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Estimation of the anisotropy of hydraulic conductivity through 3D fracture networks using the directional geological entropy

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International Journal of Mining Science and Technology 2024年第2期34卷 137-148页

作者： Chuangbing Zhou Zuyang ye Chi Yao Xincheng Fan Feng Xiong School of Infrastructure Engineering Nanchang UniversityNanchang 330031China b School of Resource and Environmental Engineering Wuhan University of Science and TechnologyWuhan 430081China School of Engineering China University of GeosciencesWuhan 430074China

With an extension of the geological entropy concept in porous media,the approach called directional entrogram is applied to link hydraulic behavior to the anisotropy of the 3D fracture networks.A metric called directional entropic scale is used to measure the anisotropy of spatial order in different *** with the traditional connectivity indexes based on the statistics of fracture geometry,the directional entropic scale is capable to quantify the anisotropy of connectivity and hydraulic conductivity in heterogeneous 3D fracture *** to the numerical analysis of directional entrogram and fluid flow in a number of the 3D fracture networks,the hydraulic conductivities and entropic scales in different directions both increase with spatial order(i.e.,trace length decreasing and spacing increasing)and are independent of the dip *** a result,the nonlinear correlation between the hydraulic conductivities and entropic scales from different directions can be unified as quadratic polynomial function,which can shed light on the anisotropic effect of spatial order and global entropy on the heterogeneous hydraulic behaviors.

关键词： 3D fracture network Geological entropy Directional entropic scale Anisotropy Hydraulic conductivity

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Transforming liquid flow fuel cells to controllable reactors for highlyefficient oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid at low temperature

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Journal of Energy Chemistry 2024年第3期90卷 621-631,I0014页

作者： ye Qiang Xi Liu Denghao Ouyang Zhao Jiang Xuebing Zhao Key Laboratory of Industrial Biocatalysis Ministry of EducationTsinghua UniversityBeijing 100084China Institute of Applied Chemistry Department of Chemical EngineeringTsinghua UniversityBeijing 100084China School of Chemical Engineering and Technology Xi'an Jiaotong UniversityXi'an 710049ShaanxiChina

Highly-efficient oxidation of 5-hydroxymethylfurtural(HMF) to 2,5-furandicarboxylic acid(FDCA) at low temperature with air as the oxidant is still ***,inspired by the respirato ry electron transport chain(ETC) of living cells mediated by electron carriers,we constructed artificial ETCs and transformed liquid flow fuel cells(LFFCs) to flexible reactors for efficient oxidation of HMF to produce FDCA under mild *** LFFC reactor employed an electrodeposition modified nickel foam as an anode to promote HMF oxidation and(VO_(2))_(2)SO_(4) as a cathode electron carrier to facilitate the electron transfer to *** reaction rate could be easily controlled by selecting the anode catalyst,adjusting the external loading and changing the cathodic electron carrier or oxidants.A maximal power density of 44.9 mW cm^(-2) at room temperature was achieved,while for FDCA production,short-circuit condition was preferred to achieve quick transfer of *** a single batch operation with 0.1 M initial HMF,FDCA yield reached 97.1%.By fed-batch operation,FDCA concentration reached 144.5 g L^(-1) with a total yield of 96%.Ni^(2+)/Ni^(3+) redox couple was the active species mediating the electron transfer,while both experimental and DFT calculation results indicated that HMFCA pathway was the preferred reaction mechanism.

关键词： 5-Hydroxymethylfurfural 2 5-Furandicarboxylic acid Electrodeposition Electron transport chain Liquid flow fuel cell

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Tuning the surface electronic structure of noble metal aerogels to promote the electrocatalytic oxygen reduction

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Journal of Energy Chemistry 2024年第2期89卷 557-564,I0013页

作者： Hongxing Yuan Wei Gao Xinhao Wan Jianqi ye Dan Wen State Key Laboratory of Solidification Processing School of Materials Science and EngineeringNorthwestern Polytechnical UniversityXi’an 710072ShaanxiChina

The sluggish kinetics of the oxygen reduction reaction(ORR)is the bottleneck for various electrochemical energy conversion *** the electronic structure of electrocatalysts by ligands has received particular attention in deriving valid ORR ***,the surface electronic structure of Ptbased noble metal aerogels(NMAs)was modulated by various organic ligands,among which the electron-withdrawing ligand of 4-methylphenylene effectively boosted the ORR *** calculations suggested the smaller energy barrier for the transformation of O^(*) to OH^(*) and downshift the d-band center of Pt due to the interaction between 4-methylphenylene and the surface metals,thus enhancing the ORR intrinsic *** Pt3Ni and Pt Pd aerogels with 4-methylphenylene decoration performed significant enhancement in ORR activity and durability in different ***,the 4-methylphenylene modified Pt Pd aerogel exhibited the higher halfwave potential of 0.952 V and the mass activity of 10.2 times of commercial Pt/*** work explained the effect of electronic structure on ORR electrocatalytic properties and would promote functionalized NMAs as efficient ORR electrocatalysts.

关键词： Noble metal aerogels Surface electronic structure ORR Electrocatalyst Organic ligands

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Clifford Deformations of Koszul Frobenius Algebras and Noncommutative Quadrics

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Algebra Colloquium 2024年第1期31卷 63-82页

作者： Jiwei He Yu ye Department of Mathematics Hangzhou Normal UniversityHangzhou 311121China School of Mathematical Sciences University of Science and Technology of China Hefei 230026China

A Clifford deformation of a Koszul Frobenius algebra E is a finite dimensional Z_(2)-graded algebra E(θ),which corresponds to a noncommutative quadric hypersurface E^(!)/(z)for some central regular element z∈E_(2)^(!).It turns out that the bounded derived category D^(b)(gr_(Z_(2))E(θ))is equivalent to the stable category of the maximal Cohen-Macaulay modules over E^(!)/(z)provided that E!is *** a consequence,E^(!)/(z)is a noncommutative isolated singularity if and only if the corresponding Clifford deformation E(θ)is a semisimple Z_(2)-graded *** preceding equivalence of triangulated categories also indicates that Clifford deformations of trivial extensions of a Koszul Frobenius algebra are related to Knörrer's periodicity theorem for quadric *** an application,we recover Knörrer's periodicity theorem without using matrix factorizations.

关键词： Koszul Frobenius algebra Clifford deformation noncommutative quadric hypersurface maximal Cohen-Macaulay module

Rapid Energy Exchange between In Situ Formed Bromine Vacancies and CO_(2)Molecules Enhances CO_(2)Photoreduction

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Research 2024年第2期2023卷 763-771页

作者： Qin Ren ye He Hong Wang Yanjuan Sun Fan Dong Research Center for Environmental and Energy Catalysis Institute of Fundamental and Frontier SciencesUniversity of Electronic Science and Technology of ChinaChengdu 611731China School of Resources and Environment University of Electronic Science and Technology of ChinaChengdu 611731China

Photocatalytic reduction of CO_(2)into fuels provides a prospective tactic for regulating the global carbon balance utilizing renewable solar ***,CO_(2)molecules are difficult to activate and reduce due to the thermodynamic stability and chemical *** this work,we develop a novel strategy to promote the adsorption and activation of CO_(2)molecules via the rapid energy exchange between the photoinduced Br vacancies and CO_(2)*** in situ continuous wave-electron paramagnetic resonance(cw-EPR)and pulsed EPR technologies,we observe that the spin-spin relaxation time(T_(2))of BiOBr is decreased by 198 ns during the CO_(2)photoreduction reaction,which is further confirmed by the broadened EPR *** result reveals that there is an energy exchange interaction between in situ formed Br vacancies and CO_(2)molecules,which promotes the formation of high-energy CO_(2)molecules to facilitate the subsequent reduction *** addition,theoretical calculations indicate that the bended CO_(2)adsorption configuration on the surface of BiOBr with Br vacancies caused the decrease of the lowest unoccupied molecular orbital of the CO_(2)molecule,which makes it easier for CO_(2)molecules to acquire electrons and get *** situ diffuse reflectance infrared Fourier transform spectroscopy further shows that the activated CO_(2)molecules are favorably converted to key intermediates of COOH*,resulting in a CO generation rate of 9.1μmol g^(-1)h^(-1)and a selectivity of 100%.This study elucidates the underlying mechanism of CO_(2)activation at active sites and deepens the understanding of CO_(2)photoreduction reaction.

关键词： reaction. adsorption activation

A hybrid memory architecture supporting fine-grained data migration

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Frontiers of Computer Science 2024年第2期18卷 31-41页

作者： ye CHI Jianhui YUE Xiaofei LIAO Haikun LIU Hai JIN National Engineering Research Center for Big Data Technology and System Services Computing Technology and System LabCluster and Grid Computing LabSchool of Computer Science and TechnologyHuazhong University of Science and TechnologyWuhan 430074China Department of Computer Science Michigan Technological UniversityMichigan 49931USA

Hybrid memory systems composed of dynamic random access memory(DRAM)and Non-volatile memory(NVM)often exploit page migration technologies to fully take the advantages of different memory *** previous proposals usually migrate data at a granularity of 4 KB pages,and thus waste memory bandwidth and DRAM *** this paper,we propose Mocha,a non-hierarchical architecture that organizes DRAM and NVM in a flat address space physically,but manages them in a cache/memory *** the commercial NVM device-Intel Optane DC Persistent Memory Modules(DCPMM)actually access the physical media at a granularity of 256 bytes(an Optane block),we manage the DRAM cache at the 256-byte size to adapt to this feature of *** design not only enables fine-grained data migration and management for the DRAM cache,but also avoids write amplification for Intel Optane *** also create an Indirect Address Cache(IAC)in Hybrid Memory Controller(HMC)and propose a reverse address mapping table in the DRAM to speed up address translation and cache ***,we exploit a utility-based caching mechanism to filter cold blocks in the NVM,and further improve the efficiency of the DRAM *** implement Mocha in an architectural *** results show that Mocha can improve application performance by 8.2%on average(up to 24.6%),reduce 6.9%energy consumption and 25.9%data migration traffic on average,compared with a typical hybrid memory architecture-HSCC.

关键词： non-volatile memory hybrid memory system data migration fine-grained caching

Hybrid concurrency control protocol for data sharing among heterogeneous blockchains

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Frontiers of Computer Science 2024年第3期18卷 1-12页

作者： Tiezheng GUO Zhiwei ZHANG ye YUAN Xiaochun YANG Guoren WANG School of Computer Science and Technology Beijing Institute of TechnologyBeijing 100029China School of Computer Science and Engineering Northeastern UniversityShenyang 110167China

With the development of information technology and cloud computing,data sharing has become an important part of scientific *** traditional data sharing,data is stored on a third-party storage platform,which causes the owner to lose control of the *** a result,there are issues of intentional data leakage and tampering by third parties,and the private information contained in the data may lead to more significant ***,data is frequently maintained on multiple storage platforms,posing significant hurdles in terms of enlisting multiple parties to engage in data sharing while maintaining *** this work,we propose a new architecture for applying blockchains to data sharing and achieve efficient and reliable data sharing among heterogeneous *** design a new data sharing transaction mechanism based on the system architecture to protect the security of the raw data and the processing *** also design and implement a hybrid concurrency control protocol to overcome issues caused by the large differences in blockchain performance in our system and to improve the success rate of data sharing *** took Ethereum and Hyperledger Fabric as examples to conduct crossblockchain data sharing *** results show that our system achieves data sharing across heterogeneous blockchains with reasonable performance and has high scalability.

关键词： data sharing blockchain concurrency control protocol crosschain

Biodegradation pathway and mechanism of tri (2-chloropropyl) phosphate by Providencia rettgeri

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Journal of Environmental Sciences 2024年第10期144卷 26-34页

作者： Jinming ye Shaoyu Tang Rongliang Qiu Shuona Chen Huiling Liu College of Natural Resources and Environment of South China Agricultural University Guangzhou 510642China Guangdong Provincial Key Laboratory of Agricultural&Rural Pollution Abatement and Environmental Safety Guangzhou 510642China Research Center for Eco-Environmental Engineering Dongguan University of TechnologyDongguan 523808China

Tri(2-chloropropyl)phosphate(TCPP)was an emerging contaminant of global concern because of its frequent occurrence,potential toxic effects,and persistence in the *** degradation might be an efficient and safe removal method,but limited information was *** this study,Providencia rettgeri was isolated from contaminated sediment and showed it could use TCPP as unique phosphorus source to promote growth,and decompose 34.7%of TCPP(1 mg/L)within 5 *** microbial inoculation and the initial concentration of TCPP could affect the biodegradation *** study results indicated that TCPP decomposition by Providencia rettgeri was mainly via phosphoester bond hydrolysis,evidenced by the production of bis(2-chloropropyl)phosphate(C6H13Cl2PO4)and mono-chloropropyl phosphate(C3H8ClPO4).Both intracellular and extracellular enzymes could degrade TCPP,but intracellular degradation was dominant in the later reaction stage,and the presence of Cu2+ions had a promoting *** findings developed novel insights into the potential mechanism of TCPP microbial degradation.

关键词： Chlorinated organophosphate flame retardants Microbial degradation Degradation pathway Providencia rettgeri Tri(2-chloropropyl)phosphate

Recent progress in the development of dielectric elastomer materials and their multilayer actuators

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2024年第3期25卷 183-205页

作者： Shengchao JIANG Junbo PENG Lvting WANG Hanzhi MA ye SHI ZJU-UIUC Institute Zhejiang UniversityJiaxing 314400China College of Mechanical Engineering Zhejiang UniversityHangzhou 310058China Department of Polymer Science and Engineering Zhejiang UniversityHangzhou 310058China

Dielectric elastomers(DEs)have emerged as one of the most promising artificial muscle technologies,due to their exceptional properties such as large actuation strain,fast response,high energy density,and flexible processibility for various *** the past two decades,researchers have been working on developing DE materials with improved properties and exploring innovative applications of dielectric elastomer actuators(DEAs).This review article focuses on two main topics:recent material innovation of DEs and development of multilayer stacking processes for DEAs,which are important to promoting commercialization of *** begins by explaining the working principle of a ***,recently developed strategies for preparing new DE materials are introduced,including reducing mechanical stiffness,increasing dielectric permittivity,suppressing viscoelasticity loss,and mitigating electromechanical instability without *** the next section,different multilayer stacking methods for fabricating multilayer DEAs are discussed,including conventional dry stacking,wet stacking,a novel dry stacking method,and micro-fabrication-enabled stacking *** review provides a comprehensive and up-to-date overview of recent developments in high-performance DE materials and multilayer stacking *** highlights the progress made in the field and also discusses potential future directions for further advancements.

关键词： Dielectric elastomer actuator(DEA) Dielectric elastomer(DE) Material svnthesis Multilaver stacking method