检索结果-南通市图书馆

Deep Insight of Design,Mechanism,and Cancer Theranostic Strategy of Nanozymes

在线全文

学校读者我要写书评

暂无评论

Nano-Micro Letters 2024年第2期16卷 165-217页

作者： Lu yang Shuming Dong Shili Gai Dan yang He Ding Lili Feng Guixin yang Ziaur Rehman Piaoping yang Key Laboratory of Superlight Materials and Surface Technology Ministry of EducationCollege of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001People’s Republic of China Yantai Research Institute Harbin Engineering UniversityYantai 264000People’s Republic of China Key Laboratory of Green Chemical Engineering and Technology of Heilongjiang Province College of Material Science and Chemical EngineeringHarbin University of Science and TechnologyHarbin 150040People’s Republic of China Department of Chemistry Quaid-i-Azam UniversityIslamabad 45320Pakistan

Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale ***,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side ***,various nanozymes have been developed and used for tumor *** this review,more than 270 research articles are discussed systematically to present progress in the past five ***,the discovery and development of nanozymes are ***,classification and catalytic mechanism of nanozymes are ***,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical ***,synergistic theranostic strategy of nanozymes are ***,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities.

关键词： Nanozymes Classification Prediction and design Catalytic mechanism Tumor theranostics

Atomic-level coupled RuO_(2)/BaRuO_(3) heterostructure for efficient alkaline hydrogen evolution reaction

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第1期88卷 356-362,I0009页

作者： Yueying Yan Tian Meng Yuting Chen yang yang Dewen Wang Zhicai Xing Xiurong yang State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022JilinChina School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei 230026AnhuiChina

The slow water dissociation is the rate-determining step that slows down the reaction rate in alkaline hydrogen evolution reaction(HER).Optimizing the surface electronic structure of the catalyst to lower the energy barrier of water dissociation and regulating the binding strength of adsorption intermediates are crucial strategy for boosting the catalytic performance of *** this study,RuO_(2)/BaRuO_(3)(RBRO)heterostructures with abundant oxygen vacancies and lattice distortion were in-situ constructed under a low temperature via the thermal decomposition of *** RBRO heterostructures obtained at 550℃ exhibited the highest HER activity in 1 M KOH,showing an ultra-low overpotential of 16 mV at 10 mA cm^(-2)and a Tafel slope of 33.37 m V dec^(-1).Additionally,the material demonstrated remarkable durability,with only 25 mV of degradation in overpotential after 200 h of stability testing at 10 mA cm^(-2).Density functional theory calculations revealed that the redistribution of charges at the heterojunction interface can optimize the binding energies of H*and OH*and effectively lower the energy barrier of water *** research offers novel perspectives on surpassing the water dissociation threshold of alkaline HER catalysts by means of a systematic design of heterogeneous interfaces.

关键词： Heterostructure Hydrogen evolution reaction Interfacial electron transfer Oxygen vacancies

Characteristics of bioaerosols under high-ozone periods,haze episodes,dust storms,and normal days in Xi'an,China

在线全文

学校读者我要写书评

暂无评论

Particuology 2024年第7期90卷 140-148页

作者： Yiming yang Liu yang Xiaoyan Hu Zhenxing Shen Department of Environmental Science and Engineering Xi’an Jiaotong UniversityXi’an710049China Key Lab of Aerosol Chemistry&Physics SKLLQGInstitute of Earth EnvironmentChinese Academy of SciencesXi’an710049China

The characteristics of bioaerosols and their effects on human beings'health have become a major public concern in the recent *** study compared the characteristics of bioaerosols under different types of pollution(high-ozone[HO]episodes,haze episodes,and dust storms[DSs]),with those of bioaerosols on normal days(NDs)in Xi'an,*** concentrations,diurnal variations,and size distribution of bacteria,fungi,and total airborne microbes(TAMs)were *** results showed that the bacterial and fungal concentrations were the highest during DSs and on NDs,reaching 425.2 and 956.9 colony-forming units/m^(3),*** concentration of TAMs was the highest during HO episodes,reaching 10.7×10^(6)cells/m^(3),which was significantly higher than that during the other *** maximum concentrations of bacteria and fungi during HO episodes were observed in the morning,while they appeared separately in the morning and evening during haze *** and TAMs during DSs reached peak concentrations in the morning and evening,which is opposite to the particulate matter(PM)distribution *** NDs,temperature and relative humidity had significant effects on *** size distributions of airborne bacteria exhibited bimodal patterns,whereas unimodal distributions were observed for *** mainly attached in fine particles(<2.1μm)with proportions of 67.4%and 60.5%during haze episodes and DSs,respectively,which means that fungi were easily penetrated into the human respiratory *** evaluation of influence factors revealed that PM_(2.5) and PM10 had negative effects on fungal concentration during DSs,and ozone concentration and temperature were inversely correlated with fungal concentration during HO *** results provide valuable reference data for elucidating the formation and evolution of bioaerosols under different types of pollution.

关键词： Bacteria Fungi Total airborne microbe Different air pollution types Influence factors

恒电位下活性艳蓝KN-R在活性炭纤维电极上的脱色行为

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

化工学报 2005年第11期56卷 2178-2182页

作者：王斌樊瑞杨卫身杨凤林大连理工大学环境与生命学院环境电化学实验室辽宁大连116024

在恒电位模式下,采用隔膜电解槽,分别以活性炭纤维(ACF)为阳极或阴极,研究了蒽醌染料活性艳蓝KN-R的脱色行为.测量了ACF的线性扫描极化曲线,进行了控电位下活性艳蓝KN-R在ACF电极上的整体电解,考察了脱色率、TOC、CODCr去除率同电极电... 详细信息

在恒电位模式下,采用隔膜电解槽,分别以活性炭纤维(ACF)为阳极或阴极,研究了蒽醌染料活性艳蓝KN-R的脱色行为.测量了ACF的线性扫描极化曲线,进行了控电位下活性艳蓝KN-R在ACF电极上的整体电解,考察了脱色率、TOC、CODCr去除率同电极电位之间的关系.结果表明:该染料在ACF电极上的起始氧化电位和起始还原电位分别为0·5V和-0·7V,氧化峰电位为1·1V;当电位为-0·6~0·4V时,脱色源于染料在ACF上的吸附,极化对吸附行为影响不大;当电位为-1·5^-0·7V时,脱色以染料的电还原为主,反应遵循准一级动力学;当电位为0·5~1·6V时,脱色以染料的电氧化为主,反应同样遵循准一级动力学.

关键词：电极电位活性炭纤维染料脱色电氧化电还原

在线全文

学校读者我要写书评

暂无评论

恒电位下原位电生成活性氯氧化降解蒽醌染料

化工学报 2005年第8期56卷 1552-1558页

作者：杨蕴哲杨卫身杨凤林张兴文大连理工大学环境与生命科学学院沈阳工业大学理学院辽宁沈阳110024

在一个阳极为形稳阳极(DSA)的分隔的流经式电化学反应器中,利用原位电生成活性氯对活性艳蓝KN-R模拟废水进行氧化降解.在恒电位模式下,分别以592nm、255nm波长处的吸光度为主要指标,对该种染料的脱色及其芳环结构的氧化降解进行了对比分... 详细信息

在一个阳极为形稳阳极(DSA)的分隔的流经式电化学反应器中,利用原位电生成活性氯对活性艳蓝KN-R模拟废水进行氧化降解.在恒电位模式下,分别以592nm、255nm波长处的吸光度为主要指标,对该种染料的脱色及其芳环结构的氧化降解进行了对比分析.实验结果表明,在一定实验条件下,经4h的电解,可使染料100%脱色,同时40%左右的染料芳环结构被破坏;阳极电位、氯化钠浓度、染料浓度、电解液pH值对染料的脱色及其芳环结构的氧化降解有较强的影响,而温度和支持电解质浓度影响较小;在整个电氧化过程中,电解液未发生明显的矿化.在本实验条件下,间接电氧化在染料的氧化脱色降解过程中起主导作用,而直接电氧化作用不明显.

关键词：电化学氧化活性氯蒽醌染料恒电位

Input-to-State Stability for Impulsive Switched Singular Systems with Mismatched Disturbances

在线全文

学校读者我要写书评

暂无评论

Journal of Systems Science & Complexity 2024年第3期37卷 924-946页

作者： yang Anqing MA Shuping School of Information Engineering Shandong Management UniversityJinan 250357China School of Mathematics Shandong UniversityJinan 250100China

This work investigates the input-to-state stability(ISS)problem for impulsive switched singular systems(ISSSs)with mismatched *** this paper,‘disturbance’is a general concept that includes model uncertainty,unknown system dynamic,external disturbance,*** modified uncertainty and disturbance estimator(UDE)-based control method is presented for singular systems and ISSSs,a virtual control is introduced to offset the effects of mismatched *** the basis of a discontinuous multiple Lyapunov functional and admissible edge-dependent average dwell time(AED-ADT)method,several sufficient conditions in terms of linear matrix inequalities(LMIs)are obtained to ensure that the closed-loop systems are regular,impulse-free and ***,two examples are given to demonstrate the effectiveness of the proposed results.

关键词： Impulsive switched singular systems input-to-state stability UDE-based control

Development in oxide metallurgy for improving the weldability of high -strength low-alloy steel-Combined deoxidizers and microalloying elements

在线全文

学校读者我要写书评

暂无评论

International Journal of Minerals,Metallurgy and Materials 2024年第6期31卷 1263-1284页

作者： Tingting Li Jian yang State Key Laboratory of Advanced Special Steel School of Materials Science and EngineeringShanghai UniversityShanghai 200444China

The mechanisms of oxide metallurgy include inducing the formation of intragranular acicular ferrite(IAF)using micron-sized inclusions and restricting the growth of prior austenite grains(PAGs)by nanosized particles during *** chaotically oriented IAF and refined PAGs inhibit crack initiation and propagation in the steel,resulting in high impact *** work summarizes the com-bined effect of deoxidizers and alloying elements,with the aim to provide a new perspective for the research and practice related to im-proving the impact toughness of the heat affected zone(HAZ)during the high heat input *** complex deoxidation with other strong deoxidants,such as Mg,Ca,Zr,and rare earth metals(REMs),can improve the toughness of the heat-affected zone(HAZ)by re-fining PAGs or increasing IAF ***,it is difficult to identify the specific phase responsible for IAF nucleation because ef-fective inclusions formed by complex deoxidation are usually *** alloying elements,such as C,Si,Al,Nb,or Cr,con-tents can impair HAZ toughness.A high C content typically increases the number of coarse carbides and decreases the potency of IAF ***,Cr,or Al addition leads to the formation of undesirable *** reduces the high-temperature stability of the ***,V,and B can enhance HAZ ***-containing precipitates present good thermal *** or V(C,N)is ef-fective in promoting IAF nucleation due to its good coherent crystallographic relationship with *** formation of the B-depleted zone around the inclusion promotes IAF *** interactions between alloying elements are complex,and the effect of adding dif-ferent alloying elements remains to be *** the future,the interactions between various alloying elements and their effects on ox-ide metallurgy,as well as the calculation of the nucleation effects of effective inclusions using first principles calculations will become the focus of

关键词： oxide metallurgy technology heat affected zone high-strength low-alloy steel intragranular acicular ferrite microalloying element

Sparse Reconstructive Evidential Clustering for Multi-View Data

在线全文

学校读者我要写书评

暂无评论

IEEE/CAA Journal of Automatica Sinica 2024年第2期11卷 459-473页

作者： Chaoyu Gong yang You School of Computing National University of SingaporeSingapore

Although many multi-view clustering(MVC) algorithms with acceptable performances have been presented, to the best of our knowledge, nearly all of them need to be fed with the correct number of clusters. In addition, these existing algorithms create only the hard and fuzzy partitions for multi-view objects,which are often located in highly-overlapping areas of multi-view feature space. The adoption of hard and fuzzy partition ignores the ambiguity and uncertainty in the assignment of objects, likely leading to performance degradation. To address these issues, we propose a novel sparse reconstructive multi-view evidential clustering algorithm(SRMVEC). Based on a sparse reconstructive procedure, SRMVEC learns a shared affinity matrix across views, and maps multi-view objects to a 2-dimensional humanreadable chart by calculating 2 newly defined mathematical metrics for each object. From this chart, users can detect the number of clusters and select several objects existing in the dataset as cluster centers. Then, SRMVEC derives a credal partition under the framework of evidence theory, improving the fault tolerance of clustering. Ablation studies show the benefits of adopting the sparse reconstructive procedure and evidence theory. Besides,SRMVEC delivers effectiveness on benchmark datasets by outperforming some state-of-the-art methods.

关键词： Evidence theory multi-view clustering(MVC) optimization sparse reconstruction

High-pressure minerals and new lunar mineral changesite-(Y) in Chang’e-5 regolith

在线全文

学校读者我要写书评

暂无评论

Matter and Radiation at Extremes 2024年第2期9卷 90-97页

作者： Jing yang Wei Du Center for Lunar and Planetary Sciences Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China State Key Laboratory of Ore Deposit Geochemistry Institute of GeochemistryChinese Academy of Sciences(CAS)Guiyang 550081China CAS Center for Excellence in Comparative Planetology Hefei 230026China

Forty-five years after the Apollo and Luna missions, China’s Chang’e-5 (CE-5) mission collected ∼1.73 kg of new lunar materials from one ofthe youngest basalt units on the Moon. The CE-5 lunar samples provide opportunities to address some key scientific questions related to theMoon, including the discovery of high-pressure silica polymorphs (seifertite and stishovite) and a new lunar mineral, changesite-(Y). Seifertitewas found to be coexist with stishovite in a silica fragment from CE-5 lunar regolith. This is the first confirmed seifertite in returned lunarsamples. Seifertite has two space group symmetries (Pnc2 and Pbcn) and formed from an α-cristobalite-like phase during “cold” compressionduring a shock event. The aftershock heating process changes some seifertite to stishovite. Thus, this silica fragment records different stagesof an impact process, and the peak shock pressure is estimated to be ∼11 to 40 GPa, which is much lower than the pressure condition forcoexistence of seifertite and stishovite on the phase diagram. Changesite-(Y), with ideal formula (Ca_(8)Y)◻Fe^(2+)(PO_(4))_(7) (where ◻ denotes avacancy) is the first new lunar mineral to be discovered in CE-5 regolith samples. This newly identified phosphate mineral is in the form ofcolumnar crystals and was found in CE-5 basalt fragments. It contains high concentrations of Y and rare earth elements (REE), reaching upto ∼14 wt. % (Y,REE)2O3. The occurrence of changesite-(Y) marks the late-stage fractional crystallization processes of CE-5 basalts combinedwith silicate liquid immiscibility. These new findings demonstrate the significance of studies on high-pressure minerals in lunar materials andthe special nature of lunar magmatic evolution.

关键词： evolution minerals basalt