检索结果-南通市图书馆

Journal of Energy Chemistry 2019年第12期28卷 109-143页

作者： Xun Hu Mortaza Gholizadeh School of Material Science and Engineering University of JinanJinan 250022ShandongChina Faculty of Chemical and Petroleum Engineering University of TabrizTabrizIran

Lignocellulosic biomass can be convert to a condensable liquid named bio-oil,a solid product named as char and a mixture of gaseous products comprising CO2,CO,H2,CH4,etc.In recent years,much effort has been made on the investigation of conversion of biomass through pyrolysis.However,commercialisation of the biomass pyrolysis technology is still challenging due to various issues such as the deleterious properties of bio-oil including the low heating value and the high instability at elevated temperatures.To overcome such issues,many processes,reactors and catalysts have been developed for pyrolysis and catalytic pyrolysis of biomass.A state to the art of pyrolysis or catalytic pyrolysis of biomass need to be summarised to have an overall evaluation of the technologies,in order to provide a useful reference for the further development of pyrolysis technology.This study reviews the various pyrolysis process,especially focus on the effects of essential parameters,the process design,the reactors and the catalysts on the pyrolysis process.In addition,progress in commercialisation of pyrolysis technology was also reviewed and the remaining issues in the process of commercialisation were discussed.

关键词： Biomass Pyrolysis Commercialisation Current plants Review

Beyond catalytic materials:Controlling local gas/liquid environment in the catalyst layer for CO_(2)electrolysis

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2022年第3期31卷 45-51,I0003页

作者： Zhuo Xing Kaige Shi Xun Hu Xiaofeng Feng School of Material Science and Engineering University of JinanJinan 250022ShandongChina Department of Physics University of Central FloridaOrlandoFL 32816United States Renewable Energy and Chemical Transformations(REACT)Cluster University of Central FloridaOrlandoFL 32816United States

Electrochemical reduction of CO_(2)to value-added chemicals using renewable electricity provides a promising strategy to achieve sustainable fuel production and carbon neutrality.Along with the development of electrocatalysts,fow cells with gas-diffusion electrodes(GDEs)have been used to reach commercially viable current densities for CO_(2)electrolysis,while the local environment and CO_(2)mass transport in the electrodes remain to be elucidated.In this review article,we highlight some insights into the microenvironment in the catalyst layer for CO_(2)electrolysis,including typical mass transport models for CO_(2)reduction in H-type cells and GDE fow cells,the effect of a hydrophobic microenvironment on CO_(2)mass transport and catalytic performance,and the formation of a gas/liquid balance and solid–liquid–gas interfaces for CO_(2)electrolysis.The insights and discussions in this article can provide important guidelines on the design of catalysts,electrodes,and electrolyzers for CO_(2)electrolysis,as well as other gas-involving electrocatalytic reactions.

关键词： Electrocatalysis CO_(2)reduction Gas-diffusion electrode Microenvironment Activity

Multi-Axis Attention With Convolution Parallel Block for Organoid Segmentation

在线全文

学校读者我要写书评

暂无评论

IEEE/CAA Journal of Automatica Sinica 2024年第5期11卷 1295-1297页

作者： Pengwei hu xun Deng Feng Tan Lun hu Xinjiang Technical Institute of Physics and Chemistry Chinese Academy of SciencesUrumqi 830011 University of Chinese Academy of Sciences Beijing 100049 Xinjiang Laboratory of Minority Speech and Language Information Processing Urumqi 830011China Merck KGaA Darmstadt 64293Germany

Dear Editor,This letter presents an organoid segmentation model based on multi-axis attention with convolution parallel *** adeptly captures dynamic dependencies within bright-field microscopy images,improving global ... 详细信息

关键词： letter convolution organo

Mg-Al-hydrotalcite with alkaline sites protects Ni/KIT-6 from formation of amorphous coke in glycerol steam reforming via tailoring reaction intermediates

同方期刊数据库博看期刊评论

在线全文

学校读者我要写书评

暂无评论

Frontiers of Chemical Science and Engineering 2024年第4期18卷 25-39页

作者： Yunyu Guo Yiran Wang Yuewen Shao Shu Zhang Yi Wang Song hu Jun Xiang Xun Hu School of Material Science and Engineering University of JinanJinan 250022China Joint International Research Laboratory of Biomass Energy and Materials College of Materials Science and EngineeringNanjing Forestry UniversityNanjing 210037China State Key Laboratory of Coal Combustion Huazhong University of Science and TechnologyWuhan 430074China

During steam reforming,the performance of a catalyst and amount/property of coke are closely related to reaction intermediates reaching surface of a catalyst.Herein,modification of reaction intermediates by placing Mg-Al-hydrotalcite above Ni/KIT-6 catalyst in steam reforming of glycerol was conducted at 300 to 600°C.The results revealed that the catalytic activity of Ni/KIT-6 in the lower bed was enhanced with either Mg1-Al5-hydrotalcite(containing more acidic sites)or Mg5-Al1-hydrotalcite(containing more alkaline sites)as upper-layer catalyst.The in situ infrared characterization of steam reforming demonstrated that Mg-Al-hydrotalcite catalyzed the deoxygenation of glycerol,facilitating the reforming of the partially deoxygenated intermediates over Ni/KIT-6.Mg-Al-hydrotalcite as protective catalyst,however,did not protect the Ni/KIT-6 from formation of more coke.Nonetheless,this did not lead to further deactivation of Ni/KIT-6 while Mg5-Al1-hydrotalcite even substantially enhanced the catalytic stability,even though the coke was much more significant than that in the use of single Ni/KIT-6(52.7%vs.28.6%).The reason beneath this was change of the property of coke from more aliphatic to more aromatic.Mg5-Al1-hydrotalcite catalyzed dehydration of glycerol,producing dominantly reaction intermediates bearing C=C,which formed the catalytic coke of with carbon nanotube as the main form with smooth outer walls as well as higher aromaticity,C/H ratio,crystallinity,crystal carbon size,thermal stability,and resistivity toward oxidation on Ni/KIT-6 in the lower bed.In comparison,the abundance of acidic sites on Mg1-Al5-hydrotalcite catalyzed the formation of more oxygen-containing species,leading to the formation of carbon nanotubes of rough surface on Ni/KIT-6.

关键词： steam reforming of glycerol Mg-Alhydrotalcite sacrificial catalyst reaction intermediates property of coke

Ni–Co bimetallic coordination effect for long lifetime rechargeable Zn–air battery

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2020年第8期29卷 146-154,I0005页

作者： Mengfei Qiao Ying Wang Thomas Wagberg Xamxikamar Mamat Xun Hu Guoan Zou Guangzhi hu Key Laboratory of Xinjiang Indigenous Medicinal Plants Resource Utilization and Key Laboratory of Plant Resources and Chemistry in Arid RegionsXinjiang Technical Institute of Physics and ChemistryChinese Academy of SciencesUrumqi 830011XinjiangChina Department of Physics Umea UniversityS-90187 UmeaSweden School of Material Science and Engineering University of JinanJinan 250022ShandongChina University of Chinese Academy of Sciences Beijing 100049China

The development of bifunctional oxygen electrocatalysts with high efficiency, high stability, and low cost is of great significance to the industrialization of rechargeable Zn–air batteries. A widely accepted view is that the oxygen reduction reaction(ORR) and the oxygen evolution reaction(OER) follow different catalytic mechanisms, and accordingly they need different active sites for catalysis. Transition metal elements have admirable electronic acceptance ability for coordinating with reactants, and this can weaken the bond energy between reactants, thus promoting the ORR or OER reactions. Herein, the ORR and OER activities of different transition metal supported nitrogen-doped carbon nanotubes were systematically studied and compared. The optimal catalyst for synchronous ORR and OER was obtained by pyrolyzing melamine, cobalt nitrate, and nickel nitrate on carbon nanotubes, called cobalt–nickel supported nitrogenmixed carbon nanotubes(CoNi–NCNT), which were equipped with two types of high-performance active sites—the Co/Ni–N–C structure for the ORR and Co Ni alloy particles for the OER—simultaneously. Remarkably, the optimized Co Ni–NCNT exhibited a satisfactory bifunctional catalytic activity for both the ORR and OER. The value of the oxygen electrode activity parameter,△E, of CoNi–NCNT was 0.81 V, which surpasses that of catalysts Pt/C and Ir/C, and most of the non-precious metal-based bifunctional electrocatalysts reported in previous literatures. Furthermore, a specially assembled rechargeable Zn–air cell with Co Ni–NCNT loaded carbon paper as an air cathode was used to evaluate the practicability. As a result, a superior specific capacity of 744.3 mAh/gZn, a peak power density of 88 mW/cm2, and an excellent rechargeable cycling stability were observed, and these endow the Co Ni–NCNT with promising prospects for practical application.

关键词： Bifunctional catalysis Oxygen reduction reaction Oxygen evolution reaction Carbon nanotubes Zn–air battery

Sequential pyrolysis for understanding specific influence of cellulose- and lignin-derived volatiles on properties of counterpart char

在线全文

学校读者我要写书评

暂无评论

Green Chemical Engineering 2024年第2期5卷 222-235页

作者： Yuewen Shao Chao Li Mengjiao Fan Guoming Gao Stelgen Inkoua Lijun Zhang Shu Zhang Jun Xiang Song hu Xun Hu School of Material Science and Engineering University of JinanJinan250022China Joint International Research Laboratory of Biomass Energy and Materials College of Materials Science and EngineeringNanjing Forestry UniversityNanjing210037China State Key Laboratory of Coal Combustion Huazhong University of Science and Technology430074China

Interactions of cellulose-and lignin-derived intermediates have been well documented during pyrolysis of lignocellulosic biomass.The reaction network for the interactions is rather complex,as cellulose-derived volatiles could interact/react with not only lignin-derived volatiles but also lignin-derived char and vice versa.To probe specifically the impacts of cellulose-derived volatiles on the lignin-derived char or the opposite,herein the sequential pyrolysis was performed by arranging cellulose in the upper bed with lignin in the lower bed or lignin above with cellulose below at 350 and 650℃,respectively.The results indicated that the sequential pyrolysis of cellulose→lignin or lignin→cellulose at 350℃induced increased char yield from formation of carbonaceous deposits via volatiles-char interactions.Compared with the lignin-derived volatiles,the cellulose-derived volatiles,especially aldehyde fractions,were more reactive towards the lignin-derived char at 350℃,forming oxygen-rich lignin-derived char with a higher yield,an abundance of aliphatic structures and consequently lower thermal stability.In sequential pyrolysis of lignin→cellulose,more aromatics-rich species were deposited on cellulose-derived char,but the lignin-derived volatiles were less reactive for enhancing the char yield.At 650℃,instead of polymerisation of the volatiles on the char,either the cellulose-or lignin-derived char catalyzed the cracking of the counterpart volatiles to remove the aliphatic functionalities,which made the char more aromatic and thermally more stable.

关键词： Cellulose Lignin Sequential pyrolysis Char Interaction

Mitochondrial malic enzyme 2 promotes breast cancer metastasis via stabilizing HIF-1α under hypoxia

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Cancer Research 2021年第3期33卷 308-322页

作者： Duo You Danfeng Du Xueke Zhao Xinmin Li Minfeng Ying Xun Hu Cancer Institute(Key Laboratory for Cancer Intervention and Prevention China National Ministry of EducationZhejiang Provincial Key Laboratory of Molecular Biology in Medical Sciences)The Second Affiliated HospitalZhejiang University School of MedicineHangzhou 310000China State Key Laboratory of Esophageal Cancer Prevention&Treatment and Henan Key Laboratory of Esophageal Cancer Research of the First Affiliated Hospital Zhengzhou UniversityZhengzhou 450000China Department of Pathology Women and Infants Hospital of ZhengzhouZhengzhou 450000China

Objective: α-ketoglutarate(α-KG) is the substrate to hydroxylate collagen and hypoxia-inducible factor-1α(HIF-1α), which are important for cancer metastasis. Previous studies have shown that the upregulation of collagen prolyl 4-hydroxylase in breast cancer cells stabilizes the expression of HIF-1α by depleting α-KG levels. We hypothesized that mitochondrial malic enzyme 2(ME2) might also affect HIF-1α expression via modulating α-KG levels in breast cancer cells.Methods: We evaluated ME2 protein expression in 100 breast cancer patients using immunohistochemistry and correlated with clinicopathological indicators. The effect of ME2 knockout on cancer metastasis was evaluated using an orthotopic breast cancer model. The effect of ME2 knockout or knockdown on the levels of α-KG and HIF-1α proteins in breast cancer cell lines was determined both in vitro and in vivo.Results: ME2 was found to be upregulated in the human breast cancerous tissues compared with the matched precancerous tissues(Phuman breast cancer samples(P=0.008).Conclusions: Our results pro

关键词： Malic enzyme 2 breast cancer metastasis malate α-ketoglutarate hypoxia-inducible factor-1α

A universal charge-compensating strategy for high-energy-density pseudocapacitors

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2023年第3期78卷 333-339,I0010页

作者： Baoyi Yin Jiaqi Zhang Yuanhui Su Yu huan Liang Hao Chen Wang Xun Hu Tao Wei School of Material Science and Engineering University of Jinan336 Nanxinzhuang West RoadJinan 250022ShandongChina School of Microelectronics Dalian University of TechnologyDalian 116024LiaoningChina Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering School of Energy and Power EngineeringUniversity of Shanghai for Science and TechnologyShanghai 200093China State Key Laboratory of ASIC and Systems School of MicroelectronicsFudan UniversityShanghai 200433China

For pseudocapacitive electrode materials(PseEMs),despite much progress having been made in achieving both high power density and high energy density,a general strategy to guide the enhancement of intrinsic capacitive properties of PseEMs remains lacking.Here,we demonstrate a universal chargecompensating strategy to improve the charge-storage capability of PseEMs intrinsically:ⅰ) in the electrolyte with anion as charge carriers(such as OH-),reducing the multivalent cations of PseEMs into lower valences could create more reversible low-to-high valence redox cou ples to promote the intercalation of the anions;ⅱ) in the electrolytes with cation as charge carriers(such as H^(+),Li^(+),Na^(+)),oxidizing the multivalent cations of PseEMs into higher valences could introduce more reversible high-to-low valence redox couples to promote the intercalation of the cations.And we demonstrated that the improved intrinsic charge-storage capability for PseEMs originates from the increased Faradaic charge storage sites.

关键词： Supercapacitors Universal charge-compensating strategy Changed valence state Increased Faradaic charge storage sites

Biomass chemical looping gasification for syngas production using modified hematite as oxygen carriers

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2023年第3期125卷 171-184页

作者： Cong Jiang Xiaoyu Jin Tingting Xu Bo Xiao Zhiquan hu xun Wang School of Environmental Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China State Key Laboratory of Coal Combustion Huazhong University of Science and TechnologyWuhan 430074China

Syngas is a clean energy carrier and a major industrial feedstock. In this paper, syngas was produced via biomass chemical looping gasification(CLG) process. Hematite, the most common Fe-based oxygen carrier(OC), was modified with different metal oxides(CeO_(2), CaO and MgO) by the impregnation method. The hematite modified by CeO_(2), CaO and MgO was namely as CeO_(2)-hematite(CeO_(2)-H), CaO-hematite(CaO-H) and MgO-hematite(MgO-H), respectively. The introduction of CeO_(2), CaO and MgO enhanced the reactivity of lattice oxygen of hematite. The optimum condition for syngas production had been explored as the mass ratio of oxygen carrier to biomass(O/B) of 0.2, the mass ratio of steam to biomass(S/B) of0.75 and temperature of 800℃in the biomass CLG process. The CeO_(2)-H exhibited the most wonderful performance compared to that for CaO-H and MgO-H. The crystal composition of OC influenced greatly in the CLG process. CeFeO_(3)had a good oxygen mobility property and lattice oxygen releasing capacity due to the most oxygen vacancy distributed on the OC surface and the most active lattice oxygen, which is conducive to the biomass chemical looping gasification process for syngas production, leading to the highest gasification efficiency of 95.86% and gas yield of 1.20 m^(3)/kg of the three. Cyclic test proved that CeO_(2)-H had well sintering resistance and cyclic performance.

关键词： Chemical looping gasification Oxygen carrier Syngas Modified hematite Pine sawdust

X-ray imager of 26-μm resolution achieved by perovskite assembly

在线全文

学校读者我要写书评

暂无评论

Nano Research 2022年第3期15卷 2399-2404页

作者： Zhaofen Wang Ruijia Sun Nianqiao Liu huailin Fan Xun Hu Depeng Shen Yuhai Zhang Hong Liu State Key Laboratory of Crystal Material Shandong UniversityJinan 250100China Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of Shandong Institute for Advanced Interdisciplinary Research(iAIR)University of JinanJinan 250022China School of Physics and Technology University of JinanJinan 250022China School of Material Science and Engineering University of JinanJinan 250022China

Spatial resolution is an important criterion to evaluate the performance of a scintillation screen for X-ray imaging.Perovskite-based X-ray screen,usually made of powders or polycrystalline films,suffers from low spatial resolution(~200μm)due to the large thickness of scintillation layer despite of their compelling sensitivity to X-ray dose.In this work,a concentrated colloid of CsPbBr_(3)nanosheets was synthesized via a co-precipitation method at ambient condition.By drop casting,smooth scintillation screens of varied thickness were formed through self-assembly,which exhibited both high internal and external photoluminescence quantum yield(PL QY)(84.5%and 75.1%,respectively).The screen-based X-ray detector showed a high sensitivity down to 27 nGy/s,two orders of magnitude lower than the regular dose for medical diagnostics.Importantly,the screen of optimal thickness of 15μm showcased an unprecedented spatial resolution(26μm)when used for X-ray radiography,representing one order of magnitude improvement in perovskite community.

关键词： perovskite scintillator high-resolution X-ray imaging self-assembly perovskite nanosheets all-inorganic perovskite