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Wear response of metastable b-type Ti–25Nb–2Mo–4Sn alloy for biomedical applications

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Rare Metals 2015年第8期34卷 564-568页

作者： Shun Guo Qi Zheng xiu-li hou Xiao-Nong Cheng Xin-Qing Zhao Institute for Advanced Materials Jiangsu University School of Materials Science and Engineering Beihang University

The wear response of a newly developed metastable b-type Ti–25Nb–2Mo–4Sn(abbreviated as Ti-2524) alloy was investigated and compared with that of(a+b)-type Ti–6Al–4V alloy. Experimental results show that solution-treated(ST) Ti-2524 specimen has the lowest wear rate due to the combined effects of excellent ductility and lubricative Nb2O5. Although similar Nb2O5 forms on the surface of the cold rolled plus annealed(CRA) Ti-2524 specimen, the beneficial effect of Nb2O5 on the wear resistance is counteracted by the increase in wear rate caused by low elongation. Thus, the wear rate of the CRA Ti-2524 alloy is higher than that of ST Ti-2524 *** for the ST Ti–6Al–4V alloy, no lubricative Nb2O5 forms on its worn surface owing to the absence of Nb. In addition, the ST Ti–6Al–4V alloy exhibits an elongation roughly similar to the CRA Ti-2524 specimen. Therefore,the ST Ti–6Al–4V specimen possesses a higher wear rate than the CRA Ti-2524 specimen.

关键词： Titanium alloy Wear response Low elastic modulus H

Rare earth texture analysis of rectangular extruded Mg alloys and a comparison of different alloying adding ways

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Rare Metals 2016年第11期35卷 850-857页

作者： xiu-li hou Yi-Xuan Zhai Peng Zhang Shun Guo Zhi-Zhong Yuan Qing-Feng Guan School of Materials Science and Engineering Jiangsu University

The microstructures and textures of four rectangular extruded Mg alloys, Mg-3Gd, Mg-3Nd, Mg-1Gd-1Nd and Mg-1.5Gd-1.5Nd（all in wt%） were investigated by using optical microscopy（OM）, X-ray diffraction（XRD） and electron backscatter diffraction（EBSD）. The results demonstrate that the extruded alloys all reveal fully recrystallized microstructure and weak non-basal *** textures of the four extruded alloys, it is shown that the basal planes of majority grains tilt away from the sheet plane normal toward the extrusion direction. Compared with two binary alloys, the ternary alloys possess weaker texture strengths. Through orientation distribution function analysis, two types of rare earth textures, {0113} 〈0223〉and {1215} 〈1213〉, were found in the extruded *** component {1215} 〈1213〉 is relatively weak, but it plays a critical role in the low texture intensities of two ternary alloys. A pairing effect of Gd and Nd elements has an influence on the texture modification. Additionally,there is a difference in the sensitivities of experimental parameters between the microstructure and texture.

关键词： Mg alloy Texture Rare earth elements Orientation distribution function

ZYGOTE-ARREST 3 that encodes the tRNA ligase is essential for zygote division in Arabidopsis

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Journal of Integrative Plant Biology 2017年第9期59卷 680-692页

作者： Ke-Jin Yang Lei Guo xiu-li hou Hua-Qin Gong Chun-Ming liu Key Laboratory of Plant Molecular Physiology Institute of BotanyChinese Academy of SciencesBeijing 100093China University of Chinese Academy of Sciences Beijing 100049China School of life Science and Technology Nanyang Normal UniversityNanyang 473061China Institute of Crop Sciences Chinese Academy of Agricultural SciencesBeijing 100081China

In sexual organisms, division of the zygote initiates a new life cycle. Although several genes involved in zygote division are known in plants, how the zygote is activated to start embryogenesis has remained elusive. Here, we showed that a mutation in ZYGOTE-ARREST 3 （ZYG3） in Arabidopsis led to a tight zygote-lethal phenotype. Map-based cloning revealed that ZYG3 encodes the transfer RNA （tRNA） ligase AtRNL, which is a single-copy gene in the Arabidopsis genome. Expression analyses showed that AtRNL is expressed throughout zygotic embryogenesis, and in meristematic tissues. Using pAtRNL：：cAtRNL-sYFP- complemented zyg3/zyg3 plants, we showed that AtRNL is localized exclusively in the cytoplasm, suggesting that tRNA splicing occurs primarily in the cytoplasm. Analyses using partially rescued embryos showed that mutation in AtRNL compromised splicing of intron-containing tRNA. Mutations of two tRNA endonuclease genes, SEN1 and SEN2, also led to a zygote-lethal phenotype. These results together suggest that tRNA splicing is critical for initiating zygote division in Arabidopsis.

关键词： NL ZYGOTE-ARREST 3 that encodes the tRNA ligase is essential for zygote division in Arabidopsis GUS Figure

Blue photoluminescence from nanocrystalline porous silicon structure fabricated by high-current pulsed electron beam irradiation

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Chinese Science Bulletin 2014年第34期59卷 4758-4762页

作者： Peng L Xiao-Tong Wang Sheng-Zhi Yang Yan li xiu-li hou Qing-Feng Guan School of Materials Science and Engineering Jiangsu University

N-type Si(111) wafers have been processed by high-current pulsed electron beam(HCPEB) treatment with an increasing number of irradiation(1, 10 and 20pulses). The results of this work show that a highly porous nanostructure was formed after irradiation. Moreover, the high-density Si nanocrystals(Si-ncs) about 3 nm were distributed on the surface of Si wafers and exhibited3.02 e V Photoluminescence(PL) emission in blue *** PL intensity increases with the increase in the Si-ncs' density in accordance with the quantum confinement model, which can be ascribed to the different pulse time of HCPEB treatment. The possible formation mechanisms of micropores and Si-ncs are discussed.

关键词：纳米多孔硅电流脉冲纳米结构光致发光电子束辐照 Si(111) HCPEB 制作

Plasmonic tandem heterojunctions enable high-efficiency charge transfer for broad spectrum photocatalytic hydrogen production

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Journal of Energy Chemistry 2025年第1期100卷 710-720页

作者： Wenxuan Chen xiu-Qing Qiao Guo Hui Bojing Sun Dongfang hou Meidi Wang Xueqian Wu Tao Wu Dong-Sheng li College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Hubei Three Gorges Laboratory College of Chemistry and Materials Science and Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry Jinan University

Rational engineering of semiconductor photocatalysts for efficient hydrogen production is of great significance but still challenging,primarily due to the limitations in charge transfer ***,a fascinating plasmonic tandem heterojunction with the hc-CdS/Mo2C@C heterostructure is aimfully prepared for effectively promoting the charge separation kinetics of the CdS photocatalyst via the synergistic strategy of phase junction,Schottky junction,and photothermal *** difference in atomic configuration between cubic-CdS （c-CdS） and hexagonal-CdS （h-CdS） leads to effective charge separation through a typical Ⅱ charge transfer mechanism,and plasmonic Schottky junction further extracts the electrons in the hc-CdS phase junction to realize gradient charge ***,the photothermal effect of Mo2C@C helps to expand the light absorption,accelerate charge transfer kinetics,and reduce the hydrogen evolution energy *** carbon layer provides a fast channel for charge transfer and protects the photocatalyst from *** a result,the optimized hc-CMC photocatalyst exhibits a significantly high photocatalytic H2production activity of 28.63 mmol/g/h and apparent quantum efficiency of 61.8%,surpassing most of the reported *** study provides a feasible strategy to enhance the charge transfer kinetics and photocatalytic activity of CdS by constructing plasmonic tandem heterogeneous junctions.

关键词： Heterojunctions LSPR Photocatalyst Phase junction Schottky junction Photothermal effect

Imiquimod-induced localized vitiligo-like hypopigmentation

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International Journal of Dermatology and Venereology 2018年第3期1卷 189-192页

作者： Yang-Yang Ma Ping Wang xiu-li hou Department of Dermatology the Third People's Hospital of Hangzhou Affiliated to Zhejiang Chinese Medical UniversityHangzhouGuangdong 310009China Department of Dermatology Dezhou People s HospitalDezhouShandong 253011China

Introduction Imiquimod is an immune response modifier,currently the 5% imiquimod cream is approved for treatment of extemal genital,perianal warts,superficial basal cell carcinoma,and actinic *** anti-viral activity and anti-tumoral activity seem to be dependent on focal activation of the immune system with induction,synthesis,and release of cytokines,such as interferonalpha,interleukin-12 and tumor necrosis factor alpha[1-2].

关键词： hypopigmentation Introduction vitiligo-like

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Interfacial Zn2+-solvation regulator towards reversible and stable Zn anode

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Journal of Energy Chemistry 2025年第1期100卷 684-692页

作者： Miao Zhou Xiongbin Luo Hang li Shan Guo Zhuang Tong Xiaotao Zhou Xu li Zhaohui hou Shuquan liang Guozhao Fang College of Mechanical Engineering Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials Hunan Institute of Science and Technology School of Materials Science and Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province Central South University College of Materials and Metallurgy Guizhou University National Energy Metal Resources and New Materials Key Laboratory Central South University

Aqueous zinc-ion batteries （AZIBs） are fundamentally challenged by the instability of the electrode/electrolyte interface,predominantly due to irreversible zinc （Zn） deposition and hydrogen ***,the intricate mechanisms behind the electrochemical discrepancies induced by interfacial Zn2+-solvation and deposition behavior demand comprehensive *** molecules endowed with special functional groups （such as hydroxyl,carboxyl,etc.） have the potential to significantly optimize the solvation structure of Zn2+and regulate the interfacial electric double layer （EDL）.By increasing nucleation overpotential and decreasing interfacial free energy,these functional groups facilitate a lower critical nucleation radius,thereby forming an asymptotic nucleation model to promote uniform Zn ***,this study presents a pioneering approach by introducing trace amounts of n-butanol as solvation regulators to engineer the homogenized Zn （H-Zn） anode with a uniform and dense *** interfacial reaction and structure evolution are explored by in/ex-situ experimental techniques,indicating that the H-Zn anode exhibits dendrite-free growth,no by-products,and weak hydrogen evolution,in sharp contrast to the bare ***,the H-Zn anode achieves a remarkable Zn utilization rate of approximately 20% and simultaneously sustains a prolonged cycle life exceeding 500 ***,the H-Zn//NH4V4O10（NVO） full battery showcases exceptional cycle stability,retaining 95.04%capacity retention after 400 cycles at a large current density of 5 A *** study enlightens solvation-regulated additives to develop Zn anode with superior utilization efficiency and extended operational lifespan.

关键词： Aqueous zinc-ion batteries Interfacial reaction Asymptotic nucleation model Reversible and stable Zn anode

Low-temperature chlorination roasting technology for the simultaneous recovery of valuable metals from spent liCoO_(2)cathode material

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 80-91页

作者： Junjie Shi Changle hou Jingjing Dong Dong Chen Jianzhong li Key Laboratory for Ecological Metallurgy of Multimetallic Mineral(Ministry of Education) Northeastern UniversityShenyang 110819China School of Metallurgy Northeastern UniversityShenyang 110819China

With the continuous increase in the disposal volume of spent lithium-ion batteries(liBs),properly recycling spent liBs has become essential for the advancement of the circular *** study presents a systematic analysis of the chlorination roasting kinetics and proposes a new two-step chlorination roasting process that integrates thermodynamics for the recycling of liB cathode *** activation energy for the chloride reaction was 88.41 kJ/mol according to thermogravimetric analysis–derivative thermogravimetry data obtained by using model-free,model-fitting,and Z(α)function(αis conversion rate).Results indicated that the reaction was dominated by the first-order(F1)model when the conversion rate was less than or equal to 0.5 and shifted to the second-order(F2)model when the conversion rate exceeded *** conditions were determined by thoroughly investigating the effects of roasting temperature,roasting time,and the mass ratio of NH_(4)Cl to liCoO_(2).Under the optimal conditions,namely 400℃,20 min,and NH_(4)Cl/liCoO_(2)mass ratio of 3:1,the leaching efficiency of li and Co reached 99.43% and 99.05%,*** of the roasted products revealed that valuable metals in liCoO_(2)transformed into CoCl_(2) and ***,the reaction mechanism was elucidated,providing insights for the establishment of a novel low-temperature chlorination roasting technology based on a crystal structure *** technology can guide the development of liB recycling processes with low energy consumption,low secondary pollution,high recovery efficiency,and high added value.

关键词： spent lithium-ion battery thermodynamics chlorination roasting kinetics circular economy

Hypidone hydrochloride(YL-0919)ameliorates functional deficits after traumatic brain injury in mice by activating the sigma-1 receptor for antioxidation

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Neural Regeneration Research 2025年第8期20卷 2325-2336页

作者： Yafan Bai Hui Ma Yue Zhang Jinfeng li Xiaojuan hou Yixin Yang Guyan Wang Yunfeng li Department of Anesthesiology Beijing Tongren HospitalCapital Medical UniversityBeijingChina Beijing Institute of Basic Medical Sciences BeijingChina Hebei North University ZhangjiakouHebei ProvinceChina Beijing Institute of Pharmacology and Toxicology State Key Laboratory of Toxicology and Medical CountermeasuresBeijing Key Laboratory of NeuropsychopharmacologyBeijingChina

Traumatic brain injury involves complex pathophysiological mechanisms,among which oxidative stress significantly contributes to the occurrence of secondary *** this study,we evaluated hypidone hydrochloride(YL-0919),a self-developed antidepressant with selective sigma-1 receptor agonist properties,and its associated mechanisms and targets in traumatic brain *** experiments to assess functional deficits were followed by assessment of neuronal damage through histological analyses and examination of blood-brain barrier permeability and brain ***,we investigated the antioxidative effects of YL-0919 by assessing the levels of traditional markers of oxidative stress in vivo in mice and in vitro in HT22 ***,the targeted action of YL-0919 was verified by employing a sigma-1 receptor antagonist(BD-1047).Our findings demonstrated that YL-0919 markedly improved deficits in motor function and spatial cognition on day 3 post traumatic brain injury,while also decreasing neuronal mortality and reversing blood-brain barrier disruption and brain ***,YL-0919 effectively combated oxidative stress both in vivo and in *** protective effects of YL-0919 were partially inhibited by *** results indicated that YL-0919 relieved impairments in motor and spatial cognition by restraining oxidative stress,a neuroprotective effect that was partially reversed by the sigma-1 receptor antagonist ***-0919 may have potential as a new treatment for traumatic brain injury.

关键词： antidepressant drug blood-brain barrier cognitive function hypidone hydrochloride(YL-0919) neurological function nuclear factor-erythroid 2 related factor 2 oxidative stress sigma-1 receptor superoxide dismutase traumatic brain injury