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Anomalous thermal expansion and enhanced magnetocaloric effect in<001>-textured Mn_(x)Fe_(5-x)Si_(3) alloys

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Rare Metals 2024年第5期43卷 2263-2274页

作者： Yong Gong xue-fei miao Tapas Samanta Chris Taake Jun Liu Feng-Jiao Qian Yan-Yan Shao Yu-Jing Zhang Qing-Yong Ren Luana Caron Feng Xu MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials Technology School of Materials Science and EngineeringNanjing University of Science and TechnologyNanjing210094China Department of Physics Bielefeld University33501BielefeldGermany College of Physics Nanjing University of Aeronautics and AstronauticsNanjing210016China Institute of High Energy Physics Chinese Academy of SciencesBeijing100049China Spallation Neutron Source Science Center Dongguan523803China Guangdong-Hong Kong-Macao Joint Laboratory for Neutron Scattering Science and Technology Dongguan523803China Department of Physics Bielefeld University33501BielefeldGermany Helmholtz-Zentrum Berlin für Materialien und Energie12489BerlinGermany

The development of zero and negative therma expansion(i.e.,ZTE and NTE)materials is of crucial importance to the control of undesirable thermal expansion for high-precision *** the present work,ZTE and NTE were obtained in directionally-solidified Mn_(x)Fe_(5-x)Si_(3)alloys with a strongtexture,in striking contrast to positive thermal expansion in their isotropic counterparts Magnetometry and in-situ X-ray diffraction(XRD)measurements were performed to uncover the origin of the anomalous thermal *** measurements indicate a strong easy-plane magnetocrystalline anisotropy in the textured samples,where the magnetic moments are aligned within the ab plane of the hexagonal structure Temperature-dependent XRD on the x=1 sample reveals a ZTE character in the ab plane that is coupled to a ferromagnetic *** a result,the macroscopic ZTE(~0.22×10^(-6)K^(-1))in the x=1 sample can be attributed to the microscopic magneto volume effect within the ab plane,which is realized by the introduction of the-textured ***,the competition between antiferromagnetic and ferromagnetic exchange coupling leads to NTE in textured x=1.5 and 2 ***,textured x=1 sample displays enhanced magnetocaloric properties as compared to the conventional counterparts with randomly-oriented *** this work demonstrates a new strategy toward the exploration of anomalous thermal expansion properties as well as the enhancement of magnetocaloric properties for materials with a strong magnetocrystalline anisotropy.

关键词： MnFeySis Magnetocaloric effect Magnetic phase transition Negative thermal expansion

Security Model for Analyzing Data Privacy in Multipath Transport

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China Communications 2012年第5期9卷 32-41页

作者： Song fei xue miao Zhang Sidong Beijing Jiaotong Univ Sch Elect & Informat Engn Natl Engn Lab Next Generat Internet Interconnect Beijing 100044 Peoples R China

In order to investigate the enhancement of data privacy by distributing data packets via multiple paths, this paper fommlates a security model and analyzes the privacy problem in mul- tipath scenarios leveraging inforrmtion theoretic concept. Based on proposed model, a privacy function related to the path number is discussed. We heuristically recommend the optin^al path num- ber and analyze the tradeoff among the perform- ance, resource consumption and privacy. For re- ducing the inforlmtion leakage, the data schedule algorithms are also proposed. The analytical model can provide guidelines for the multipath protocol design.

关键词： data privacy multipath transport in-formation theory tradeoff

Chlorine-rich lithium argyrodites enables superior performances for solid-state Li-Se batteries at wide temperature range

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Rare Metals 2022年第12期41卷 4065-4074页

作者： Jin-Yan Lin Shuai Chen Jia-Yang Li Dian Yu Xiang-Ling Xu Chuang Yu Shao-Qing Chen xue-fei miao Lin-Feng Peng Chao-Chao Wei Chong-Xuan Liu Shi-Jie Cheng Jia Xie State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Materials Huazhong University of Science and TechnologyWuhan 430074China Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen 518055China Key Laboratory of Advanced Metallic and Intermetallic Materials Technology School of Materials Science and EngineeringNanjing University of Science and TechnologyNanjing 210094China School of Environmental Science and Engineering Southern University of Science and TechnologyShenzhen 518055China

All-solid-state Li-Se battery shows great potential as a candidate for next-generation energy storage devices due to its high energy density and ***,the low ionic conductivity of the solid electrolytes and large volume changes of Se active materials are two of the major issues that limit its ***,a simple solid-state reaction method is applied to synthesize chlorine-rich argyrodite Li_(5.5)PS_(4.5)CI_(1.5)electrolyte with high conductivity of 6.25 mS·cm^(-1)at room *** nanotube(CNT)is introduced as the host for Se to obtain Se/CNT composite with both enhanced electronic conductivity and lower volume expansion during the electrochemical reaction ***-solid-state Li-Se battery using Li_(5.5)PS_(4.5)CI_(1.5)as solid electrolyte combined with Se/CNT cathode and Li-In anode shows a discharge capacity of 866 mAh·g-1for the 2nd cycle under0.433 mA·cm-2at room ***,the assembled battery delivers a high discharge capacity of1026 mAh·g^(-1)for the 2nd cycle when cycled at the same current density at 60℃and maintains a discharge capacity of 380 mAh·g^(-1)after 150 *** to the high Li-ion conductivity of Li_(5.5)PS_(4.5)CI_(1.5)electrolyte,the assembled battery displays a high discharge capacity of 344 mAh·g^(-1)under 0.113 mA·cm^(-2)at-20℃C and remains 66.1%after200 *** addition,this all-solid-state Li-Se battery shows ultralong cycling performances up to 1000 cycles under 0.433 mA·cm^(-2)at-20℃.This work offers the design clue to fabricate the all-solid-state Li-Se battery workable at different operating temperatures with an ultralong cycling life.

关键词： Lithium argyrodite Chlorine-rich All-solidstate Li-Se batteries Operating temperatures Long cycling performances

Frontiers in high entropy alloys and high entropy functional materials

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Rare Metals 2024年第10期43卷 4639-4776页

作者： Wen-Tao Zhang xue-Qian Wang Feng-Qi Zhang Xiao-Ya Cui Bing-Bing Fan Jia-Ming Guo Zhi-Min Guo Rui Huang Wen Huang Xu-Bo Li Meng-Ru Li Yan Ma Zhi-Hua Shen Yong-Gang Sun De-Zhuang Wang fei-Yang Wang Li-Qiang Wang Nan Wang Tian-Li Wang Wei Wang Xiao-Yang Wang Yi-Han Wang Fu-Jie Yu Yu-Zhen Yin Ling-Kun Zhang Yi Zhang Jian-Yang Zhang Qi Zhao Yu-Ping Zhao Xin-Dong Zhu Yasir Sohail Ya-Nan Chen Tao Feng Qi-Long Gao Hai-Yan He Yong-Jiang Huang Zeng-Bao Jiao Hua Ji Yao Jiang Qiang Li Xiao-Ming Li Wei-Bing Liao Huai-Jun Lin Hui Liu Qi Liu Qing-Feng Liu Wei-Di Liu Xiong-Jun Liu Yang Lu Yi-Ping Lu Wen Ma xue-fei miao Jie Pan Qing Wang Hong-Hui Wu Yuan Wu Tao Yang Wei-Ming Yang Qian Yu Jin-Yu Zhang Zhi-Gang Chen Liang Mao Yang Ren Bao-Long Shen Xun-Li Wang Zhe Jia He Zhu Zhen-Duo Wu Si Lan School of Materials Science and Engineering Nanjing University of Science and TechnologyNanjing 210094China Jiangsu Key Laboratory for Advanced Metallic Materials School of Materials Science and EngineeringSoutheast UniversityNanjing 211189China Department of Physics City University of Hong KongHongKong 999077China School of Materials Science and Engineering Tianjin UniversityTianjin 300072China School of Physics and Microelectronics Zhengzhou UniversityZhengzhou 450001China Department of Mechanical Engineering Research Institute for Advanced ManufacturingThe Hong Kong Polytechnic UniversityHong Kong 100872China Center of Electron Microscopy and State Key Laboratory of Silicon Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027China Key Laboratory of Solidification Control and Digital Preparation Technology(Liaoning Province) School of Materials Science and EngineeringDalian University of TechnologyDalian 116024China Institute of Advanced Wear&Corrosion Resistance and Functional Materials Jinan UniversityGuangzhou 510632China School of Mechanics and Civil Engineering China University of Mining and TechnologyXuzhou 221116China School of Physical Sciences Great Bay UniversityDongguan 523000China School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001China State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing 211816China Beijing Advanced Innovation Center for Materials Genome Engineering Research Institute for Carbon NeutralityUniversity of Science and Technology BeijingBeijing 100083China Department of Mechanical Engineering The University of Hong KongHong Kong 999077China School of Computing Macquarie UniversitySydney 2113Australia Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province College of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen 518060China State Key Laborato

Owing to their exceptional properties,high-entropy alloys(HEAs)and high-entropy materials have emerged as promising research areas and shown diverse ***,the recent advances in the field are comprehensively reviewed,organized into five *** first section introduces the background of HEAs,covering their definition,significance,application prospects,basic properties,design principles,and *** subsequent section focuses on cutting-edge high-entropy structural materials,highlighting developments such as nanostructured alloys,grain boundary engineering,eutectic systems,cryogenic alloys,thin films,micro-nano-lattice structures,additive manufacturing,high entropy metallic glasses,nano-precipitate strengthened alloys,composition modulation,alloy fibers,and refractory *** the following section,the emphasis shifts to functional materials,exploring HEAs as catalysts,magneto-caloric materials,corrosion-resistant alloys,radiation-resistant alloys,hydrogen storage systems,and materials for ***,the review encompasses functional high-entropy materials outside the realm of alloys,including thermoelectric,quantum dots,nanooxide catalysts,energy storage materials,negative thermal expansion ceramics,and high-entropy wave absorption *** paper concludes with an outlook,discussing future directions and potential growth areas in the *** this comprehensive review,researchers,engineers,and scientists may gain valuable insights into the recent progress and opportunities for further exploration in the exciting domains of high-entropy alloys and functional materials.

关键词： High entropy alloys Cutting-edge structural materials Cutting-edgefunctional materials

Magnetic resonance imaging and Crohn's disease endoscopic index of severity: Correlations and concordance

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World Journal of Gastroenterology 2018年第21期24卷 2279-2290页

作者： Nai-Yi Zhu xue-Song Zhao fei miao Department of Radiology Ruijin HospitalShanghai Jiao Tong University School of Medicine

AIM To examine the correlation between magnetic resonance imaging(MRI) and endoscopic index of severity(CDEIS) in patients with Crohn's disease(CD).METHODS This was a retrospective study of 104 patients with CD that were treated at the Ruijin Hospital between March 2015 and May 2016. Among them, 61 patients with active CD were evaluated before/after treatment. MRI and endoscopy were performed within 7 d. CDEIS was evaluated. MRI parameters included Ma RIA scores, total relative contrast enhancement(tRCE), arterialRCE(aRCE), portalRCE(pRCE), delay phaseRCE(dRCE), and apparent diffusion coefficient. The correlation and concordance between multiple MRI findings and CDEIS changes before and after CD treatment were *** Among the 104 patients, 61 patients were classified as active CD and 43 patients as inactive CD. Gender, age, disease duration, and disease location were not significantly different between the two groups(all P > 0.05). CRP levels were higher in the active group than in the inactive group(25.12 ± 4.12 vs 5.14 ± 0.98 mg/L, P < 0.001). Before treatment, the correlations between CDEIS and MaRIAs in all patients were r = 0.772 for tRCE, r = 0.754 for aRCE, r = 0.738 for pRCE, and r = 0.712 for dRCE(all MaRIAs, P < 0.001), followed by MRI single indexes. Among the active CD patients, 44 cases were remitted to inactive CD after treatment. The correlations between CDEIS and MaRIAs were r = 0.712 for aRCE, r = 0.705 for tRCE, r = 0.685 for pRCE, and r = 0.634 for dRCE(all MaRIAs, P < 0.001).CONCLUSION Arterial Ma RIA should be an indicator for CD follow-up and dynamic assessment. CD treatment assessment was not completely concordant between CDEIS and MRI.

关键词： Magnetic resonance imaging Bowel Crohn’s disease Crohn’s disease endoscopic index of severity Concordance

Numerical method of static aeroelastic correction and jig-shape design for large airliners

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Science China(Technological Sciences) 2012年第9期55卷 2447-2452页

作者： HUANG Wei LU ZhiLiang GUO TongQing xue fei ZHANG miao Department of Aerodynamics Nanjing University of Aeronautics and AstronauticsNanjing 210016China Shanghai Aircraft Design and Research Institute Shanghai 200232China

In this paper,a coupled CFD-CSD method based on N-S equations is described for static aeroelastic correction and jig-shape design of large *** wing structural flexibility matrix is analyzed by a finite element method with a double-beam *** viscous multi-block structured grid is used in aerodynamic *** matrix interpolation is fulfilled by use of a surface spline *** load distributions on wing surface are evaluated by solving N-S equations with a parallel algorithm.A flexibility approach is employed to calculate the structural *** successive iterations between steady aerodynamic forces and structural deformations,a coupled CFD-CSD method is achieved for the static aeroelastic correction and jig-shape design of a large *** present method is applied to the static aeroelastic analysis and jig-shape design for a typical large airliner with engine nacelle and *** numerical results indicate that calculations of static aeroelastic correction should employ tightly coupled CFD-CSD iterations,and that on a given cruise shape only one round of iterative design is needed to obtain the jig-shape meeting design requirements.

关键词： N-S equations large airliner static aeroelasticity flexibility matrix jig-shape

Special diaphragm-like strictures of small bowel unrelated to non-steroidal anti-inflammatory drugs

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World Journal of Gastroenterology 2011年第31期17卷 3596-3604页

作者： Ming-Liang Wang fei miao Yong-Hua Tang xue-Song Zhao Jie Zhong fei YuanMing-Liang Department of Radiology Ruijin HospitalShanghai Jiao Tong University School of MedicineShanghai 200025China Department of Gastroenterology Ruijin HospitalShanghai Jiao Tong University School of MedicineShanghai 200025China Department of Pathology Ruijin HospitalShanghai Jiao Tong University School of MedicineShanghai 200025China

AIM:To summarize clinical,endoscopic,radiologic and pathologic features of special diaphragm-like strictures found in small bowel,with no patient use of nonsteroidal anti-inflammatory drugs(NSAIDs).METHODS:From January 2000 to fecember 2009,5 cases(2 men and 3 women,with a mean age of 41.6 years) were diagnosed as having diaphragm-like strictures of small bowel on imaging,,operation and *** the patients denied the use of *** clinical,endoscopic,radiologic and pathologic findings in these 5 patients were retrospectively reviewedfrom the hospital *** of capsule endoscopy(CE) and small bowel follow-through(SBFT) obtained in 3 and 3 patients,respectively,and images of double-balloon enteroscopy and computed tomography enterography(CTE) obtained in all 5 patients were available for ***:All patients presented with long-term(2-16 years) symptoms of gastrointestinal bleeding and varying degrees of *** was only one stricture in ?our cases and three lesions in one case,and all the lesions were located in the middle or distal segment of *** stricture was shown in the small bowel in three cases in the CE image,but the capsule was retained in the small bowel of 2 *** abdomen computed tomography scan showed no other abnormal results except gallstones in one *** lesions were shown as circumferential strictures accompanied by dilated small bowel loops in the small bowel on the images of CTE(in all 5 cases),SBFT(in 2 cases) and double-balloon enteroscopy(in all cases).On microscopy,a chronic inflammatory infiltrate and circumferential diaphragm were found in all ***:fiaphragm-like strictures of small bowel might be a special consequence of unclear damaging insults to the intestine,having similar clinical,endoscopic,radiologic and pathologic features.

关键词： Small bowel Gastrointestinal bleeding Diaphragm Stricture Endoscopy Computed tomography Enterography

COPPER(0)-MEDIATED RADICAL POLYMERIZATION OF STYRENE AT ROOM TEMPERATURE

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Chinese Journal of Polymer Science 2013年第4期31卷 702-712页

作者： Xiao-fei Zhang Yang Wu Jun Huang xue-lang miao 张正彪朱秀林 Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application Department of Polymer Science and EngineeringCollege of ChemistryChemical Engineering and Materials ScienceSoochow University

The ＂living＇/controlled radical polymerization （LRP） of styrene （St） at room temperature is rarely reported. In this work, copper（0）（Cu（0））-mediated radical polymerization of St at room temperature was investigated in detail. Dimethyl sulfoxide （DMSO）, N,N-dimethylformamide （DMF） as well as a binary solvent, tetrahydrofuravdl,l,l,3,3,3-hexafluoro-2- propanol were used as the solvents, respectively. Methyl-2-bromopropionate and ethyl 2-bromoisobutyrate were used as the initiators, respectively. The polymerization proceeded smoothly with moderate conversions at room temperature. It was found that DMF was a good solvent with the essential features of LRP, while DMSO was a poor solvent with uncontrollable molecular weights. Besides, the match among the initiator, solvent and molar ratios of reactants can modulate the livingness of the polymerization, and the proper selection of ligand was also crucial to a controlled process. This work provided a first example of Cu（0）-mediated radical polymerization of St at room temperature, which would enrich and strength the LRP technique.

关键词： Gel permeation chromatography (GPC) Kinetics (polym.) Cu(0)-mediated radical polymerization Styrene.

Electrochemical energy storage applications of “pristine” graphene produced by non-oxidative routes

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Science China(Technological Sciences) 2015年第11期58卷 1841-1850页

作者： LIU fei xue DongFeng State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences

Graphene is a promising material as both active components and additives in electrochemical energy storage devices. The properties of graphene strongly depend on the fabrication methods. The applications of reduced graphene oxide as electrode materials have been well studied and reviewed, but the using of "pristine" graphene as electrode material for energy storage is still a new topic. In this paper, we review state-of-the-art progress in the fabrication of "pristine" graphene by different methods and the electrochemical performance of graphene-based electrodes. The achievements in this area will be summarized and compared with the graphene oxide route in terms of cost, scalability, material properties and performances, and the challenges in these methods will be discussed as well.

关键词： pristine graphene energy storage exfoliation electrochemical