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尾砂胶结物充填采空区围岩稳定性数值模拟

金属矿山 2012年第7期41卷 19-22页

作者：费鸿禄杨卫风张国辉辽宁工程技术大学爆破技术研究院

矿柱的安全回采及采空区处理直接关系到矿山的可持续发展与人员的安全。以内蒙古某矿区铁锌多金属矿山工程地质为依据,采用超声波测试技术,探测多次爆破下回采巷道围岩损伤累计增长规律,通过尾砂胶结物充填技术,以FLAC3D模拟巷道围岩在... 详细信息

矿柱的安全回采及采空区处理直接关系到矿山的可持续发展与人员的安全。以内蒙古某矿区铁锌多金属矿山工程地质为依据,采用超声波测试技术,探测多次爆破下回采巷道围岩损伤累计增长规律,通过尾砂胶结物充填技术,以FLAC3D模拟巷道围岩在外界荷载作用下的受力情况,主要是应力、应变及变形位移量的分析,对矿山安全回采方面具有较为重要的理论意义和工程应用价值。

关键词：爆破震动弹性模量应力应变矿柱回采

高层住宅中震下受拉墙体型钢配置比较与工程应用研究

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福建建筑 2023年第4期 56-60页

作者：杨伟峰漳州市建设工程施工图咨询审查有限公司福建漳州363000

高层住宅建筑当高宽较大,或所处地区抗震设防烈度较高,底部剪力墙可能会出现较大的拉应力,导致混凝土过早开裂,造成墙肢抗剪能力和抗弯刚度下降。为此,《福建省住宅工程设计若干技术规定》规定,中震下剪力墙拉应力超过混凝土强度抗拉强... 详细信息

高层住宅建筑当高宽较大,或所处地区抗震设防烈度较高,底部剪力墙可能会出现较大的拉应力,导致混凝土过早开裂,造成墙肢抗剪能力和抗弯刚度下降。为此,《福建省住宅工程设计若干技术规定》规定,中震下剪力墙拉应力超过混凝土强度抗拉强度标准值时,必须设置型钢并承担全部拉力。本条要求与《超限高层建筑工程抗震设防专项审查技术要点》的规定一致,但确定型钢面积的方法略有不同。通过公式推导,建立轴拉比和截面含钢率、轴拉比和型钢拉应力最大值的关系曲线,比较这两个文件规定的不同之处,总结一些规律;前者的用钢量虽然较多,但是计算公式更简洁,方便设计。另外,通过一个高层住宅的工程案例,分析了墙肢轴拉比计算、型钢配置的设计流程,并对计算参数、组合墙范围、型钢布置的原则进行说明。

关键词：中震轴拉比名义拉应力截面含钢率组合墙型钢配置

Recent advances in phenazine-linked porous catalysts toward photo/electrocatalytic applications and mechanism

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Green Energy & Environment 2024年第10期9卷 1518-1549页

作者： yang Liu Yu Zhang Zhao-Di yang Liqiang Jing Heilongjiang Provincial Key Laboratory of CO2 Resource Utilization and Energy Catalytic Materials School of Material Science and Chemical EngineeringHarbin University of Science and Technology Institute of Process Engineering Chinese Academy of Sciences Key Laboratory of Functional Inorganic Materials Chemistry(Ministry of Education) School of Chemistry and Materials Science International Joint Research Center for Catalytic Technology Heilongjiang University

In recent years, porous organic catalysts have been developed and become research hotspots in photo/electrocatalysis due to their inherent pores, high specific surface area, chemical and thermal stability, and diverse functional building blocks. Phenazine-linked organic catalysts,exhibited excellent conjugation, electrical conductivity, chemical, and thermal stability, could bring in N atoms with specific numbers and positions to regulate electron levels, anchor metals, and absorb near-infrared light, which expands solar energy utilization. These advantages of the phenazine-linked catalysts attracted our group and numerous researchers to conduct experimental and computational work on photo/electrocatalytic applications and mechanisms. This review summarizes the recent significant research progress, synthesis methods, photo/electrocatalytic performance, and applications of relative phenazine-linked catalysts. Furthermore, the photo/electrocatalytic mechanism was systematized and summarized by combining experiments and density functional theory calculations simultaneously.

关键词： Phenazine-linked porous catalysts Photo/electrocatalytic applications Catalytic mechanism

Phase engineering of Ni-Mn binary layered oxide cathodes for sodiumion batteries

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Journal of Energy Chemistry 2024年第4期91卷 501-511页

作者： Feifei Hong Xin Zhou Xiaohong Liu Guilin Feng Heng Zhang weifeng Fan Bin Zhang Meihua Zuo Wangyan Xing Ping Zhang Hua Yan Wei Xiang College of Materials and Chemistry&Chemical Engineering Chengdu University of TechnologyChengdu 610059SichuanChina College of Chemical Engineering Sichuan UniversityChengdu 610065SichuanChina Research Institute for Electronic Science(RIES)and Division of Information Science and Technology Graduate School of Information Science and TechnologyHokkaido UniversityN20W10SapporoHokkaido 001-0020Japan School of Materials Science and Engineering Suzhou University of Science and TechnologySuzhou 215009JiangsuChina Yibin Libode New Materials Co. Ltd.Yibin 644200SichuanChina Engineering Research Center of the Ministry of Education for Advanced Battery Materials School of Metallurgy and EnvironmentCentral South UniversityChangsha 410083HunanChina

Nickel-manganese binary layered oxides with high working potential and low cost are potential candidates for sodium-ion batteries,but their electrochemical properties are highly related to compositional *** composite materials with various phase structures of P3,P2/P3,P2,P2/O3,and P2/P3/O3 were synthesized by manipulating the sodium content and calcination conditions,leading to the construction of a synthetic phase diagram for Na_(x)Ni_(0.25)Mn_(0.75)O_(2)(0.45≤x≤1.1).Then,we compared the electrochemical characteristics and structural evolution during the desodiation/sodiation process of P2,P2/P3,P2/03,and P2/P3/O3-Na_(x)Ni_(0.25)Mn_(0.75)O_(2).Among them,P2/P3-Na0.75Ni0.25Mn0.75O2exhibits the best rate capability of 90.9 mA h g^(-1)at 5 C,with an initial discharge capacity of 142.62 mA h g^(-1)at 0.1 C and a capacity retention rate of 78.25%after 100 cycles at 1 C in the voltage range of 2-4.3 *** observed superior sodium storage performance of P2/P3 hybrids compared to other composite phases can be attributed to the enhanced Na^(+)transfer dynamic,reduction of the Jahn-teller effect,and improved reaction reversibility induced by the synergistic effect of P2 and P3 *** systematic research and exploration of phases in Na_(x)Ni_(0.25)Mn_(0.75)O_(2)provide new sights into high-performance nickel-manganese binary layered oxide for sodium-ion batteries.

关键词： Phase engineering Ni-Mn layered oxide Cathode Sodium-ion batteries

Evolutionary dynamics of tax-based strong altruistic reward andpunishment in a public goods game

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Chinese Physics B 2024年第9期33卷 247-257页

作者： Zhi-Hao yang Yan-Long yang Mathematics and Statistics School Guizhou UniversityGuiyang 550025China

In public goods games, punishments and rewards have been shown to be effective mechanisms for maintaining individualcooperation. However, punishments and rewards are costly to incentivize cooperation. Therefore, the generation ofcostly penalties and rewards has been a complex problem in promoting the development of cooperation. In real society,specialized institutions exist to punish evil people or reward good people by collecting taxes. We propose a strong altruisticpunishment or reward strategy in the public goods game through this phenomenon. Through theoretical analysis and numericalcalculation, we can get that tax-based strong altruistic punishment (reward) has more evolutionary advantages thantraditional strong altruistic punishment (reward) in maintaining cooperation and tax-based strong altruistic reward leads toa higher level of cooperation than tax-based strong altruistic punishment.

关键词： evolutionary game theory strong altruism punishment reward

A novel Bayesian-based INS/GNSS integrated positioning method with both adaptability and robustness in urban environments

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Chinese Journal of Aeronautics 2024年第6期37卷 205-218页

作者： Zhe yang Hongbo ZHAO School of Electronics and Information Engineering Beihang UniversityBeijing 100191China

Achieving higher accuracy positioning results in urban environments at a lower cost has been an important pursuit in areas such as autonomous driving and intelligent *** Inertial Navigation System and Global Navigation Satellite System(INS/GNSS)integrated navigation systems have been an important means of fulfilling the above quest due to the complementary error characteristics between INS and *** complex urban driving environment requires the system sufficiently adaptive to keep up with the time-varying measurement noise and sufficiently robust to cope with measurement outliers and prior ***,many efforts lack a balance between adaptability and *** this paper,a novel positioning method with both adaptability and robustness is proposed by coupling the Mahalanobis distance method,the Variational Bayesian method and the student’s t-distribution in one process(M-VBt method).This method is robust against non-Gaussian noise and priori uncertainties,plus adaptive against measurement noise uncertainty and time-varying *** field test results show that the M-VBt method(especially the Mahalanobis distance part)has significantly improved the system performance in the complex urban driving environment.

关键词： Urban environments Mahalanobis distance Adaptability Robustness Integrated navigation

Composition Engineering Opens an Avenue Toward Efficient and Sustainable Nitrogen Fixation

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Energy & Environmental Materials 2024年第1期7卷 313-325页

作者： Xiaolin Wang Liming yang Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationWuhan 430074China Hubei Key Laboratory of Materials Chemistry and Service Failure Wuhan 430074China Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica Wuhan 430074China Hubei Engineering Research Center for Biomaterials and Medical Protective Materials Wuhan 430074China School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074China

In this work,we open an avenue toward rational design of potential efficient catalysts for sustainable ammonia synthesis through composition engineering strategy by exploiting the synergistic effects among the active sites as exemplified by diatomic metals anchored graphdiyne via the combination of hierarchical high-throughput screening,first-principles calculations,and molecular dynamics *** 43 highly efficient catalysts feature ultralow onset potentials(|U_(onset)|≤0.40 V)with Rh-Hf and Rh-Ta showing negligible onset potentials of 0 and-0.04 V,*** high catalytic activities of Rh-Hf and Rh-Ta can be ascribed to the synergistic *** forming heteronuclears,the combinations of relatively weak(such as Rh)and relatively strong(such as Hf or Ta)components usually lead to the optimal strengths of adsorption Gibbs free energies of reaction *** origin can be ascribed to the mediate d-band centers of Rh-Hf and Rh-Ta,which lead to the optimal adsorption strengths of intermediates,thereby bringing the high catalytic *** work provides a new and general strategy toward the architecture of highly efficient catalysts not only for electrocatalytic nitrogen reduction reaction(eNRR)but also for other important *** expect that our work will boost both experimental and theoretical efforts in this direction.

关键词： composition engineering strategy diatomic catalysts electrocatalytic nitrogen reduction reaction first-principles calculations graphdiyne hierarchical high-throughput screening synergistic effects

Development in oxide metallurgy for improving the weldability of high -strength low-alloy steel-Combined deoxidizers and microalloying elements

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International Journal of Minerals,Metallurgy and Materials 2024年第6期31卷 1263-1284页

作者： Tingting Li Jian yang State Key Laboratory of Advanced Special Steel School of Materials Science and EngineeringShanghai UniversityShanghai 200444China

The mechanisms of oxide metallurgy include inducing the formation of intragranular acicular ferrite(IAF)using micron-sized inclusions and restricting the growth of prior austenite grains(PAGs)by nanosized particles during *** chaotically oriented IAF and refined PAGs inhibit crack initiation and propagation in the steel,resulting in high impact *** work summarizes the com-bined effect of deoxidizers and alloying elements,with the aim to provide a new perspective for the research and practice related to im-proving the impact toughness of the heat affected zone(HAZ)during the high heat input *** complex deoxidation with other strong deoxidants,such as Mg,Ca,Zr,and rare earth metals(REMs),can improve the toughness of the heat-affected zone(HAZ)by re-fining PAGs or increasing IAF ***,it is difficult to identify the specific phase responsible for IAF nucleation because ef-fective inclusions formed by complex deoxidation are usually *** alloying elements,such as C,Si,Al,Nb,or Cr,con-tents can impair HAZ toughness.A high C content typically increases the number of coarse carbides and decreases the potency of IAF ***,Cr,or Al addition leads to the formation of undesirable *** reduces the high-temperature stability of the ***,V,and B can enhance HAZ ***-containing precipitates present good thermal *** or V(C,N)is ef-fective in promoting IAF nucleation due to its good coherent crystallographic relationship with *** formation of the B-depleted zone around the inclusion promotes IAF *** interactions between alloying elements are complex,and the effect of adding dif-ferent alloying elements remains to be *** the future,the interactions between various alloying elements and their effects on ox-ide metallurgy,as well as the calculation of the nucleation effects of effective inclusions using first principles calculations will become the focus of

关键词： oxide metallurgy technology heat affected zone high-strength low-alloy steel intragranular acicular ferrite microalloying element

An organic free radical generator independent on hydrogen peroxide for chemodynamic and immunotherapy in vivo

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Journal of Materials Science & Technology 2024年第7期174卷 85-94页

作者： yang Chen Yunpeng Song Chaojie Tang Hong yang Wu Wang Shiping yang Zhiguo Zhou College of Chemistry and Materials Science International Joint Laboratory on Resource Chemistry of Ministry EducationShanghai Frontiers Science Center of Biomimetic CatalysisShanghai Normal UniversityShanghai 200234China Institute of Diagnostic and Interventional Radiology Shanghai Jiao Tong University Affiliated Sixth People’s HospitalShanghai 200233China

It is desirable to develop a free radical generator that is neither dependent on hydrogen peroxide nor external stimuli-triggered to achieve effective tumor ***,the free radical genera-tor MNPs-mCPBA was constructed with Zn_(0.4)Co_(0.6)F_(e2)O_(4)@Zn_(0.4)Mn_(0.6)Fe_(2)O_(4)nanoparticles(MNPs)and 3-chloroperbenzoic acid(mCPBA).We believe that the iron(Ⅱ)on the surface of MNPs-mCPBA maybe represent high reactive activity and promote the generation of a large number of organic free radicals(C_(6)H_(4)ClCOOO)in an acidic tumor microenvironment,which realizes the acid-dependent tumor treat-ment strategy independent on the H_(2)O_(2)level in *** addition,the generated organic free radicals(C_(6)H_(4)ClCOOO)effectively induced immunogenic cell death(ICD)and increased T cell ***-der the synergetic treatment with an anti-PD-L1 antibody(α-PD-L1),a favorable anti-tumor effect was achieved.

关键词： Organic free radicals Immunogenic cell death Immunotherapy Chemodynamic therapy