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Deep Insight of Design,Mechanism,and Cancer Theranostic Strategy of Nanozymes

Nano-Micro Letters 2024年第2期16卷 165-217页

作者： Lu yang Shuming Dong Shili Gai Dan yang He Ding Lili Feng Guixin yang Ziaur Rehman Piaoping yang Key Laboratory of Superlight Materials and Surface Technology Ministry of EducationCollege of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001People’s Republic of China Yantai Research Institute Harbin Engineering UniversityYantai 264000People’s Republic of China Key Laboratory of Green Chemical Engineering and Technology of Heilongjiang Province College of Material Science and Chemical EngineeringHarbin University of Science and TechnologyHarbin 150040People’s Republic of China Department of Chemistry Quaid-i-Azam UniversityIslamabad 45320Pakistan

Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale ***,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side ***,various nanozymes have been developed and used for tumor *** this review,more than 270 research articles are discussed systematically to present progress in the past five ***,the discovery and development of nanozymes are ***,classification and catalytic mechanism of nanozymes are ***,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical ***,synergistic theranostic strategy of nanozymes are ***,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities.

关键词： Nanozymes Classification Prediction and design Catalytic mechanism Tumor theranostics

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Mixed iridium-nickel oxides supported on antimony-doped tin oxide as highly efficient and stable acidic oxygen evolution catalysts

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Materials Futures 2024年第1期3卷 165-180页

作者： Jonathan Ruiz Esquius Alec P LaGrow Haiyan Jin zhipeng Yu Ana Araujo Rita Marques Adélio Mendes Lifeng Liu Clean Energy Cluster International Iberian Nanotechnology LaboratoryAv.Mestre JoséVeigaBraga 4715-330Portugal Carbon Science and Technology Institute INCAR-CSICFrancisco Pintado Fe 26Oviedo 33011Spain Scientific Imaging Section Okinawa Institute of Science and Technology Graduate UniversityKunigami-gunOkinawa 904-0412Japan Songshan Lake Materials Laboratory Dongguan 523808People’s Republic of China Laboratory for Process Engineering EnvironmentBiotechnology and EnergyFaculty of EngineeringUniversity of PortoRua Dr Roberto FriasPorto 4200-465Portugal Associate Laboratory in Chemical Engineering Faculty of EngineeringUniversity of PortoRua Dr Roberto FriasPorto 4200-465Portugal.

Proton exchange membrane(PEM)water electrolysis represents a promising technology for green hydrogen production,but its widespread deployment is greatly hindered by the indispensable usage of platinum group metal catalysts,especially iridium(Ir)based materials for the energy-demanding oxygen evolution reaction(OER).Herein,we report a new sequential precipitation approach to the synthesis of mixed Ir-nickel(Ni)oxy-hydroxide supported on antimony-doped tin oxide(ATO)nanoparticles(IrNiyO_(x)/ATO,20 wt.%(Ir+Ni),y=0,1,2,and 3),aiming to reduce the utilisation of scarce and precious Ir while maintaining its good acidic OER *** tested in strongly acidic electrolyte(0.1 M HClO_(4)),the optimised IrNi1Ox/ATO shows a mass activity of 1.0 mAµgIr^(−1) and a large turnover frequency of 123 s^(−1) at an overpotential of 350 mV,as well as a comparatively small Tafel slope of 50 mV dec^(−1),better than the IrOx/ATO control,particularly with a markedly reduced Ir loading of only 19.7µgIr cm^(−2).Importantly,IrNi1O_(x)/ATO also exhibits substantially better catalytic stability than other reference catalysts,able to continuously catalyse acidic OER at 10 mA cm^(−2) for 15 h without obvious *** in-situ synchrotron-based x-ray absorption spectroscopy confirmed that the Ir^(3+)/Ir^(4+)species are the active sites for the acidic ***,the performance of IrNi1Ox/ATO was also preliminarily evaluated in a membrane electrode assembly,which shows better activity and stability than other reference *** IrNi1Ox/ATO reported in this work is a promising alternative to commercial IrO_(2) based catalysts for PEM electrolysis.

关键词： mixed oxides oxygen evolution reaction polymer electrolyte membrane antimony doped tin oxide membrane electrode assembly

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基于视觉信息增强的服役燃机控制系统传感器故障分类方法研究

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动力工程学报 2023年第9期43卷 1160-1165页

作者：杨喜连王玉璋杨志鹏程侃如赵群飞上海交通大学电子信息与电气工程学院上海200240 上海交通大学机械与动力工程学院上海200240 上海发电设备成套设计研究院有限责任公司上海200240

将一维时间序列数据通过格拉姆角场转换为二维图像,利用方向梯度的直方图完成图像特征提取,利用多分类的支持向量机完成故障分类。基于某电厂9F燃机实际运行数据,在正常数据上叠加带有噪声的5类常见典型故障信号,以验证所提方法的有效性... 详细信息

将一维时间序列数据通过格拉姆角场转换为二维图像,利用方向梯度的直方图完成图像特征提取,利用多分类的支持向量机完成故障分类。基于某电厂9F燃机实际运行数据,在正常数据上叠加带有噪声的5类常见典型故障信号,以验证所提方法的有效性,并采用混淆矩阵进一步对故障分类结果进行可视化。结果表明:所提方法能有效识别微小渐变故障信号,故障的分类准确率为96.6%;格拉姆角场和马尔可夫转换场均具有较高的故障分类准确率。

关键词：燃气轮机控制系统传感器信号计算机视觉故障分类

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Customizable multifunctional metasurface absorber based on bidirectional deep neural networks covering the quasi-entire terahertz band

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Chinese Optics Letters 2024年第6期22卷 182-190页

作者： zhipeng Ding Wei Su Lipeng’an Ye Yuanhang Zhou Wenlong Li Riaz Ali Bin Tang Hongbing Yao College of Mechanics and Engineering Science Hohai UniversityNanjing 211100China School of Microelectronics and Control Engineering Changzhou UniversityChangzhou 213164China

In this work, we propose a novel approach that combines a bidirectional deep neural network(BDNN) with a multifunctional metasurface absorber(MMA) for inverse design, which can effectively address the challenge of on-demand customization for absorbers. The inverse design of absorption peak frequencies can be achieved from 0.5 to 10 terahertz(THz), covering the quasi-entire THz band. Based on this, the BDNN is extended to broadband absorption, and the inverse design yields an MMA at the desired frequency. This work provides a broadly applicable approach to the custom design of multifunctional devices that can facilitate the evaluation and design of metasurfaces in electromagnetic absorption.

关键词： terahertz inverse design bidirectional deep neural network metasurface

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The δ^(15)N values of foxtail millet(Setaria italica)and common millet(Panicum miliaceum)are reliable indicators of manuring practices

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Science China Earth Sciences 2024年第9期67卷 2910-2923页

作者： Jishuai yang Xiaoyan yang Ting YOU Fahu CHEN Key Scientific Research Base of Bioarchaeology in Cold and Arid Regions(National Cultural Heritage Administration) Key Laboratory of Western China’s Environmental Systems(Ministry of Education)College of Earth and Environmental SciencesLanzhou UniversityLanzhou 730000China Group of Alpine Paleoecology and Human Adaptation(ALPHA) State Key Laboratory of Tibetan Plateau Earth SystemResources and Environment(TPESRE)Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China State Key Laboratory of Herbage Improvement and Grassland Agro-ecosystems College of Pastoral Agriculture Science and TechnologyLanzhou UniversityLanzhou 730000China

Millet agriculture,which originated in northern China,alongside rice agriculture,have nurtured the Chinese *** manuring practices likely promoted and maintained sustainable millet agricultural production in the loess area of northern ***,ongoing controversy exists regarding the indicators of prehistoric manuring intensity of foxtail millet(Setaria italica)and common millet(Panicum miliaceum).Here,we present the results of pot and field fertilization experiments on two millet *** findings suggest that manuring can significantly increase the δ^(15)N values of foxtail millet,and its δ^(15)N values increase with increasing manuring *** δ^(15)N values of foxtail millet leaves are systematically greater than those of grains by approximately 1.6‰.Manuring could have a long-term residual impact on increasing the δ^(15)N values of soil and millet *** with previous crop fertilization experiment results,we propose that the impact of manuring on the δ^(15)N values of non-nitrogen-fixing crops is roughly *** δ^(15)N value and amount of manure are key factors determining the extent of change in plant δ^(15)N *** millet grain δ^(15)N values can serve as reliable indicators of manuring ***,we provide an interpretive framework for assessing the correlation between manuring levels and the δ^(15)N values of archaeological millet *** δ^(15)N values of ancient millet grains suggest widespread and intensive manuring practices in prehistoric millet agriculture in northern China,spanning from the early yangshao period to the Longshan period.

关键词： Millet farming Manuring experiment Farming system Archaeobotany North China

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Pressure effects on metal/covalent-organic frameworks:structural and optical properties

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Science China Chemistry 2024年第9期67卷 2890-2903页

作者： Yixuan Wang Yunfeng yang Xinyi yang Bo Zou Synergetic Extreme Condition High-Pressure Science Center State Key Laboratory of Superhard MaterialsCollege of PhysicsJilin UniversityChangchun 130012China

Metal-organic frameworks(MOFs)and covalent organic frameworks(COFs)with highly ordered porous structure,tunable bandgap,large specific surface area and structural diversity,provide an appealing platform for the development of stimulus response,sensing,imaging and *** various tuning methods,pressure engineering using the diamond anvil cell is a highly powerful in-situ technique,which can efficiently modulate the structural and optical properties of MOFs/*** is beyond the realization of traditional chemical *** review outlines the research progress in the experimentoriented discovery of new phases or unique properties under high pressure,including phase transition,abnormal compression,photoluminescence(PL)discoloration and ***,the improvement of PL quantum yield in MOFs could be achieved by pressure-treated engineering and hydrogen-bonding cooperativity *** also propose and establish the relationship between structure and optical properties under high ***,the challenge and outlook of the current fields are *** hope that this review will supply guidance for comprehending the development of high-pressure MOF/COF-related research fields,and offer novel strategies for designing more high-performance MOF/COF materials to ultimately expand their applications.

关键词： metal/covalent-organic frameworks pressure engineering phase transition abnormal compressive behaviors piezochromic behaviors emission enhancement

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Enhanced Ion-Selective Diffusion Achieved by Supramolecular Interaction for High Thermovoltage and Thermal Stability

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Energy & Environmental Materials 2024年第2期7卷 200-208页

作者： Jiale Ke Xing Zhao Jie yang Kai Ke Yu Wang Mingbo yang Wei yang College of Polymer Science and Engineering Sichuan UniversityState Key Laboratory of Polymer Materials EngineeringChengdu 610065China

Thermoelectric(TE)generators capable of converting thermal energy into applicable electricity have gained great popularity among emerging energy conversion ***-based ionic thermoelectric(i-TE)materials are promising candidates for energy conversion systems because of their wide sources,innocuity,and low manufacturing ***,common physically crosslinked biopolymer gels induced by single hydrogen bonding or hydrophobic interaction suffer from low differential thermal voltage and poor thermodynamic ***,we develop a novel i-TE gel with supramolecular structures through multiple noncovalent interactions between ionic liquids(ILs)and gelatin molecular *** thermopower and thermoelectric power factor of the ionic gels are as high as 2.83 mV K-1 and 18.33μW m^(-1)K^(-2),*** quasi-solid-state gelatin-[EMIM]DCA i-TE cells achieve ultrahigh 2 h output energy density(E_(2h)=9.9 mJ m^(-2))under an optimal temperature ***,the remarkable stability of the supramolecular structure provides the i-TE hydrogels with a thermal stability of up to 80℃.It breaks the limitation that biopolymer-based i-TE gels can only be applied in the low temperature range and enables biopolymer-based i-TE materials to pursue better performance in a higher temperature range.

关键词： biopolymer gel ionic liquid multiple noncovalent interactions supramolecular structure thermoelectric conversion

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Atomic-level coupled RuO_(2)/BaRuO_(3) heterostructure for efficient alkaline hydrogen evolution reaction

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Journal of Energy Chemistry 2024年第1期88卷 356-362,I0009页

作者： Yueying Yan Tian Meng Yuting Chen yang yang Dewen Wang Zhicai Xing Xiurong yang State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022JilinChina School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei 230026AnhuiChina

The slow water dissociation is the rate-determining step that slows down the reaction rate in alkaline hydrogen evolution reaction(HER).Optimizing the surface electronic structure of the catalyst to lower the energy barrier of water dissociation and regulating the binding strength of adsorption intermediates are crucial strategy for boosting the catalytic performance of *** this study,RuO_(2)/BaRuO_(3)(RBRO)heterostructures with abundant oxygen vacancies and lattice distortion were in-situ constructed under a low temperature via the thermal decomposition of *** RBRO heterostructures obtained at 550℃ exhibited the highest HER activity in 1 M KOH,showing an ultra-low overpotential of 16 mV at 10 mA cm^(-2)and a Tafel slope of 33.37 m V dec^(-1).Additionally,the material demonstrated remarkable durability,with only 25 mV of degradation in overpotential after 200 h of stability testing at 10 mA cm^(-2).Density functional theory calculations revealed that the redistribution of charges at the heterojunction interface can optimize the binding energies of H*and OH*and effectively lower the energy barrier of water *** research offers novel perspectives on surpassing the water dissociation threshold of alkaline HER catalysts by means of a systematic design of heterogeneous interfaces.

关键词： Heterostructure Hydrogen evolution reaction Interfacial electron transfer Oxygen vacancies

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大直径钻孔卸压防治冲击地压探讨

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江西煤炭科技 2019年第2期 129-131,135页

作者：杨志鹏山西新景矿煤业有限责任公司

新景煤矿8118工作面采用钻孔卸压措施防治冲击地压,通过监测巷道两帮、顶底板的移近量及超前应力随距工作面推进的变化规律,验证缷压钻孔参数的合理性及措施的有效性。结果表明:卸压区域两帮及顶底板移近量明显小于未卸压区域,且围岩应... 详细信息

新景煤矿8118工作面采用钻孔卸压措施防治冲击地压,通过监测巷道两帮、顶底板的移近量及超前应力随距工作面推进的变化规律,验证缷压钻孔参数的合理性及措施的有效性。结果表明:卸压区域两帮及顶底板移近量明显小于未卸压区域,且围岩应力也有明显下降,二次卸压更有利于形成应力弱化带,卸压效果明显。实践结果验证了二次钻孔卸压的有效性及相应参数的合理性。

关键词：钻孔卸压钻孔参数围岩变形超前应力

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高职院校品牌文化建设内涵、实践意义和路径探析

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淮南职业技术学院学报 2020年第3期20卷 66-67页

作者：杨志鹏陕西铁路工程职业技术学院陕西渭南714000

在新媒体快速发展的时代,品牌文化是高职院校发展的重要软实力之一。高职院校的品牌文化是区别于其他教育产品所特有的属性,在办学理念、办学条件和办学实践当中不断总结和升华。沉淀提炼后的品牌文化对高职院校的发展有提纲挈领的理论... 详细信息

在新媒体快速发展的时代,品牌文化是高职院校发展的重要软实力之一。高职院校的品牌文化是区别于其他教育产品所特有的属性,在办学理念、办学条件和办学实践当中不断总结和升华。沉淀提炼后的品牌文化对高职院校的发展有提纲挈领的理论指导意义,同时对学校的快速发展起到了重要的指导作用。探索高职院校品牌文化建设的内涵、实践意义和路径,分析其对提高教学品质、塑造硬核品牌文化、承担育人使命、提升社会认同和学校形象有深远的影响。

关键词：高职院校品牌文化内涵意义路径

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