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Recent progress on photoactive nonprecious transition-metal complexes

Science China Chemistry 2025年第1期68卷 46-95页

作者： Zhong-Liang Gong Hong-Jie Zhang yan Cheng Jianxun Liu Yuhan Ai yaqin Li Zhihui Feng Qiong Zhang Shaolong Gong Yong Chen chang-Jiang yao Yuan-Yuan Zhu Liang-Jin xu Yu-Wu Zhong CAS Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences State Key Laboratory of Structural Cemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences School of Chemistry and Chemical Engineering Anhui Key Laboratory of Advanced Catalytic Materials and Reaction EngineeringHefei University of Technology State Key Laboratory of Explosion Science and Safety Protection School of Mechatronical Engineering Beijing Institute of Technology College of Chemistry and Molecular Sciences Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Wuhan University School of Chemistry and Chemical Engineering Anhui University Key Laboratory of Photochemical Conversion and Optoelectronic Materials & CAS-HKU Joint Laboratory on New Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences

Photoactive complexes of nonprecious transition metals, mainly including those in the first-row and partially the second-row of the Periodic table of elements, have received increasing attention in view of their low cost and long-term sustainability. They are recognized as promising alternatives to noble transition metal complex congeners that have been extensively studied in optoelectronic devices, artificial photosynthesis, photocatalysis, biodiagnostics, and therapeutics, etc. This review is devoted to a comprehensive summary on the classical and recent advances on photoactive nonprecious transition metal complexes, including photoactive Zr, V, Cr, Mo, and W complexes, Mn complexes and hybrids, Fe, Co, Ni, and Cu complexes, and Zn and Cd complexes and hybrids. A particular focus is given on the molecular design, modulation of photophysical and photochemical properties, and applications of the representative and lately-developed nonprecious metal complexes. In addition, a perspective on the future development in this field is provided at the end of this review.

关键词： photoactive metal complexes earth-abundant metals nonprecious metal complexes luminescence photochemistry

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A versatile synthetic strategy towards rare earth based metal-organic frameworks

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Science China Chemistry 2025年

作者： Quan Shi Yun-Hao xu Ming-Hui Chen Peng Zhao Wen-Bo Deng Ji Xiong Kai Guo ya-Qing Feng Bao Zhang School of Chemical Engineering and Technology Tianjin University Tianjin Collaborative Innovation Center of Chemical Science and Engineering Guangdong Laboratory Chemistry & Fine Chemical Industry Jieyang Center

Rare earth metal-organic frameworks (RE-MOFs) have drawn wide attention owing to diverse network structures and various application ***,due to the unpredictable formation of the nodes,it is still challenging to design novel RE-MOFs.A novel versatile strategy was developed employing a RE-acetate complex (RE2(CH3COO)6·4H2O) as a precursor to construct RE-MOFs.2D RE-MOFs (RE-DBP) and 3D RE-MOFs (RE-TCPP) could be obtained by using dicarboxylic porphyrin ligands H2DBP and tetracarboxylic porphyrin ligands H2TCPP,*** RE-MOFs were further synthesized to verify the universality of the *** crystalline RE-MOFs could also be prepared at room temperature via the developed strategy,which could significantly promote large-scale preparation and practical application of *** proof of the concept,the performance of porphyrin-based RE-MOFs was investigated in the photocatalytic cycloaddition of CO2with *** the RE-DBP(Co) MOFs,Tb-DBP(Co) exhibited the best photocatalytic performance,which was also greater than that of the corresponding 3D MOF Tb-TCPP(Co) due to the optimal 2D structure and thus the accelerated photogenerated charge separation and transfer *** work not only provides a novel versatile strategy to design and develop RE-MOFs,but also proposes a promising approach for the potential bulk production of RE-MOFs at room temperature.

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Deciphering the molecular mechanisms of Simiaowan in the treatment of hyperuricemia: in vivo and in silico approaches

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Traditional Medicine Research 2025年第2期10卷 37-54页

作者： Yong-chang Zeng Jun-Hong Wu Dan-Dan xu Kang He chang-Qing Liu Li-Fei Song Zheng-Zhi Wu Qian-Qian Jiang Shao-Yu Liang Department of Neurology The First Affiliated Hospital of Shenzhen UniversityShenzhen 518020China Pharmaceutical Department The Affiliated TCM Hospital of Guangzhou Medical UniversityGuangzhou 510000China School of Pharmacy Guizhou University of Traditional Chinese MedicineGuiyang 550025China Guangzhou Zeli Medical Technology Co. Ltd.Guangzhou 510700China

Background:Simiaowan(SMW),a well-known traditional Chinese medicine,has been employed to treat hyperuricemia(HUA)and gout for ***,the bioactive components and underlying mechanisms have not been *** objective of this study was to identify the active components and potential mechanisms of SMW by integrating pharmacological experimentation,serum pharmacochemistry,network pharmacology and molecular ***:HUA rats modelling by high-fat/high-sugar diet and potassium oxonate/adenine oral administration were used to evaluate the pharmacodynamic effects of ***-Q-Exactive-MS/MS was employed to detect the bioactive components present in SMW-containing *** pharmacology and molecular docking were utilized to elucidate the potential targets and underlying ***:SMW effectively ameliorated HUA rats via the inhibition of uric acid(UA)production,promotion of UA excretion,improvement of lipid and glucose metabolic abnormalities,antioxidant,anti-inflammatory and anti-insulin resistance effects.A total of 73 compounds detected in SMW-containing serum were identified as potential active components,with alkaloids,flavonoids,organic acids,and terpenoids emerging as the primary active *** 203 corresponding targets were obtained as SMW anti-HUA/gout targets,which mainly participated in apoptosis,insulin resistance,TNF,PI3K-Akt,HIF-1,NF-κB,MAPK,IL-17 and TLR signaling *** docking indicated that active compounds(***,phellodendrine,quercetin,formononetin,ferulic acid)had superior binding abilities to the key targets(*** carrier family 22 member 12(URAT1),solute carrier family 22 member 6(OAT1),ATP-binding cassette sub-family G member 2(ABCG2),solute carrier family 2,facilitated glucose transporter member 9(GLUT9),xanthine dehydrogenase/oxidase(XDH),transcription factor p65(RELA),toll-like receptor 4(TLR4),prostaglandin G/H synthase 2(PTGS2),caspase-3(CASP3),insulin(INS)).Conclusion:S

关键词： hyperuricemia network pharmacology serum pharmacochemistry Simiaowan UPLC-Q-Exactive-MS/MS

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Bullous pemphigoid associated with acquired hemophilia A: A case report

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World Journal of Clinical Cases 2025年第4期13卷 28-33页

作者： Su-Ye Hu Meng-Can Li Zi-Jia Hao xu-ya Chai Pei-Sai Li yang Liu Li-Xia Liu Ying xu Pan-Pan yang Ling-E Li Department of Dermatology Shijiazhuang Traditional Chinese Medicine HospitalShijiazhuang 050051Hebei ProvinceChina Graduate School Hebei University of Traditional Chinese MedicineShijiazhuang 050051Hebei ProvinceChina Department of Pathology Shijiazhuang Traditional Chinese Medicine HospitalShijiazhuang 050051Hebei ProvinceChina

BACKGROUND Acquired hemophilia A (AHA) is a rare and potentially severe bleeding disordercaused by circulating autoantibodies against factor Ⅷ (FⅧ). In approximately50% of the patients, the condition is associated with autoimmune diseases,cancers, medication use, pregnancy, and the post-partum period. Bullous pemphigoid(BP) is a chronic autoimmune subepidermal blistering disease associatedwith tissue-bound and circulating autoantibodies against BP antigens 180 (BP180)and 230 (BP230). AHA-associated BP has a high mortality rate;hence, the understandingof this disease must *** SUMMARY A 69-year-old man presented with erythema, blisters, blood blisters, and crustsaccompanied by severe pruritus for more than 20 days, and ecchymosis andswelling on his left upper arm for 3 days. Pathological examination revealed asubepidermal blister that contained eosinophils. Laboratory tests showed that theBP180 autoantibody levels had increased, isolated activated partial thromboplastintime was notably prolonged (115.6 s), and coagulation FⅧ activity wasextremely low (< 1.0%). Furthermore, the FⅧ inhibitor titer had greatlyincreased (59.2 Bethesda units). Therefore, the patient was diagnosed as having BP associated with AHA, prescribed 0.05% topical halometasone cream, and transferred to a higher-level hospitalfor effective treatment;however, he died after 2 *** AHA associated BP is rare, dangerous, and has a high mortality rate. Therefore, its timely diagnosis and effectivetreatment are necessary.

关键词： Bullous pemphigoid Acquired hemophilia A Acquired hemophilia A FactorⅧ Case report

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Screening of plane S waves by an array of rigid piles in poroelastic soil

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2008年第5期9卷 589-599页

作者： Yuan-qiang CAI Guang-ya DING chang-jie xu MOE Key Laboratory of Soft Soils and Geoenvironmental Engineering Zhejiang Universiry Hangzhou 310027 China College of Architecture and Civil Engineering Wenzhou University Wenzhou 325035 China

An array of rigid piles used as a screening barrier for plane shear (S) waves is investigated in a homogeneous unbounded space. The dynamic poroelastic theory of Biot is employed, under the assumption of an incompressible solid grain. Using Fourier-Bessel series, the problem of multiple scattering is solved by imposing continuity conditions and equilibrium conditions at the soil-pile interfaces with the translational addition theorem. A parametric analysis is conducted to investigate the influence of the permeability of poroelastic soil, separation between piles, number of piles and frequency of incident waves on screening effectiveness of the barrier, and the results are compared with those in an elastic soil medium. Computed results show that the intrinsic permeability of the soil medium displays an apparent effect on the screening of plane S waves.

关键词： Array of rigid piles Poroelastic soil Theory of Biot Scattering Screening effectiveness

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Based on non-targeted metabolomics for differential components screening of Rosae Chinensis Flos and Rosae Rugosae Flos and their quality evaluation

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Traditional Medicine Research 2025年第2期10卷 1-15页

作者： xu Liang Ni-Hui Zhang Zhi-Lai Zhan Guang-Lu chang yan Gao Xia Li Wen-Yuan Gao School of Pharmaceutical Science and Technology Faculty of MedicineTianjin UniversityTianjin 300193China State Key Laboratory for Quality Ensurance and Sustainable Use of Dao-di Herbs China Academy of Chinese Medical SciencesBeijing 100700China Key Laboratory of Modern Chinese Medicine Resources Research Enterprises Tianjin 300402China

Background:Rosa chinensis *** Rosa rugosa *** not only of ornamental value,but also edible flowers and the flower buds have been listed in the Chinese Pharmacopoeia as traditional *** two plants have some differences in efficacy,but the flower buds are easily confused for similar *** addition,large-scale cultivation of ornamental rose flowers may lead to a decrease in the effective components of medicinal ***,it is necessary to study the chemical composition and make quality evaluation of Rosae Chinensis Flos(Yueji)and Rosae Rugosae Flos(Meigui).Methods:In this study,40 batches of samples including Meigui and Yueji from different regions in China were collected to establish high-performance liquid chromatography ***,the fingerprints data was analyzed using principal component analysis,hierarchical cluster analysis,and partial least squares discriminant analysis analysis chemometrics to obtain information on intergroup differences,and non-targeted metabolomic techniques were applied to identify and compare chemical compositions of samples which were chosen from groups with large *** compounds were screened by orthogonal partial least-squares discriminant analysis and S-plot,and finally multi-component quantification was performed to comprehensively evaluate the quality of Yueji and ***:The similarity between the fingerprints of 40 batches roses and the reference print R was 0.73 to 0.93,indicating that there were similarities and differences between the *** principal component analysis and hierarchical cluster analysis of fingerprints data,the samples from different origins and varieties were intuitively divided into four *** least-squares discriminant analysis analysis showed that Meigui and Yueji cluster into two categories and the model was reliable.A total of 89 compounds were identified by high resolution mass spectrometry,mainly were flavonoids and flavon

关键词： Rosa chinensis Jacq. Rosa rugosa Thunb. metabolomics chemometrics multiple component quantification quality evaluation

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阻燃增塑剂对PVC材料阻燃性能影响的研究

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浙江理工大学学报（自然科学版） 2013年第5期30卷 663-666页

作者：康迷韩建丁新波徐国平于斌徐长亚浙江理工大学材料与纺织学院杭州310018 浙江理工大学浙江省产业用纺织材料制备技术重点实验室杭州310018 浙江锦达新材料股份有限公司浙江海宁314419

使用不同比例的阻燃增塑剂磷酸甲苯二苯酯(DPK)与常规增塑剂苯二甲酸二异壬酯(DINP)增塑PVC树脂,制得相应的PVC建筑膜材涂层材料。考察两者对PVC材料阻燃及加工性能的作用效果,通过热重分析法研究DPK对PVC材料热降解过程的影响,并利用... 详细信息

使用不同比例的阻燃增塑剂磷酸甲苯二苯酯(DPK)与常规增塑剂苯二甲酸二异壬酯(DINP)增塑PVC树脂,制得相应的PVC建筑膜材涂层材料。考察两者对PVC材料阻燃及加工性能的作用效果,通过热重分析法研究DPK对PVC材料热降解过程的影响,并利用扫描电镜对材料残碳形貌进行观察,分析DPK的阻燃机理。结果表明:阻燃增塑剂DPK能促进PVC脱氯化氢气体,使材料表面形成一层致密的碳化膜,具有优异的阻燃性;且w(DPK)∶w(DINP)=10∶50复合使用时,能有效改善PVC涂层材料的阻燃性和可加工性。

关键词：阻燃增塑剂阻燃性能粘度 PVC材料

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Effects of climate change on water resources in Tarim River Basin, Northwest China

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Journal of Environmental Sciences 2007年第4期19卷 488-493页

作者： CHEN ya-ning LI Wei-hong xu chang-chun HAO Xin-ming Xinjiang Institute of Ecology and Geography Chinese Academy of Sciences Urumqi 830011 China.

Based on hydrology, temperature, and precipitation data from the past 50 years, the effects of climate change on water resources in Tarim River Basin in Northwest China were investigated. The long-term trends of the hydrological time series were detected using both parametric and nonparametric techniques. The results showed that the increasing tendency of the temperature has a 5% level of significance, and the temperature increased by nearly 1℃ over the past 50 years. The precipitation showed a significant increase in the 1980s and 1990s, and the average annual precipitation exhibited an increasing trend with a magnitude of 6.8 mm per decade. A step change occurred in both the temperature and precipitation time series around 1986. The streamflow from the headwater of the Tarim River exhibited a significant increase during the last 20 years. The increase in temperature, precipitation, and streamflow may be attributed to global climate change.

关键词： climate change temperature precipitation streamflow Tarim River

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Lake water storage change estimation and its linkage with terrestrial water storage change in the northeastern Tibetan Plateau

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Journal of Mountain Science 2021年第7期18卷 1737-1747页

作者： LI ya-wei WANG Yu-zhe xu Min KANG Shi-chang Key Laboratory of Tibetan Environment changes and Land Surface Processes Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China University of Chinese Academy of Sciences Beijing 100039China State Key Laboratory of Cryospheric Science Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China CAS Centre for Excellence in Tibetan Plateau Earth Sciences Beijing 100101China

Tibetan Plateau(TP) lakes are important water resources,which are experiencing quick expansion in recent *** researches mainly focus on analyzing the relationship between terrestrial water storage(TWS) change and lake water storage(LWS) change in the total inner TP,it is still lack of researches about the spatial difference and the characteristic of sub-region in the inner *** this study,we estimated the area change of 34 lakes by using Landsat images in the northeastern TP during 1976–2013,and LWS change by using the Shuttle Radar Topography Mission(SRTM).The results suggested that LWS had shrunk from 1976 to 1994,and then expanded quickly until *** had a serious decrease by 13.6 Gt during 1976–1994,and then it increased quickly by 35.4 Gt during 1994–*** estimated TWS change,soil moisture change,and permafrost degradation based on the satellite data and related models during 2003–*** results indicated that their changing rates were 1.86 Gt/y,0.22 Gt/y,and –0.19 Gt/y,*** also calculated the change of groundwater based on the mass balance with a decreasing trend of –0.054 Gt/*** results suggested that the cause of TWS change was the increase of *** analyzed the cause of lake change according to water balance,and found that the primary cause of lake expansion was the increasing precipitation(80.7%),followed by glacier meltwater(10.3%) and permafrost degradation(9%).The spatial difference between LWS change and TWS change should be studied further,which is important to understand the driving mechanism of water resources change.

关键词： Lake expansion GRACE Water storage change Precipitation Glacier meltwater

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Regulatory networks between Polycomb complexes and non-coding RNAs in the central nervous system

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Journal of Molecular Cell Biology 2020年第5期12卷 327-336页

作者： ya-Jie xu Pei-Pei Liu Shyh-chang Ng Zhao-Qian Teng chang-Mei Liu State Key Laboratory of Stem Cell and Reproductive Biology Institute of ZoologyChinese Academy of SciencesBeijing 100101China Savaid Medical School University of Chinese Academy of SciencesBeijing 100049China Institute for Stem Cell and Regeneration Chinese Academy of SciencesBeijing 100101China

High-throughput sequencing has facilitated the identification of many types of non-coding RNAs(ncRNAs)involved in diverse cellular *** as epigenetic mediators play key roles in neuronal development,maintenance,and dysfunction by controlling gene expression at multiple *** may not only target specific DNA or RNA for gene silence but may also directly interact with chromatin-modifying proteins like Polycomb group(PcG)proteins to drive orchestrated transcriptional *** significant progress has been made in characterizing ncRNAs and PcG proteins involved in transcriptional,post-transcriptional,and epigenetic *** importantly,dysregulation of ncRNAs,PcG proteins,and interplay among them is closely associated with the pathogenesis of central nervous system(CNS)*** this review,we focus on the interplay between ncRNAs and PcG proteins in the CNS and highlight the functional roles of the partnership during neural development and diseases.

关键词： epigenetics Polycomb complexes non-coding RNAs central nervous system neurological diseases

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