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Bio-Based Waterborne Poly(Vanillin-Butyl Acrylate)/MXene Coatings for Leather with Desired Warmth Retention and Antibacterial Properties

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engineering 2024年第5期36卷 250-263页

作者： jianzhong Ma Li Ma lei zhang Wenbo zhang Qianqian Fan Buxing Han College of Bioresources Chemical and Materials engineering Shaanxi University of Science and TechnologyXi’an 710021China Xi’an key Laboratory of Green Chemicals and Functional Materials Xi’an 710021China College of Chemistry and Chemical engineering Shaanxi University of Science and TechnologyXi’an 710021China Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology Shaanxi University of Science and TechnologyXi’an 710021China institute of Chemistry Chinese Academy of SciencesBeijing 100190China

This study presents a solvent-free,facile synthesis of a bio-based green antibacterial agent and aromatic monomer methacrylated vanillin(MV)using *** resulting MV not only imparted antibacterial properties to coatings layered on leather,but could also be employed as a green alternative to petroleum-based carcinogen styrene(St).Herein,MV was copolymerized with butyl acrylate(BA)to obtain waterborne bio-based P(MV-BA)miniemulsion via miniemulsion ***,MXene nanosheets with excellent photothermal conversion performance and antibacterial properties,were introduced into the P(MV-BA)miniemulsion by ultrasonic *** the gradual solidification of P(MV-BA)/MXene nanocomposite miniemulsion on the leather surface,MXene gradually migrated to the surface of leather coatings due to the cavitation effect of ultrasonication and amphiphilicity of MXene,which prompted its full exposure to light and bacteria,exerting the maximum photothermal conversion efficiency and significant antibacterial *** particular,when the dosage of MXene nanosheets was 1.4 wt%,the surface temperature of P(MV-BA)/MXene nanocomposite miniemulsioncoated leather(PML)increased by about 15℃ in an outdoor environment during winter,and the antibacterial rate against Escherichia coli and Staphylococcus aureus was nearly 100%under the simulated sunlight treatment for 3. ***,the introduction of MXene nanosheets increased the air permeability,water vapor permeability,and thermal stability of these *** study provides a new insight into the preparation of novel,green,and waterborne bio-based nanocomposite coatings for leather,with desired warmth retention and antibacterial *** can not only realize zerocarbon heating based on sunlight in winter,reducing the use of fossil fuels and greenhouse gas emissions,but also improve ability to fight off invasion by harmful bacteria,viruses,and other microorganisms.

关键词： MXene nanosheets Vanillin Styrene substitute Leather coating Photothermal conversion Warmth retention Antibacterial properties

Facile Surface engineering of NiCo_(2)O_(4) to Boost Propane Oxidation Activity

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China Petroleum Processing & Petrochemical Technology 2024年第1期26卷 19-26页

作者： yang Jialei Wang Fengyi lei yang zhang Mingchao Sun Shiqiang xu Wenfan ke Jiaxiang Wu Haojie Li Xingyun Qi Jian institute of Materials for Energy and Environment College of Materials Science and EngineeringQingdao UniversityQingdao 266071China School of Chemistry and Chemical engineering Hubei Key Laboratory of Coal Conversion and New Carbon MaterialsWuhan University of Science and TechnologyWuhan 430081China Department of Burn and Plastic Surgery Qingdao Municipal Hospital Affiliated to Rehabilitation UniversityQingdao 266000China State key Laboratory of Biochemical engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China

Spinel oxide(NiCo_(2)O_(4))has demonstrated great potential to replace noble metal catalysts for the oxidation reaction of air *** further boost the oxidation ability of such catalysts,in this study,a facile surface-engineering strategy wherein NiCo_(2)O_(4) was treated with different alkali solvents was *** obtained catalyst(NiCo_(2)O_(4)-OH)showed a higher surface alkalinity and more surface defects compared to the pristine spinel oxide,including enhanced structural distortion as well as promoted oxygen *** propane oxidation ability of NiCo_(2)O_(4)-OH was greatly enhanced,with a propane conversion rate that was approximately 6.4 times higher than that of pristine NiCo_(2)O_(4) at a reaction temperature 193..This work sets a valuable paradigm for the surface modulation of spinel oxide via alkali treatment to ensure a high-performance oxidation catalyst.

关键词： NiCo_(2)O_(4) surface defects alkali treatment propane oxidation

Effect of internal bubbly flow on pipe vibrations

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Science China(Technological sciences) 2010年第2期53卷 423-428页

作者： zhang MingMing & xu jianzhong {3. of {3. thermophysics, chinese academy of sciences, beijing 100190, China 1. institute of engineering thermophysics Chinese Academy of Sciences Beijing 100190 China

This paper presents an experimental investigation on wall vibrations of a pipe due to injection of a uniform bubble cloud into the pipe flow. For different bubble void fractions and averaged bubble sizes, the vibrations were measured using accelerometers. To understand the underlying physics, the evolution of the vibration spectra along the streamwise direction was examined. Results showed that wall vibrations were greatly enhanced up to 25 dB, compared with no bubble case. The characteristics of the vibration were mainly dependent on void fraction. These vibrations were believed to be caused by two mechanisms: acoustic resonance and normal modes of the bubble cloud. The former, originating from the interaction between the first mode of the bubble cloud and the first acoustic mode of the pipe, persisted along the entire pipe to enhance the vibration over a broad band frequency range, while the later, due to the process of bubble formation, successively decayed in the streamwise direction.

关键词： pipe vibration bubbly flow acoustic resonance normal mode decay rate

Bionic lightweight design of limb leg units for hydraulic quadruped robots by additive manufacturing and topology optimization

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Bio-Design and Manufacturing 2024年第1期7卷 1-13页

作者： Huaizhi Zong Junhui zhang lei Jiang Kun zhang Jun Shen Zhenyu Lu {3. Wang Yanli Wang Bing xu The State key Laboratory of Fluid Power and Mechatronic Systems Zhejiang UniversityHangzhou 310058China Unmanned Vehicle Research and Development Center China North Vehicle Research InstituteBeijing 100072China School of Mechatronic engineering Nanchang UniversityNanchang 330031China Auclean High-Tech Ltd. Wuxi 214108China

Galloping cheetahs,climbing mountain goats,and load hauling horses all show desirable locomotion capability,which motivates the development of quadruped *** various quadruped robots,hydraulically driven quadruped robots show great potential in unstructured environments due to their discrete landing positions and large *** the most critical movement unit of a quadruped robot,the limb leg unit(LLU)directly affects movement speed and reliability,and requires a compact and lightweight *** by the dexterous skeleton–muscle systems of cheetahs and humans,this paper proposes a highly integrated bionic actuator system for a better dynamic performance of an *** propose that a cylinder barrel with multiple element interfaces and internal smooth channels is realized using metal additive manufacturing,and hybrid lattice structures are introduced into the lightweight design of the piston *** addition,additive manufacturing and topology optimization are incorporated to reduce the redundant material of the structural parts of the *** mechanical properties of the actuator system are verified by numerical simulation and experiments,and the power density of the actuators is far greater than that of cheetah *** mass of the optimized LLU is reduced by 24.5%,and the optimized LLU shows better response time performance when given a step signal,and presents a good trajectory tracking ability with the increase in motion frequency.

关键词： Additive manufacturing Bionic lightweight design Limb leg unit Quadruped robot Trajectory tracking

Influence factors of sparse microwave imaging radar system performance:approaches to waveform design and platform motion analysis

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Science China(Information sciences) 2012年第10期55卷 2301-2317页

作者： zhang Zhe 1,2,3.zhang BingChen 1,2,JIANG ChengLong 1,2,3.XIANG Yin 1,2,HONG Wen 1,2 & WU YiRong 1,2 1 Science and Technology on Microwave Imaging Laboratory,beijing 100190,China 2 {3. of Electronics,chinese academy of sciences,beijing 100190,China 3.Graduate University,chinese academy of sciences,beijing 100190,China 1. Science and Technology on Microwave Imaging Laboratory Beijing 100190 China 2. institute of Electronics Chinese Academy of Sciences Beijing 100190 China 3. Graduate University Chinese Academy of Sciences Beijing 100190 China

Sparse microwave imaging radar is a newly developed concept of microwave imaging system,which tries to combine the traditional radar imaging system with sparse signal processing theories,achieving the aim of reducing the complexity of microwave imaging systems and enhancing the system *** this paper,we introduce some basic concepts of sparse signal processing theory,and then apply it to the traditional radar imaging system to get the mathematical model of sparse microwave imaging *** analyze the factors that determine the performance of sparse microwave imaging radar,including scene,waveform and *** to the radar model,we analyze how these factors influence the radar system and how to optimize *** results of the sparse microwave imaging radar system are also provided.

关键词： sparse microwave imaging radar synthetic aperture radar compressive sensing Lq regularization waveform design

A new principle of synthetic cascade utilization of chemical energy and physical energy

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Science China(Technological sciences) 2005年第2期48卷 163-179页

作者： JIN Hongguang1, HONG Hui1,2, WANG Baoqun1,2, HAN Wei1,2 & LIN Rumou1,2 1. institute of engineering thermophysics, {3., beijing 100080, China 2. Graduate School of the {3., beijing 10003., China 1. institute of engineering thermophysics Chinese Academy of Sciences 100080 Beijing China 2. Graduate School of the chinese academy of sciences 100039 Beijing China

We propose a new principle of the cascade utilization of both chemical energy and physical energy in energy systems with the integration of chemical processes and thermal cycles. Particularly, a general equation of energy levels of substance, Gibbs free energy of chemical reaction and physical energy is explicitly founded. On the basis of this equation, a chemical-looping combustion and an indirect combustion are investigated. Furthermore, a mechanism of energy release, with the combination of decreasing the energy level of Gibbs free energy and upgrading the energy level of low or middle- temperature thermal energy, is clarified. The promising results obtained here establish a theoretical basis for the further investigation of multi-function systems in which energy and the environment are compatible, and create a new approach to improve the performance of traditional thermal cycles.

关键词： chemical energy, cascade utilization, exergy, energy conversion.

Possible Energy Network with polygeneration system and CCS for China

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中国科学：技术科学英文版 2010年第1期53卷 33-39页

作者： GAO Lin1,LI Sheng1,2,JIN HongGuang1 & LIN Hu1 1 institute of engineering thermophysics,{3.,beijing 100190,China 2 Graduate School of {3.,beijing 10003.,China 1. institute of engineering thermophysics Chinese Academy of Sciences Beijing 100190 China2. Graduate School of Chinese Academy of Sciences Beijing 100039 China

On basis of adopting polygeneration systems for power and alternative fuels,capturing CO2 with near zero energy penalties,and storing CO2 on sites,a new kind of Energy Network can integrate energy utilization,CO2 capture,transportation and storage ***-economic analysis of this solution focusing on Inner Mongolia and the yangtze River Delta districts had been carried with comparison to the chain method for energy utilization and CO2 *** solution can save 21.5% of energy,and reduce 3.% of total *** adoption of advanced polygeneration systems contributes 52.2% of the total saved costs,and the integration of energy utilization and CO2 sequestration in the Energy Network contributes 47.8%.From the aspect of CCS,the CO2 sequestration cost in the Energy Network can be as low as 12 $/t due to the lower energy penalties of capture in polygeneration systems and the combination of CO2 source and *** Energy Network exhibits attractive performance on energy saving,costs reduction for CCS,which may be a promising solution for sustainable development of China.

关键词： CO2 capture and storage Energy Network polygeneration system

Latest Scientific Results of China's Lunar and Deep Space Exploration(2022–2024)

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空间科学学报 2024年第4期44卷 622-632页

作者： xu Lin LI lei LIU jianzhong LIN Honglei LI yang LIU yang XIE Lianghai {3. Jinhai QIAO Fuhao HAN Juanjuan ZOU Yongliao General Office of the Lunar and Deep Space Exploration Chinese Academy of SciencesBeijng 100190 State key Laboratory of Space Weather National Space Science CenterChinese Academy of SciencesBeijing 100190 institute of Geochemistry Chinese Academy of SciencesGuiyang 550081 institute of Geology and Geophysics Chinese Academy of SciencesBeijing 100029

China has successfully launched six lunar probes so *** Chang'E-1 to Chang'E-4,they completed the circling,landing and roving exploration,of which Chang'E-4 was the first landing on the far side of the Moon in human ***'E-5 was launched in December 2020,bringing back 173. g of lunar soil *** the detailed analysis of the samples,the scientists understand the history of late lunar volcanism,specifically extending lunar volcanism by about 800 million to 1 billion years,and proposed possible *** addition,there are many new understandings of space weathering such as meteorite impacts and solar wind radiation on the ***'s first Mars exploration mission Tianwen-1 was successfully launched in July *** the study of scientific data,a number of important scientific achievements have been made in the topography,water environment and shallow surface structure of *** paper introduces the main scientific achievements of Chang'E-4,Chang'E-5 and Tianwen-1 in the past two years,excluding technical and engineering *** to the large number of articles involved,this paper only introduces part of the results.

关键词： Lunar and deep space exploration of China Chang’E-4 mission Chang’E-5 mission Tianwen-1 mission

Dynamics of morphological changes for mitochondrial fission and fusion

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Science China(Physics,Mechanics & Astronomy) 2010年第4期53卷 680-689页

作者： WANG ShiQi 1,2,4 , FU ChangLiang 1,2 , zhang Yan 1,2 , CHEN Quan 3.& LONG Mian 1,2 1 key Laboratory of Microgravity (National Microgravity Laboratory), {3., China 2 Center for Biomechanics and Bioengineering, {3. of Mechanics, chinese academy of sciences, {3., China 3.State key Laboratory of Biomembrane and Membrane Biotechnology, {3. of Zoology, chinese academy of sciences, beijing 100101, China 4 {3. of Vertebrate Paleontology and Paleoanthropology, chinese academy of sciences, beijing 100044, China 1. key Laboratory of Microgravity (National Microgravity Laboratory) Beijing 100190 China2. Center for Biomechanics and Bioengineering Institute of Mechanics Chinese Academy of Sciences Beijing 100190 China4. Institute of Vertebrate Paleontology and Paleoanthropology Chinese Academy of Sciences Beijing 100044 China3. State Key Laboratory of Biomembrane and Membrane Biotechnology Institute of Zoology Chinese Academy of Sciences Beijing 100101 China

Mitochondria experience continuous fusion and fission in a living cell, but their dynamics remains poorly quantified. Here a theoretical model was developed, upon a simplified population balance equation (PBE), to predict the morphological changes induced by mitochondrial fission and fusion. Assuming that both fission and fusion events are statistically independent, the survival probability of mitochondria staying in the fission or fusion state was formulated as an exponentially-decayed function with time, which depended on the time-dependent distribution of the mitochondrial volume and the fission and fusion rates. Parametric analysis was done for two typical volume distributions. One was Gamma distribution and the other was Gaussian distribution, derived from the measurements of volume distribution for individual mitochondria in a living cell and purified mitochondria in vitro. The predictions indicated that the survival probability strongly depended on morphological changes of individual mitochondria and was inversely correlated to the fission and fusion rates. This work provided a new insight into quantifying the mitochondrial dynamics via monitoring the evolution of the mitochondrial volume.

关键词： mitochondria morphology fission fusion dynamics modeling