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Realizing the excellent oxidation resistance of an environmental barrier coating through aluminum surface modification

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Journal of Advanced Ceramics 2024年第7期13卷 976-986页

作者： lin Dong Wen-Qi yang lin Chen guan-jun yang chang-jiu li State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi’an Jiaotong UniversityXi’an 710049China Xi’an Aerospace Engine Company limited in China Aerospace Science and Technology Corporation Xi’an 710065China

The lifetime of Si-based environmental barrier coatings(EBCs)is constrained by thermally grown SiO_(2)oxidelayer(SiO_(2)-TGO),which can cause premature cracking and *** address this issue,a new approach for surfacemodification using aluminum is *** oxidation performance was examined in a 50 vol%H_(2)O-50 vol%O_(2)environment at 1350℃for up to 300 *** results indicate that a dense ytterbium aluminum garnet(YbAG)layer wasformed after modification,decreasing the porosity by 80%.Due to the elimination of fast diffusion channels and the lowoxygen permeability of YbAG,aluminum modification significantly reduced the growth rate of SiO_(2)-TGO by nearly twoorders of ***,its thickness decreased by more than 70%after 300 h of exposure.A diffusioncontrolled oxidation mechanism indicates that the modified dense surface is equivalent to an initial SiO_(2)layer with a specificthickness,causing a shift in the oxidation time and increasing the oxidation *** research provides valuableinsights for designing Si-based EBC with improved lifetimes.

关键词： environmental barrier coating(EBC) oxidation modification diffusion cracking

Durable dual-state duplex Si-HfO_(2)with excellent oxidation and cracking resistance

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Journal of Advanced Ceramics 2024年第3期13卷 388-401页

作者： lin Chen Jing-Chuan Luo Wen-Qi yang chang-jiu li guan-jun yang State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi’an Jiaotong UniversityXi’an 710049China Xi’an Aerospace Engine Company limited in CASC Xi’an 710065China

The lifetime of Si bond coatings in environmental barrier coatings is constrained by phase-transition-induced cracking of the SiO_(2)*** this study,Si-HfO_(2)dual-state duplex composite materials are proposed to address this issue by partially forming HfSiO_(4)and minimizing the SiO_(2)*** as-prepared composite exhibited a structure comprising discrete HfO_(2)“bricks”embedded in a continuous Si“mortar”,while the oxidized state transformed into discrete HfSiO_(4)“bricks”within continuous thin SiO_(2)“mortars”.The results indicate that continuous thin SiO_(2)contributes to reducing the oxidation rate to a level comparable to that of pure Si,and discrete HfSiO_(4)particles aid in relieving phase transition-induced stress and inhibiting crack propagation,thereby enhancing oxidation and cracking resistance ***,the composite with 20 mol%HfO_(2)and a mean particle size of~500 nm at 1370℃exhibited a service lifetime 10 times greater than that of pure *** research provides valuable insights for designing Si-based bond coatings with improved service lifetime.

关键词： oxidation environmental barrier coatings(EBCs) phase transition cracking bond coatings

Colorectal cancer’s burden attributable to a diet high in processed meat in the Belt and Road Initiative countries

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World Journal of Gastrointestinal Oncology 2024年第1期16卷 182-196页

作者： Gu liu chang-Min li Fei Xie Qi-Lai li liang-Yan liao Wen-jun Jiang Xiao-Pan li guan-Ming Lu Department of Gastrointestinal Surgery The First Affiliated HospitalJinan UniversityGuangzhou 510630Guangdong ProvinceChina Department of Gastrointestinal Surgery Chenzhou Third People’s HospitalChenzhou 423000Hunan ProvinceChina Department of Gastrointestinal Surgery Chenzhou First People’s Hospital and the First Affiliated Hospital of Xiangnan UniversityChenzhou423000 Hunan ProvinceChina Department of Breast and Thyroid Surgery the Affiliated Hospital of Youjiang Medical University for NationalitiesBaise 533000Guangxi Zhuang Autonomous RegionChina Department of Health Management Center Zhongshan HospitalShanghai Medical College of Fudan UniversityShanghai 200032China

BACKGROUND Colorectal cancer(CRC)plays a significant role in morbidity,mortality,and economic cost in the Belt and Road Initiative(“B and R”)*** addition,these countries have a substantial consumption of processed ***,the burden and trend of CRC in relation to the consumption of a diet high in processed meat(DHPM-CRC)in these“B and R”countries remain *** To analyze the burden and trend of DHPM-CRC in the“B and R”countries from 1990 to *** We used the 2019 Global Burden of Disease Study to collate information regarding the burden of *** and age-standardized rates(ASRs)of deaths along with the disability-adjusted life years(DALYs)were determined among the“B and R”countries in 1990 and *** joinpoint regression analysis,the average annual percent change(AAPC)was used to analyze the temporal trends of age-standardized DALYs rate(ASDALR)from 1990 to 2019 and in the final decade(2010–2019).RESULTS We found geographical differences in the burden of DHPM-CRC among“B and R”countries,with the three highest-ranking countries being the Russian Federation,China,and Ukraine in 1990,and China,the Russian Federation,and Poland in *** burden of DHPM-CRC generally increased in most member countries from 1990 to 2019(all Pline was observed in Kyrgyzstan,Central Asia,with an AAPC value of-2.05%(95%CI:-2.37%to-1.73%).A substantial upward trend in ASR of mortality,years lived with disability,years of life lost,and DALYs from DHPM-CRC changes in 1990-2019 and the final de

关键词： Belt and Road Initiative countries Colorectal cancer Burden of disease Dietary risk factors Processed meat Disability-adjusted life years Trend analysis

Effect of flame conditions on abrasive wear performance of HVOF sprayed nanostructured WC-12Co coatings

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中国有色金属学会会刊：英文版 2004年第Z1期14卷 72-76页

作者： wang yu-yue li chang-jiu MA Jian yang guan-jun State Key Laboratory for Mechanical Behavior of Materials Xi''an Jiaotong University Xi''an 710049 China State Key Laboratory for Mechanical Behavior of MaterialsXi''an Jiaotong University Xi''an 710049 China State Key Laboratory for Mechanical Behavior of MaterialsXi''an Jiaotong University Xi''an 710049 China State Key Laboratory for Mechanical Behavior of MaterialsXi''an Jiaotong University Xi''an 710049 China

Nanostructured WC-12Co coatings were deposited by high velocity oxy-fuel (HVOF) spraying with an agglomerated powder. The effect of flame conditions on the microstructure of the nanostructured coatings was investigated. The wear properties of the coatings were characterized using a dry rubber-wheel wear test. The results show that the nanostructured WC-Co coatings consist of WC, W2C, W and an amorphous binder phase. The microstructure of the coating is significantly influenced by the ratio of oxygen flow to fuel flow. Under the lower ratio of oxygen/fuel flow, the nanostructured coating presents a relative dense microstructure and severe decarburization of WC phase occurs during spraying. With increasing ratio of oxygen/fuel flow, the bonding of WC particles in the coating becomes loose resulting from the original structure of feedstock and the decarburization of WC becomes less owing to limited heating to the powder. Both the decarburization of WC particles in spraying and the bonding among WC particles in the coatings affect the wear performance. The examination of the worn surfaces of the nanostructured coatings reveals that the dominant wear mechanisms would be spalling from the interface of WCCo splats when spray particles undergo a limited melting. While the melting state of the spray particles is improved,the dominant wear mechanisms become the plastic deformation and plowing of the matrix and spalling of WC particles from the matrix.

关键词： high velocity oxy-fuel spraying nanostructure abrasive wear performance WC-Co coating

Improving WC-Co coating adhesive strength on rough substrate:Finite element modeling and experiment

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Journal of Materials Science & Technology 2020年第2期37卷 1-8页

作者： Adnan Tahir guang-Rong li Mei-jun liu guan-jun yang Cheng-Xin li yu-yue wang chang-jiu li State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi’an Jiaotong UniversityXi’an710049China

The adhesive strength in a coating-substrate system is of primary importance for the coating lifetime in ***,the underlying mechanism is not fully understood due to the complex internal structure of composite *** this study,the effect of substrate roughness on the adhesive strength of WCCo coatings was investigated by experiment and *** show that the adhesive strength is significantly affected by the *** the case of the Rachanged from concentrated state to widespread state,which decreases the critical stress to result in crack ***’s why a larger roughness can cause a higher adhesive *** study gives understanding on the mechanism of adhesive strength affected by roughness,which contributes to the parameter optimization with better performance.

关键词： Adhesive strength Roughness lifetime Simulation XFEM Residual stress

The Chinese Society of Clinical Oncology (CSCO): Clinical guidelines for the diagnosis and treatment of gastric cancer, 2023

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Cancer Communications 2024年第1期44卷 127-172页

作者： Feng-Hua wang Xiao-Tian Zhang Lei Tang Qi Wu Mu-Yan Cai yuan-Fang li Xiu-Juan Qu Hong Qiu yu-Jing Zhang Jie-Er Ying jun Zhang ling-yu Sun Rong-Bo lin chang wang Hao liu Miao-Zhen Qiu Wen-Long guan Sheng-Xiang Rao Jia-Fu Ji Yan Xin Wei-Qi Sheng Hui-Mian Xu Zhi-Wei Zhou Ai-Ping Zhou Jing Jin Xiang-lin yuan Feng Bi Tian-Shu liu Han liang Yan-Qiao Zhang Guo-Xin li jun liang Bao-Rui liu lin Shen Jin li Rui-Hua Xu Department of Medical Oncology Sun Yat-sen University Cancer CenterState Key Laboratory of Oncology in South ChinaCollaborative Innovation Center for Cancer MedicineGuangzhouGuangdongP.R.China Department of Gastrointestinal Oncology Key Laboratory of Carcinogenesis and Translational Research(Ministry of Education)Peking University Cancer HospitalBeijingP.R.China Department of Radiology Peking University Cancer HospitalBeijingP.R.China Department of Endoscopy Center Peking University Cancer HospitalBeijingP.R.China Department of Pathology Sun Yat-sen University Cancer CenterState Key Laboratory of Oncology in South ChinaCollaborative Innovation Center of Cancer MedicineGuangzhouGuangdongP.R.China Department of Gastric Surgery Sun Yat-sen University Cancer CenterState Key Laboratory of Oncology in South ChinaCollaborative Innovation Center for Cancer MedicineGuangzhouGuangdongP.R.China Department of Medical Oncology The First Hospital of China Medical UniversityShenyangLiaoningP.R.China Department of Medical Oncology Tongji Hospital Affiliated to Tongji Medical College of Huazhong University of Science and TechnologyWuhanHubeiP.R.China Department of Radiotherapy Sun Yat-sen University Cancer CenterState Key Laboratory of Oncology in South ChinaCollaborative Innovation Center for Cancer MedicineGuangzhouGuangdongP.R.China Department of Medical Oncology Zhejiang Cancer HospitalHangzhouZhejiangP.R.China Department of Medical Oncology Ruijin HospitalShanghai Jiaotong University School of MedicineShanghaiP.R.China Department of Surgical Oncology The Fourth Affiliated Hospital of Harbin Medical UniversityHarbinHeilongjiangP.R.China Department of Medical Oncology Fujian Cancer HospitalFuzhouFujianP.R.China Tumor Center The First Hospital of Jilin UniversityChangchunJilinP.R.China Department of General Surgery Nanfang HospitalSouthern Medical UniversityGuangzhouGuangdongP.R.China Department of Radiology Zhongshan HospitalFudan UniversityShanghaiP.R.China Department of

The 2023 update of the Chinese Society of Clinical Oncology(CSCO)Clini-cal Guidelines for Gastric Cancer focuses on standardizing cancer diagnosis and treatment in China,reflecting the latest advancements in evidence-based medicine,healthcare resource availability,and precision *** updates address the differences in epidemiological characteristics,clinicopatho-logical features,tumor biology,treatment patterns,and drug selections between Eastern and Western gastric cancer *** revisions include a structured template for imaging diagnosis reports,updated standards for molecular marker testing in pathological diagnosis,and an elevated recommendation for neoadju-vant chemotherapy in stage III gastric *** advanced metastatic gastric cancer,the guidelines introduce new recommendations for immunotherapy,anti-angiogenic therapy and targeted drugs,along with updated management strategies for human epidermal growth factor receptor 2(HER2)-positive and deficient DNA mismatch repair(dMMR)/microsatellite instability-high(MSI-H)***,the guidelines offer detailed screening recommendations for hereditary gastric cancer and an appendix listing drug treatment regimens for various stages of gastric *** 2023 CSCO Clinical Guidelines for Gastric Cancer updates are based on both Chinese and international clinical research and expert consensus to enhance their applicability and relevance in clinical practice,particularly in the heterogeneous healthcare landscape of China,while maintaining a commitment to scientific rigor,impartiality,and timely revisions.

关键词： Chinese Society of Clinical Oncology(CSCO) gastric cancer diagnosis surgery neoadjuvant adjuvant radiotherapy chemotherapy targeted therapy immunotherapy

Critical scale grain size for optimal lifetime of TBCs

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Journal of Materials Science & Technology 2022年第20期115卷 241-250页

作者： lin Chen Guo-Hui Meng chang-jiu li guan-jun yang State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi’an Jiaotong UniversityXi’an 710049China

Thermal barrier coatings(TBCs)suffer from spalling failure resulting from the rapid growth of thermally grown oxides(TGO)on the metallic bond *** this study,to achieve the optimal lifetime of TBCs,a lifetime phase diagram was constructed for the entire service of ***,both the thermal mismatch stress during thermal cycling and the TGO growth stress during thermal exposure were ***,thickening behavior of the Al_(2)O_(3) scale related to grain size was ***,transverse delamination failure due to the thermal mismatch stress was ***,vertical cracking failure related to early scale growth was ***,a critical scale grain size of~2.5μm was identified for achieving the optimal lifetime of *** was experimentally proved that vertical cracking of the Al_(2)O_(3) scale occurred during early oxidation as the scale grain size was larger than~4μm after *** proposed lifetime phase diagram and critical scale grain size effect serve as novel criteria for the design of next-generation durable TBCs.

关键词： TGO growth Grain size Grain boundaries Channel cracking Service lifetime

Achieving the high phase purity of CH_3NH_3PbI_3 film by two-step solution processable crystal engineering

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Journal of Materials Science & Technology 2018年第8期34卷 1405-1411页

作者： Yan li Bin Ding guan-jun yang chang-jiu li Cheng-Xin li State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi'an Jiaotong University

To date, it is still a great challenge for highly efficient perovskite devices to realize the high quality per- ovskite films with high purity, high coverage ratio and good crystallization by two-step scalable solution method. In this study, a series PbI2 films with tunable micro-architecture of Pbl2 crystals are prepared via solution processable crystal engineering. The perovskite film, prepared by optimized pit spacing in gas pumped PbI2 film at 1000 Pa, shows the highest film quality, including no residual Pbl2 phase, compact morphology, and improved photoluminescence intensity. A transformation kinetics shows that the pit spacing strongly influences both the mass transfer and the sequential intercalation reaction between CH3NH31 and PbI2 crystals, which ultimately determines the full reaction state of the perovskite film. The perovskite solar cells assembled by the perovskite film show both high power-conversion efficiency and good reproducibility of photovoltaic performance due to the restrained charge recombination arising from the high quality perovskite film.

关键词： High phase purity CHHNH3PbI3 film Two-step solution method Perovskite solar cells

Heterogeneous layered structure in thermal barrier coatings by plasma spray-physical vapor deposition

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Journal of Advanced Ceramics 2023年第2期12卷 386-398页

作者： Yan-Hong LU Lu HUANG Mei-jun liU guan-jun yang chang-jiu li State Key Laboratory for Mechanical Behavior of Materials School of Materials Science and EngineeringXi’an Jiaotong UniversityXi’an 710049China

The unique columnar structure endows thermal barrier coatings(TBCs)prepared by plasma spray-physical vapor deposition(PS-PVD)with high thermal insulation and long ***,the coating delamination failure resulting from an intra-column fracture(within a column rather than between columns)is a bottleneck in the solid dust particle impact environment for *** clarify the intra-column fracture mechanism,a basic layer deposition model is developed to explore a heterogeneous weak-to-strong layered structure formed by a local transient in-situ deposit *** the PS-PVD,an in-situ deposit surface is continuously updated due to constantly being covered by vapor condensation,showing a transient temperature,which means that the in-situ deposit surface temperature rises sharply in short period of 0.2 s of depositing a thin layer during a single ***,the increasing temperature of the in-situ deposit surface results in an experimentally observed heterogeneous weak-to-strong structure,showing a continuous transition from a porous weak structure at the bottom region to a dense strong structure at the top *** structure easily makes the intra-column fracture at the porous weak *** results shed light on improving TBC lifetime by restraining the intra-column fracture.

关键词： transient temperature in-situ deposit surface heterogeneous layered structure fracture mechanism plasma spray-physical vapor deposition(PS-PVD)