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Two-state energy model and experimental study of coal adsorb methane

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Journal of Coal Science & Engineering(China) 2013年第4期19卷 488-492页

作者： Zeng-Chao FENG Dong ZHAO Zhi-Xiang LIU yan-Qi wang hong-Qiang GOU Mining Technology Institute Taiyuan University of Technology Taiyuan 030024 China

There are two states of methane existing in coal, free methane and adsorptive methane. The two states of methane exchanged with each other which need the energy exchange with outside. It is released heat when methane adsorption on coal, instead of absorbed heat. According to the gas molecules Boltzmann energy distribution, is obtained the equilibrium equations of the two states of methane in coal, as well as the heat of adsorption equation when exchanged into each other. At the same time, high temperature experiments of methane adsorption on coal have been certificated to the theoretical model. At last the experimental results presented that： the two-state energy model could be accurately described the distribution of the two states of methane in the coal; the adsorption heat is related to the initial equilibrium state of methane adsorption; the adsorption heats are different with different coal ranks.

关键词： two-state energy model adsorption heat chemical potential experimental study

Achieving high power factor in GaSb with intrinsically high mobility via Ge doping

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Rare Metals 2024年第10期43卷 5435-5441页

作者： yan-Ci yan Guo-Wei wang Qi-hong Xiong Xu Lu Peng Chen Wei Zou Deng-Feng Li hong Wu Yun Zhou Xiao-Yuan Zhou School of Science Chongqing University of Posts and Telecommunications College of Physics Chongqing University College of Ocean Science and Engineering Shanghai Maritime University

The thermoelectric power factor is as crucial as their overall thermoelectric ***-based compounds are deemed to achieve high power factor owing to their intrinsically high mobility compared to classical thermoelectric ***,the carrier concentration of pristine GaSb is considerably lower than the optimum value,which hinders its ability to attain high electrical *** this paper,we present the investigations on the thermoelectric performance of p-type *** experimental results reveal that Ge doping can effectively tune the carrier concentration.

关键词： Carrier concentration

Steel-refractory reactions in lanthanum-,cerium-,and ytrium-added steels

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Journal of Iron and Steel Research International 2024年第6期31卷 1473-1485页

作者： Jian Kang hong-po wang Yu wang College of Materials Science and Engineering Chongqing UniversityChongqing 400044China The State Key Laboratory of Mechanical Transmissions Chongqing UniversityChongqing 400044China

A systematic experimental study was conducted on the similarities and differences in the reactions between commonly used rare earth elements(REEs)and frequently used refractories in the steelmaking *** results indicate that the reaction behaviors of La,Ce,and Y with MgO,Al_(2)O_(3),and MgO·Al_(2)O_(3) crucibles differed *** consumption rates of La,Ce,and Y in the molten steel were in descending order of La>Ce>Y for smelting with all three kinds of *** the REEs reacted with the crucible,the contents of Mg and Al showed a trend of first increasing and then *** laboratory-scale smelting conditions,the reactions related to REEs were dominated by steel-crucible reactions,and the contact area between the unit mass of molten steel and refractory materials mainly determined the consumption rates of ***-and Ce-crucible reactions generated loose and porous reaction interfaces;however,Y-crucible reactions generated a dense Y_(2)O_(3) layer,dramatically suppressing the consumption rate of *** calculation indicated that the reactions between rare earth and different refractory materials were first-order *** crucible materials significantly affected the product type and morphology of the steel-crucible reaction interfaces,thereby influencing the consumption rate of *** reactions between REEs and refractories must be seriously considered,especially for small-scale smelting.

关键词： Rare earth Inclusion Refractory Thermodynamics Dynamics

Three-Coordinate Copper 2-Hydroxy-1,10-phenanthroline Dinuclear Complex Catalyzed Homocoupling of Arylboronic Acids towards Biphenyls under Air Condition

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Three-Coordinate Copper 2-Hydroxy-1,10-phenanthroline Dinucl...

Prevalence of hypertension and its associations with body composition across Chinese and American children and adolescents

中国化学会第九届全国有机化学学术会议

作者： yan-hong wang School of Chemistry and Material Science Shanxi Normal University

An efficient synthesis of biphenyls via three-coordinate planar dinuclear Cu(ophen)1] complex catalyzed homocoupling of arylboronic acids under air condition and in the absence of any base was demonstrated. This method tolerates various substituents of aromatic ring such as alkyl, alkoxy, halogens, and nitro groups. It is noted that the catalytic abnormality of Cu(ophen) was reflected for high selectivity of biphenyls when the reaction was conducted in environmentally friendly aqueous solution, which is significantly different from selectivity of phenols in reported results.2-6]

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World Journal of Pediatrics 2024年第4期20卷 392-403页

作者： Li-wang Gao Yi-Wen Huang hong Cheng Xi wang hong-Bo Dong Pei Xiao Yin-Kun yan Xin-Ying Shan Xiao-Yuan Zhao Jie Mi Center for Non-Communicable Disease Management Beijing Children’s HospitalCapital Medical UniversityNational Center for Children’s HealthNo.56 Nanlishi RoadXicheng DistrictBeijing100045China Department of Epidemiology Capital Institute of PediatricsNo.2 Yabao RoadChaoyang DistrictBeijing100020China Key Laboratory of Major Diseases in Children Ministry of EducationBeijingChina

Background The age of onset of hypertension(HTN)is decreasing,and obesity is a significant risk *** prevalence and racial disparities in pediatric HTN and the association between body composition and blood pressure are insufficiently *** study aimed to evaluate the prevalence of HTN in Chinese and American children and adolescents and to assess the relationship between various body composition indices and *** Seven thousand,five hundred and seventy-three Chinese and 6239 American children and adolescents aged 8–18 years from the 2013–2015 China Child and Adolescent Cardiovascular Health study and the 2011–2018 National Health and Nutrition Examination Surveys were *** pressure and body composition(fat and muscle)were measured by trained *** crude prevalence and age-standardized prevalence rate(ASPR)of primary HTN and its subtypes[isolated systolic hypertension(ISH)and isolated diastolic hypertension(IDH)]were calculated based on 2017 American Academy of Pediatrics ***-adjusted linear regression coefficients and odds ratios(ORs)were calculated to assess the associations of body composition indicators with HTN,ISH and *** The ASPR of HTN was 18.5%in China(CN)and 4.6%in the United States(US),whereas the obesity prevalence was 7.4%and 18.6%,and the population attributable risk of HTN caused by overweight and obesity was higher in the US than in *** fat mass,muscle mass and body fat percentage mass were associated with a higher risk of HTN in both *** percent of muscle body mass had a protective effect on HTN and ISH in both countries[HTN(CN:OR=0.83,95%CI=0.78–0.88;US:OR=0.72,95%CI=0.64–0.81);ISH(CN:OR=0.87,95%CI=0.80–0.94;US:OR=0.71,95%CI=0.62–0.81)],and the protective effect was more common among children and adolescents with high levels of physical *** The burden of HTN in Chinese children and adolescents was substantial and much greater than that in the US,and th

关键词： Body composition Children and adolescents China Child and Adolescent Cardiovascular Health Hypertension National Health and Nutrition Examination Surveys

Branch-Chain-Rich Diisopropyl Ether with Steric Hindrance Facilitates Stable Cycling of Lithium Batteries at-20℃

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Nano-Micro Letters 2024年第10期16卷 121-135页

作者： Houzhen Li Yongchao Kang wangran Wei Chuncheng yan Xinrui Ma Hao Chen Yuanhua Sang hong Liu Shuhua wang State Key Laboratory of Crystal Materials Shandong UniversityJinan 250100People's Republic of China

Li metal batteries(LMBs)offer signifi-cant potential as high energy density alternatives;nev-ertheless,their performance is hindered by the slow desolvation process of electrolytes,particularly at low temperatures(LT),leading to low coulombic efficiency and limited cycle ***,it is essential to opti-mize the solvation structure thereby achieving a rapid desolvation process in LMBs at ***,we introduce branch chain-rich diisopropyl ether(DIPE)into a 2.5 M Li bis(fluorosulfonyl)imide dipropyl ether(DPE)elec-trolyte as a co-solvent for high-performance LMBs at-20℃.The incorporation of DIPE not only enhances the disorder within the electrolyte,but also induces a steric hindrance effect form DIPE’s branch chain,excluding other solvent molecules from Li+solvation *** of these factors contribute to the weak interactions between Li^(+)and solvent molecules,effectively reducing the desolvation energy of the ***,Li(50μm)||LFP(mass loading~10 mg cm^(-2))cells in DPE/DIPE based electrolyte demonstrate stable performance over 650 cycles at-20℃,delivering 87.2 mAh g^(-1),and over 255 cycles at 25℃ with 124.8 mAh g^(-1).DIPE broadens the electrolyte design from molecular structure considera-tions,offering a promising avenue for highly stable LMBs at LT.

关键词： Solvation structure Li metal battery Low temperature Steric hindrance Disorder

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Interference mitigation and target detection for automotive FMCW radar with range-Doppler sparse regularization

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Science China(Information Sciences) 2024年第9期67卷 342-343页

作者： yan HUANG Yunxuan wang Xiao ZHOU Hui ZHANG Yuan MAO Guisheng LIAO Wei hong State Key Lab of Millimeter Waves Southeast University Department of Computer Science University College London National Key Lab of Radar Signal Processing Xidian University

The invention of vehicles has shaped our modern society and accelerated our economy while causing many tragic incidents simultaneously. Some advanced driver-assistance systems(ADAS) based on surrounding environment se... 详细信息

关键词： Radar interference

High specificity detection of Pb^2＋ ions by p-SCN-Bz-DTPA immunogen and p-NH2-Bn-DTPA coating antigen

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Frontiers of Environmental Science & Engineering 2014年第5期8卷 729-736页

作者： Ruozhen YU Zheng FANG Wei MENG Zhenguang yan Lina DU hong wang Zhengtao LIU State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental Sciences Beijing 100012 China

Only one bifunctional metal-chelator was used to prepare immunogen and coating antigen in all of the previous researches. However, the antibody-specific recognition to the spacer arm of the bifunctional metal- chelator might lower the specificity of heavy metal ions immunoassay. Two different bifunctional metal-chelators were adopted to prepare the immunogen and coating antigen respectively in our study to avoid this problem. The conjugates of keyhole limpet hemocyanin （KLH） and p-SCN-Bz-DTPA-Pb were used as immunogen, whereas the conjugates of bovine sentrn albumin （BSA） and p- NH2-Bn-DTPA-Pb were used as coating antigen. Poly- clonal antibodies specific to DTPA-Pb chelates were obtained from rabbits. Indirect competitive enzyme-linked immunosorbent assay （ELISA） was adopted to detect Pb^2＋ ion solutions prepared by Pb^2＋ standard solution and ultrapure water. In the mixing microplate, DTPA and Pb2＋ ions formed chelates and combined with specific anti- bodies. After incubation, the DTPA-Pb and the antibodies complex were added into the wells of the reaction microplate. The reaction microplate was coated by the conjugates ofBSA andp-NH2-DTPA-Pb, which competed for the specific antibodies. The result signals presented a good sigmoid curve when the Pb^2＋ concentration ranges from 0.01 to 100mg·L^-1 The IC50 of the indirect competitive ELISA is 0.23±0.04mg·L^-1 Pb2＋ ion. The cross-reaction with Cd^2＋, Cu^2＋, Fe^2＋, Mn^2＋, Zn^2＋, and other divalent ions were less than 5%.

关键词： p-SCN-Bz-DTPA p-NH2-Bn-DTPA leadion polyclonal antibody

一种两自由度的压电-电磁复合能量收集器(英文)

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2014年第9期15卷 711-722页

作者： hong-yan wang Li-hua TANG Yuan GUO Xiao-biao SHAN Tao XIE College of Computer and Control Engineering Qiqihar University State Key Laboratory of Robotics and System Harbin Institute of Technology Department of Mechanical Engineering University of AucklandAuckland 1010 New Zealand

研究目的:对一种两自由度的压电-电磁复合能量收集器进行发电性能研究。创新要点:建立了一种两自由度压电-电磁复合能量收集器发电性能的数学模型,该数学模型可以评估两自由度压电-电磁复合能量收集器中压电元件、电磁元件以及系统总输... 详细信息

研究目的:对一种两自由度的压电-电磁复合能量收集器进行发电性能研究。创新要点:建立了一种两自由度压电-电磁复合能量收集器发电性能的数学模型,该数学模型可以评估两自由度压电-电磁复合能量收集器中压电元件、电磁元件以及系统总输出功率。研究方法:对一种两自由度的压电-电磁复合能量收集器进行数学建模,并实验验证数学模型的正确性。基于实验测试得到的系统参数值,理论研究压电元件和电磁元件的机电耦合系数对不同能量收集器发电性能的影响关系,并对几种能量收集器的发电能力进行对比分析。重要结论:对于非强耦合(弱或中间耦合)的两自由度机电转换器,复合能量收集器(压电+电磁)具有比单一能量收集器(压电或电磁)更高的发电能力。

关键词：振动复合能量收集两自由度模型压电电磁

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