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Silicon dioxide-protection boosting the peroxidase-like activity of Fe single-atom catalyst for combining chemo-photothermal therapy

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Nano Research 2024年第6期17卷 4924-4933页

作者： yu Fan yu Yi Hongpan Rong Jiatao Zhang Beijing Key Laboratory of Construction-Tailorable Advanced Functional Materials and Green Applications School of Materials Science&EngineeringBeijing Institute of TechnologyBeijing 100081China CAS Center for Excellence in Nanoscience CAS KeyLaboratory for Biomedical Effects of Nanomaterials and NanosafetyNational Center for Nanoscience and Technology(NCNST)Beijing 100190China Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering Ministry of Industry and Information TechnologySchool of Chemistry&Chemical EngineeringBeijing Key Laboratory of Construction-Tailorable Advanced Functional Materials and Green ApplicationsSchool of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China

Carbon-based single-atom catalysts(SACs)have been widely studied in the field of biomedicine due to their excellent catalytic ***,carbon-based SACs usually aggregate during pyrolysis,which leads to the reduction of catalytic ***,we describe a method to improve the monodispersion of SACs using silicon dioxide as a protective *** decoration of silicon dioxide serves as a buffer layer for individual nanoparticles,which is not destroyed during the pyrolysis process,ensuring the single-particle dispersion of the nanoparticles after *** approach increased the hydroxyl groups on the surface of Fe-SAC(Fe-SAC-SE)and improved its water solubility,resulting in a four times enhancement of the peroxidase(POD)-like activity of Fe-SAC-SE(58.4 U/mg)than that of non-protected SACs(13.9 U/mg).The SiO_(2)-protection approach could also improve the catalytic activities of SACs with other metals such as Mn,Co,Ni,and Cu,indicating its generality for SACs *** advantage of the high POD-like activity,photothermal properties,and large specific surface area of Fe-SAC-SE,we constructed a synergistic therapeutic system(Fe-SAC-SE@DOX@PEG)for combining the photothermal therapy,catalytic therapy,and *** was verified that the photothermal properties of Fe-SAC-SE@DOX@PEG could effectively improve its POD-like activity,exhibiting excellent tumor-killing performance at the cellular *** work may provide a general approach to improve the performances of SACs for disease therapy and diagnosis.

关键词： single-atom catalysts peroxidase-like activity SiO2-protection photothermal therapy catalytic therapy chemotherapy

U-Pb zircon geochronology of basaltic pyroclastic rocks from the basement beneath the Xisha Islands in the northwestern South China Sea and its geological significance

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Acta Oceanologica Sinica 2024年第2期43卷 83-93页

作者： yu Zhang Kefu yu Shiying Li Guangxi Laboratory on the Study of Coral Reefs in the South China Sea Guangxi UniversityNanning 530004China Coral Reef Research Center of China Guangxi UniversityNanning 530004China School of Marine Sciences Guangxi UniversityNanning 530004China Key Laboratory of Ocean and Marginal Sea Geology South China Sea Institute of OceanologyChinese Academy of ScienceGuangzhou 510301China

As one of the micro-blocks dispersed in the South China Sea(SCS), the basement of the Xisha Islands has rarely been drilled because of the thick overlying Cenozoic sediments, which has led to a confused understanding of the pre-Cenozoic basement of the Xisha Islands. Well CK-1, a kilometer-scale major scientific drill in the Xisha Islands in the northwestern SCS, penetrated thick reefal limestone(0–888.4 m) and the underlying basement rocks(888.4–901.4 m). In this study, we present the zircon U-Pb ages of basement basaltic pyroclastic rocks from Well CK-1 in the Xisha Islands of the northwestern SCS to investigate the basement nature of the Xisha microblock. The basement of Well CK-1 consists of basaltic pyroclastic rocks on the seamount. The zircon grains yielded apparent ages ranging from ca. 2 138.9 Ma to ca. 36 Ma. The old group of zircon grains from Well CK-1 was considered to be inherited zircons. Two Cenozoic zircons gave a weighted mean 206Pb/238U age of(36.3 ± 1.1) Ma,Mean Squared Weighted Deviations(MSWD) = 1.2, which may represent the maximum age of the volcano eruption. The Yanshanian inherited zircons(116.9–105.7 Ma and 146.1–130.2 Ma) from Well CK-1 are consistent with the zircons from Well XK-1, indicating that the basement of Chenhang Island may be similar to that of Well XK-1. We propose that the Xisha micro-block may have developed on a uniform Late Jurassic metamorphic crystalline basement, intruded by Cretaceous granitic magma.

关键词： South China Sea Xisha Islands basaltic pyroclastic rocks zircon

Quantum Spin Exchange Interactions to Accelerate the Redox Kinetics in Li–S Batteries

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Nano-Micro Letters 2024年第5期16卷 370-383页

作者： yu Du Weijie Chen yu Wang yue yu Kai Guo Gan Qu Jianan Zhang Key Laboratory of Advanced Energy Catalytic and Functional Materials Preparation of Zhengzhou City College of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001People’s Republic of China

Spin-engineering with electrocatalysts have been exploited to suppress the“shuttle effect”in Li–S *** selec-tion,spin-dependent electron mobility and spin potentials in activation barriers can be optimized as quantum spin exchange interactions lead-ing to a significant reduction of the electronic repulsions in the orbitals of ***,we anchor the MgPc molecules on fluorinated carbon nanotubes(MgPc@FCNT),which exhibits the single active Mg sites with axial *** to the density functional theory calculations,the electronic spin polarization in MgPc@FCNT not only increases the adsorption energy toward LiPSs intermediates but also facilitates the tunneling process of electron in Li–S *** a result,the MgPc@FCNT provides an initial capacity of 6.1 mAh cm^(-2) even when the high sulfur loading is 4.5 mg cm^(-2),and still maintains 5.1 mAh cm^(-2) after 100 *** work provides a new perspective to extend the main group single-atom catalysts enabling high-performance Li–S batteries.

关键词： Metal phthalocyanines Spin polarization Electrocatalysis Li–S batteries

基于GIS的内蒙古中部地区多源雷达回波拼图

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科技导报 2011年第28期29卷 37-42页

作者：于雪涛余志伟芮小平奚砚涛董前林中国矿业大学(北京)煤炭资源与安全开采国家重点实验室北京100083 中国矿业大学(北京)地球科学与测绘工程学院北京100083 中国科学院研究生院资源与环境学院．北京100049 中国矿业大学资源与地球科学学院江苏徐州221116

为了做到内蒙古中部地区天气的实时监测,研究了该地区新一代天气雷达基本反射率产品和713雷达平显回波等多源雷达回波数据的拼合方法。首先阐述了两类回波数据的存储结构和格式,然后设计了两类径向数据向二维矩阵数据转换的算法,研究了... 详细信息

为了做到内蒙古中部地区天气的实时监测,研究了该地区新一代天气雷达基本反射率产品和713雷达平显回波等多源雷达回波数据的拼合方法。首先阐述了两类回波数据的存储结构和格式,然后设计了两类径向数据向二维矩阵数据转换的算法,研究了该类数据转为栅格类型存储的直角坐标绘制模式,并采用ArcGISEngine二次开发组件进行了实现。最后基于GIS技术研究了两种回波图像进行区域拼图的方法,并设计了回波图像拼合平台,其能够根据用户的选择条件实时对该地区4部雷达的回波图像进行拼合。在包头市气象局的测试应用表明,该平台可实现内蒙古中部地区天气的实时监测,同时为气象预报员制作气象预警预报提供辅助决策。

关键词：内蒙古中部地区:多源雷达 ArcGIS Engine 回波拼图

基于地学研究的CINRAD/CB雷达回波显示与提取

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解放军理工大学学报（自然科学版） 2014年第4期15卷 398-404页

作者：朱黎明芮小平朱雷平余学祥于雪涛安徽理工大学测绘学院安徽淮南232001 中国科学院大学资源与环境学院北京100049 徐州工程学院江苏徐州221008 石家庄铁道大学交通运输学院河北石家庄050043

为准确显示天气雷达指定回波强度的回波区域,基于CINRAD/CB新一代天气雷达(简称CB雷达)的基数据,从地学角度提出一种CB雷达反射率因子回波的可视化方法,即将雷达基数据中的反射率因子数据采用地学中栅格数据格式进行显示。然后生成反射... 详细信息

为准确显示天气雷达指定回波强度的回波区域,基于CINRAD/CB新一代天气雷达(简称CB雷达)的基数据,从地学角度提出一种CB雷达反射率因子回波的可视化方法,即将雷达基数据中的反射率因子数据采用地学中栅格数据格式进行显示。然后生成反射率因子图,结合风暴单体识别与跟踪算法(SCIT)中对风暴单体的识别模式,提出能够提取指定回波强度的雷达回波区域的方法。通过鄂尔多斯气象雷达站的CB雷达基数据提出方法并进行了验证。实验结果表明,提出的反射率因子图可视化方法可以显示雷达的反射率因子特征,针对反射率因子图提出的回波区域提取方法能够提取指定强度的回波区域。

关键词：天气雷达反射率回波

还原剂对镁合金表面化学镀Ni-P合金性能的影响

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热加工工艺 2010年第22期39卷 100-102页

作者：苌清华于雪涛陈艳芳熊毅河南科技大学材料学院河南洛阳471003

通过镀速测量、SEM、EDS等方法研究了AZ31B镁合金的化学镀Ni-P合金工艺。结果表明:镁合金表面化学镀Ni-P合金的最佳还原剂为次磷酸钠,还原剂的最佳浓度为20 g/L。所制备的镀层耐腐蚀性能良好。

关键词：镁合金化学镀还原剂 Ni-P合金

Study on viscosity mechanism of caffeine crystallization solutions Author links open overlay panel

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Particuology 2024年第8期91卷 341-350页

作者： Linjing yu Min Su School of Chemical Engineering Hebei University of TechnologyTianjin300130China

The solid-liquid viscous system formed by high viscosity crystallization solution impacts the flow and separation ***,it is very important to study the viscosity mechanism to improve viscosity and regulate crystallization,ensuring a seamless production ***,the viscosity of crystallization solution was taken as the measurement parameter of caffeine as a model *** investigated the viscosity mechanism of caffeine crystallization solutions by combining experiment and *** results indicated that the weak interactions between caffeine and water result in increased viscosity of the caffeine crystallization ***,caffeine crystals possess elongated needle-like shapes,featuring a substantial specific surface ***,there isπ-πstacking occurring between the(200)crystal face and(110)crystal face,effectively fostering coalescence of the crystals towards the radial side of the crystal along its elongated axis,resulting in a more viscous crystallization *** results contribute to comprehending the viscosity mechanism of crystal systems and provide theoretical foundation to enhance engineering efficiency in crystallization.

关键词： Crystallization Caffeine Viscosity mechanism Molecular simulation

Light People:Professor Laura Na Liu

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Light(Science & Applications) 2024年第2期13卷 184-189页

作者： Hui Wang Cun yu Changchun Institute of Optics Fine Mechanics and PhysicsChinese Academy of Sciences130033ChangchunChina

Editorial The DNA nanotechnology outlines a new chapter in biological sciences,opening a new era of scientific and technological advancements.A pioneer of DNA nanotechnology,Professor Liu from the University of Stuttgart in Germany,our latest Light People,has been working at the interface,where nanophotonics meets biology and *** the path of scientific explorations.

关键词： chemistry. advancement pioneer

Microscopic ensemble bootstrap in phase space

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Communications in Theoretical Physics 2024年第6期76卷 72-76页

作者： yu Zhang College of Mechanics and Engineering Science Hohai UniversityNanjing 211100China

The bootstrap method which has been studied under many quantum mechanical models turns out to be feasible in microcanonical ensembles as *** the approach of Nakayama(2022 ***.A 372250054)produces a sector when energy is negative,in this paper we report a method that has stronger constraints and results in a smaller *** also study other models to demonstrate the effectiveness of our method.

关键词： numerical bootstrap microcanonical ensemble Poisson bracket bootstrap oscillator