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Emplacement Ages and Petrogenesis of the Molybdenum-bearing Granites in the Jinduicheng Area of East Qinling, China: Constraints from Zircon U-Pb Ages and Hf Isotopes

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Acta Geologica Sinica(English Edition) 2012年第3期86卷 661-679页

作者： LI Hongying WANG Xiaoxia ye huishou YANG Key Laboratory of Metallogeny and Mineral Resource Assessment Ministry of Land and ResourcesInstitute of Mineral ResourcesCAGSBeijing 100037China Research Institute China National offshore Oil Corp.(CNOOC)Beijing 100027

The Mesozoic porphyry assemblage in the Jinduicheng area is a special molybdenum area in China, the Mo deposits, including the Jinduicheng, Balipo, Shijiawan, Huanglongpu, are distributed. The emplacement age and geochemical features of the granites in the Jinduicheng area can provide essential information for the exploration and development of the porphyry molybdenum deposit. In this study, we report LA-ICP-MS zircon U-Pb age and zircon Hf isotopic compositions of granite porphyries from the Jinduicheng area, and provide insights on the petrogensis and source characteristics of the granites. The results show that the zircon U-Pb ages of the Jinduicheng granite porphyry （143±1 Ma） and the Balipo granite （154±1 Ma）, agree well with the Re-Os ages of molybdenite in the Jinduicheng molybdenum polymetallic deposit （139±3 Ma） and the Balipo molybdenum polymetallic deposit （156±2 Ma）, indicating that the emplacement of granite porphyries occurred between Late Jurassic and Early Cretaceous. Zircons granite from the Jinduicheng area give the εHf（t） values mainly ranging from -10 to -16, and -20 to -24, respectively, corresponding to two- stage model ages （tDM2： mainly focused on 1.86-2.0 Ga, and 2.2-2.6 Ga, respectively） of zircons of the granite from the Jinduicheng values. The ore-forming materials are mainly derived from crust, with minor mantle substances. Zircons of the granite from the Balipo area give εHf（t） values ranging from -18 to -20, -28 to -38, and -42 to -44, respectively, corresponding to two-stage model ages （tDM2： mainly focused on 1.88-3.0 Ga, and 3.2-3.90 Ga, respectively）. the εHf（t） values of the Jinduicheng porphyry more than that of the Balipo porphyry, and two-stage model ages （tDM2） less than that of the Balipo porphyry, shows that he source of the porphyries originated from ancient lower crustal materials in the Jinduicheng area, and mixed younger components, more younger components contributed for the source of the Jinduicheng porphyry.

关键词： granites petrogensis LA–ICP–MS U–Pb dating Zircon Hf isotope Jinduicheng

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Genesis of the Huoshenmiao Mo deposit in the Luanchuan ore district, China: Constraints from geochronology, ?uid inclusion, and H-O-Sisotopes

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Geoscience Frontiers 2019年第1期10卷 331-349页

作者： Sai Wang Bing Li Xingkang Zhang Peng Wang Weiwei Chao huishou ye Yongqiang Yang Key Laboratory of Marine Sedimentology and Environmental Geology First Institute of Oceanography State Oceanic Administration Laboratory for Marine Mineral Resources Qingdao National Laboratory for Marine Science and Technology Hebei Institute of Geological Survey School of Earth Sciences and Resources China University of Geosciences MLR Key Laboratory of Metallogeny and Mineral Assessment Institute of Mineral Resources CAGS

The Huoshenmiao δeposit is Mo skarn δeposit, located in the western part of the Luanchuan ore δ*** process can be δivided into a skarn and a quartz-sulfide episodes with six stages: prograde(I), retrograde(II), quartz-K-feldspar(III), quartz-molybdenite(IV), quartz-pyrite(V), and quartzcalcite(VI). A combined study of geochronology, fluid inclusion(FI), and stable isotopes was conducted to constrain the mineralization age, source of ore materials, as well as the origin and evolution of the ore-forming fluids. Molybdenite Ree Os δating indicates that the δeposit was formed in the Late Jurassic(~145 Ma). The δ^(34)S values of sulfides range from 3.0‰ to 7.1‰, implying that the ore materials in the δeposit are magmatic in origin. Three types and six subtypes of FIs are δistinguished, namely, aqueous two-phase(W_1-and W_2-type), δaughter mineral-bearing multiphase(S_1-and S_2-type), and CO_2-bearing three-phase(C_1-and C_2-type). In stages I and II, the W_1-type FIs δisplay homogenization temperatures(Th) from 496°C to >600°C, with salinities of 14.9-18.3 wt.% NaCl eqv. The FIs in stages III, IV and early stage V composed of coeval S-, C-and W-types, respectively homogenize at similar Th, suggesting the occurrence of boiling. The W1-type FIs in late stage V and stage VI, yield Th of 102-406°C and salinities of 0-4.7 wt.% NaCl eqv. The δD_(H_2O)and δ^(18) O(H_2O)values of the ore-forming fluids in quartz-sulfide episode vary from-112‰ to-76‰, and 11.0‰ to 1.0‰, respectively. All these above observations reveal that the early ore-forming fluids are magmatic in origin, and characterized by high temperature and moderate to high salinity, and gradually evolve to low temperature, low salinity meteoric water. The Huoshenmiao Mo δeposit is associated with the magmatism event induced by the protracted subduction of the Izanagi plate beneath the eastern China continent. The δecrease in temperature, salinity and f(O_2), as well as change of p H δue to boiling an

关键词： Molybdenite Ree Os age Fluid inclusion H-O-S isotopes Huoshenmiao Mo deposit Luanchuan ore district

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SHRIMP zircon U-Pb dating for volcanic rocks of the Dasi Formation in southeast Hubei Province,middle-lower reaches of the Yangtze River and its implications

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Chinese Science Bulletin 2006年第24期51卷 3000-3009页

作者： XIE Guiqing MAO Jingwen LI Ruiling ZHOU Shaodong ye huishou YAN Quanren ZHANG Zusong State Key Laboratory of Geological Processes and Mineral Resources China University of Geosciences Beijing 100083 China Institute of Mineral Resources Chinese-Academy of Geological Sciences Beijing 100037 China Institute of Geochemistry Chinese Academy of Sciences Guiyang 550002 China No. 4 Geological Party of Hubei Province Xianning 437100 China Institute of Geology Chinese Academy of Geosciences Beijing 100037 China Southeast Hubei Geological Party of Hubei Province Daye 435100China

The Jinniu Basin in southeast Hubei,located at the westernmost part of middle-lower val-ley of the Yangtze River,is one of the important vol-canic basins in East China. Volcanic rocks in the Jin-niu Basin are distributed mainly in the Majiashan Formation,the Lingxiang Formation and the Dasi Formation,consisting of rhyolite,basalt and basaltic andesite,(trachy)-basalt and basaltic trachy-andesite and (trachy)-andesite and (trachy)-dacite and rhyolite respectively,in which the Dasi volcanism is volumet-rically dominant and widespread. The Dasi volcanic rocks were selected for SHRIMP zircon U-Pb dating to confirm the timing of volcanism. The results indi-cate that there exist a large amount of magmatic zir-cons characterized by high U and Th contents in the volcanic rocks. The concordia ages for 13 points are 128 ± 1Ma (MSWD = 3.0). On account of the shape of zircons and Th/U ratios,this age is considered to represent the crystallization time of the Dasi volcan-ism. The volcanic rocks in the Dasi,Majiashan and Lingxiang Formations share similar trace elementand REE partition patterns as well as Sr-Nd isotopic compositions. In combination with the regional geol-ogy,it is proposed that the southeast Hubei volcanic rocks were formed mainly during the Early Creta-ceous,just like other volcanic basins in middle-lower Yangtze valley. A lithospheric extension is also sug-gested for tectonic regime in this region in the Cre-taceous Period.

关键词：火山岩 SHRIMP锆石U-Pb测年湖北东南部地质构造年代学长江中下游地区

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SHRIMP Zircon U-Pb and Molybdenite Re-Os Datings of the Superlarge Donggou Porphyry Molybdenum Deposit in the East Qinling,China,and Its Geological Implications

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Acta Geologica Sinica(English Edition) 2008年第1期82卷 134-145页

作者： ye huishou MAO Jingwen LI Yongfeng GUO Baojian ZHANG Changqing LIU Jun YAN Quanren LIU Guoyin Institute of Mineral Resources Chinese Academy of Geological Sciences 26 Baiwanzhuang Road Beijing 100037 China University of Geosciences Beijing 100083 Beijing SHRIMP Center Institute of Geology Chinese Academy of Geological Sciences Beijing 100037

Located in the eastern part of the East Qinling molybdenum belt, the Donggou deposit is a superlarge porphyry molybdenum deposit discovered in recent years. The authors performed highly precise dating of the mineralized porphyry and ores in the Donggou molybdenum deposit. A SHRIMP U-Pb zircon dating of the Donggou aluminous A-type granite-porphyry gave a rock-forming age of 112±1 Ma, and the ICP-MS Re-Os analyses of molybdenite from the molybdenum deposit yielded ReOs model ages ranging from 116.5±1.7 to 115.5±1.7 Ma for the deposit. The ages obtained by the two methods are quite close, suggesting that the rocks and ores formed approximately at the same time. The Donggou molybdenum deposit formed at least 20 Ma later than the Jinduicheng, Nannihu, Shangfanggou and Leimengou porphyry molybdenum deposits in the same molybdenum belt, implying that these deposits were formed in different tectonic settings.

关键词： SHRIMP U-Pb zircon age aluminous A-type granite-porphyry molybdenite Re-Os age Donggou molybdenum deposit East Qinling

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Age and fluid source constraints of the Haoyaoerhudong orogenic gold deposit,North China:Evidence from geochronology and noble gas isotopes

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Geoscience Frontiers 2024年第4期15卷 176-195页

作者： Chenglong Fan Jingwen Mao huishou ye Yitian Wang Junchen Liu Wei Jian Xuyang Meng Wenhao Tang Weiwei Chao Peng Wang School of Earth Sciences and Resources China University of GeosciencesBeijing 100083China MNR Key Laboratory for Exploration Theory&Technology of Critical Mineral Resources China University of GeosciencesBeijing 100083China Ministry of Natural Resources(MNR)Key Laboratory of Metallogeny and Mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological SciencesBeijing 100037China Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources by the Province and Ministry Guilin University of TechnologyGuilin 541004China State Key Laboratory of Nuclear Resources and Environment East China University of TechnologyNanchang 330013JiangxiChina School of Earth Sciences and Spatial Information Engineering Hunan University of Science and TechnologyXiangtan 411201China

The Haoyaoerhudong gold deposit,located in the northwestern part of the North China craton(NCC),has produced over 120 metric tonnes(t)of gold since *** has a total reserve of>240 t at average gold grade of 0.62 g/t,making it one of the largest open pit gold mines in *** steeply dipping,large-tonnage,low-grade,vein-or veinlet-type gold orebodies are hosted in strongly-deformed Mesoproterozoic carbonaceous schist of the Bayan Obo *** laminated/boudinaged veins/veinlets in the sinistral ductile-brittle shear zones are dominated by quartz,biotite,gold-bearing löllingite,pyr-rhotite,(arseno)pyrite,with minor native gold,titanite and *** this paper,we present new in situ U-Pb geochronological data on magmatic zircon from the preore dikes,on metamorphic and hydrothermal xenotime,and on hydrothermal titanite from the hydrothermally altered carbonaceous schist and auriferous quartzsulfides veins/veinlets,as well as He-Ar isotopic analysis on gold-bearing(arseno)pyrite in the syn-ore *** metamorphic xenotime U-Pb age of 426±6.0 Ma(2σ)records a regional metamorphic event,possibly related to the accretion of the Bainaimiao arc onto the *** pre-ore andesitic dikes yielded similar emplacement ages at~278 Ma constrained by laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)U-Pb zircon *** xenotime grains from the altered carbonaceous schist and auriferous quartz-sulfides veins yielded U-Pb ages of 256.0±4.1 Ma(2σ)and 254.4±2.1 Ma(2σ),respectively,overlapping with that of the hydrothermal titanite at 255.4±0.8 Ma(2σ)from the laminated quartz-sulfides *** indicates that the gold mineralization occurred at ca.255 ***~255 Ma gold mineralization age is much younger than the previously reported Early-Middle Permian regional magmatic activity(ca.291 Ma to 268 Ma),and may be associated with the regional sinistral strike-slip event in the late orogenic cycle related to the collision between the Siberian craton

关键词： Xenotime Titanite In situ U-Pb dating Noble gas Orogenic gold deposit North China Craton

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冀东唐杖子金(钼)多金属矿区侵入岩体锆石U-Pb年龄、Hf同位素特征及其地质意义

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岩石学报 2018年第9期34卷 2703-2715页

作者：贺文叶会寿曹晶中国地质大学地球科学与资源学院北京100083 中国地质科学院矿产资源研究所、国土资源部成矿作用与资源评价重点开放实验室北京100037

唐杖子金(钼)多金属矿床位于冀东地区,矿区内出露的主要岩性为花岗斑岩、石英二长岩和辉绿岩。本文对矿区主要的侵入岩进行锆石U-Pb定年和Hf同位素研究,探讨成岩-成矿相互关系,获取岩体源区信息。锆石U-Pb定年结果显示,花岗斑岩^(206)Pb... 详细信息

唐杖子金(钼)多金属矿床位于冀东地区,矿区内出露的主要岩性为花岗斑岩、石英二长岩和辉绿岩。本文对矿区主要的侵入岩进行锆石U-Pb定年和Hf同位素研究,探讨成岩-成矿相互关系,获取岩体源区信息。锆石U-Pb定年结果显示,花岗斑岩^(206)Pb/^(238)U加权平均年龄分别是161. 2±0. 7Ma、173. 0±5. 5Ma,结合锆石特征、锆石U-Pb定年结果,推测该矿区存在两期花岗质岩浆侵位;辉绿岩^(206)Pb/^(238)U加权平均年龄为166. 0±0. 9Ma;石英二长岩^(206)Pb/^(238)U加权平均年龄为176. 7±3. 3Ma。唐杖子矿区辉钼矿Re-Os年龄为170Ma,从时间尺度上来看辉钼矿化与早期花岗斑岩(173Ma)关系密切。花岗斑岩εHf(t)=-24. 4^-14. 1,tCDM=2104~2744Ma,表明岩石来源于古老地壳;辉绿岩εHf(t)=7. 8~10. 9,tDM=391~523Ma,表明岩石源区为古生代的亏损地幔。唐杖子花岗斑岩和辉绿岩都形成于中侏罗世,成岩时代相近,但源区明显不同,表明冀东地区在中侏罗世既存在下地壳的部分熔融的过程(形成了唐杖子花岗斑岩),又存在亏损地幔物质上涌侵入地壳的过程(形成了唐杖子辉绿岩),暗示了华北克拉通东缘在中侏罗世经历了一次岩石圈减薄的过程。

关键词：锆石U-Pb定年 Hf同位素组成岩石圈减薄唐杖子金(钼)多金属矿床

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扬子板块北缘早—中志留世硅质岩成因及古沉积环境的地球化学研究

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地质学报 2017年第10期91卷 2322-2350页

作者：张岩漆富成陈文叶会寿中国地质科学院地质研究所北京100037 核工业北京地质研究院北京100029 中国地质科学院矿产资源研究所北京100037

本文对四川省若尔盖县北部-甘肃省迭部县中-下志留统[兰多维列统(Llandovery)-温洛克统(Wenlock)]富有机碳硅质岩进行了无机化学研究,目的是探讨其成因及形成环境,并建立研究区硅质岩形成及相关元素富集模式。主要对1个钻孔、2个剖面共2... 详细信息

本文对四川省若尔盖县北部-甘肃省迭部县中-下志留统[兰多维列统(Llandovery)-温洛克统(Wenlock)]富有机碳硅质岩进行了无机化学研究,目的是探讨其成因及形成环境,并建立研究区硅质岩形成及相关元素富集模式。主要对1个钻孔、2个剖面共28件硅质岩的岩相学、扫描电镜、主量、微量、稀土元素、有机碳及Si、O稳定同位素特征进行了研究。(1)岩相学、扫描电镜分析,Fe/Ti、Al/(Al+Fe+Mn)(0.08~0.79)均值0.31、(Fe+Mn)/Ti,(La/Yb)N(0.12~1.41)均值0.54、δEu(0.81~3.36)均值1.55、∑REE(7.59~253.48)均值82.90,Si同位素(-0.2‰~2.1‰)均值0.66‰、O同位素(13.5‰~21.8‰)均值19.53‰、同位素对成岩温度的反演,显示硅质岩为热水沉积成因,并伴有生物作用(Si、O稳定同位素显示),益哇硅质岩形成时陆源物质供给适量,导致与碳酸盐相关生物繁盛,少量样品受陆源物质影响显著。(2)岩相学、扫描电镜分析,MnO_2/TiO_2、Al2O3/(Al2O3+Fe2O3)、Al/(Al+Fe)(0.08~0.80)均值0.33、Th/U、V(28.6×10^(-6)~2261×10^(-6))均值454.42×10^(-6)、Ti/V,δCe(0.65~1.58)均值1.01、(La/Ce)N(0.60~1.314)均值0.97、有机碳(TOC)-微量元素二元图解,显示研究区硅质岩形成于大陆边缘的热水喷流导致海底局部水动力较强的缺氧环境[特别是δCe、(La/Ce)N、稀土配分模式],部分硅质岩由于富集热液元素导致其具有洋脊、大洋盆地硅质岩的特征。结合前人研究成果,认为研究区硅质岩形成于扬子板块北缘(古商丹洋南缘)热水喷流系统发育(导致海底水动能较强的)、缺氧状态的陆缘拉张裂陷环境,这种环境有利于U、V、Mo、Cu、Ni等变价元素的富集,扬子板块北缘早古生代(寒武纪-志留纪)黑色页岩系产自扩张的大陆边缘缺氧-还原环境。

关键词：硅质岩成因古构造环境早-中志留世扬子板块北缘

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扬子板块西北缘热水沉积硅质岩稀土元素配分模式的影响因素

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地质学报 2018年第2期92卷 378-394页

作者：张岩漆富成陈文叶会寿中国地质科学院地质研究所北京100037 核工业北京地质研究院北京100029 中国地质科学院矿产资源研究所北京100037

本文对四川省若尔盖县北部-甘肃省迭部县中-下志留统(兰多维列统(Llandovery)-温洛克统(Wenlock))富有机质热水沉积硅质岩及下伏震旦系火山岩进行了以稀土元素地球化学为主的研究,目的是探讨热水沉积硅质岩稀土元素来源及其配分模式的... 详细信息

本文对四川省若尔盖县北部-甘肃省迭部县中-下志留统(兰多维列统(Llandovery)-温洛克统(Wenlock))富有机质热水沉积硅质岩及下伏震旦系火山岩进行了以稀土元素地球化学为主的研究,目的是探讨热水沉积硅质岩稀土元素来源及其配分模式的主要控制因素,并建立相应模式图。主要对1个钻孔、2个剖面共28件硅质岩的岩相学、扫描电镜、稀土元素(重点)特征,1个剖面的14件火山岩的主量元素、稀土元素(重点)特征进行了研究。黑色热水沉积硅质岩的岩相学、扫描电镜分析显示,其具有典型的沉积构造特征,后期弱变质;下伏震旦系火山岩样品的TAS图显示其主要为酸性火山岩,少量为基性火山岩。结合前人研究成果,对下伏震旦系火山岩与上覆地层中早-中志留世热水沉积硅质岩的稀土元素对比分析后发现:(1)张性构造环境是产生热水沉积硅质岩的动力学因素,而热水沉积硅质岩稀土元素主要来源于热水流体、古海水(混有陆源物质)、下伏地层中的稀土元素。(2)热水沉积硅质岩的稀土元素的相对丰度中存在一个阈值(或区间):在这个阈值之下,轻稀土元素(LREEs)配分模式及含量与热水流体一致,而重稀土元素(HREEs)配分模式与下伏火山岩的重稀土元素配分模式一致;在这个阈值之上,轻稀土元素(LREEs)配分模式则主要显示了与热水流体混合的古海水(混入有陆源物质)的特征,此时的热水沉积硅质岩的轻稀土元素配分模式及含量与平均上地壳的轻稀土元素配分模式一致,而重稀土元素(HREEs)配分模式仍然与下伏火山岩的重稀土元素配分模式一致。因此,在一定条件下热水沉积硅质岩可以指示古沉积构造环境。

关键词：热水沉积硅质岩稀土元素来源影响因素古构造环境

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小秦岭金矿田三叠纪成矿事件的伸展构造背景:构造岩的 ^(40)Ar- ^(39)Ar年代学证据

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岩石学报 2021年第8期37卷 2419-2430页

作者：王义天叶会寿刘俊辰郝建瑞张向卫郝蛟龙叶安旺中国地质科学院矿产资源研究所自然资源部成矿作用与资源评价重点实验室北京100037 中国地质大学(北京)地球科学与资源学院北京100083 灵宝金源矿业股份有限公司灵宝472500

小秦岭金矿田位于华北克拉通南缘,同时也是秦岭复合型造山带的北缘组成部分。这里是我国第二大黄金产地,大规模金的成矿作用形成于早白垩世岩石圈大规模减薄的区域伸展构造背景。此外,越来越多的同位素年代学数据显示区内还存在三叠纪... 详细信息

小秦岭金矿田位于华北克拉通南缘,同时也是秦岭复合型造山带的北缘组成部分。这里是我国第二大黄金产地,大规模金的成矿作用形成于早白垩世岩石圈大规模减薄的区域伸展构造背景。此外,越来越多的同位素年代学数据显示区内还存在三叠纪的成矿事件,发育钼、铅、铀、铌等与岩浆热液活动密切相关的多金属矿床,主要分布在小秦岭的南北边缘。目前,对于三叠纪多金属成矿作用的构造背景研究尚属薄弱,还没有直接对有关的构造变形开展过专题研究。为此,我们对小秦岭金矿田东端边缘的构造带进行构造观察和测量,并采用40 Ar-39 Ar年代学方法厘定变形时限,揭示三叠纪成矿事件的构造背景,为深入认识区内三叠纪多金属成矿作用特征和规律提供构造证据。研究表明,小秦岭金矿田三叠纪成矿事件发生于晚三叠世的伸展构造背景,可以划分为两个阶段,早期(221~216Ma)是在碰撞向后碰撞转折阶段的重力滑脱构造环境中,发育火成碳酸岩型钼铅、铀铌铅多金属矿床;晚期(214~203Ma)是在后碰撞阶段由俯冲板片断离或岩石圈拆沉作用等深部过程导致的区域伸展构造环境中,发育石英脉型和斑岩型钼矿床。小秦岭中生代晚三叠世和早白垩世两期成矿事件都是在伸展构造背景中的构造-岩浆-流体活动的产物。

关键词：三叠纪成矿事件伸展构造背景构造岩 40 Ar-39 Ar年代学小秦岭金矿田

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南秦岭地区下寒武统黑色页岩赋存的千家坪大型钒矿地球化学特征及成矿环境

引用

地学前缘 2022年第1期29卷 160-175页

作者：徐林刚付雪瑞叶会寿郑伟陈勃方正龙中国地质大学(北京)地球科学与资源学院北京100083 自然资源部战略性金属矿产找矿理论与技术重点实验室北京100083 中国地质科学院矿产资源研究所北京100037 陕西华源矿业有限责任公司陕西商洛726000

南秦岭地区下寒武统黑色页岩是我国主要的富钒层位,其中千家坪大型钒矿是典型代表。矿体主要赋存在水沟口组第一岩性段的碳硅质岩石中。为了探讨钒矿的成矿物质来源和南秦岭早寒武世古海洋氧化-还原环境,本文对水沟口组第一岩性段富钒... 详细信息

南秦岭地区下寒武统黑色页岩是我国主要的富钒层位,其中千家坪大型钒矿是典型代表。矿体主要赋存在水沟口组第一岩性段的碳硅质岩石中。为了探讨钒矿的成矿物质来源和南秦岭早寒武世古海洋氧化-还原环境,本文对水沟口组第一岩性段富钒碳硅质岩和上覆的第二岩性段泥质灰岩开展了岩石地球化学研究。第一岩性段碳硅质岩比第二岩性段泥质灰岩具有更高的Y/Ho比值,说明碳硅质岩主要为海水自生沉积形成的,而泥质灰岩的物质组成主要来自陆源碎屑。Eu/Eu^(*)与V含量不具备正相关关系,且Y/P_(2)O_(5)-Zr/Cr和Fe/Ti-Al/(Al+Fe+Mn)图解均显示钒矿主要是海水沉积形成的,热液作用对成矿元素的富集贡献很小。水沟口组样品Ce/Ce^(*)均为负异常,变化范围为0.26~0.96,第一岩性段钒矿石比第二岩性段泥质灰岩具有高Mo/Sc、V/Sc、V/Cr比值,低Th/U比值的特征,反映了早寒武世早期南秦岭为氧化-还原分层的古海洋结构,而晚期古海洋则全部被氧化。

关键词：千家坪钒矿微量元素稀土元素矿床成因氧化-还原环境南秦岭

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