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Effects of the grain size distribution on the temperature-dependent magnetic susceptibility of magnetite nanoparticles

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Science china Earth sciences 2010年第7期53卷 1071-1078页

作者： ZHAO XiangYu1,2.& LIU QingSong1 1 Paleomagnetism and Geochronology Laboratory (SKL-LE), Institute of geology and Geophysics, Chinese academy of {2., beijing 100029, china 2.Graduate University of Chinese academy of {2., beijing 100049, china 1. Paleomagnetism and Geochronology Laboratory (SKL-LE) Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China2. Graduate University of Chinese Academy of Sciences Beijing 100049 China

Magnetite is an important magnetic remanence carrier in natural samples and therefore is of great interest in paleo-, rock-, and environmental magnetism. The magnetic properties of magnetite depend on many factors, e.g., concentration and grain size distribution (GSD). In this study, we theoretically investigated the temperature-dependent susceptibility (TDS) of magnetite nanoparticles with a lognormal GSD. Results show that the TDS is affected highly by the GSD mainly in three aspects. Firstly, the unblocking process becomes smoother with the increase of distribution width, characterizing as a wider Hopkinson peak on the TDS curve. Secondly, the blocking temperature increases with the increase of the median diameter or/and the distribution width. Thirdly, the maximum susceptibility decreases with the increase of distribution width, and has a logarithmic function relation with the standard deviation of the distribution. As a case study, this model was further applied to the thermal products of the Chinese loess/paleosol samples to determine the granulometry of newly-formed magnetite upon heating based on TDS curves. The results demonstrate the fidelity and feasibility of this method to determine the GSD of nano-sized magnetic particles.

关键词： Néel theory temperature dependence of susceptibility grain size distribution

A new method for spatio-temporal prediction of rainfall-induced landslide

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Science china Earth sciences 2006年第4期49卷 421-430页

作者： DING Jixin1,2. yang Zhifa2. SHANG Yanjun2. ZHOU Shenghua1 & YIN Juntao3.1. china Non-ferrous Metals Resource Geological Survey, {2. 100012. china 2. Institute of geology and Geophysics, Chinese academy of sciences, Key Laboratory of Engineering Geomechanics, beijing 100029, china 3. School of Geoscience & Environmental Engineering, Central South University, Changsha 410083. china 1. china Non-ferrous Metals Resource Geological Survey Beijing 100012 China 2. Institute of geology and Geophysics Chinese Academy of Sciences Key Laboratory of Engineering Geomechanics Beijing 100029 China 3. School of Geoscience & Environmental Engineering Central South University Changsha 410083 China

Geological condition and rainfall are two most principal conditions inducing landslides in the Chongqing region. By analyzing the forming conditions of rainfall-induced landslides, a new method for spatio-temporal prediction of rainfall-induced landslide is brought forward on the basis of grading and overlapping geological condition and rainfall factor in this paper. At first, semi-quantitative assessment and grading for the geological condition of a certain area or slope can be carried out with the multi-factor interactive matrix. Then the severity of rainfall in that area is grading according to the maximum daily rainfall and the total rainfall in a rainfall course. Finally, the “landslide probability judgement factor” can be worked out through grading and overlapping “geological condition influenc- ing factor” and “rainfall influencing factor”, by which the landslide can be graded into 4 grades, they are landslide extremely easily happening, landslide easily happening, landslide difficultly happening and landslide hardly ever happening respectively. More accurate spatio-temporal prediction of rain- fall-induced landslides can come true on the ground of detailed geological survey of some dangerous slopes in an area and more precise weather forecast. Finally, the reliability and feasibility of carrying out the spatio-temporal prediction of rainfall-induced landslides with the method of “two factors” grading and overlapping are validated by the example of Jipazi landslide.

关键词： rainfall-induced landslide, geological condition, rainfall, two factors, grading and overlapping, interactive matrix, spatio-temporal prediction.

Petrogenesis and dating of the Kangding complex,Sichuan Province

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Science china Earth sciences 2005年第5期48卷 622-634页

作者： CHEN Yuelong 1 , LUO Zhaohua 1 , ZHAO Junxiang, LI Zhihong, ZHANG Hongfei & SONG Biao 3.1. Faculty of Earth sciences and Natural Resources, china University of Geosciences, {3. 100083. china 2. Faculty of Earth sciences, china University of Geosciences, Wuhan 43.074, china 3. {3. SHRIMP Center, Institute of geology, Chinese academy of Geological sciences, {3. 10003., china 1. Faculty of Earth sciences and Natural Resources China University of Geosciences 100083 Beijing China 2. Faculty of Earth sciences China University of Geosciences 430074 Wuhan China 3. beijing SHRIMP Center Institute of Geology Chinese Academy of Geological Sciences 100037 Beijing China

An analysis of major and trace element geochemistry and SHRIMP U-Pb zircon dating of mafic, intermediate, and felsic rocks from the Mianning metamorphic complex of Si- chuan Province was conducted. One of our conclusions is that a majority of the zircons crystal- lized between 72. and 773.Ma in a magmatic regime. The complexes contain early to late Pa- leo-proterozoic relict zircons from ancient continental crust. The oldest age, 2.68 Ma, may rep- resent the basement of the yangtze block. Overgrowth zircon rims and palingenetic zircons have been observed and dated, and are believed to have formed after crystallization, during Paleozoic and Mesozoic metamorphic-anatexis. We also conclude that depletion of Nb, Ta, HREE, in a spider-diagram normalized to primitive mantle and calc-alkaline association, implies that they formed in island-arc or under-plating settings.

关键词： Kangding complex, zircons, SHRIMP, tectonic setting.

Geomorphologic evidence of phased uplift of the northeastern Qinghai-Tibet Plateau since 14 million years ago

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Science china Earth sciences 2004年第9期47卷 822-833页

作者： LU Huayu1, WANG Xiaoyong1, AN Zhisheng1, MIAO Xiaodong1, ZHU Rixiang3. MA Haizhou2. LI Zhen4, TAN Hongbing2.& WANG Xianyan1 1. State Key Laboratory of Loess and Quaternary geology, Institute of Earth Environment, Chinese {3. of {2., Xi’an 710075 china 2. Qinghai Institute of Salt Lakes, Chinese {3. of {2.. Xining 810008, china 3. Institute of geology and Geophysics, Chinese {3. of {2.,{13., china 4. Department of Geography, Qinghai Normal University, Xining 810008, china Chinese Acad Sci Inst Earth Environm State Key Lab Loess & Quaternary Geol Xian 710075 Peoples R China Chinese Acad Sci Qinghai Inst Salt Lakes Xining 810008 Peoples R China Chinese Acad Sci Inst Geol & Geophys Beijing 100029 Peoples R China Qinghai Normal Univ Dept Geog Xining 810008 Peoples R China

A typical sequence of fluvial terraces and aeolian deposits overlying these ter- races were multidisciplinary investigated. New evidences for uplift process of the northeastern Qinghai-Tibetan Plateau in the past 14 million years were obtained. At least 11 river terraces along Huangshui, the first-class tributary of Yellow River, at the Xining-Huzhu region are identi- fied. While the first one (T1) is classified as an accumulation terrace, the others are all basement river terraces, which consist of the Tertiary sandstone and siltstone bedrock, fluvial gravel and pebbles and the overlying aeolian loess-Red Clay deposit. Samples from the aeolian deposits were examined for paleomagnetic stratigraphic reconstruction (103. samples), luminescence dating (16 samples), magnetic susceptibility and grain-size distribution (more than 4000 sam- ples). The luminescence dating and stratigraphic correlation suggest that terraces of Tll, T10, T8, T7, T3. T2. T1 were formed at 14, 11.3. 1.55, 1.2. 0.15, 0.07 and 0.01 million years ago, re- spectively. Sedimentological analysis and geomorphological observation indicate that formation and evolution of these terraces were mainly driven by tectonic uplift. Therefore, the terrace se- quence provides an ideal geological record, of the uplift process of the northeastern during the past 14 million years, and the timings of the terraces formation are regarded as the timings of tectonic uplift. The significant uplifting events took place at 14, 11.3. 1.2.and 0.15 mil- lion years ago, respectively. The fluvial incision at the Xining-Huzhu region is less than 100 m during a period of ~12.million years in the Miocene era (between the Tll and T9), while the Huangshui River had incised 43.0}m during the past 1.2.million years (from T7 to the present floodplain). The river incision process clearly demonstrates that accelerated rising of the north- eastern Qinghai-Tibet Plateau during the late Cenozoic, and provides new evidence of previous thoughts

关键词： river terrace, tectonic uplift, loess-Red Clay, the past 14 million years, northeastern Qinghai-Tibet Plateau.

Carbon isotopic variations of Proterozoic carbonates in Jixian, Tianjin, china

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Science china Earth sciences 2004年第2期47卷 160-170页

作者： CHU Xuelei, ZHANG Tonggang, ZHANG Qirui, FENG Lianjun & ZHANG Fusong1. Institute of geology and Geophysics, Chinese academy of {2.,{3., china 2. Key Laboratory for Mineral Resources Research, Chinese academy of {2.,{3., china Correspondence should be addressed to Chu Xuelei (email: xlchu@***) 1. Institute of geology and Geophysics Chinese Academy of Sciences 100029 Beijing China 2. Key Laboratory for Mineral Resources Research Chinese Academy of Sciences 100029 Beijing China

Along the Proterozoic stratigraphic sections of Jixian, Tianjin, the ??13. values of carbonates are mostly negative in the Changchengian (Changcheng System), varying approximately within a range of (0±1)‰ in the Jixianian (Jixian System), and have commonly positive values of (2.2.‰ in the Qingbaikouan (Qingbaikou System). From Chuanlinggou Formation to Dahongyu Formation, i.e. from ca. 1700 Ma to 1600 Ma, the δ13. values of carbonates increase from about -3. to 0‰, but oscillate with large excursion in Dahongyu Formation. Two large excursions occur in the Jixianian, one in yangzhuang Formation and the other in the third submember of Wumishan Formation overlaying. These integrated and continuous records of carbon isotope reflect secular variations of δ13. value in ancient seawater from ca. 1700 Ma to ca. 800 Ma. The increase and subsequent oscillation of seawater δ13. value occurring from the ages of ca. 1700 to ca. 1600 Ma and ＜13.0 Ma may signify two correlative global tectonic events.

关键词： Proterozoic, Jixian, carbon isotope, chemostratigraphy, secular variation, global tectonic event.

Experimental study of ore gabbro liquid immiscibility

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Science china Earth sciences 2005年第4期48卷 496-505页

作者： SANG Zunan1,2. XIA Bin1, ZHOU Yongsheng3.& JIN Zhenmin4 1. Guangzhou Institute of Geochemistry, Chinese academy of sciences, Guangzhou 510640,{2. 2. Wuhan University, Wuhan 43.072.{2. 3. Institute of geology,{2. Seismological Bureau, beijing 100029,{2. 4. Faculty of Earth sciences,{2. University of Geosciences, Wuhan 43.074,{2. 1. Guangzhou Institute of Geochemistry Chinese Academy of Sciences 510640 Guangzhou China 2. Wuhan University 430072 Wuhan China 3. Institute of geology China Seismological Bureau 100029 Beijing China 4. Faculty of Earth sciences China University of Geosciences 430074 Wuhan China

In this paper, the authors present the results of a preliminary experimental study on partial melting of fine-grained gabbro, Panzhihua, Sichuan Province, china. Experiments were conducted under (confining) pressure ranging from 450 to 500 MPa and temperature of 900— 12.0℃. The results show that the initial melt is distributed along grain boundaries and triple junctions. Liquid immiscibility phenomena are noted in the melt with two compositional different melt phases, i.e. matrix and sphere phases. The matrix phase is relatively rich in Si, Al and K, and is depleted in Mg, Fe, Ca, Na and Ti, whereas the sphere phase shows opposite trends. The calculation of the melt free energy indicates that the liquid immiscibility is governed by the rule of thermodynamics, as the liquid immiscibility would result in the decrease in free energy of the melt system. The field relationships suggest that the liquid immiscibility may have played an important role in the generation of ore magma of Panzhihua V-Ti magnetite ore deposit. This study thus provides experimental constraints on the mechanism of the formation of V-Ti magnetite deposite.

关键词： partial melting, experimental study, gabbro, liquid immiscibility, ore formation mechanism.

Characteristics and origins of primary fluids and noble gases in mantle-derived minerals from the Yishu area,Shandong Province,china

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Science china Earth sciences 2006年第1期49卷 77-87页

作者： MA Jinlong1,2. TAO Mingxin2.3.& YE Xianren2.1. Resources and Environmental School, Lanzhou University, Lanzhou 73.000,{3. 2. Key Laboratory of Gas Geochemistry, Institute of geology and Geophysics, Chinese {2. of sciences, Lanzhou 73.000,{3. 3. College of Resources Science & Technology, beijing Normal University, beijing 100875,{3. 1. Resources and Environmental School Lanzhou University Lanzhou 730000 China 2. Key Laboratory of Gas Geochemistry Institute of Geology and Geophysics Chinese Academy of Sciences Lanzhou 730000 China 3. College of Resources Science & Technology Beijing Normal University Beijing 100875 China

Fluids and noble gases of mantle-derived materials are important tracers forthe mantle information. Compositions of primary fluids and noble gases in mantle-derived mineralsfrom the Yishu area, Shandong Province, china, were tested by the methods of heat-bursting andheat-melting respectively. The fluids are mainly composed of CO_2. CO and H_2. which account forabout 90% of the total, and are similar to the mantle-derived rocks from other areas of eastern{3.; ratios of ~3.e/~4He in almost all samples range from 0.82.Ra to 2.74 Ra, whereas^(40)Ar/^(3.)Ar from 2.9.5 to 758.8. Both ranges are much lower than those of the typical oceanmantle-derived samples (such as MORB) and primarily reflect the influences of the atmosphericcomponents and the radiogenic isotopes. Ratios of C/~3.e range from 2..6 x 10~9 to 1050 x 10~9,N_2.Ar from 92. to 56612. and N_2.~3.e from 2.5 x 10~9 to 2. x 10~9, similar to those in westernUnited States and New Zealand which belong to the tectonic plate collision regions. The ratios fallin the intersect of mantle-crust-atmosphere in the comprehensive tracer-charts, reflecting theinfluences of the atmosphere and the crusts with organic components. Our results suggest that thecomposition of the primary fluids and the isotopic ratios of the noble gases may either reflect theevolution process of mantle-derived rocks connected with the rise and eruption of magma, or theinfluence of the ancient subduction-plate on the continental mantle of this region.

关键词： noble gases, primary fluids, mantle-derived minerals, Yishu area.

The species diversity of fusulinaceans and high-frequency sea-level changes in the Carboniferous-Permian boundary section at Xikou, Zhen'an County,Shaanxi Province, china

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Science china Earth sciences 2006年第7期49卷 673-683页

作者： ZHANG Haijun1, WANG Xunlian2. DING Lin1, XIA Guoying3.& WANG Lei2.1. Institute of Tibetan Plateau Research, Chinese academy of {3., {2. 100085, china 2. Faculty of Earth {3. and Mineral Resources, china University of Geo{3., {2. 100083. china 3. Tianjin Institute of geology and Mineral Resources, Tianjin 3.0170, china 1. Institute of Tibetan Plateau Research Chinese Academy of Sciences Beijing 100085 China 2. Faculty of Earth sciences and Mineral Resources China University of Geosciences Beijing 100083 China 3. Tianjin Institute of geology and Mineral Resources Tianjin 300170 China

The study on the interrelation between sea-level changes and biodiversity with its evolu-tion has great significance for understanding the impact of global changes on organic evolution and exploring the inherent laws of life-environment coevolution in geological history. In this paper, the stratigraphic distribution of fusulinacean fauna in the Carboniferous-Permian boundary section at Xikou, Zhen’an County, Shaanxi Province, is analyzed quantitatively, and the relationship between the species diversity of fusulinaceans and relative sea-level changes is discussed. As a whole, the spe-cies numbers of fusulinacean fauna experience a rapid increase and an obvious decline in Xikou, Zhen’an County, from the Late Carboniferous to the Early Permian. There is a significant increase in species diversity around the Carboniferous-Permian boundary, which is one of the biggest bio-events of the fusulinacean fauna, and represents the radiation of Pseudoschwagerininae subfamily in the studied area. Integrated fusulinacean species diversity into sequence stratigraphic framework, de-tailed study suggests that the species diversity of the fusulinaceans is closely related to its relative stratigraphic location, and is essentially controlled by the sea-level changes, especially by the high-frequency sea-level changes. Generally, the species diversity of fusulinaceans is low, and the number of first and last appearance datum is small in the lower unit of high-frequency depositional cycle formed during the quick rise of the sea level; whereas the species diversity of fusulinaceans is high, and the number of first and last appearance datum is large in the upper unit of high-frequency cycle formed during the slow fall of the sea level. Within the third-order depositional sequence, the species diversity of the fusulinaceans at the first flooding surfaces and the maximum flooding surfaces is low, and it increases upward. The fusulinacean species diversity is low within the transgressive syst

关键词： fusulinaceans, species diversity, high-frequency cyclothem, sequence stratigraphy, sea-level changes, Carboniferous-Permian boundary, Zhen'an, Shaanxi.

Neogene eolian deposits within the West Qinling Mountains:Climatic and tectonic implications

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Chinese Science Bulletin 2010年第15期55卷 1483-1487页

作者： GE JunYi 1,2.& GUO ZhengTang 3.1 State Key Laboratory of Loess and Quaternary geology (SKLLQG),Institute of Earth Environment,Chinese academy of {2.,Xi’an 710075,china 2.Graduate University of Chinese academy of {2.,beijing 100049,china 3.Key Laboratory of Cenozoic geology and Environment,Institute of geology and Geophysics,Chinese academy of {2.,beijing 100029,china State Key Laboratory of Loess and Quaternary geology (SKLLQG) Institute of Earth Environment Chinese Academy of Sciences Xi''an 710075 China Graduate University of Chinese academy of sciences Beijing 100049 China Key Laboratory of Cenozoic geology and Environment Institute of Geology and Geophysics Chinese Academy of Sciences Beijing 100029 China

The Qinling Mountains constitute a key climate barrier between southern and northern *** recent investigations revealed widely spread eolian deposits of Neogene age mantling the piedmont highlands of the intermountain basins within West ***-mammalian fossils dated a 150.2.m section (NL-VI) near Xihe for the late Miocene to Pliocene (～10-4 Ma).Soil micromorphology,grain-size and geochemical analysis consistently define typical loess-soil alternations for the upper (0-66 m) and lower (98-150.2.m) parts of the section,with the middle section (66-98 m) having been affected by episodic slope *** results add important insights to the earlier studies about the widespread eolian deposition in northern china during the Miocene,prior to 8 *** also suggest that the basic configuration of the ridges and inter-ridge basins of West Qinling has already formed by ～10 *** well-preserved eolian deposits are unlikely to support intense substratum deformation and rapid uplift of West Qinling since the late Miocene.

关键词：秦岭山脉风尘堆积构造意义气候新近纪晚中新世地球化学分析风尘沉积