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Zoological Research 2022年第1期43卷 33-39页

作者： Zhi-Xian Sun xue-jian li Wen-Qiao Tang Ya-Hui Zhao Key Laboratory of Zoological Systematics and Evolution Institute of ZoologyChinese Academy of SciencesBeijing100101China Shanghai Universities Key Laboratory of Marine Animal Taxonomy and Evolution Shanghai Ocean UniversityShanghai201306China

During revision of the genus Microphysogobio Mori,1934,we discovered a new species of Huigobio from the Yangtze River Basin in China.The new species,named Huigobio heterocheilus sp.nov.,can be distinguished from its congeners by a combination of the following characters:medial pad on lower lip not visible;ventral region scaleless before pelvic-fin insertion;lateral-line scales 39-40;caudal peduncle depth 49.2%-59.1%of length;barbel length 6.6%-10.7%of head length;black blotch between anterior margin of eye and upper lip.Using the K2P model and cytochrome b(cyt b)sequences,interspecific genetic distances between the new species and Huigobio exilicauda jiang&Zhang,2013 and Huigobio chenhsienensis Fang,1938 were 13.2%and 15.1%,respectively.The new species is known from the upper reaches of the Xiangjiang River in the middle Yangtze River Basin.A diagnostic key for species of Huigobio Fang,1938 is provided.

关键词： Cyprinidae Yangtze insertion

Examining the influence of the loading path on the cracking characteristics of a pre-fractured rock specimen with discrete element method simulation

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2023年第4期24卷 332-349页

作者： Kang DUAN Ri-hua jianG xue-jian li Lu-chao WANG Ze-ying YANG School of Civil Engineering Shandong UniversityJinan 250061China

Damage in a rock mass is heavily dependent on the existence and growth of joints,which are also influenced by the complex stress states induced by human activities(e.g.,tunneling and excavation).A proper representation of the loading path is essential for understanding the mechanical behaviors of rock masses.Based on the discrete element method(DEM),the influence of the loading path on the cracking process of a rock specimen containing an open flaw is examined.The effectiveness of the model is confirmed by comparing the simulation results under a uniaxial compression test to existing research findings,where wing crack initiates first and secondary cracks contribute to the failure of the specimen.Simulation results confirm that the cracking process is dependent upon both the confining pressure and the loading path.Under the axial loading test,a higher confining pressure suppresses the development of tensile wing cracks and forces the formation of secondary cracks in the form of shear bands perpendicular to the flaw.Increase of confining pressure also decreases the influence of the loading path on the cracking process.Reduction of confining pressure during an unloading test amplifies the concentration of tensile stress and ultimately promotes the appearance of a tensile splitting fracture at meso-scale.Confining pressure at the failure stage is well predicted by the Hoek-Brown failure criterion under quasi-static conditions.

关键词： Cracking process Loading path Fractured rock mass Discrete element method(DEM) Local stress concentration

Triplophysa xuanweiensis sp. nov., a new blind loach species from a cave in China(Teleostei:Cypriniformes:Nemacheilidae)

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Zoological Research 2022年第2期43卷 221-224页

作者： Zong-Min Lu xue-jian li Wen-jian Lu Jin-Qing Huang Tian-Ke Xu Gang Huang Fen-Qiong Qian Peng Yang Shu-Guo Chen Wei-Ning Mao Ya-Hui Zhao Key Laboratory of Zoological Systematics and Evolution Institute of ZoologyChinese Academy of SciencesBeijing 100101China Qujing Aquaculture Station QujingYunnan 655099China Shanghai Universities Key Laboratory of Marine Animal Taxonomy and Evolution Shanghai Ocean UniversityShanghai 201306China Xuanwei Fisheries Management Station XuanweiYunnan 655499China School of Basic Medical Sciences Guilin Medical UniversityGuilinGuangxi 541001China

Triplophysa xuanweiensis sp.nov.,a new blind loach species from the family Nemacheilidae,is described based on specimens collected from a subterranean river in Xuanwei City,Yunnan Province,China.The new species can be distinguished from all known congeners by a combination of the following characters:eyes absent,dorsal-fin origin anterior to pelvic-fin origin,tip of pelvic fin reaching anus,dorsal fin with 7-8 branched rays,caudal fin forked with 16-18 branched rays,body scaleless and colorless,lateral line complete,and posterior chamber of air bladder well developed and connected to anterior chamber by long,slender tube.

关键词： blind bladder reaching

Research on ozone formation sensitivity based on observational methods:Development history,methodology,and application and prospects in China

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Journal of Environmental Sciences 2024年第4期138卷 543-560页

作者： Wanghui Chu Hong li Yuanyuan Ji Xin Zhang likun xue jian Gao Cong An State Key Laboratory of Environmental Criteria and Risk Assessment Chinese Research Academy of Environmental SciencesBeijing 100012China Environment Research Institute Shandong UniversityQingdao 266237China

Observation-based method for O_(3)formation sensitivity research is an important tool to analyze the causes of ground-level O_(3)pollution,which has broad application potentials in determining the O_(3)pollution formation mechanism and developing prevention and control strategies.This paper outlined the development history of research on O_(3)formation sensitivity based on observational methods,described the principle and applicability of the methodology,summarized the relative application results in China and provided recommendations on the prevention and control of O_(3)pollution in China based on relevant study results,and finally pointed out the shortcomings and future development prospects in this field in China.The overview study showed that the O_(3)formation sensitivity in some urban areas in China in recent years presented a gradual shifting tendency from the VOC-limited regime to the transition regime or the NO_(x)-limited regime due to the implementation of the O_(3)precursors emission reduction policies;O_(3)pollution control strategies and precursor control countermeasures should be formulated based on local conditions and the dynamic control capability of O_(3)pollution control measures should be improved.There are still some current deficiencies in the study field in China.Therefore,it is recommended that a stereoscopic monitoring network for atmospheric photochemical components should be further constructed and improved;the atmospheric chemical mechanisms should be vigorously developed,and standardized methods for determining the O_(3)formation sensitivity should be established in China in the near future.

关键词： Observation-based method Ozone formation sensitivity Ozone pollution prevention and control VOCs NO_(x) OBM

Hexagonal boron nitride based slippery liquid infused porous surface with anti-corrosion, anti-contaminant and anti-icing properties for protecting magnesium alloy

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Chinese Chemical Letters 2024年第4期35卷 532-538页

作者： Wenhao Yan Shuaiya xue xuerui Zhao Wei Zhang jian li Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education College of Chemistry and Chemical EngineeringNorthwest Normal UniversityLanzhou 730070China

In an era where the concept of green development is deeply rooted, magnesium(Mg) alloy as a light metal has a long-term development prospect in the process of energy saving, emission reduction and environmental improvement. However, anti-corrosion performance of Mg alloy is poor due to the high chemical activity and low equilibrium potential, which limits the development of Mg alloy products.Herein, three-dimensional mesopore hollow polypyrrole spheres(MHPS) were prepared, and the MHPS was inserted into the middle of the stacked hexagon boron nitride(h-BN) lamellae, which allowed the hBN to be separated forming a further composite with abundant pore structure. Subsequently, the MHPS/hBN-OH composite was uniformly sprayed on the Mg alloy surface via simple spraying method to form the superhydrophobic surface(SHS). Finally, the slippery liquid infused porous surface(SliPS) was successfully fabricated by applying drops of silicone lubricant on the superhydrophobic coating surface. After a series of characterization and testing, the results showed that the stacking of h-BN lamellae was significantly reduced after h-BN was successfully embedded by MHPS. In addition, the fabricated SliPS have excellent self-cleaning, mechanical stability, anti-icing and anti-corrosion properties. Therefore, the method of embedding polymer microspheres not only offers a new strategy for h-BN exfoliation, but also the successful prepared SliPS largely retards the corrosion of Mg alloy while providing new ideas for the development of SliPS.

关键词： Anti-corrosion Mg alloy Hexagon boron nitride Polypyrrole SliPS

LaMnO_(3)/Co_(3)O_(4) nanocomposite for enhanced triethylamine sensing properties

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Journal of Rare Earths 2024年第4期42卷 733-742页

作者： jian Zhang Yanping Chen ling li xue Chen Wenya An Xiujuan Qian Yuye Tao School of Science Shandong Jianzhu UniversityJinan250100China

LaMnO_(3) modified Co_(3)O_(4) nanocomposites were prepared by simple hydrothermal method co mbined with sol-gel method.The gas sensitivity properties of pure Co_(3)O_(4) and LaMnO_(3)/Co_(3)O_(4) with different composite proportions are compared.It is found that 0.6-LMO/Co_(3)O_(4) sensor has higher sensitivity to triethylamine(TEA)than pure Co_(3)O_(4) sensor,which is improved by 9.27 times.And the working temperature is reduced from 150 to 130℃.Besides,it has excellent gas selectivity and repeatability.The improvement of the gas sensitivity of LaMnO_(3)/Co_(3)O_(4) sensor may be due to the fact that LaMnO_(3) is an effective catalyst,and the catalytic performance perhaps is beneficial to improving the sensing performance.In addition,the formation of p-p heterojunctions may be the key factor to improve the gas sensing performance.This work provides a new Co_(3)O_(4)-based gas sensing material for the detection of TEA.

关键词： Gas sensing Co_(3)O_(4) LaMnO_(3) Triethylamine Rareearths

Ni-Catalyzed Enantioselective Difunctionalization of Alkynes to Azepine Derivatives Bearing a Quaternary Center and an Unprotected Imine

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Chinese Journal of Chemistry 2024年第8期42卷 873-878页

作者： jian Long Zhiwu Lu Xiao-lin li Peng xue Wen-Bo liu Engineering Research Center of Organosilicon Compounds&Materials(Ministry of Education)and College of Chemistry and Molecular Sciences Wuhan UniversityWuhanHubei430072 China

Comprehensive Summary,The azepine ring is a prominent structural scaffold in biologically significant molecules. In this study, we present a Ni(II)-catalyzed asymmetric difunctionalization of alkynes, involving intermolecular regioselective arylation and intramolecular nitrile addition, enabling the synthesis of enantioenriched azepine derivatives. This reaction simultaneously installs an all-carbon quaternary stereocenter and introduces an unprotected imine functionality, showing great promise for subsequent transformations. The reaction exhibits good tolerance toward various functional groups, resulting in high yields and enantioselectivities. The synthetic utility of this methodology is further demonstrated through gram-scale synthesis and product derivatization. This research offers an efficient approach to the synthesis of seven-membered nitrogen heterocycles.

关键词： Nickel Asymmetric catalysis N-Heterocycles Alkyne functionalization Quaternary centers

Synthetic Control of Thorium Metal-Organic Frameworks for Sequencing and Sensing of Radioiodine Species

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Chinese Journal of Chemistry 2024年第1期42卷 20-28,I0004页

作者： Yu Ju Zi-jian li xue Wang Jie Qiu Yiuhon Chan Zhi-Hui Zhang Mingyang He jian lin jiangsu Key Laboratory of Advanced Catalytic Materials and Technology Changzhou UniversityNo.21Gehu Middle RoadChangzhouJiangsu 213164China Schoolof Nuclear Science and Technology Xi'an Jiaotong UniversityNo.28West Xianning RoadXianShaanxi 710049China Key Laboratoryof Interfacial Physics and Technology Shanghai Institute of Applied PhysicsChinese Academy of Sciences2019JiaLuoRoadShanghai 201800China

Exploring the physiochemical properties and expanding the applications of actinide-containing materials is paramount to address the escalating challenge of radioactive waste accumulation.However,unlocking the full potential of these materials is largely crippled by the radiotoxicity of the actinides.We report here two porous and luminescent thorium-based metal-organic frameworks(Th-BITD-1 and Th-BITD-2)that serve as a bifunctional platform for sequencing and sensing of radioiodine,a much more radioactive fission product discharged during the nuclear fuel reprocessing.In particular,Th-BITD-1 displays better iodine uptake performance than Th-BITD-2 via the solution-based process and vapor diffusion with the maximum adsorption capacities of 831 and 1099 mg/g,respectively.Fur thermore,Th-BITD-1 can function as a highly sensitive luminescence sensor for iodate with a quenching constant(Ksv)of 6.6(5)×10^(3) M^(-1)and a detection limit of 2.02μM,respectively,outperforming 2.96(6)×10^(3)M^(-1)and 10.5μM of Th-BITD-2.Moreover,a positive correlation between the sensing efficacy and the iodate adsorption capacity has been revealed.This work highlights the opportunity in designing novel actinide-based MOFs for their potential applications in radiological fields,e.g.,radionuclide separation and detection.

关键词： Thorium Metal-organic frameworks Adsorption Detection lodine Actinides Radiochemistry Luminescence

Nano-alumina@cellulose-coated separators with the reinforcedconcrete-like structure for high-safety lithium-ion batteries

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Chinese Journal of Chemical Engineering 2024年第4期68卷 83-93页

作者： Zhihao Yang li Chen jian xue Miaomiao Su Fangdan Zhang liangxin Ding Suqing Wang Haihui Wang Guangdong Provincial Key Lab of Green Chemical Product Technology School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640China Beijing Key Laboratory of Membrane Materials and Engineering Department of Chemical EngineeringTsinghua UniversityBeijing 100084China

Separators play a critical role in the safety and performance of lithium-ion batteries.However,commercial polyolefin separators are limited by their poor affinity with electrolytes and low melting points.In this work,we constructed a reinforced-concrete-like structure by homogeneously dispersing nano-Al_(2)O_(3) and cellulose on the separators to improve their stability and performance.In this reinforcedconcrete-like structure,the cellulose is a reinforcing mesh,and the nano-Al_(2)O_(3) acts as concrete to support the separator.After constructing the reinforced-concrete-like structure,the separators exhibit good stability even at 200℃(thermal shrinkage of 0.3%),enhanced tensile strain(tensile stress of 133.4 MPa and tensile strains of 62%),and better electrolyte wettability(a contact angle of 6.5°).Combining these advantages,the cells with nano-Al_(2)O_(3)@cellulose-coated separators exhibit stable cycling performance and good rate performance.Therefore,the construction of the reinforced-concretelike structure is a promising technology to promote the application of lithium-ion batteries in extreme environments.

关键词： Alumina Nanomaterials lithium-ion batteries Membranes Cellulose Reinforced-concrete-like structure

Persymmetric adaptive polarimetric detection of subspace range-spread targets in compound Gaussian sea clutter

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Journal of Systems Engineering and Electronics 2024年第1期35卷 31-42页

作者： XU Shuwen HAO Yifan WANG Zhuo xue jian National Key Laboratory of Radar Signal Processing Xidian UniversityXi’an 710071China Xi’an Electronic Engineering Research Institute Xi’an 710100China Beijing Institute of Radio Measurement Beijing 100039China School of Communications and Information Engineering Xi’an University of Posts and TelecommunicationsXi’an 710121China

This paper focuses on the adaptive detection of range and Doppler dual-spread targets in non-homogeneous and nonGaussian sea clutter.The sea clutter from two polarimetric channels is modeled as a compound-Gaussian model with different parameters,and the target is modeled as a subspace rangespread target model.The persymmetric structure is used to model the clutter covariance matrix,in order to reduce the reliance on secondary data of the designed detectors.Three adaptive polarimetric persymmetric detectors are designed based on the generalized likelihood ratio test(GLRT),Rao test,and Wald test.All the proposed detectors have constant falsealarm rate property with respect to the clutter texture,the speckle covariance matrix.Experimental results on simulated and measured data show that three adaptive detectors outperform the competitors in different clutter environments,and the proposed GLRT detector has the best detection performance under different parameters.

关键词： sea clutter adaptive polarimetric detection compound Gaussian model subspace range-spread target persymmetric structure