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Strong hetero-interface interaction in 2D/2D WSe_(2)/ZnIn_(2)S_(4) heterostructures for highly-efficient photocatalytic hydrogen generation

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Journal of Energy Chemistry 2024年第10期97卷 379-387,I0008页

作者： xu Guo Xing Liu jing Shan Zhuo xu Zhiming Fang Lu Wang Shengzhong Liu School of Energy Powerand Mechanical EngineeringNorth China Electric Power UniversityBeijing 102206China Shaanxi Key Laboratory for Advanced Energy Devices School of Materials Science and EngineeringShanxi Normal UniversityXi'an 710119ShanxiChina Qinghai Advanced Energy Storage Laboratory SPIC Qinghai Photovoltaic Industry Innovation Center Co.Ltd.State Power Investment CorporationXining 810oo7QinghaiChina Key Laboratory of Photoelectric Conversion and Utilization of Solar Energy Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Green hydrogen is urgently required for sustainable development of human beings and rational construction of heterostructures holds great promising for photocatalytic hydrogen ***,2D/2D WSe_(2)/ZnIn_(2)S_(4) heterostructures with strong hetero-interface interaction and abundant contact were constructed via an impregnation-annealing *** charge transfer from ZnIn_(2)S_(4) to WSe_(2)was evidenced by transient absorption spectroscopy in crafted heterostructures owing to the tight and2D face-to-face *** a result,the prepared WSe_(2)/ZnIn_(2)S_(4) heterostructures exhibited boosted photocatalytic performance and a highest hydrogen evolution rate of 3.377 mmol/(g h)was achieved with an apparent quantum yield of 45.7%at 420 *** work not only provides new strategies to achieve efficient 2D/2D heterostructures but also paves the way for the development of green hydrogen in the future.

关键词： Strong hetero-interface interaction in 2D/2D WSe_(2)/ZnIn_(2)S_(4) heterostructures for highly-efficient photocatalytic hydrogen generation

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Unsaturated bi-heterometal clusters in metal-vacancy sites of 2D MoS2 for efficient hydrogen evolution

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Carbon Energy 2024年第3期6卷 264-275页

作者： Gonglei Shao Jie xu Shasha Gao Zhang Zhang Song Liu xu Zhang Zhen Zhou Interdisciplinary Research Center for Sustainable Energy Science and Engineering(IRC4SE2) School of Chemical EngineeringZhengzhou UniversityZhengzhouHenanChina College of Chemistry and Materials Engineering Wenzhou UniversityWenzhouZhejiangChina Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) College of ChemistryNankai UniversityTianjinChina State Key Laboratory of Chemo/Biosensing and Chemometrics Institute of Chemical Biology and Nanomedicine(ICBN)College of Chemistry and Chemical EngineeringHunan UniversityChangshaHunanChina Institute of New Energy Material Chemistry School of Materials Science and EngineeringNankai UniversityTianjinChina

The valence states and coordination structures of doped heterometal atoms in two-dimensional(2D)nanomaterials lack predictable regulation ***,a robust method is proposed to form unsaturated heteroatom clusters via the metal-vacancy restraint mechanism,which can precisely regulate the bonding and valence state of heterometal atoms doped in 2D molybdenum *** unsaturated valence state of heterometal Pt and Ru cluster atoms form a spatial coordination structure with Pt–S and Ru–O–S as catalytically active *** them,the strong binding energy of negatively charged suspended S and O sites for H+,as well as the weak adsorption of positively charged unsaturated heterometal atoms for H*,reduces the energy barrier of the hydrogen evolution reaction proved by theoretical ***,the electrocatalytic hydrogen evolution performance is markedly improved by the ensemble effect of unsaturated heterometal atoms and highlighted with an overpotential of 84 mV and Tafel slope of 68.5 mV dec^(−1).In brief,this metal vacancy-induced valence state regulation of heterometal can manipulate the coordination structure and catalytic activity of heterometal atoms doped in the 2D atomic lattice but not limited to 2D nanomaterials.

关键词： clusters hydrogen evolution reaction metal vacancy MoS2 unsaturated heterometal

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Exhaustive review of acceleration strategies for Monte Carlo simulations in photon transit

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Journal of Innovative Optical Health Sciences 2024年第5期17卷 5-21页

作者： Louzhe xu Zijie Zhu Ting Li Institute of Biomedical Engineering Chinese Academy of Medical Sciences&Peking Union Medical College Tianjin 300192 P.R.China

Monte Carlo simulation techniques have become the quintessence and a pivotal nexus of inquiry in the realm of simulating photon movement within biological *** the stochastic sampling of tissue archetypes delineated by explicit optical characteristics,Monte Carlo simulations possess the theoretical capacity to render unparalleled accuracy in the depiction of exceedingly intricate ***,the quintessential challenge associated with Monte Carlo simulation methodologies resides in their extended computational duration,which significantly impedes the re¯nement of their ***,this discourse is speci¯cally dedicated to exploring innovations in strategies and technologies aimed at expediting Monte Carlo *** delves into the foundational concepts of various acceleration tactics,evaluates these strategies concerning their speed,accuracy,and practicality,and amalgamates a comprehensive overview and critique of acceleration methodologies for Monte Carlo ***,the discourse envisages prospective trajectories for the employment of Monte Carlo techniques within the domain of tissue optics.

关键词： Medical optics photon transport simulation Monte Carlo simulation acceleration

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LEP/sLEP-R在女性类风湿关节炎中的变化及其与骨质疏松的关系研究

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中国骨质疏松杂志 2011年第10期17卷 856-859页

作者：邓娟徐胜前徐建华安徽医科大学第一附属医院风湿免疫科合肥230032

目的探讨女性类风湿关节炎(RA)患者外周血瘦素(LEP)和可溶性瘦素受体(sLEP-R)的变化及其与女性RA骨质疏松的相关性。方法采用ELISA法测定55例女性RA患者和53例正常女性外周血中LEP、sLEP-R水平,采用双能X线骨密度吸收仪测定骨密度(BMD)... 详细信息

目的探讨女性类风湿关节炎(RA)患者外周血瘦素(LEP)和可溶性瘦素受体(sLEP-R)的变化及其与女性RA骨质疏松的相关性。方法采用ELISA法测定55例女性RA患者和53例正常女性外周血中LEP、sLEP-R水平,采用双能X线骨密度吸收仪测定骨密度(BMD)。结果 (1)和正常女性相比,女性RA患者LEP水平明显升高(P<0.0001),sLEP-R水平明显降低(P<0.0001)。(2)女性RA组中骨质疏松发生率为38.2%,明显高于正常女性组的11.3%(χ2=10.386,P=0.001);绝经后或绝经前女性RA患者BMD均明显低于绝经后或绝经前(Neck部位除外)正常女性(P<0.001～0.0001);绝经后女性RA患者BMD亦明显低于绝经前女性RA患者(P<0.05)。(3)LinearRegression分析显示:女性RA患者外周血LEP水平与C反应蛋白呈直线正相关(P=0.045),与前臂、股骨Ward区和腰椎1-4 BMD呈直线负相关(P<0.05～0.0001);外周血sLEP-R水平与股骨Ward区、大转子和腰椎1-4 BMD呈直线正相关(P<0.05～0.0001)。结论女性RA患者外周血LEP和sLEP-R水平的变化与RA患者的骨代谢状态的变化密切相关。

关键词：瘦素可溶性瘦素受体类风湿关节炎骨质疏松骨密度

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On the upper bounds of (1,0)-super solutions for the regular balanced random (k,2s)-SAT problem

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Frontiers of Computer Science 2024年第4期18卷 139-146页

作者： Yongping WANG Daoyun xu Jincheng ZHOU School of Information Guizhou University of Finance and EconomicsGuiyang 550025China College of Computer Science and Technology Guizhou UniversityGuiyang 550025China School of Computer and Information Qiannan Normal University for NationalitiesDuyun 558000China Key Laboratory of Complex Systems and Intelligent Optimization of Guizhou Province Duyun 558000China

This paper explores the conditions which make a regular balancedrandom(k,2s)-CNFformula(1,O)-unsatisfiable with high *** conditions also make a random instance of the regular balanced(k-1,2(k-1)s)-SAT problem unsatisfiable with high probability,where the instance obeys a distribution which differs from the distribution obeyed by a regular balanced random(k-1,2(k-1)s)-CNF *** F be a regular balanced random(k,2s)-CNF formula where k≥3,then there exists a number so such that F is(1,O)-unsatisfiable with high probability if s>so.A numerical solution of the number so when k e(5,6,...,14)is given to conduct simulated *** simulated experiments verify the theoretical ***,the experiments also suggest that F is(1,O)-satisfiable with high probability if s is less than a certain value.

关键词： regular balanced random(k,2s)-SAT problem (1,0)-super solution upper bound

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Contribution of high-latitude permafrost regions in the Northern Hemisphere to global wildfire carbon emissions

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Science China Earth Sciences 2024年第10期67卷 3239-3251页

作者： Xingru ZHU Xiyan xu Gensuo JIA Key Laboratory of Regional Climate-Environment for East Asia Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China College of Earth and Planetary Sciences University of Chinese Academy of SciencesBeijing 100049China

Wildfires are major disturbances in permafrost ecosystems, with increasing frequency and intensity in recent years. In permafrost regions, wildfires not only burn surface and subsurface organic matter but also accelerate permafrost thawing,releasing significant amounts of greenhouse gases such as carbon dioxide and methane into the atmosphere. However, the contribution of high-latitude permafrost regions in the Northern Hemisphere to global wildfire carbon emissions remains poorly understood. This study integrates remote sensing data and ground observations to analyze the contributions of aboveground and belowground fuel combustion in high-latitude permafrost regions to global wildfire carbon emissions from 2002 to 2020, as well as the spatiotemporal variations in these contributions. Our findings indicate that permafrost regions contribute approximately11.96% of global wildfire carbon emissions, with aboveground emissions accounting for approximately 3.94% of global aboveground emissions and belowground emissions contributing approximately 63.57% of global belowground emissions. The contribution of high-latitude permafrost regions to global emissions peaked in July and August, whereas the continuous permafrost zones(areas with more than 90% permafrost coverage) showed the most significant increase in June and July. The contributions of both aboveground and belowground emissions from high-latitude permafrost regions to global wildfire emissions have been increasing, primarily due to the reduction in global wildfire emissions, in contrast with the rising emissions from wildfires in high-latitude permafrost regions. This study highlights the significant role of wildfires, particularly the combustion of belowground biomass in high-latitude permafrost regions, in global carbon emissions. The decomposition and combustion of organic carbon in permafrost regions due to wildfires release more greenhouse gases into the atmosphere, potentially amplifying the positive feedback

关键词： Wildfire Permafrost Carbon emissions Climate change Belowground fuel consumption

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Even-odd layer-dependent multiferroic in freestanding rare-earth orthorhombic perovskite

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Science China(Physics,Mechanics & Astronomy) 2024年第7期67卷 151-157页

作者： Shaowen xu Fanhao Jia Ning Dai School of Physics and Optoelectronic Engineering Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of SciencesHangzhou 310024China Department of Physics College of ScienceHangzhou Dianzi UniversityHangzhou 310018China State Key Laboratory of Infrared Physics Shanghai Institute of Technical PhysicsChinese Academy of SciencesShanghai 200083China

Freestanding oxide perovskites possess strong interlayer coupling between adjacent atomic layers,thus exerting a determinative effect on the magnetism and ferroelectricity of these atomic-scale ***,we propose an effective strategy to manipulate magnetism and ferroelectricity in freestanding rare-earth orthorhombic perovskite via modulation of layer *** performing first-principles calculations,an even-odd oscillation is demonstrated in few-layer GdAlO_(3)perovskite(GAP).Specifically,odd-layer systems with charged atomic layers are ferromagnetic polar metals,while even-layer systems are antiferromagnetic ferroelectric *** thickness-dependent magnetic phase transition originates from carrier doping,as rationalized by the Stoner ***,we demonstrate the promotion of in-plane ferroelectricity via the concurrent application of two distinct antiferrodistortive displacements,each driven by formation and breaking of *** multiferroic phases may emerge in other transition metal oxide perovskites supporting multiple valence states,e.g.,few-layer Gd MO_(3)(M=V,Cr,Mn,and Ni).This work puts forward a strategy for layer thickness engineering of magnetism and ferroelectricity in 2D oxide perovskite multiferroic materials.

关键词： few-layer rare-earth perovskite multiferroicity size effect first principles calculations

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Analysis of Fatty Acid in Biological Samples Using Liquid Chromatography–Quadrupole-Orbitrap Mass Spectrometry Under Parallel Reaction Monitoring Mode

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Journal of Analysis and Testing 2024年第2期8卷 210-217页

作者： Jingxuan Yang Wenjun Guo Xiaohang xu Liang Zhao Yajuan xu Yang Wang School of Pharmaceutical Sciences Changchun University of Chinese MedicineChangchun130117China Key Laboratory of Medicinal Materials Jilin Academy of Chinese Medicine SciencesChangchun130021China Jilin Ginseng Academy Changchun University of Chinese MedicineChangchun130117China

Fatty acids(FAs)are an important class of functional small molecules and participate in a variety of life biological *** experiment proposed a liquid chromatography–quadrupole-Qrbitrap mass spectrometry(LC–Q-Orbitrap MS)method to perform FA profiling under parallel reaction monitoring(PRM)acquisition *** FA was derivatized by 2-dimethylaminoethylamine(DMED)to increase the ionization e fficiency and provide the characterized fragment *** mass spectra obtained from full scan,multiple ion monitoring(MIM),and PRM were *** results showed that the protonated ion of FA+DMED–H2O was detected and the neutral loss of 45.06 Da was observed in the tandem mass *** PRM method provided the highest selectivity and sensitivity for FA detection with the help of accurate mass weight and specific neutral loss-based *** method validation was performed using the FA standards and pooled quality control serum sample,which showed that the established method had good repeatability,stability,and ***,the developed method was successfully applied to analyze the rat serum and brain tissue samples for the drug e ffi-cacy evaluation of gross saponin of Tribulus terrestris ***(GSTTF)against middle cerebral artery occlusion(MCAO)-induced ischemic *** method has extensive practicability and great potential in the detection of FA,especially for the analysis of samples with complex matrices.

关键词： Fatty acid Derivatization LC-Q-Orbitrap MS Parallel reaction monitoring Biological sample

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A modern survey method for determining live loads based on multi-source and open-access data on the Internet

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Frontiers of Structural and Civil Engineering 2024年第8期18卷 1135-1147页

作者： Chi xu Jun CHEN Jie LI School of Civil Engineering Tongji UniversityShanghai 200092China The State Key Laboratory on Disaster Reduction in Civil Engineering Tongji UniversityShanghai 200092China

Sufficient survey data are required to describe the stochastic behaviors of live ***,due to manual and on-site operation required by traditional survey methods,traditional surveys face challenges like occupant resistance,high costs,and long implementation *** study proposes a new survey method to access live load data online and *** samples are acquired from multi-source,open-access and dynamically updated data on the *** change intervals,geometrical dimensions and object quantities are obtained from transaction information,building attributes and virtual reality models on real estate websites,*** object weights are collected from commodity information on e-commerce *** integration of the aforementioned data allows for the extraction of necessary statistics to describe a live load *** proposed method is applied to a live load survey in China,covering 20040 m^(2),with around 90000 samples acquired for object weights and load *** survey results reveal that about 70%−80%of the amplitude statistics are attributable to 1/6 of the total object types.

关键词： live load online survey method data acquisition data integration

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Challenges and opportunities in Quaternary palynology

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Science China Earth Sciences 2024年第7期67卷 2148-2161页

作者： Qinghai xu Houyuan LU Zhuo ZHENG College of Geographical Sciences Hebei Key Laboratory of Environmental Change and Ecological ConstructionHebei Normal UniversityShijiazhuang 050024China Key Laboratory of Cenozoic Geology and Environment Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China School of Earth Sciences and Engineering Sun Yat-sen UniversityZhuhai 519082China

Quaternary palynology plays a pivotal role in investigating global climate change and various other research fields,serving as an essential tool for the quantitative analysis of paleoenvironment ***,due to the vast diversity of terrestrial ecosystems and intricate interactions between vegetation,climate,and human activities,further advancements are required in the following aspects within this discipline.(1)The accuracy of classification in pollen morphology and fossil pollen identification needs improvement,particularly at the species *** represents a significant challenge in present Quaternary ***-aided intelligent recognition holds promise as a solution for species identification based on more detail pollen morphology.(2)Most pollen-based vegetation and climate reconstructions overlook the significance of bare *** bare ground can lead to substantial inaccuracies when quantitatively reconstructing past vegetation and climate.(3)While pollen records provide reliable information on paleoclimate changes,current quantitative climate reconstruction models heavily rely on modern pollen datasets derived from present-day vegetation disturbed more or less by human *** introduces bias and uncertainties into paleoclimate reconstruction.(4)Although pollen can serve as an indicator of human activities,accurately quantifying the intensity of human influence remains *** accurate identification of crop pollen,reconstructing reliable land cover/use data,and integrating multidisciplinary data may enhance the identification and quantification of signals related to human activity in pollen records.

关键词： Quaternary palynology Paleoclimate Paleovegetation Human activity

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