检索结果-南通市图书馆

Multifunctional Nacre-Like Nanocomposite Papers for Electromagnetic Interference Shielding via Heterocyclic Aramid/MXene Template-Assisted In-Situ Polypyrrole Assembly

在线全文

学校读者我要写书评

暂无评论

NANO-MICRO LETTERS 2025年第1期17卷 1-18页

作者： Xiong, Jinhua Zhao, xu Liu, Zonglin Chen, He Yan, Qian lian, Huanxin Chen, Yunxiang Peng, Qingyu He, Xiaodong Harbin Inst Technol Ctr Composite Mat & Struct Natl Key Lab Sci & Technol Adv Composites Special Harbin 150080 Peoples R China

The large-scale, high-strength, super-tough, and multifunctional nacre-like heterocyclic aramid (HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite papers were fabricated using the in-situ assembly of PPy onto the HA/MXene hydrogel *** "brick-and-mortar" layered structure and abundant hydrogen-bonding interactions among MXene, PPy, and HA respond cooperatively to external stress and effectively increase the mechanical properties of HMP nanocomposite *** templating effect from HA/MXene was utilized to guide the assembly of conducting polymers, leading to high electrical conductivity and outstanding electromagnetic interference shielding performance. Robust, ultra-flexible, and multifunctional MXene-based electromagnetic interference (EMI) shielding nanocomposite films exhibit enormous potential for applications in artificial intelligence, wireless telecommunication, and portable/wearable electronic equipment. In this work, a nacre-inspired multifunctional heterocyclic aramid (HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper with large-scale, high strength, super toughness, and excellent tolerance to complex conditions is fabricated through the strategy of HA/MXene hydrogel template-assisted in-situ assembly of PPy. Benefiting from the "brick-and-mortar" layered structure and the strong hydrogen-bonding interactions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa), outstanding toughness (57.6 MJ m-3), exceptional foldability, and structural stability against ultrasonication. By using the template effect of HA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly, the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dB at an ultra-thin thickness (25.4 mu m) and a high specific EMI SE of 17,204.7 dB cm2 g-1. In addit

关键词： MXene Remarkable mechanical properties Heterocyclic aramid Electromagnetic interference shielding Polypyrrole Multifunctionality

Integration of perioperative features and intragraft TCF7L2 expression to predict lipid metabolic disorder in liver transplant recipients

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China Life Sciences 2025年第1期 297-299页

作者： Junbin Zhou Rongli Wei Guanghan Fan Zhengxing lian xuanyu Zhang Linsong Tang Zhetuo Qi Haiyang Xie Shusen Zheng Qiang Wei Xiao xu Department of Hepatobiliary and Pancreatic Surgery People's Hospital of LishuiAffiliated Lishui Hospital of Wenzhou Medical UniversityThe First Affiliated Hospital of Lishui University NHFPC Key Laboratory of Combined Multi-Organ Transplantation Key Laboratory of Integrated Oncology and Intelligent Medicine of Zhejiang Province Department of Hepatobiliary and Pancreatic SurgeryHangzhou First People's Hospital Department of Hepatobiliary and Pancreatic Surgery The First Affiliated HospitalZhejiang University School of Medicine Department of Urology The Second Affiliated HospitalZhejiang University School of Medicine Department of Hepatobiliary and Pancreatic Surgery Department of Liver TransplantationShulan (Hangzhou) Hospital Hangzhou Medical College Zhejiang University School of Medicine

Dear Editor, Liver transplantation(LT) is the only curative therapy for patients with endstage liver disease(He et al., 2023; Ling et al., 2022). Post-transplant hypertriglyceridemia(PTHT), which has an incidence of up to 32.8% in 6 months after LT, is one of the major post-transplant complications(Toshima et al., 2020).

关键词：

同方期刊数据库

Synthesis and characterization of iron clusters with an icosahedral [Fe@Fe12]16+ Core

在线全文

学校读者我要写书评

暂无评论

National Science Review 2024年第4期11卷 123-129页

作者： gan xu Yun-Shu Cui xue-lian Jiang Cong-Qiao xu Jun Li xu-Dong Chen Jiangsu Collaborative Innovation Center of Biomedical Functional Materials and Jiangsu Key Laboratory of New Power Batteries School of Chemistry and Materials Science Nanjing Normal University Department of Chemistry and Guangdong Provincial Key Laboratory of Catalytic Chemistry Southern University of Science and Technology Department of Chemistry and Engineering Research Center of Advanced Rare-Earth Materials of Ministry of Education Tsinghua University State Key Laboratory of Coordination Chemistry Nanjing University

Iron-metal clusters are crucial in a variety of critical biological and material systems,including metalloenzymes,catalysts,and magnetic storage ***,a synthetic high-nuclear iron cluster has been absent due to the extreme difficulty in stabilizing species with direct iron-iron *** this work,we have synthesized,crystallized,and characterized a（Tp*）4W4S12(Fe@Fe12) cluster(Tp*=tris（3,5-dimethyl-1-pyrazolyl）borate（1-）),which features a rare trideca-nuclear,icosahedral[Fe@Fe12] cluster core with direct multicenter iron-iron bonding between the interstitial iron（Fei） and peripheral irons（Fep）,as well as Fep…Fepferromagnetic *** chemistry studies reveal that the stability of the cluster arises from the 18-electron shell-closing of the [Fe@Fe12]16+core,assisted by its bonding interactions with the peripheral tridentate [（Tp*）WS3]4-ligands which possess both S→Fe donation and spin-polarized Fe-Wσ *** ground-state electron spin is theoretically predicted to be S=32/2 for the *** existence of low oxidation-state（OS～+1.23） iron in this compound may find interesting applications in magnetic storage,spintronics,redox chemistry,and cluster catalysis.

关键词： Fe13 cluster iron-sulfur cluster low-valence iron iron−iron bond high spin complex

Numerical investigation of shallow wake behind a patch of rigid emergent vegetation

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Hydrodynamics 2021年第4期33卷 673-687页

作者： Jian Wang Jing-xin Zhang Dongfang liang lian gan School of Naval Architecture Ocean and Civil EngineeringShanghai Jiao Tong UniversityShanghai200240China Key Laboratory of Hydrodynamics(Ministry of Education) Shanghai Jiao Tong UniversityShanghai200240China Department of Engineering University of CambridgeCambridgeUK Department of Engineering Durham UniversityDurhamUK

The shallow water flow through and around a patch of rigid emergent vegetation was investigated numerically. The mean flow field and turbulent structures were studied, especially their dependence on the solid volume fraction (SVF) of the patch and the bed friction. Two streamwise velocity scales, U1s at the starting point of the steady wake and U1e at the downstream end of the steady wake, and the length of the steady wake L1 were used to describe the steady wake behind the patch. U1s was found to be related to SVF only. However, U1e and L1 were influenced by both the SVF and the wake stability parameter S. For a sparse patch, U1e was equal to U1s, and L1 decreased with the increase of S. For a mid-dense patch, U1e was always smaller than U1s, and it increased with S and gradually approached U1s. The increase of U1e reduced the lateral velocity difference between the flows inside and outside the wake, which resulted in the increase of L1. For a highly dense patch, U1e and L1 did not increase unless S was larger than a critical value. A new parameter, r, was proposed to represent the development rate of the steady wake. The numerical results showed that r increased monotonously with S for mid-dense patches.

关键词： Shallow water vegetated flow wake bed friction

Maximal-minimal correlation atoms algorithm for sparse recovery

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Systems Engineering and Electronics 2013年第4期24卷 579-585页

作者： Wei gan Luping xu Hua Zhang School of Electronic Engineering Xidian University

A new iterative algorithm is proposed to reconstruct an unknown sparse signal from a set of projected measurements. Unlike existing greedy pursuit methods which only consider the atoms having the highest correlation with the residual signal, the proposed algorithm not only considers the higher correlation atoms but also reserves the lower correlation atoms with the residual signal. In the lower correlation atoms, only a few are correct which usually impact the reconstructive performance and decide the reconstruction dynamic range of greedy pursuit methods. The others are redundant. In order to avoid redundant atoms impacting the reconstructive accuracy, the Bayesian pursuit algorithm is used to eliminate them. Simulation results show that the proposed algorithm can improve the reconstructive dynamic range and the reconstructive accuracy. Furthermore, better noise immunity compared with the existing greedy pursuit methods can be obtained.

关键词： compressive sensing (CS) correlation atom Bayesian hypothesis sparse reconstruction.

The synergism of sequential paired electrosynthesis with halogen bonding activation for the cyclization of organochlorides with olefins

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2023年第2期66卷 540-547页

作者： Fei lian Kun xu Chengchu Zeng Faculty of Environment and Life Beijing University of TechnologyBeijing100124China

Reported herein is the design of a new catalytic paradigm by synergistically combining sequential paired electrosynthesis with halogen-bonding(XB)activation for the cyclization of organochlorides with *** dual activation strategy enables rapid access to densely functionalized 2-alkylidene-tetrahydrofurans with exclusive Z-selectivities,which are challenging to be synthesized by other methods.4,4′-Di-tert-butyl-2,2′-bipyridine(dtbbpy)showed an unprecedented reactivity as a XB acceptor to activate C-Cl bond by shifting its reduction potential positively by 220 m *** different from previous electroreductions of C-Cl bonds relying upon high electrode potentials or matched redox properties between mediators and organochlorides,the XB activator employed herein has no limit on the abovementioned redox property matching but can lower the applied electrode *** decreased operating potential allows broad functional group tolerance,which was highlighted by the late-stage functionalization of 11 examples of drugs and natural products-derived alkenes.

关键词： electrochemistry cross-electrophile coupling electrocatalysis paired electrolysis

Two new secoiridoid glycosides from the roots of Picrorhiza scrophulariiflora

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2008年第10期19卷 1224-1227页

作者： lian Chun Zou Tong Fei Zhu Shu Cai gan Da Cheng Wang Yu Zhang xu Ming Deng College of Animal Science and Veterinary Medicine Jilin University Changchun 130062 China College of Chemistry Jilin University Changchun 130062 China Department of Traditional Chinese Materia Medica Shenyang Pharmaceutical University Shenyang 110016 China School of pharmacy Shenyang Pharmaceutical University Shenyang 110016 China

From the roots ofPicrorhiza scrophulariiflora, two new secoifidoid glycosides, named picrosecosides Ⅰ and Ⅱ （1, 2） have been isolated. Their structures were elucidated on the basis of chemical and spectropic evide... 详细信息

关键词： Picrorhiza scrophulariiflora Secoiridoid glycosides Picrosecosides Ⅰ and Ⅱ

Efficient implementation of the Barnes-Hut octree algorithm for Monte Carlo simulations of charged systems

在线全文

学校读者我要写书评

暂无评论

Science China Mathematics 2014年第7期57卷 1331-1340页

作者： gan ZeCheng xu ZhenLi Department of Mathematics Institute of Natural Sciencesand MoE Key Lab of Scientific and Engineering ComputingShanghai Jiao Tong University

Computer simulation with Monte Carlo is an important tool to investigate the function and equilibrium properties of many biological and soft matter materials solvable in *** appropriate treatment of long-range electrostatic interaction is essential for these charged systems,but remains a challenging problem for large-scale *** develop an efficient Barnes-Hut treecode algorithm for electrostatic evaluation in Monte Carlo simulations of Coulomb many-body *** algorithm is based on a divide-and-conquer strategy and fast update of the octree data structure in each trial move through a local adjustment *** test the accuracy of the tree algorithm,and use it to perform computer simulations of electric double layer near a spherical *** is shown that the computational cost of the Monte Carlo method with treecode acceleration scales as log N in each *** a typical system with ten thousand particles,by using the new algorithm,the speed has been improved by two orders of magnitude from the direct summation.

关键词： electrostatics Monte Carlo fast algorithms octree colloidal interfaces

在线全文

学校读者我要写书评

暂无评论

巴西龟代谢性骨病CT诊断病例报告

动物医学进展 2025年第1期46卷 141-144页

作者：孙嘉徐甘靖宇江蓝刘波俞峰中国农业大学北京100193

代谢性骨病(MBD)是一种因钙缺乏或维生素D 3摄入不足引起的骨骼代谢障碍疾病,其临床表现为骨折、脊椎异常、难产、脱垂等症状。计算机断层扫描(CT)在兽医临床中应用的逐渐增加为龟、鳖类MBD提供了新的诊断方式。该病例中红耳巴西龟血检... 详细信息

代谢性骨病(MBD)是一种因钙缺乏或维生素D 3摄入不足引起的骨骼代谢障碍疾病,其临床表现为骨折、脊椎异常、难产、脱垂等症状。计算机断层扫描(CT)在兽医临床中应用的逐渐增加为龟、鳖类MBD提供了新的诊断方式。该病例中红耳巴西龟血检结果提示其肾脏、肝脏功能损害,钙磷代谢异常。CT扫查提示患龟全身组织大面积矿化、背甲凹陷,定量测量患龟背椎骨、神经骨和胸膜骨3处的骨骼密度远低于正常龟,诊断患龟有严重的MBD。治疗方案为对症治疗、改善饲养管理条件,同时对该龟补充维生素D 3。该病例报告系统陈述了龟鳖MBD的诊疗流程,同时表明了CT扫查可为龟鳖MBD精确诊断、治疗和预后提供新的参考。

关键词：龟代谢性骨病计算机断层扫描骨密度