alloy.

关键词： Zr_(2)Fe alloy Ce Pressure-composition isotherm Hydrogen absorption Nitrogen absorption Rare earths

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Rational surface charge engineering of haloalkane dehalogenase for boosting the enzymatic performance in organic solvent solutions

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Chinese Journal of Chemical Engineering 2024年第1期65卷 276-285页

作者： yin Wu Yan Sun Department of Biochemical Engineering School of Chemical Engineering and Technology and Key Laboratory of Systems Bioengineering and Frontiers Science Center for Synthetic Biology(Ministry of Education)Tianjin UniversityTianjin 300350China

Biocatalysis in organic solvents(OSs)has numerous important applications,but native enzymes in OSs often exhibit limited catalytic ***,we proposed a computation-aided surface charge engineering strategy to improve the catalytic performance of haloalkane dehalogenase DhaA in OSs based on the energetic analysis of substrate binding to the DhaA *** variants with enhanced OS resistance were obtained by replacing negative charged residues on the surface with positive charged residue(Arg).Particularly,a four-substitution variant E16R/E93R/E121R/E257R exhibited the best catalytic performance(five-fold improvement in OS resistance and seven-fold half-life increase in 40%(vol)dimethylsulfoxide).As a result,the overall catalytic performance of the variant could be at least 26 times higher than the wild-type *** spectroscopy and molecular dynamics simulation studies revealed that the residue substitution mainly enhanced OS resistance from four aspects:(a)improved the overall structural stability,(b)increased the hydrophobicity of the local microenvironment around the catalytic triad,(c)enriched the hydrophobic substrate around the enzyme molecule,and(d)lowered the contact frequency between OS molecules and the catalytic *** findings validate that computationaided surface charge engineering is an effective and ingenious rational strategy for tailoring enzyme performance in OSs.

关键词： Surface charge engineering Organic solvent resistance Molecular dynamics simulation Haloalkane dehalogenase

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A generalized presentation of multi-caloric effects based on exterior derivative theory and its applications

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Communications in Theoretical Physics 2024年第8期76卷 156-163页

作者： Jun yin School of Materials Science and Engineering Nankai UniversityTianjin 300350China School of Mechanical Engineering and Automation Fuzhou UniversityFuzhou 350108China

The emerging concept of multi-caloric effects, introduced in 2010, entails the application of multiple interplay fields to a thermodynamic system. While multi-caloric effects are the main focus of experimental endeavors, theoretical considerations fall short of providing a thorough understanding. This paper introduces a comprehensive presentation on multi-caloric effects,employing the method and theory of exterior derivative formations. It addresses every aspect of thermodynamic systems, showcasing its applicability to multi-caloric materials(both singlephase and multi-phase materials), and its adaptability to different scenarios(either in single or multiple force fields). The formulation of Maxwell relationships, characterized by their generality and universality, enables a clear prediction in entropy and temperature, facilitating a distinct identification between independent and interdependent contributions from multi-caloric effects. These insights hold significant importance in designing and developing specialized thermodynamic materials, optimizing functional performances and exploring innovative mechanisms.

关键词： multicaloric effects Maxwell relations isothermal entropy adiabatic temperature

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Variational Analysis Based on Proximal Subdifferential on Smooth Banach Spaces

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Acta Mathematica Sinica,English Series 2024年第2期40卷 595-618页

作者： Xi yin ZHENG Department of Mathematics Yunnan UniversityKunming 650091P.R.China

This paper first shows that for any p∈(1,2)there exists a continuously differentiable function f on l^(p)(and L^(p))such that the proximal subdifferential of f is empty everywhere,and hence it is not suitable to develop theory on proximal subdifferential in the classical Banach spaces l^(P)and L^(P) with p∈(1,2).On the other hand,this paper establishes variational analysis based on the proximal subdifferential in the framework of smooth Banach spaces of power type 2,which conclude all Hilbert spaces and all the classical spaces l^(P)and L^(P)with p∈(2,+∞).In particular,in such a smooth space,we provide the proximal subdifferential rules for sum functions,product functions,composite functions and supremum functions,which extend the basic results on the proximal subdifferential established in the framework of Hilbert *** of our main results are new even in the Hilbert space *** applications,we provide KKT-like conditions for nonsmooth optimization problems in terms of proximal subdifferential.

关键词： Smooth Banach space proximal subdifferential proximal normal cone KKT condition

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乡村振兴规划共生策略构建及广西实践

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规划师 2018年第8期34卷 68-73页

作者：尹仕美廖丽萍李奎同济大学建筑与城市规划学院华蓝设计(集团)有限公司规划研究所

乡村振兴战略是对我国乡建实践的全面升级与超越。文章立足于共生理论与乡村振兴的互适性分析,提出了乡村振兴规划共生策略,即从乡村振兴核心体解构与再构的视角明确共生单元,建立以农业为核心的三次产业融合共生产业链与价值链、以农... 详细信息

乡村振兴战略是对我国乡建实践的全面升级与超越。文章立足于共生理论与乡村振兴的互适性分析,提出了乡村振兴规划共生策略,即从乡村振兴核心体解构与再构的视角明确共生单元,建立以农业为核心的三次产业融合共生产业链与价值链、以农民为核心的三域主体整合共生利益链和竞合链、以农村为核心的三大空间耦合共生载体链和功能链,从而打造以"三农"为核心的利益相关者群落;从乡村振兴支撑体供给与需求的视角构建共生界面,重点推动功能性设施植入和自治性规制缔结;从乡村振兴基质体导引和管控的视角优化共生环境,实现自然生态和人文社会的时空协同进化。同时,文章将乡村振兴规划共生策略应用于广西绿留村振兴规划中,以期为相关工作提供参考。

关键词：共生理论乡村振兴规划策略广西绿留村

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Origin of the Dashuigou independent tellurium deposit at Qinghai–Xizang Plateau: constraints from the light stable isotopes C, O, and H

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Acta Geochimica 2024年第2期43卷 385-398页

作者： Jianzhao yin Yuhong Chao Haoyu yin Hongyun Shi Shoupu Xiang Wuhan Institute of Technology Wuhan 430074China College of Earth Sciences Jilin UniversityChangchun 130061China Ganzhongnan Institute of Geology and Mineral Exploration Nanchang 330002China Guinea Westfi eld Mining Company-Sarlu Jinzhong 031300China Orient Resources Ltd. RichmondB.C.V7E 1M8Canada Silvercorp Metals Inc. Beijing 100027China

By studying the light isotopic compositions of carbon,oxygen,and hydrogen,combined with previous research results on the ore-forming source of the deposit,the authors try to uncover its metallogenic *** δ^(18)O and δ^(13)C isotope signatures of dolomite samples vary between 10.2 and 13.0‰,and between−7.2 and−5.2‰,respectively,implying that the carbon derives from the upper mantle.δD and δ^(18) O of quartz,biotite,and muscovite from diff erent ore veins of the deposit vary between−82 and−59‰,and between 11.6 and 12.4‰,respectively,implying that the metallogenic solutions are mainly *** to the relevant research results of many isotope geologists,the fractionation degree of hydrogen isotopes increases as the depth to the Earth’s core increases,and the more diff erentiated the hydrogen isotopes are,the lower their values will *** other words,mantle-derived solutions can have extremely low hydrogen isotope *** means that the δD‰ value−134 of the pyrrhotite sample numbered SD-34 in this article may indicate mantle-derived oreforming fl uid of the *** formation of the Dashuigou tellurium deposit occurred between 91.71 and 80.19 Ma.

关键词： Carbon oxygen and hydrogen isotopes Origin Independent tellurium deposit The Qinghai–Xizang Plateau

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