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Electrochemical Study on the Interaction of Protein with Bromothymol Blue and Its Analytical Application

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Chemical Research in Chinese Universities 2008年第6期24卷 701-706页

作者： WANG xue-liang yang Jie jiao Kui College of Chemistry and Molecular Engineering Qingdao University of Science and Technology Qingdao 266042 P. R. China

The interaction of bromothymol blue（BB） with human serum albumin（HSA） was studied by electrochemical techniques and a sensitive method for proteins assay was developed. When BB interacted with HSA, the voltammetric peak current value of BB decreased linearly with the concentration of HSA in a range of 1.0--40.0 mg/L, and the peak potential shifted negatively. Based on the results, a sensitive assay method for proteins, such as HSA, bovine serum albumin（BSA）, and egg albumin etc. was established. This method was further applied to determining the HSA in healthy human blood samples, and the results are not significantly different from those obtained by the classic Coomassie Brilliant Blue G-250 spectrophotometic method. The detecting conditions of this method were optimized and the interaction mechanism was discussed. The results show that the electrochemical parameters（formal potential E^0, standard rate constant of the electrode reaction ks, parameter of kinetic nα） of BB have no obvious changes before and after the interaction, which indicate that BB can interact with HSA, forming an electrochemical non-active complex. The equilibrium constant（βs） and the binding ratio（m） for this complex were calculated. The m is 4 and βs is 1.41 × 10^19. This method is fast, simple, highly sensitive, and has good selectivity, which can be used in clinical measurements.

关键词： Bromothymol blue(BB) Human serum albumin Serum sample Voltammetry

Regulation of substrate surface topography on differentiation of mesenchymal stem cells

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Acta Mechanica Sinica 2020年第5期36卷 1158-1169,I0004页

作者： Bo Huo yang Zhao xue Bai Qing Sun Fei jiao Biomechanics Lab Department of MechanicsSchool of Aerospace EngineeringBeijing Institute of TechnologyBeijing 100081China

Mesenchymal stem pells(MSCs)have been extensively used in the field of tissue engineering and regenerative *** effect of surface properties on the differentiation of MSCs is a very important issue for the design and fabrication of scaffolds or *** review is mainly focused on the morphological or topographic characteristics of cell adhesion substrate,*** area and shape for individual cell,cell density and cell-cell contact for multiple cells,substrate roughnessridge width,micropillar height,nanoparticle diameter and aspect ratio of *** results from different studies were quantitativcly analyzed using comparable or unified parameters and definitions under the specific experimental conditions such as cell source,culture time,induction medium,matrix material and differentiation *** interesting phenomena and properties were discovered by this integrated and systematic analysis,which might give insights into the regulatory mechanism of surface morphology or topography on MSCs differentiation.

关键词： Mesenchymal stem cell Adhesion morphology Surface topography Differentiation Biomaterial

Microcrack-and microvoid-related impact damage and ignition responses for HMX-based polymer-bonded explosives at high temperature

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Defence Technology（防务技术） 2022年第9期18卷 1602-1621页

作者： Hai-jiao xue Yan-qing Wu Kun yang Yi Wu State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing100081China School of Aerospace Engineering Beijing Institute of TechnologyBeijing100081China

Investigating the damage and ignition behaviors of polymer-bonded explosive(PBX) under a coupled impact and high-temperature loading condition is required for the safe use of charged PBXs. An improved combined microcrack and microvoid model(CMM) was developed for better describing the thermal effects of deformation, damage, and ignition responses of PBXs. The main features of the model under typical dynamic loadings(i.e. uniaxial tension and compression, and lateral confinement) at different initial temperature were first studied. And then the effects of temperature on impact-shear sensitivity of HMX-based PBXs were investigated. The results showed that the ignition threshold velocity of shear-crack hotspots exhibits an increase from 260 to 270 to 315-325 m/s when initial temperature increases from 301 to 348 K;and then the threshold velocity decreases to 290-300 m/s with the initial temperature continually increasing to 378 K. The predicted ignition threshold velocity level of the explosives under coupled impact and high temperature loading conditions were consistent with the experimental data.

关键词： PBX Thermal-mechanical coupling Numerical simulation Impact Sensitivity

Electrochemical Study of Lincomycin on Au-PtNPs/nanoPAN/ Chitosan Nanocomposite Membrane and Its Determination in Injections

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Chemical Research in Chinese Universities 2010年第3期26卷 371-375页

作者： WANG xue-liang yang Tao jiao Kui College of Chemistry and Molecular Engineering Qingdao University of Science and Technology Qingdao 266042 P. R. China

The Au-Pt alloy nanoparticles（Au-PtNPs） were electrochemically deposited on the surface of polyaniline nanotube（nanoPAN） and chitosan（CS） modified glassy carbon electrode（GCE）. The electrochemical behavior of lincomycin at Au-PtNPs/nanoPAN/CS modified GCE was investigated by cyclic voltammetry, linear sweep voltammetry and chronocoulometry. Cyclic voltammetric experiments show that lincomycin at the nanocomposite membrane modified electrode exhibited a pair of quasi-reversible redox peaks in pH=6.0 PBS. The membrane could accelerate the electron transfer of lincomycin on the electrode and significantly enhance the peak current. In a range of 3.0-100.0 mg/L, the reductive peak current of lincomycin at 0.42 V was linearly related to its concentration and the linear regression equation was ip,c=0.2703ρ-0.0042（ip, c： μA; ρ： mg/L; r=0.998, n=7） with a detection limit of 1.0 mg/L（S/N =3）. Compared with other methods, this method exhibited many advantages such as high sensitivity, selectivity, wide linear range and low detection limit. The method was used to determine the content of lincomycin in injections commercially available with satisfactory results. Some electrochemical parameters involved in the redox reaction of lincomycin, such as parameter of kinetic ha, standard rate constant ks and the number of H^＋, were also calculated.

关键词： Lincomycin Au-Pt alloy nanoparticle Polyaniline nanotube Nanocomposite membrane

高压下Fe_(2)S的相变及热力学性质的第一性原理研究

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原子与分子物理学报 2025年第5期42卷 102-107页

作者：余柏树焦亩鑫杨学楠曾召益重庆师范大学物理与电子工程学院重庆401331

本文采用基于密度泛函理论的赝势平面波方法研究了高压下Fe_(2)S的结构相变、弹性性质和热力学性质.计算表明,当压强增加到124±10 GPa时,Fe_(2)S(Co_(2)P型)的晶格常数发生了突变,轴向比c/a从1.20跃迁到1.35,向C37结构(Co_(2)Si型)转变... 详细信息

本文采用基于密度泛函理论的赝势平面波方法研究了高压下Fe_(2)S的结构相变、弹性性质和热力学性质.计算表明,当压强增加到124±10 GPa时,Fe_(2)S(Co_(2)P型)的晶格常数发生了突变,轴向比c/a从1.20跃迁到1.35,向C37结构(Co_(2)Si型)转变.弹性模量的计算结果也证实了Fe_(2)S的这一结构相变.根据弹性模量,获得了高压下Fe_(2)S的声速,相对于纯Fe,S元素提升了纵波声速.通过准谐德拜模型预测了200 GPa,2000 K范围内Fe_(2)S的热力学性质.

关键词：相变弹性性质热力学性质第一性原理

Kinetics and mechanism of hexavalent chromium removal by basic oxygen furnace slag

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Journal of Environmental Sciences 2016年第8期28卷 63-71页

作者： Chong Han Yanan jiao Qianqian Wu Wangjin yang He yang Xiangxin xue School of Metallurgy Northeastern University

Basic oxygen furnace slag（BOFS） has the potential to remove hexavalent chromium（Cr（VI））from wastewater by a redox process due to the presence of minerals containing Fe2＋. The effects of the solution p H, initial Cr（VI） concentration, BOFS dosage, BOFS particle size, and temperature on the removal of Cr（VI） was investigated in detail through batch tests. The chemical and mineral compositions of fresh and reacted BOFS were characterized using scanning electron microscope（SEM） equipped with an energy dispersive spectrometer（EDS）system and X-ray diffractometer（XRD）. The results show that Cr（VI） in wastewater can be efficiently removed by Fe2＋released from BOFS under appropriate acidic conditions. The removal of Cr（VI） by BOFS significantly depended on the parameters mentioned above. The reaction of Cr（VI） with BOFS followed the pseudo-second-order kinetic model. Fe2＋responsible for Cr（VI） removal was primarily derived from the dissolution of Fe O and Fe3O4 in BOFS. When H2SO4 was used to adjust the solution acidity, gypsum（Ca SO4·2H2O）could be formed and become an armoring precipitate layer on the BOFS surface, hindering the release of Fe2＋and the removal of Cr（VI）. Finally, the main mechanism of Cr（VI） removal by BOFS was described using several consecutive reaction steps.

关键词： Hexavalent chromium Basic oxygen furnace slag Fe2+ Redox process Kinetics

Synthesis of uniform two-dimensional MoS_(2) films via thermal evaporation

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Nano Research 2024年第4期17卷 3217-3223页

作者： xue-Wei Lu Zhewei Li Chen-Kai yang Weijia Mou Liying jiao Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education Department of ChemistryTsinghua UniversityBeijing 100084China

Two-dimensional(2D)molybdenum disulfide(MoS_(2))holds great potential for various applications such as electronic devices,catalysis,lubrication,anti-corrosion and so *** evaporation is a versatile thin film deposition technique,however,the conventional thermal evaporation techniques face challenges in producing uniform thin films of MoS_(2) due to its high melting temperature of 1375℃.As a result,only thick and rough MoS_(2) films can be obtained using these *** address this issue,we have designed a vacuum thermal evaporation system specifically for large-scale preparation of MoS_(2) thin *** using K2MoS4 as the precursor,we achieved reliable deposition of uniform polycrystalline MoS_(2) thin films with a size of 50 mm×50 mm and controllable thickness ranging from 0.8 to 2.4 *** approach also allows for patterned deposition of MoS_(2) using shadow masks and sequential deposition of MoS_(2) and tungsten disulfide(WS_(2)),similar to conventional thermal evaporation ***,we have demonstrated the potential applications of the obtained MoS_(2) thin films in field effect transistors(FETs),memristors and electrocatalysts for hydrogen evolution reaction(HER).

关键词： thermal evaporation molybdenum disulfide two-dimensional memristors hydrogen evolution reaction

Physical rehabilitation for sensorineural hearing loss in childhood:Progress and challenges

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World Journal of Clinical Cases 2025年第7期13卷 57-62页

作者： Lu Zhang Pu-Jue Huang xue Deng jiao Tang yang Zhai Tao Wang Department of Pediatrics Luzhou Maternal and Child Health HospitalLuzhou 646600Sichuan ProvinceChina Department of Pediatrics West China Second University HospitalSichuan UniversityChengdu 610041Sichuan ProvinceChina Department of Pediatrics The First People's Hospital of Longquanyi DistrictChengdu 610100Sichuan ProvinceChina Ministry of Education Key Laboratory of Birth Defects and Related Diseases of Women and Children(Sichuan University)Chengdu 610041Sichuan ProvinceChina Department of Pediatrics Chengdu Women’s and Children’s Central HospitalChengdu 610000Sichuan ProvinceChina

Early intervention for sensorineural hearing loss(SNHL)in childhood is crucial for auditory and language *** recent years,innovative auditory stimulation techniques and speech therapy strategies,such as middle ear implants,cochlear implants,auditory brainstem implants,and midbrain implants,have provided new avenues for improving patient ***,basic research advancements in cell reprogramming and regeneration,stem cell therapy,and targeted drug delivery offer promising approaches to meet the individualized needs of children with ***,many challenges and unresolved issues remain in the treatment of *** article comments on the case report,which describes a female pediatric patient with SNHL who underwent foot reflexology which led to the normalization of hearing *** is considered to have potential benefits in physical rehabilitation,but its efficacy in hearing restoration requires further scientific validation through rigorous clinical trials and large-scale prospective studies.

关键词： Sensorineural hearing loss Childhood Physical rehabilitation therapy Recent advances in rehabilitation techniques Reflexology

Evaluation and improvement of pearlite microstructure and mechanical properties in 45Cr4NiMoV and 50Cr5NiMoV steels

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Journal of Iron and Steel Research International 2022年第12期29卷 1995-2005页

作者： Kai-quan Liu xue-jiao Zhang Xiao-yang Song Lin Zhao Lin Zhu State Key Laboratory of Metastable Materials Science and Technology Yanshan UniversityQinhuangdao 066004HebeiChina Tianjin Heavy Industries Research&Development Co. Ltd.CFHITianjin 300457China China First Heavy Industry Qiqihar 161042HeilongjiangChina Central Iron and Steel Research Institute Co. Ltd.Beijing 100081China

The microstructure and mechanical properties of pearlite in 45Cr4NiMoV and 50Cr5NiMoV steels were studied and *** microstructural characteristics of pearlite of two steels were carefully examined by optical microscopy,scanning electron microscopy and transmission electron microscopy(TEM),and the type,size and relative amount of extracted carbide particles were analyzed by X-ray diffraction and TEM coupled with selected area electron *** hardness,tensile property,impact and fracture toughness of pearlite of two steels were also ***,the carbide dissolution kinetics of 45Cr4NiMoV and 50Cr5NiMoV steels were *** results indicated that the carbides in 50Cr5NiMoV steel exhibited higher dissolution temperature than those in 45Cr4NiMoV steel,which induced different morphologies of pearlite after eutectoid *** to the pearlite with lamellar M_(23)C_(6)carbides in 45Cr4NiMoV steel,the pearlite with the mixture of spheroidized M_(7)C_(3)and lamellar M_(23)C_(6)carbides in 50Cr5NiMoV steel possessed higher impact and plane-strain fracture toughness but lower hardness and strength,because different pearlite morphologies led to different mechanical *** order to further improve the comprehensive properties of the steels,the fraction of M_(7)C_(3)for the material with acceptable properties was examined and dissolution kinetic of M_(7)C_(3)was ***,the austenitizing temperature and holding time could be appropriately selected to keep enough undissolved M_(7)C_(3)in the steels.

关键词： Microstructure Carbide Back-up roll Mechanical property Toughness Spheroidization