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Effect of Eu3+,Bi3+,and Li+ doping on luminescent property of GdNbO4

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Journal of Rare Earths 2024年第1期42卷 66-75页

作者： s.W.Wi y.s.Lee Department of Physics and integrative institute of Basic sciences Soongsil University

We investigated the emission properties of Eu3+-doped GdNbO4-based oxide phosphors,aiming at improving the Eu3+emission by codoping of Bi3+and Li+.Eu3+singly doped,Eu3+and Bi3+doubly doped,and Eu3+,Bi3+,and Li+triply doped GdNbO4were prepared using a high-temperature solid-state reaction *** red-orange emissions from Eu3+in the singly doped samples are significantly improved by the codoping of Bi3+,mainly due to the energy transfer from Bi3+to Eu3+.The additional codoping of Li+is found to increase the Eu3+emission *** improvement might be attributed to the increase in the photoluminescent quantum yield originating from larger grain sizes and better crystallinity.A detailed analysis of the X-ray diffraction pattern and the asymmetric ratio estimated from the photoluminescence spectra show that the local lattice environment around Eu3+in GdNbO4does not change significantly with the codoping of Bi3+and Li+.Our results indicate that Li+doping is a promising way to improve the emission properties of rare-earth ion-doped GdNbO4phosphors.

关键词： Eu3+ GdNbO4 Codoping of Li+ Photoluminescence sensitizer Rare earths

Decomposition solutions and Bäcklund transformations of the B-type and C-type Kadomtsev-Petviashvili equations

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Communications in Theoretical Physics 2024年第6期76卷 34-44页

作者： Xiazhi Hao s y Lou College of science Zhejiang University of TechnologyHangzhou 310014China school of Physical science and Technology Ningbo UniversityNingbo 315211China

This paper introduces a modified formal variable separation approach,showcasing a systematic and notably straightforward methodology for analyzing the B-type Kadomtsev-Petviashvili(BKP)*** the application of this approach,we successfully ascertain decomposition solutions,Bäcklund transformations,the Lax pair,and the linear superposition solution associated with the aforementioned ***,we expand the utilization of this technique to the C-type Kadomtsev-Petviashvili(CKP)equation,leading to the derivation of decomposition solutions,Bäcklund transformations,and the Lax pair specific to this *** results obtained not only underscore the efficacy of the proposed approach,but also highlight its potential in offering a profound comprehension of integrable behaviors in nonlinear ***,this approach demonstrates an efficient framework for establishing interrelations between diverse systems.

关键词： decomposition solution Backlund transformation Lax pair linear superposition solution

Construction of 2D/2D Ti_(3)C_(2)T_(x)MXene/Cds heterojunction with photothermal effect for efficient photocatalytic hydrogen production

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Journal of Materials science & Technology 2024年第4期171卷 1-9页

作者： T.y.Huang Z.yang s.y.yang Z.H.Dai y.J.Liu J.H.Liao G.y.Zhong Z.J.Xie y.P.Fang s.s.Zhang Key Laboratory for Biobased Materials and Energy of Ministry of Education Guangdong Laboratory for Lingnan Modern AgricultureCollege of Materials and EnergySouth China Agricultural UniversityGuangzhou 510643China school of Physics and Optoelectronics South China University of TechnologyGuangzhou 510640China school of Chemical Engineering and Energy Technology Guangdong Provincial Key Laboratory of Distributed Energy SystemsDongguan University of TechnologyDongguan 523808China

The insensitivity of semiconductors to visible and infrared light is a key constraint on the utilization of light energy in photocatalytic *** photocatalysts with full-spectrum absorption through surface engineering is an effective approach to fully harnessing light energy in semiconductor ***,a novel stable Ti_(3)C_(2)T_(x)MXene/Cds heterojunction catalyst is obtained by in-situ epitaxial growth of two-dimensional(2D)Cds nanosheets on 2D MXene interface via a solvothermal *** exceptional light absorption properties of MXene confer outstanding full-spectrum driven photocat-alytic hydrogen evolution capability upon the heterogeneous *** unique 2D/2D structure effectively mitigated the recombination of photogenerated carriers,enhancing the photocatalytic performance of the ***,the composite catalyst exhibits a significantly higher surface temperature of 80.4℃under visible light irradiation at an intensity of 0.1 W/cm^(2),which is 1.84 times higher than that of *** irradiation of visible and near infrared light,the composite catalyst with photothermal ef-fect demonstrates a remarkable hydrogen evolution rate of 65.4 mmol g^(-1)h^(-1),which is 7.2 times higher than that of Cds *** study introduces a novel approach for constructing full-spectrum absorption catalysts and expands the application of the photothermal effect in photocatalytic hydrogen evolution research.

关键词： Two-dimensional structure Heterostructure Photothermal effect Photocatalyst Hydrogen evolution

Distinct Electrical and Mechanical Responses of a Cu-10Fe Composite Prepared by Hot-Pressed sintering and Post Treatment

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Acta Metallurgica sinica(English Letters) 2024年第2期37卷 255-265页

作者： X.y.yue s.y.Peng X.Zhang C.N.He y.Z.Tian Key Laboratory for Anisotropy and Texture of Materials(Ministry of Education) School of Materials Science and EngineeringNortheastern UniversityShenyang110819China school of Materials science and Engineering and Tianjin Key Laboratory of Composite and Functional Materials Tianjin UniversityTianjin300350China Research Centre for Metallic Wires Northeastern UniversityShenyang110819China

A Cu-10wt%Fe composite was prepared through hot-pressed sintering,and the material was subsequently solution *** hot-pressed sintered and solution treated materials were rolled and *** precipitation behavior and performance changes were systematically studied by using scanning electron microscopy and transmission electron *** contrast to the hot-pressed sintered specimen,the solution treatment significantly affects the thermal stability and properties of the Cu-10wt%Fe *** Cu-10wt%Fe composite was prepared after solid solution,cold rolling and aging at 773 K for 1 h,and it obtained excellent tensile strength of 494 MPa,uniform elongation of 16.3%,electrical conductivity of 51.1%iACs and softening temperature of 838 *** for the distinct difference in thermal stability and properties between hot-pressed sintered and solution treated specimens were *** findings provide a theoretical basis for designing high-performance Cu-based in-situ composites by post treatment.

关键词： Cu-Fe composite Hot-pressed sintering Thermal stability strength Electrical conductivity

Cognition on oxidation behavior of Ni-based superalloy GH4742 when exposed to water vapor

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Journal of Materials science & Technology 2024年第7期174卷 15-22页

作者： H.Xu s.F.yang E.H.Wang C.y.Guo y.s.Liu X.M.Hou y.L.Zhang state Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China institute for Carbon Neutrality University of Science and Technology BeijingBeijing 100083China

The oxidation behavior of Ni-based superalloy GH4742 exposed to water vapor was investigated at 900-1100℃for 50 h in Ar+20%H_(2)O,with Ar+20%O_(2)included for *** presence of H_(2)O is adverse to formation of continuous Cr_(2)O_(3)oxide layer but contributes to generation of big *** on this,Ni^(2+)and Co^(2+)are more easily to diffuse towards the outermost oxide layer(OOL),forming non-protective Ni-and Co-rich oxides with high *** leads to a higher weight gain in Ar+20%H_(2)O than that in Ar+20%O_(2).At elevated temperatures,the spallation of oxide scale occurs while the consumption of Cr is reduced in Ar+20%H_(2)O,and the contents of Ni-and Co-rich oxides at this moment are reduced in the *** oxidation mechanism was also discussed.

关键词： GH4742 superalloy H_(2)O Diffusion Oxidation Mechanism

Thermo-kinetic characteristics on stabilizing hetero-phase interface of metal matrix composites by crystal plasticity finite element method

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Journal of Materials science & Technology 2024年第2期169卷 53-67页

作者： y.B.Zhang s.J.song F.Liu state Key Laboratory of solidification Processing Northwestern Polytechnical UniversityXi’an 710072China Analytical&Testing Center Northwestern Polytechnical UniversityXi’an 710072China

Using dislocation-based constitutive modeling in three-dimension crystal plasticity finite element(3D CPFE)simulations,co-deformation and instability of hetero-phase interface in different material systems were herein studied for polycrystalline metal matrix composites(MMCs).Local stress and strain fields in two types of 3layer MMCs such as fcc/fcc Cu-Ag and fcc/bcc Cu-Nb have been predicted under simple compressive ***,more severe strain-induced interface instability can be observed in the fcc/bcc systems than in the fcc/fcc systems upon refining to metallic nanolayered composites(MNCs).By detailed analysis of stress and strain localization,it has been demonstrated that the interface instability is always accompanied by high-stress concentration,i.e.,thermodynamic characteristics,or high strain prevention i.e.,kinetic characteristics,at the hetero-phase *** then follows that the thermodynamic driving forceG and the kinetic energy barrier Q during dislocation and shear banding can be adopted to classify the deformation modes,following the so-called thermo-kinetic *** by inserting a high density of high-energy interfaces into the Cu-Nb composites,such thermo-kinetic integration at the hetero-phase interface allows a successful establishment of MMCs with the high△G-high Q deformation mode,which ensures high hardening and uniform strain distri-bution,thus efficiently suppressing the shear band,stabilizing the hetero-phase interface,and obtaining an exceptional combination in strength and *** hetero-phase interface chosen by a couple of thermodynamics and kinetics can be defined as breaking the thermo-kinetic correlation and has been proposed for artificially designing MNCs.

关键词： Thermodynamics and kinetics Physics-based constitutive modeling Hetero-phase interface Crystal plasticity finite element

Reactive destabilization and bidirectional catalyzation for reversible hydrogen storage of LiBH_(4) by novel waxberry-like nano-additive assembled from ultrafine Fe_(3)O_(4) particles

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Journal of Materials science & Technology 2024年第6期173卷 63-71页

作者： s.Wang M.H.Wu y.y.Zhu Z.L.Li y.X.yang y.Z.Li H.F.Liu M.X.Gao Department of Material science Shenzhen MSU-BIT UniversityShenzhen 518172China state Key Laboratory of silicon and Advanced semiconductor Materials&school of Materials science and Engineering Zhejiang UniversityHangzhou 310027China institute of Resources Utilization and Rare Earth Development State Key Laboratory of Rare Metals Separation and Comprehensive UtilizationGuangdong Provincial Key Laboratory of Rare Earth Development and ApplicationGuangdong Academy of SciencesGuangzhou 510650China institute of science and Technology for New Energy Xi’an Technological UniversityXi’an 710021China National supercomputing Center in shenzhen Shenzhen 518055China

LiBH_(4) containing 18.5 wt.%H_(2) is an attractive high-capacity hydrogen storage material,however,it suffers from high operation temperature and poor ***,a novel and low-cost bifunctional additive,waxberry-like Fe_(3)O_(4) secondary nanospheres assembled from ultrafine primary Fe_(3)O_(4) nanoparticles,is synthesized,which exhibits significant destabilization and bidirectional catalyzation towards(de)hydrogenation of LiBH_(4).With an optimized addition of 30 wt.% waxberry-like Fe_(3)O_(4),the system initiated dehydrogenation below 100℃ and released a total of 8.1 wt.%H_(2) to 400℃.After 10 cycles,a capacity retention of 70% was achieved,greatly superior to previously reported oxides-modified *** destabilizing and catalyzing mechanisms of waxberry-like Fe_(3)O_(4) on LiBH_(4) were systematically analyzed by phase and microstructural evolutions during dehydrogenation and hydrogenation cycling as well as density functional theory(DFT)*** present work provides new insights in developing advanced nano-additives with unique structural and multifunctional designs towards LiBH4 hydrogen storage.

关键词： LiBH_(4) Hydrogen storage Waxberry-like Fe_(3)O_(4) Destabilization Catalysis

Factors influencing farmers’adoption of solar water-pumping systems in Gujarat

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Clean Energy 2024年第3期8卷 157-165页

作者： M sathish Kumar y.A.Lad R.s.Pundir international Agribusiness Management institute Anand Agricultural UniversityAnand388110GujaratIndia Department of HRD&PM International Agribusiness Management InstituteAnand Agricultural UniversityAnand388110GujaratIndia Department of Agribusiness Economics and Policies International Agribusiness Management InstituteAnand Agricultural UniversityAnand388110GujaratIndia

Agriculture has played an important role in the growth of the indian *** and electricity are essential inputs for agriculture *** produces the third-largest amount of electricity in the world,behind China and the *** an incentive to increase production,most states provide free electricity to *** electricity has decreased groundwater levels and increased electricity *** objective of this study was to find out the factors that influenced farmers to adopt a solar water-pumping system in *** samples were randomly *** study examined the entire state of *** hundred and fifty farmers who adopted solar water-pumping systems were interviewed,including 50 banana farmers,50 cotton farmers and 50 groundnut *** data were collected through an *** adoption of solar water-pumping systems by farmers was identified using factor *** software was used to analyse the data *** this study,only two factors contributed to the variance of 59.469%.The adoption of solar water pumps by farmers was influenced by government policy and economic *** economic benefit variance of 33.20%was found,while a government policy variance was 26.27%.A solar water-pumping system has low initial costs,flexible credit policies motivate adoption,solar water-pumping systems can save electricity,and maintenance and repair costs are *** policy that includes solar water-pumping systems is motivated by awareness,subsidies for adoption and a fair price to sell energy *** are recommended to adopt a solar water-pumping system in conjunction with a drip irrigation system to receive additional *** successful scheme will be recommended to other states in india for implementation.

关键词： solar water-pumping system factor analysis banana cotton groundnut famers

Research on Defect Detection ofWind Turbine Blades Based onMorphology and improved Otsu Algorithm Using infrared images

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Computers, Materials and Continua 2024年第1期81卷 933-949页

作者： Kang s. He y. Li W. Liu s. school of Mechanical and Control Engineering Baicheng Normal University Baicheng 137000 China school of information and Control Engineering Jilin Institute of Chemical Technology Jilin 132022 China

To address the issues of low accuracy and high false positive rate in traditional Otsu algorithm for defect detection on infrared images of wind turbine blades (WTB), this paper proposes a technique that combines morphological image enhancement with an improved Otsu algorithm. First, mathematical morphology's differential multi-scale white and black top-hat operations are applied to enhance the image. The algorithm employs entropy as the objective function to guide the iteration process of image enhancement, selecting appropriate structural element scales to execute differential multi-scale white and black top-hat transformations, effectively enhancing the detail features of defect regions and improving the contrast between defects and background. Afterwards, grayscale inversion is performed on the enhanced infrared defect image to better adapt to the improved Otsu algorithm. Finally, by introducing a parameter K to adjust the calculation of inter-class variance in theOtsumethod, theweight of the target pixels is increased. Combined with the adaptive iterative threshold algorithm, the threshold selection process is further fine-tuned. Experimental results show that compared to traditional Otsu algorithms and other improvements, the proposed method has significant advantages in terms of defect detection accuracy and reducing false positive rates. The average defect detection rate approaches 1, and the average Hausdorff distance decreases to 0.825, indicating strong robustness and accuracy of the method. © 2024 The Authors.

关键词： adaptive iterative thresholding grayscale inversion improved Otsu algorithm infrared image Morphological enhancement