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Arsenic methylation and microbial communities in paddy soils under alternating anoxic and oxic conditions

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Journal of Environmental Sciences 2025年第2期148卷 468-475页

作者： jing Liu Rui Pei Runzeng Liu Chuanyong jing Wenjing Liu Shandong Key Laboratory of Environmental Processes and Health School of Environmental Science and EngineeringShandong UniversityQingdao 266237China State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

Arsenic(As)methylation in soils affects the environmental behavior of As,excessive accumulation of dimethylarsenate(DMA)in rice plants leads to straighthead disease and a serious drop in crop *** the mobility and transformation of methylated arsenic in redox-changing paddy fields is crucial for food ***,soils including unarsenic contaminated(N-As),low-arsenic(L-As),medium-arsenic(M-As),and high-arsenic(H-As)soils were incubated under continuous anoxic,continuous oxic,and consecutive anoxic/oxic treatments respectively,to profile arsenic methylating process and microbial species involved in the As *** anoxic-oxic(A-O)treatment,methylated arsenic was significantly increased once oxygen was introduced into the incubation *** methylated arsenic concentrations were up to 2-24 times higher than those in anoxic(A),oxic(O),and oxic-anoxic(O-A)treatments,under which arsenic was methylated slightly and then decreased in all four As concentration *** fact,the most plentiful arsenite S-adenosylmethionine methyltransferase genes(arsM)contributed to the increase in As ***(40.8%-62.4%),Firmicutes(3.5%-15.7%),and Desulfobacterota(5.3%-13.3%)were the major microorganisms related to this *** microbial increasedmarkedly and played more important roles after oxygen was introduced,indicating that they were potential keystone microbial groups for As methylation in the alternating anoxic(flooding)and oxic(drainage)*** novel findings provided newinsights into the reoxidation-driven arsenic methylation processes and the model could be used for further risk estimation in periodically flooded paddy fields.

关键词： Arsenic methylation Anoxic-oxic Straighthead disease arsM gene Microbial community

Highly conductive and stable iodine doped argyrodite electrolyte for all-solid-state lithium batteries

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Journal of Energy Chemistry 2025年第1期100卷 50-58页

作者： Gaozhan Liu jing Zhang jing Yang jinghui Chen Xingyue Xiao Xiayin Yao Ningbo Institute of Materials Technology and Engineering Chinese Academy of SciencesNingbo 315201ZhejiangChina Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Lithium argyrodites with high ionic conductivity and low cost are considered as one of the most prospective solid electrolytes for all-solid-state lithium ***,the poor chemical stability and compatibility with lithium metal limit their ***,Li_(5.4)PS_(4.4)Cl1.4I0.2solid electrolyte with high ionic conductivity of 11.49 m S ccm^(-1)and improved chemical stability is synthesized by iodine *** ultra-thin Li_(5.4)PS_(4.4)Cl_(1.4)I_(0.2)membrane with thickness of 10μm can be obtained by wet coating process,exhibiting a high ionic conductivity of 2.09 mS ccm^(-1)and low areal resistance of 1.17Ωcm^(-2).Moreover,iodine doping could in-situ form LiI at the lithium/electrolyte interface and improve the critical current density of Li_(5.4)PS_(4.4)Cl_(1.6)from 0.8 to 1.35 mA cm^(-2).The resultant LiCoO_(2)/Li_(5.4)PS_(4.4)Cl_(1.4)I_(0.2)/Li battery shows excellent cycling stability at 1 C,with a reversible specific capacity of 110.1 mA h g^(-1)and a retention of 80.5% after 1000 *** addition,the assembled LiCoO_(2)/Li_(5.4)PS_(4.4)Cl_(1.4)I_(0.2)membrane/Li pouch cell delivers an initial discharge capacity of 110.4 mA h g^(-1)and 80.5% capacity retention after 100 cycles.

关键词： Argyrodite electrolytes lodine doping lonic conductivity Stability All-solid-state lithium battery

Environmental Inequality in China’s Urban Expansion:A Case Study of Guangzhou,China

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Chinese Geographical Science 2025年第1期35卷 187-202页

作者： WANG Shaogu SHEN jing School of Geography and Planning Sun Yat-sen UniversityGuangzhou 510006China

Environmental inequality is a prevalent issue in developing countries undergoing urban *** expansion induces the formation and evolution of environmental inequality by creating environmental and structural conditions that lead to the spatial relocation of environmental hazards and the socio-spatial segregation of different groups in developing *** study investigated the spatial patterns and temporal trends of environmental inequality under urban expansion in Guangzhou,a megacity in *** considered how environmental disparities and socio-demographic attributes interact in terms of industrial pollution exposure using additive semiparametric quantile regression,combined with spatial visualisation,on the basis of the economic and population census data from 1990 to *** study revealed that urban expansion sparked the spatial displacement of environmental risks and the social-spatial differentiation,exposing the peripheral regions and disadvantaged groups to higher environmental risks.A reciprocal transformation occurred between central and peripheral regions,as well as a process of redistributing environmental risks across social *** the context of urban expansion in developing countries,the causes of environmental inequality shifted from individual socio-economic differences to structural factors,such as industrial layout and social division of labour in cities,leading to the spatial displacement and concealment of environmental *** study provides insights and guidance for policymakers to address the issue of environmental inequality in the context of urban expansion.

关键词： environmental inequality urban expansion spatiotemporal evolution additive semiparametric quantile regression Guangzhou,China

Obesogenic effects of six classes of emerging contaminants

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Journal of Environmental Sciences 2025年第5期151卷 252-272页

作者： Siying Wu Chaoyu Tong jing Liu MOE Key Laboratory of Environmental Remediation and Ecosystem Health College of Environmental and Resource SciencesZhejiang UniversityHangzhou 310058China

There is growing concern about the concept that exposure to environmental chemicals may be contributing to the obesity ***,there is no consensus on the obesogenic effects of emerging contaminants from a toxicological and environmental *** potential human exposure and experimental evidence for obesogenic effects of emerging contaminants need to be systematically *** main objective of this review is to provide recommendations for further subsequent policy development following a critical analysis of the literature for humans and experimental animals exposed to emerging *** article reviews human exposure to emerging contaminants(with a focus on antimicrobials,preservatives,water and oil repellents,flame retardants,antibiotics and bisphenols)and the impact of emerging contaminants on *** emerging contaminants have been widely detected in human biological *** studies provide evidence linking exposure to emerging contaminants to the risks of obesity in *** based on animalmodels and adipose cells show the obesogenic effects of emerging contaminants and identify modes of action by which contaminants may induce changes in body fat accumulation and lipid metabolic *** knowledge gaps in this area and future directions for further investigation are discussed.

关键词： Emerging contaminants Obesity Human exposure Preservatives Flame retardants Plasticizers Antibiotics

Catalytic production of high-energy-density spiro polycyclic jet fuel with biomass derivatives

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Journal of Energy Chemistry 2025年第2期101卷 760-768页

作者： Wen-jing Zhang Yan-Cheng Hu Yan-Hong Tan Jia Li Ning Li jing-Pei Cao School of Chemical Engineering and Technology China University of Mining and Technology CAS Key Laboratory of Science and Technology on Applied Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences

High-energy-density（HED） fuel（*** used JP-10 and RJ-4）,featuring compact 3D polycyclic structure with high strain,is of critical importance for volume-limited military aircraft,since their high density and combustion heat can provide more propulsion *** reduce the reliance on petroleum source,it is highly desirable to develop renewable alternatives for the production of strained polycyclic HED fuel,but which remains a big challenge because of the inaccessibility caused by the high strain,We herein demonstrate a three-step catalytic route towards highly strained C17and C18spirofuel with biomass *** process includes catalytic aldol condensation of renewable cyclohexanone/cyclopentanone with benzaldehyde,catalytic spiro Diels-Alder（D-A） reaction of aldol adduct with isoprene,and catalytic *** key spiro D-A reaction is enabled by the catalysis of heterogeneous Lewis acidic ionic *** chloroaluminate IL,formed by benign urea and AICl3,exhibits good catalytic performance and reusability for this *** eventual hydrodeoxygenation（HDO）over Pd/C and H-Y produces strained tricyclic spirofuel with density>0.93 g/mL,combustion heat>41 MJ/L and freezing point <-40℃,which are better than the properties of tactical fuel ***,it is anticipated that the as-prepared renewable fuels have the potential to replace traditional petroleum-derived HED fuels.

关键词： Biomass derivatives Cycloaddition High-energy-density Lewis acidic ionic liquid Spiro polycyclic fuel

Applications of in-situ solid-state nuclear magnetic resonance in methanol to olefins reaction

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Science China Chemistry 2025年第1期68卷 134-151页

作者： jing Niu Shutao Xu Yingxu Wei Zhongmin Liu National Engineering Research Center of Lower-Carbon Catalysis Technology Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023China University of Chinese Academy of Sciences Beijing 100049China

The methanol-to-olefins(MTO)reaction offers an alternative pathway for the production of low-carbon olefins from non-oil *** research has been impeded by a lack of comprehensive understanding of its underlying mechanism,despite the significant progress made in ***-situ solid-state nuclear magnetic resonance(ss NMR)spectroscopy has emerged as a pivotal tool,offering crucial insights into key species under real-time operando ***,the host–guest interaction between zeolites or surface species residing on zeolites and the reactant/active intermediates is revealed by the combination of in-situ^(13)C MAS NMR and 2D correlation ***,recent technological advancements in hyperpolarization(HP)methods,including HP^(129)Xe NMR and dynamic nuclear polarization(DNP),have significantly improved the sensitivity of ssNMR,enabling detailed structural and kinetic analysis as well as the detection of trace *** this feature article,we summarized recent advancements in(in-situ)ssNMR spectroscopy applied to MTO reaction processes,encompassing mechanistic investigations at various stages and the intricate host–guest *** theoretical insights into the dynamic evolution of MTO reactions lay a solid foundation for the optimization of catalytic processes and the development of efficient catalysts,thereby advancing the techniques towards more sustainable and economical production route for olefins.

关键词： MTO zeolites in-situ ssNMR reactive intermediates reaction mechanism

Merging polymers of intrinsic microporosity and porous carbon-based zinc oxide composites in novel mixed matrix membranes for efficient gas separation

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Green Energy & Environment 2025年第1期10卷 203-213页

作者： Muning Chen Jiemei Zhou jing Ma Weigang Zheng Guanying Dong Xin Li Zhihong Tian Yatao Zhang jing Wang Yong Wang School of Chemical Engineering Zhengzhou UniversityZhengzhou450001HenanChina State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemical Engineering Nanjing Tech UniversityNanjing211816JiangsuChina Singapore Membrane Technology Centre Nanyang Environment and Water Research InstituteNanyang Technological UniversitySingapore637141Singapore Engineering Research Center for Nanomaterials Henan UniversityKaifeng475004HenanChina State Key Laboratory of Coking Coal Resources Green Exploitation Zhengzhou UniversityZhengzhou 450001China School of Energy and Environment Southeast UniversityNanjing210096JiangsuChina

Mixed matrix membranes(MMMs)have demonstrated significant promise in energy-intensive gas separations by amalgamating the unique properties of fillers with the facile processability of ***,achieving a simultaneous enhancement of permeability and selectivity remains a formidable challenge,due to the difficulty of achieving an optimal match between polymers and *** this study,we incorporate a porous carbon-based zinc oxide composite(C@ZnO)into high-permeability polymers of intrinsic microporosity(PIMs)to fabricate *** dipole–dipole interaction between C@ZnO and PIMs ensures their exceptional compatibility,mitigating the formation of non-selective voids in the resulting ***,C@ZnO with abundant interconnected pores can provide additional low-resistance pathways for gas transport in *** a result,the CO_(2) permeability of the optimized C@ZnO/PIM-1 MMMs is elevated to 13,215 barrer,while the CO_(2)/N_(2) and CO_(2)/CH_(4) selectivity reached 21.5 and 14.4,respectively,substantially surpassing the 2008 Robeson upper ***,molecular simulation results further corroborate that the augmented membrane gas selectivity is attributed to the superior CO_(2) affinity of C@*** summary,we believe that this work not only expands the application of MMMs for gas separation but also heralds a paradigm shift in the application of porous carbon materials.

关键词： Mixed matrix membranes Polymers of intrinsic microporosity CO_(2)separation Porous carbon materials

Quantum instability and Ehrenfest time for an inverted harmonic oscillator

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Communications in Theoretical Physics 2025年第1期77卷 35-40页

作者： Shangyun Wang Songbai Chen Jiliang jing College of Physics and Electronic Engineering Hengyang Normal UniversityHengyang 421002China Department of Physics Key Laboratory of Low Dimensional Quantum Structures and Quantum Control of Ministry of EducationSynergetic Innovation Center for Quantum Effects and ApplicationsHunan Normal UniversityChangsha 410081China Center for Gravitation and Cosmology College of Physical Science and TechnologyYangzhou UniversityYangzhou 225009China

We use out-of-time order correlators(OTOCs)to investigate the quantum instability and Ehrenfest time for an inverted harmonic oscillator(IHO).For initial states located in the stable manifolds of the IHO we find that the corresponding OTOC exhibits identical evolutionary characteristics to the saddle point before the Ehrenfest *** initial states located in the unstable manifolds,the OTOCs still grow exponentially but the time to maintain exponential growth is related to the center position of its wave packet in phase ***,we use the Husimi Q function to visualize the quantum wave packets during exponential growth of the *** results show that quantum instability exists at arbitrary orbits in the IHO system,and the Ehrenfest time in the IHO system depends not only on the photon number of the initial system but also on the central positions of the initial states in phase space.

关键词： out-of-time order correlators inverted harmonic oscillator quantum instability Ehrenfest time

Domain generalization with semi-supervised learning for people-centric activity recognition

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Science China(Information Sciences) 2025年第1期68卷 171-188页

作者： jing LIU Wei ZHU Di LI Xing HU Liang SONG Academy for Engineering & Technology Fudan University Shanghai East-bund Research Institute on Networking Systems of AI School of Optoelectronic Information and Computer Engineering University of Shanghai for Science & Technology

People-centric activity recognition is one of the most critical technologies in a wide range of real-world applications,including intelligent transportation systems, healthcare services, and brain-computer interfaces. Large-scale data collection and annotation make the application of machine learning algorithms prohibitively expensive when adapting to new tasks. One way of circumventing this limitation is to train the model in a semi-supervised learning manner that utilizes a percentage of unlabeled data to reduce the labeling burden in prediction tasks. Despite their appeal, these models often assume that labeled and unlabeled data come from similar distributions, which leads to the domain shift problem caused by the presence of distribution gaps. To address these limitations, we propose herein a novel method for people-centric activity recognition,called domain generalization with semi-supervised learning(DGSSL), that effectively enhances the representation learning and domain alignment capabilities of a model. We first design a new autoregressive discriminator for adversarial training between unlabeled and labeled source domains, extracting domain-specific features to reduce the distribution gaps. Second, we introduce two reconstruction tasks to capture the task-specific features to avoid losing information related to representation learning while maintaining task-specific consistency. Finally, benefiting from the collaborative optimization of these two tasks, the model can accurately predict both the domain and category labels of the source domains for the classification task. We conduct extensive experiments on three real-world sensing datasets. The experimental results show that DGSSL surpasses the three state-of-the-art methods with better performance and generalization.

关键词： activity recognition deep learning domain generalization semi-supervised learning adversarial training

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